Destruction of n-hexane from the air stream by pulsed discharge plasma: Modelling and key process parameters optimization by CCD-RSM

Abstract

In this study, a Dielectric-Barrier Discharge (DBD) plasma reactor was used for the degradation of n-hexane from an air stream. a Central Composite Design (CCD) based Response Surface Methodology (RSM), (CCD-RSM) was utilized to explore the effects of experimental parameters including discharge voltage, initial concentration, gas flow rate, relative humidity and their interactions on the reactor performance. The proposed optimization model showed a satisfactory correlation between the predicted and actual results. According to the results, discharge voltage was the most significant parameter affecting the removal efficiency, CO2 selectivity and the level of O3 and NOx formation, whereas energy yield was mainly influenced by gas flow rate and initial concentration. At optimized conditions (discharge voltage of 8.5 kV, inlet concentration of 94.3 ppm, relative humidity of 55 % and gas flow rate of 733.16 ml/min with combined desirability of 0.921), removal efficiency of 92.57 %, CO2 selectivity of 58.87 %, energy efficiency of 0.25 g/kWh, O3 formation of 140.88 mg/m3 and NOx formation of 122.46 ppm were obtained. Water vapour significantly increased the removal efficiency and CO2 selectivity as well as reduced O3 and NOx. The results revealed that the CCD-RSM provided the optimum process parameters for the Non-Thermal Plasma (NTP) system.