Recent years have witnessed energy crises in various regions and the utilization of new energy is crucial. Dye-sensitized solar cells (DSSCs) are the third generation of photovoltaic cells that are expected to be more cost-effective than other types of solar cells. In this work, we report the synthesis of 1T-2H-MoS2/honeycomb shaped carbon (HSC) heterojunction composite counter electrodes for DSSCs via adding porous carbon in the facile hydrothermal method. The effects of HSC on the morphology, structure, electrochemical and photoelectric conversion properties of the 1T-2H-MoS2/HSC composites were investigated systematically. Both the results of electrochemical and photoelectric measurement suggest the excellent performance of the reduction of I3- and the regeneration of dye. The whole cell assembled with the MoS2/HSC-5.0 counter electrode achieved a short current density 22.24 mA∙cm−2 and a power conversion efficiency (PCE) of 8.42 %, which is significantly higher than that of the pure MoS2 electrode (5.89 %) and Platinum electrode (6.76 %), implying the MoS2/HSC-5.0 composite is a promising candidate for counter electrodes catalyst of DSSCs.