UV Pulses Research Articles

Heteroepitaxy of ε‐Ga2O3 thin film for artificial synaptic device

AbstractEmerging‐wide bandgap semiconductor Ga2O3 shows distinct characteristics for optoelectronic applications and a stable crystal phase of Ga2O3 is highly desired. Herein, we have first reported a metal‐semiconductor‐metal structure photonic synaptic device based on the ε‐Ga2O3 thin film. The ε‐Ga2O3 epilayer is grown on the c‐sapphire with a low temperature nucleation layer, which presents a crystal orientation relationship with the c‐sapphire (ε‐Ga2O3 <010> // c‐sapphire <1–100> and ε‐Ga2O3 <001> // c‐sapphire <0001>). The ε‐Ga2O3 photonic device was stimulated by UV pulses at different pulse widths, pulse intervals, and reading voltages. Under the UV pulse excitation, the photonic device exhibits primary synaptic functions including excitatory postsynaptic current, short term memory, pair pulse facilitation, long term memory, and STM‐to‐LTM conversion. In addition, stronger and repeated stimuli can naturally contribute to the higher learning capability, thus prolonging the memory time.

Influence of defocusing of UV pulse laser radiation on LIG synthesis on Polyetheretherketone

Laser-induced graphene (LIG) technology, a technique for preparing three-dimensional porous graphene by laser direct writing on carbon precursors under ambient condition, has been widely used due to its low cost and high efficiency. However, there is still a lack of research on the influence of the defocusing on LIG synthesis. In this paper, LIG is prepared by UV laser on Polyetheretherketone (PEEK) film, and a finite element simulation of this process is established to infer the temperature field. The influence of the defocusing on the structure, morphology, specific surface area SSA, and electrical properties of PEEK-LIG is investigated while maintaining the same energy radiated per unit area. The results show that the defocusing changes the structure and morphology of PEEK-LIG by affecting the temperature field distribution in both the surface and thickness directions, which affects the properties of LIG, where the surface area ratio Sdr does not depend on the defocusing amount monotonically. As the UV laser nears the beam waist at the threshold of LIG formation, Sdr has its maximum value and improves its electrical conductivity.

Direct temporal characterization of sub-3-fs deep UV pulses generated by resonant dispersive wave emission: erratum

An erratum is presented to include the correct upper horizontal axis in Fig. 3 in our published manuscript [“Direct temporal characterization of sub-3-fs deep UV pulses generated by resonant dispersive wave emission” Opt. Express 31, 26854 (2023).10.1364/OE.494879

Improving the beam pointing and intensity stability of the third harmonic generated in air filament

Third harmonic generation (THG) by laser filamentation in gases is immune to the damage threshold and phase matching limit for UV and EUV pulse generation. Here, we report on the jitter measurements of the beam pointing and the intensity of the THG through filamentation with different repetition rates in air. The THG jitters are stronger at the high repetition rates (1 kHz) filaments. A technique of applying an external DC electric field on the filament was found to suppress the jitters. The beam pointing and intensity jitters of the 1 kHz THG from laser filament in air were reduced by about 1 fold with the extreme external electric field electric field applied on the filament. This technique provides a way to generate a stable, high repetition rate UV and EUV sources.

22.56% total area efficiency of n-TOPCon solar cell with screen-printed Al paste

Screen-printing Ag paste on the rear side of the Tunnel Oxide Passivated Contact solar cells (TOPCon) is still the mainstream method to form electrodes. However, the high price of precious metals increases the cost of TOPCon cells. Al is a cheap and high-performance conductor, and its work function is compatible with the rear side of TOPCon cells. In this study, we used a UV pulse laser (355 nm, 10 ps) to ablate the rear side SiNx passivation layer of TOPCon cells and then printed Al paste with different weight percentages of silicon (Si-wt.%) on the phosphorus-doped polycrystalline silicon (n+-poly-Si) layer to reduce the cost. We investigated the damage mechanism of laser on SiOx/n+-poly-Si/SiNx passivation structure and the contact mechanism between Al paste and n+-poly-Si layer. The results show that the Voc of SiOx/n+-poly-Si/SiNx passivation structure reduced about 6–7 mV when the laser energy density was 0.431 J/cm2. We got the best electrical performance of TOPCon cells printed with Al paste (25 wt%-29 wt% silicon). The open-circuit voltage (Voc) and the conversion efficiency (Eff), have reached 663.60 mV and 22.56 % respectively. Although the efficiency was 9.40 % relative lower than that of TOPCon cells printed with Ag paste, but the cost of Al paste only accounted for 10 % of Ag paste. In the future, the highest Eff of TOPCon solar cells printed with Al paste on the rear side are expected to reach the commercial TOPCon based on Ag paste, which applies laser doping selective emitter technology (SE) and bifacial poly-Si passivation structure.

Generation of sub-10-fs deep and extreme ultraviolet pulses for time-resolved photoemission spectroscopy.

We present a light source capable of generating sub-10-fs deep UV (DUV) and extreme UV (EUV) pulses for use in time-resolved photoemission spectroscopy. The fundamental output of a Ti:sapphire laser was compressed using the multi-plate method and mixed with the uncompressed second harmonic in a filamentation four-wave mixing process to generate sub-10-fs DUV pulses. Sub-10-fs EUV pulses were generated via high-order harmonic generation driven by the second harmonic pulses that were compressed using Ar gas and chirped mirrors. The minimum cross correlation time between 267 and 57 nm (corresponding to 21.7 eV) was measured to be 10.6 ± 0.4 fs.

Exciton migration in two-dimensional materials

Excitons play an essential role in the optical response of two-dimensional materials. These are bound states showing up in the band gaps of many-body systems and are conceived as quasiparticles formed by an electron and a hole. By performing real-time simulations in hBN, we show that an ultrashort (few-fs) UV pulse can produce a coherent superposition of excitonic states that induces an oscillatory motion of electrons and holes between different valleys in reciprocal space, leading to a sizeable exciton migration in real space. We also show that an ultrafast spectroscopy scheme based on the absorption of an attosecond pulse in combination with the UV pulse can be used to read out the laser-induced coherences, hence to extract the characteristic time for exciton migration. This work opens the door towards ultrafast electronics and valleytronics adding time as a control knob and exploiting electron coherence at the early times of excitation.

Application of deep UV resonance Raman spectroscopy to column liquid chromatography: Development of a low-flow method for the identification of active pharmaceutical ingredients

In this study, deep UV resonance Raman spectroscopy (DUV-RRS) was coupled with high performance liquid chromatography (HPLC) to be applied in the field of pharmaceutical analysis. Naproxen, Metformin and Epirubicin were employed as active pharmaceutical ingredients (APIs) covering different areas of the pharmacological spectrum. Raman signals were successfully generated and attributed to the test substances, even in the presence of the dominant solvent bands of the mobile phase. To increase sensitivity, a low-flow method was developed to extend the exposure time of the sample. This approach enabled the use of a deep UV pulse laser with a low average power of 0.5 mW. Compared to previous studies, where energy-intensive argon ion lasers were commonly used, we were able to achieve similar detection limits with our setup. Using affordable lasers with low operating costs may facilitate the transfer of the results of this study into practical applications.

Site-Specific Photochemistry along a Protonated Peptide Scaffold.

We present a detailed study of the time-dependent photophysics and photochemistry of a known conformation of the two protonated pentapeptides Leu-enkephalin (Tyrosine-Glycine-Glycine-Phenylalanine-Leucine, YGGFL) and its chromophore-swapped analogue FGGYL, carried out under cryo-cooled conditions in the gas phase. Using ultraviolet-infrared (UV-IR) double resonance, we record excited state IR spectra as a function of time delay between UV and IR pulses. We identify unique Tyr OH stretch transitions due to the S1 state and the vibrationally excited triplet state(s) formed by intersystem crossing, Tn(v). Photofragment mass spectra are recorded out of the S1 origin and following UV-IR double resonance. Several competing site-specific fragmentation pathways are discovered involving peptide backbone cleavage, Tyr side chain loss, and N-terminal NH3 loss mediated by electron transfer. In YGGFL, IR excitation in the S1 state promotes electron transfer (ET) from the aromatic ring to the N-terminal R-NH3+ group leading to loss of neutral NH3. This product channel is missing in FGGYL due to the larger distance for ET from Y(4) to NH3+. Selective loss of the Tyr side chain occurs out of an excited state process following UV excitation and is further enhanced by IR excitation in S1 and Tn(v) states of both YGGFL and FGGYL. Finally, IR excitation in the S1 or Tn(v) states fragments the peptide backbone exclusively at amide(4), producing the b4 cation. We postulate that this selective fragmentation results from intersystem crossing to produce vibrationally excited triplets with enough energy to launch the proton along a proton conduit present in the known starting structure.

KrF laser-driven shock tube: Realization and first experiments

We report on the first implementation of a miniature laser-driven shock tube (LDST) of 5 × 5 mm cross section and 50-mm length for generating and studying strong shock waves (SW) and hypersonic gas flows with M > 10. Operation of the LDST is based on the acceleration of a thin CH-film by ablative plasma pressure produced when the film is irradiated by high-energy UV pulse of the GARPUN KrF laser (100 J & 100-ns). The film serves as a piston that pushes a SW in the gas filling the LDST. An optical system based on a multi-element prism raster provides focusing of KrF laser beam into 7 × 7 mm square spot with 100 J/cm2 energy fluence (1 GW/cm2 intensity) with inhomogeneity ∼3 % across the LDST aperture. It is expected that the LDST with KrF laser driver can be an effective tool for studying hydrodynamic phenomena, such as hydrodynamic instabilities and transition to a turbulence, hypersonic gas flow around bodies, reflection and cumulation of strong SW.

Ion imaging of spatially inhomogeneous nanoplasmas in NaCl particles.

Studying photoemission from free, unsupported aerosol particles is a powerful method for gaining insight into light-matter interactions at the nanoscale. We used single-shot velocity map imaging to experimentally measure kinetic energy and angular distributions of ions emitted following interaction of sub-micrometer NaCl particles with femtosecond pulses of near infrared (NIR, 800 nm) and ultraviolet (UV, 266 nm) light. We combined this with time-dependent simulations of light propagation through the particles and a rate equation approach to computationally address the origin of the observed ion emission. For both NIR and UV pulses, ion emission is caused by the formation of an under-dense nanoplasma with similar densities, although using an order of magnitude weaker UV intensities. Such conditions result in remarkably similar ion fragments with similar kinetic energies, and no obvious influence of the plasma formation mechanism (photoionization or collisional ionization). Our data suggests that Coulomb explosion does not play a significant role for ion emission, and we discuss alternative mechanisms that can lead to material ablation from under-dense nanoplasma. Finally, we show how finite size effects play an important role in photoemission through generation of spatially inhomogeneous nanoplasmas, which result in asymmetric ion emission that depends on particle size and laser wavelength. By utilizing the single-particle information available from our experiments, we show how finite size effects and inhomogeneous nanoplasma formation can be exploited to retrieve the size and orientation of individual submicrometer aerosol particles.

Nonlinear post-compression of a hybrid vortex mode in a gas-filled capillary.

We demonstrate nonlinear temporal compression of a vortex beam by propagation in a gas-filled capillary. Starting from an ytterbium-based laser delivering 700 μJ 640 fs pulses at a 100 kHz repetition rate, the vortex beam is generated using a spiral phase plate and coupled to a capillary where it excites a set of four modes that have an overlap integral of 97% with a Laguerre-Gauss LG10 mode. Nonlinear propagation of this hybrid, orbital angular momentum (OAM)-carrying mode results in temporal compression down to 74 fs at the output. Beam and pulse characterizations are carried out to determine the spatial profile and temporal duration of compressed pulses. This result in multimode nonlinear optics paves the way towards the generation of OAM-carrying few-cycle pulses, isolated attosecond XUV pulses, and tunable UV pulses through resonant dispersive wave emission.

Electro-optic solution to overcome the transient regime of a cavity dumped UV laser source?

Laser marking is one of the main industrial applications of lasers. To mark many materials or to obtain patterns of small dimensions, triggered pulsed solid laser sources are increasingly used emitting in the fundamental in the infrared and to which two nonlinear (NL) stages are added to obtain an emission in the UV. The conversion efficiency as well as that of the marking then depends mainly on the peak power of the UV pulses generated. One of the solutions for obtaining a higher peak power is to reduce the duration of the laser pulses. To do this, it is possible to change the architecture of the laser cavity by switching from a Q-Switch operating mode (QS) to a cavity dumped mode (CD). With this architecture it is thus possible to reduce the duration of the pulses by an order of magnitude. This peak power gain is unfortunately achieved at the cost of a very long transient regime, up to a few tens of milliseconds, compared to the classic QS which generally only occurs for the first laser pulse. Unfortunately, laser marking is by nature based on chopped operation for the laser, which corresponds to working permanently in a transient state. Marking with a CD architecture laser is then often full of defects and therefore unacceptable in terms of quality. After a study of the problem specific to the use of a UV source with CD architecture in the context of marking, we propose an original solution to dissociate the chopped regime, specific to marking, from the transient regime of the laser. This solution is based on the use of an RTP (Rubidium Titanyle Phosphate RTiOPO4) electro-optical crystal placed between the laser output and the NL stages. This crystal is driven like a half-wave plate by high voltage square pulses of a duration corresponding to the duration of the marking laser pulse trains. This thus makes it possible to obtain laser operation in a stabilized regime, therefore outside the transient regime, and simultaneously chopped operation characteristic of laser marking. The new operating mode obtained is characterized in detail with the new marking performances which prove to be optimal and compatible with the requirements of a quality marking. In addition to making the CD architecture compatible with laser marking, this solution also makes it possible to adjust the average power, and therefore the energy of the laser pulses to adapt it according to the materials and this without changing the thermal behavior of the laser. Last advantage, by adjusting the extinction voltage applied to the RTP outside the cavity, it is also possible to keep a few milliwatts of the marking laser beam as the aiming beam, with the certainty of perfect alignment with the full power beam.

Ultrafast laser pulse stretching via dispersive materials including high dispersion orders

Ultrafast laser systems typically employ complicated systems for varying their pulse length (duration) such as an ultrafast IR mode-locked laser used at the Schlesinger Compact Accelerator Center at Ariel University. The laser is an Astrella manufactured by Coherent generating an 800nm pulse. The pulse duration can be varied from 10 ps to 35 fs using a remote-controlled grating-based compressor. In order to measure the time duration of the pulse, an automated compact autocorrelator was designed and developed. The laser is mainly used to extract electrons from a photo-cathode using dual BBO frequency tripling system, providing a UV (266nm) ultra-short pulse. The electrons are formed into a beam, which is used to generate a THz FEL. Using an fs-level UV pulse, the extracted electron beam is unstable, resulting in high space-charge effects, high emittance values, and lowered radiation power dramatically. For this reason, we aim to stretch the UV pulse to a ps level. We study here an applicative method that uses dispersive materials. This method is convenient, compact, and can be easily installed. However, ultrafast lasers can suffer from high dispersion orders. Therefore, we study the contribution of the third and fourth orders of dispersion using analytical and numerical methods. Furthermore, our analysis takes into account the self-phase modulation effect when intense lasers are used. An experimental measurement is executed to confirm our numerical results, and a comparison between the experimental and simulation results is presented.

Acetylacetone Photolysis at 280 nm Studied by Velocity-Map Ion Imaging.

The photolysis of acetylacetone (AcAc) has been studied using velocity-map ion imaging with pulsed nanosecond lasers. The enolone tautomer of AcAc (CH3C(O)CH═C(OH)CH3) was excited in the strong UV absorption band by UV pulses at 280 nm, preparing the S2(ππ*) state, and products were probed after a short time delay by single-photon VUV ionization at 118.2 nm. Two-color UV + VUV time-of-flight mass spectra show enhancement of fragments at m/z = 15, 42, 43, 58, and 85 at the lowest UV pulse energies and depletion of the parent ion at m/z = 100. Ion images of the five major fragments are all isotropic, indicating dissociation lifetimes that are long on the timescale of molecular rotation but shorter than the laser pulse duration (<6 ns). The m/z = 15 and 85 fragments have identical momentum distributions with moderate translational energy release, suggesting that they are formed as a neutral product pair and likely via a Norrish type I dissociation of the enolone to form CH3 + C(O)CH═C(OH)CH3 over a barrier on a triplet surface. The m/z = 43 fragment may be tentatively assigned to the alternative Norrish type I pathway that produces CH3CO + CH2C(O)CH3 on S0 following phototautomerization to the diketone, although alternative mechanisms involving dissociative ionization of a larger primary photoproduct cannot be conclusively ruled out. The m/z = 42 and 58 fragments are not momentum-matched and consequently are not formed as a neutral pair via a unimolecular dissociation pathway on S0. They also likely originate from the dissociative ionization of primary photofragments. RRKM calculations suggest that unimolecular dissociation pathways that lead to molecular products on S0 are generally slow, implying an upper-limit lifetime of <46 ns after excitation at 280 nm. Time-dependent measurements suggest that the observed photofragments likely do not arise from dissociative ionization of energized AcAc S0*.

Direct temporal characterization of sub-3-fs deep UV pulses generated by resonant dispersive wave emission.

We report on the complete temporal characterization of ultrashort pulses, generated by resonant dispersive wave emission in gas-filled hollow-capillary fibers, with energy in the microjoule range and continuously tunable from the deep-ultraviolet to the ultraviolet. Temporal characterization of such ultrabroad pulses, particularly challenging in this spectral region, was performed using an all-in-vacuum setup for self-diffraction frequency resolved optical gating (SD-FROG). Sub-3-fs pulses were measured, tunable from 250 nm to 350 nm, with a minimum pulse duration of 2.4 ± 0.1 fs.

Roll-to-roll gravure printed large-area flexible carbon nanotube synaptic photogating transistor arrays for image recognitions

The development of novel large-area flexible optoelectronic synaptic devices is of great interest for visual neuromorphic computing. In this paper, we have successfully manufactured 33 × 34 flexible carbon nanotube synaptic photogating transistor arrays via the roll-to-roll gravure printing technology using the mixture of photosensitive rhodamine 6G and poly(vinylidene fluoride-co-hexa-fluoropropylene) as the composite dielectric layer. The resulting thin-film transistor devices exhibit excellent electrical properties with high Ion/Ioff (>105), the maximum carrier mobility (10.71 cm2V−1s−1) and low operating voltage (−1.5 V∼ 0.5 V), and excellent optoelectronic synaptic properties, which are capable of performing not only the excitatory postsynaptic current and paired pulse facilitation but also complex biological synaptic functions such as optical writing and electrical erasure, dynamic learning and forgetting processes, and Pavlov's dog experiment. Significantly, the ultralow energy consumption per light spike event as low as 0.03 fJ can be achieved under the pulse UV light illumination. Moreover, according to the trend that the LTP/LTD curve conforms to the concave function, we successfully embed the specific update rules of our synaptic devices into the generative adversarial network (GAN) that can generate high-quality (7680 × 4096 pixels) images, which is impossible for the human eye to distinguish the difference between the original labels and real labels.

Reversible Photomodulation of Two-Dimensional Electron Gas in LaAlO3/SrTiO3 Heterostructures.

Long-lived photoinduced conductance changes in LaAlO3/SrTiO3 (LAO/STO) heterostructures enable their use in optoelectronic memory applications. However, it remains challenging to quench the persistent photoconductivity (PPC) instantly and reproducibly, which limits the reversible optoelectronic switching. Herein, we demonstrate a reversible photomodulation of two-dimensional electron gas (2DEG) in LAO/STO heterostructures with high reproducibility. By irradiating UV pulses, the 2DEG at the LAO/STO interface is gradually transformed to the PPC state. Notably, the PPC can be completely removed by water treatment when two key requirements are met: (1) the moderate oxygen deficiency in STO and (2) the minimal band edge fluctuation at the interface. Through our X-ray photoelectron spectroscopy and electrical noise analysis, we reveal that the reproducible change in the conductivity of 2DEG is directly attributed to the surface-driven electron relaxation in the STO. Our results provide a stepping-stone toward developing optically tunable memristive devices based on oxide 2DEG systems.

High precision control of laser energy for laser-matter interaction studies.

Precise, highly reproducible control of the laser energy is required for high confidence laser-matter interaction research such as in dynamic compression science and high energy density physics. The energy must be adjustable without affecting the pulse shape (time varying intensity) or beam smoothness. We have developed a convenient two-stage energy tuning method for a nominal 100J, 351nm (UV) laser. The energy is adjusted in 10J (10%) increments by operating the laser at full energy and inserting a beam splitter in the laser output. As the splitter is located after the final frequency tripling optics, the UV pulse shape is unchanged. The energy is varied by substituting a splitter of different reflectivity. For finer 3J (3%) increments, the infrared pulse is attenuated inside the laser before the final amplifier. This requires modest tuning to preserve the pulse shape. The demonstrated variation in shot-to-shot reproducibility is less than +/-2.5J (5% of the full energy), irrespective of the laser output energy. These approaches can be adapted to most ∼100J class lasers. We describe these techniques and show two examples where they have elucidated the underlying physics in laser shock compression experiments. One used only the beam splitters to establish the pressure for melting in iron. The other combined both techniques to finely increment the peak stress (∼2GPa steps) in germanium to precisely determine the onset and completion of melting-including the melting kinetics. These unambiguous results would not be possible without the developments described here.

Estimation of elapsed time after an unnoticed radiation exposure using the weathering resistant radiophotoluminescence glass (SAPANS)

A method using a newly developed radiophotoluminescence (RPL) glass for estimating the elapsed time after an unnoticed radiation exposure was proposed and tested. Cuboid-shaped samples of a silver-activated glass composed of P2O5–Al2O3–Na2O–Ag2O, named “SAPANS”, were irradiated with 137Cs-source γ-rays at five dose levels (1.0, 2.0, 3.5, 5.5 and 8.5 Gy) and the time changes of the RPL intensities emitted from the samples stimulated by the UV pulses were observed for up to 97 days after irradiation. It was found that the RPL intensities continuously increased with the same build-up patterns keeping linear dose responses at all dose levels, and reached to about 86% of those after preheating at 160 °C for 1 h at 97 days after irradiation. According to this finding, it was proposed to use the SAPANS for estimation of the elapsed time after an accidental high-dose exposure as well as for the determination of radiation doses. The practicality of this approach was examined in a blinded experiment wherein five sets of the SAPANS samples were irradiated with unknown γ-ray doses at unknown timings in the period of 53 days. As results, the errors of estimated elapsed times were −25% for 4.5 h, 18% for 3.3 days, 70% for 10 days, 30% for 30 days and 0% for 45 days after irradiation. These findings indicate that the proposed method could be applied to retrospective dose assessment even when a few months have passed after an unnoticed radiation exposure.