Magnetic hyperthermia has a specific limitation in treating localized and relatively accessible malignant tumors regardless of its promising therapeutic regime. In this present work, Tb doped Fe3O4 magnetic nanoparticles (MNPs) prepared via coprecipitation root and confirmed the structural conformation and phase purity by XRD, FTIR, TEM, and SEM analysis. TGA analysis was carried out for thermal stabilization and to verify the formation of a stable phase. The occupancy of Tb ions at the octahedral sites and cationic distribution can be calculated from Rietveld refinement analysis. The relaxation mechanism, dipolar- dipolar interactions among the particles, and randomly directed magnetic anisotropy axes were investigated by ESR spectroscopy. The magnetic results enumerate that increasing Tb doping concentration leads to increased saturation magnetization and decreased coercivity and retentivity. The self-heating properties of the doped nanoparticles were characterized by measuring specific absorption rate (SAR). The improved saturation magnetization and enriched SAR value enable the doped MNPs for magnetic hyperthermia application with excellent efficacy.
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