Ultracold Mixtures Research Articles

Heteronuclear Rydberg molecules

We report the creation of heteronuclear ultralong-range Rydberg-molecule dimers by excitation of minority $^{88}\text{Sr}$ atoms to $5sns\,^3S_1$ Rydberg states ($n=31-39$) in a dense background of $^{84}\text{Sr}$. We observe an isotope shift of the $\nu=0$ vibrational state over this range of $n$ and compare our measurements with a theoretical prediction and a simple scaling argument. With the appropriate choice of principal quantum number the isotope shift is sufficiently large to produce heteronuclear dimers with almost perfect fidelity. When the spectral selectivity is limited, we obtain a lower bound on the ratio of heteronuclear to homonuclear excitation probability of 30 to 1 by measuring the scaling of the molecular excitation rate with varying relative densities of $^{88}\text{Sr}$ and $^{84}\text{Sr}$ in the ultracold mixture.

Realising a species-selective double well with multiple-radiofrequency-dressed potentials

Techniques to manipulate the individual constituents of an ultracold mixture are key to investigating impurity physics. In this work, we confine a mixture of hyperfine ground states of 87Rb atoms in a double-well potential. The potential is produced by dressing the atoms with multiple radiofrequencies. The amplitude and phase of each frequency component of the dressing field are controlled to independently manipulate each species. Furthermore, we verify that our mixture of hyperfine states is collisionally stable, with no observable inelastic loss.

Observation of Spin-Spin Fermion-Mediated Interactions between Ultracold Bosons.

Interactions in an ultracold boson-fermion mixture are often manifested by elastic collisions. In a mixture of a condensed Bose gas (BEC) and spin polarized degenerate Fermi gas (DFG), fermions can mediate spin-spin interactions between bosons, leading to an effective long-range magnetic interaction analogous to Ruderman-Kittel-Kasuya-Yosida [Phys. Rev. 96, 99 (1954); Prog. Theor. Phys. 16, 45 (1956); Phys. Rev. 106, 893 (1957)] interaction in solids. We used Ramsey spectroscopy of the hyperfine clock transition in a ^{87}Rb BEC to measure the interaction mediated by a ^{40}K DFG. By controlling the boson density we isolated the effect of mediated interactions from mean-field frequency shifts due to direct collision with fermions. We measured an increase of boson spin-spin interaction by a factor of η=1.45±0.05^{stat}±0.13^{syst} in the presence of the DFG, providing clear evidence of spin-spin fermion mediated interaction. Decoherence in our system was dominated by inhomogeneous boson density shift, which increased significantly in the presence of the DFG, again indicating mediated interactions. We also measured a frequency shift due to boson-fermion interactions in accordance with a scattering length difference of a_{bf_{2}}-a_{bf_{1}}=-5.36±0.44^{stat}±1.43^{syst}a_{0} between the clock-transition states, a first measurement beyond the low-energy elastic approximation [R. Côté, A. Dalgarno, H. Wang, and W. C. Stwalley, Phys. Rev. A 57, R4118 (1998); A. Dalgarno and M. Rudge, Proc. R. Soc. A 286, 519 (1965)] in this mixture. This interaction can be tuned with a future use of a boson-fermion Feshbach resonance.Fermion-mediated interactions can potentially give rise to interesting new magnetic phases and extend the Bose-Hubbard model when the atoms are placed in an optical lattice.

Observation of state-to-state hyperfine-changing collisions in a Bose-Fermi mixture of Li6 and K41 atoms

Hyperfine-changing collisions are of fundamental interest for the studying of ultracold heteronuclear mixtures. Here, we report the state-to-state study of the hyperfine-changing-collision dynamics in a Bose-Fermi mixture of $^6$Li and $^{41}$K atoms. The collision products are directly observed and the spin-changing dynamics is measured. Based on a two-body collision model, the experimental results are simultaneously fitted from which the spin-changing rate coefficient of $ 1.9(2)\times 10^{-12}~\rm{cm^3\cdot s^{-1}}$ is gained, being consistent with the multi-channel quantum defect theory calculation. We further show that the contact parameter of $^6$Li-$^{41}$K mixture can be extracted from the measured spin-changing dynamics. The obtained results are consistent with the first order perturbation theory in the weakly-interacting limit. Our system offers great promise for studying spin-changing interactions in heteronuclear mixtures.

Observation of a threshold behavior in an ultracold endothermic atom-exchange process involving Feshbach molecules

Chemical reactions at ultracold temperature provide an ideal platform to study chemical reactivity at the fundamental level, and to understand how chemical reactions are governed by quantum mechanics. Recent years have witnessed the remarkable progress in studying ultracold chemistry with ultracold molecules. However, these works were limited to exothermic reactions. The direct observation of state-to-state ultracold endothermic reaction remains elusive. Here we report on the investigation of endothermic and nearly thermoneutral atom-exchange reactions in an ultracold atom-dimer mixture. By developing an indirect reactant-preparation method based on a molecular bound-bound transition, we are able to directly observe a universal endothermic reaction with tunable energy threshold and study the state-to-state reaction dynamics. The reaction rate coefficients show a strikingly threshold phenomenon. The influence of the reverse reaction on the reaction dynamics is observed for the endothermic and nearly thermoneutral reactions. We carry out zero-range quantum mechanical scattering calculations to obtain the reaction rate coefficients, and the three-body parameter is determined by comparison with the experiments. The observed endothermic and nearly thermoneutral reaction may be employed to implement collisional Sisyphus cooling of molecules, study the chemical reactions in degenerate quantum gases and conduct quantum simulation of Kondo effect with ultracold atoms.

Berezinskii-Kosterlitz-Thouless Transition of Two-Component Bose Mixtures with Intercomponent Josephson Coupling.

We study the Berezinskii-Kosterlitz-Thouless (BKT) transition of two-component Bose mixtures in two spatial dimensions. When phases of both components are decoupled, half-quantized vortex-antivortex pairs of each component induce two-step BKT transitions. On the other hand, when phases of both components are synchronized through the intercomponent Josephson coupling, two species of vortices of each component are bound to form a molecule, and, in this case, we find that there is only one BKT transition by molecule-antimolecule pairs. Our results can be tested by two weakly connected Bose systems such as two-component ultracold diluted Bose mixtures with the Rabi oscillation, and multiband superconductors.

Pathway toward the formation of supermixed states in ultracold boson mixtures loaded in ring lattices

We investigate the mechanism of formation of supermixed soliton-like states in bosonic binary mixtures loaded in ring lattices. We evidence the presence of a common pathway which, irrespective of the number of lattice sites and upon variation of the interspecies attraction, leads the system from a mixed and delocalized phase to a supermixed and localized one, passing through an intermediate phase where the supermixed soliton progressively emerges. The degrees of mixing, localization and quantum correlation of the two condensed species, quantified by means of suitable indicators commonly used in Statistical Thermodynamics and Quantum Information Theory, allow one to reconstruct a bi-dimensional mixing-supermixing phase diagram featuring two characteristic critical lines. Our analysis is developed both within a semiclassical approach capable of capturing the essential features of the two-step mixing-demixing transition and with a fully-quantum approach.

Two-photon photoassociation spectroscopy of the Σ+2 YbLi molecular ground state

We report on measurements of the binding energies of several weakly bound vibrational states of the paramagnetic $^{174}$Yb$^{6}$Li molecule in the electronic ground state using two-photon spectroscopy in an ultracold atomic mixture confined in an optical dipole trap. We theoretically analyze the experimental spectrum to obtain an accurate description of the long-range potential of the ground state molecule. Based on the measured binding energies, we arrive at an improved value of the interspecies $s$-wave scattering length $a_{s0}=30$ $a_0$. Employing coherent two-photon spectroscopy we also observe the creation of ''dark'' atom-molecule superposition states in the heteronuclear Yb-Li system. This work is an important step towards the efficient production of ultracold YbLi molecules via association from an ultracold atomic mixture.

The mixing-demixing phase diagram of ultracold heteronuclear mixtures in a ring trimer

We derive the complete mixing-demixing phase-diagram relevant to a bosonic binary mixture confined in a ring trimer and modeled within the Bose-Hubbard picture. The mixing properties of the two quantum fluids, which are shown to be strongly affected by the fragmented character of the confining potential, are evaluated by means of a specific indicator imported from Statistical Thermodynamics and are shown to depend only on two effective parameters incorporating the asymmetry between the heteronuclear species. To closely match realistic experimental conditions, our study is extended also beyond the pointlike approximation of potential wells by describing the systems in terms of two coupled Gross-Pitaevskii equations. The resulting mean-field analysis confirms the rich scenario of mixing-demixing transitions of the mixture and also constitutes an effective springboard towards a viable experimental realization. We additionally propose an experimental realization based on a realistic optical-tweezers system and on the bosonic mixture 23Na + 39K, thanks to the large tunability of their intra- and inter-species scattering lengths.

Superfluid density reduction and spin-imbalanced pairing in a fermionic superfluid due to dynamical boson exchange

We explore novel features of a nonrelativistic fermionic superfluid in which the pairing interaction includes a contribution from the exchange of a dynamical bosonic mode. We show that the dynamical boson exchange (DBE), which causes a retarded pairing interaction and thus violates the Galilean invariance of the fermion sector, generically leads to a quantum reduction of the superfluid density and hence a nonzero normal fraction even at zero temperature. For spin-singlet pairing, the DBE also leads to a nonvanishing spin susceptibility at zero temperature, providing a mechanism for the coexistence of pairing and magnetization. While these effects are negligible for weak pairing, they become sizable at strong pairing. For the double superfluidity in ultracold Fermi-Bose mixtures, the superfluid density reduction for the fermion sector induced by the DBE just gives rise to the Andreev-Bashkin drag effect, indicating a strong entrainment between the two superfluid components. The DBE may also provide a new source for the superfluid fraction reduction of neutron matter, which is crucial for models of neutron star glitches based on neutron superfluidity.

Phase-separation dynamics induced by an interaction quench of a correlated Fermi-Fermi mixture in a double well

We explore the interspecies interaction quench dynamics of ultracold spin-polarized few-body mass balanced Fermi-Fermi mixtures confined in a double-well with an emphasis on the beyond Hartree-Fock correlation effects. It is shown that the ground state of particle imbalanced mixtures exhibits a symmetry breaking of the single-particle density for strong interactions in the Hartree-Fock limit, which is altered within the many-body approach. Quenching the interspecies repulsion towards the strongly interacting regime the two species phase separate within the Hartree-Fock approximation while remaining miscible in the many-body treatment. Despite their miscible character on the one-body level the two species are found to be strongly correlated and exhibit a phase separation on the two-body level that suggests the anti-ferromagnetic like behavior of the few-body mixture. For particle balanced mixtures we show that an intrawell fragmentation (filamentation) of the density occurs both for the ground state as well as upon quenching from weak to strong interactions, a result that is exclusively caused by the presence of strong correlations. Inspecting the two-body correlations a phase separation of the two species is unveiled being a precursor towards an anti-ferromagnetic state. Finally, we simulate in-situ single-shot measurements and showcase how our findings can be retrieved by averaging over a sample of single-shot images.

Feshbach resonances in potassium Bose-Bose mixtures

We present a detailed study of the scattering properties of ultracold mixtures of bosonic potassium atoms. We locate 20 previously unobserved Feshbach resonances in isotopic 39K-41K mixtures. These are assigned to s-wave molecular channels by comparison to an asymptotic bound state model and coupled channels calculations. Additional Feshbach resonances are studied in spin mixtures of a single potassium isotope, both in 39K and 41K. In particular, we characterize the parameters of a selected 39K Feshbach resonance by radio-frequency association of Feshbach molecules. Our results could be exploited to refine the model potentials for potassium scattering. Furthermore, these new Feshbach resonances enlarge the range of experiments possible with degenerate Bose-Bose mixtures.

Correlated tunneling dynamics of an ultracold Fermi-Fermi mixture confined in a double well

We unravel the correlated tunneling dynamics of a mass imbalanced few-body fermi-fermi mixture upon quenching the tilt of a double-well. The non-equilibrium dynamics of both species changes from Rabi-oscillations close to the non-interacting limit to a delayed tunneling dynamics for moderate interspecies repulsions. Considering strong interspecies interactions the lighter species experiences quantum self-trapping due to the heavier species which acts as an effective material barrier, while performing almost perfect Rabi-oscillations. The degree of entanglement, inherent in the system, is analyzed and found to be significant both at moderate and strong repulsions. To relate our findings with possible experimental realizations we simulate in-situ single-shot measurements and discuss how a sampling of such images dictates the observed dynamics. Finally, the dependence of the tunneling behavior on the mass ratio, the particle number in each species and the height of the barrier of the double-well is showcased.

Formation of long-range Rydberg molecules in two-component ultracold gases

We present a comprehensive study of the diverse properties of heteronuclear Rydberg molecules, placing a special emphasis on those composed of the light alkali atoms, Li, Na, and K. Electron-atom scattering phase shifts, which determine the strength of the molecular bond, are calculated at very low energy and then used in a spin-dependent theoretical model to calculate accurate Rydberg molecule potential energy curves. The wide parameter range accessible by combining the various properties of different alkali atoms often leads to hybridized electronic states accessible via one or two photon excitation schemes. This analysis of heteronuclear molecules leads to a prediction that the relative densities and spatial distributions of atoms in an ultracold mixture can be probed at controllable length scales via spectroscopic detection of these molecules.

Spin-orbit-coupling-induced quantum droplet in ultracold Bose-Fermi mixtures

Quantum droplets have intrigued much attention recently in view of their successful observations in the ultracold homonuclear atoms. In this work, we demonstrate a new mechanism for the formation of quantum droplet in heteronuclear atomic systems, i.e., by applying the synthetic spin-orbit coupling(SOC). Take the Bose-Fermi mixture for example, we show that by imposing a Rashba SOC between the spin states of fermions, the greatly suppressed Fermi pressure can enable the formation of Bose-Fermi droplets even for very weak boson-fermion attractions, which are insufficient to bound a droplet if without SOC. In such SOC-induced quantum droplets, the boson/fermion density ratio universally depends on the SOC strength, and they occur in the mean-field collapsing regime but with a negative fluctuation energy, distinct from the interaction-induced droplets found in literature. The accessibility of these Bose-Fermi droplets in ultracold Cs-Li and Rb-K mixtures is also discussed. Our results shed light on the droplet formation in a vast class of heteronuclear atomic systems through the manipulation of single-particle physics.

NASA\u2019s Cold Atom Lab (CAL): system development and ground test status

We report the status of the Cold Atom Lab (CAL) instrument to be operated aboard the International Space Station (ISS). Utilizing a compact atom chip-based system to create ultracold mixtures and degenerate samples of 87Rb, 39K, and 41K, CAL is a multi-user facility developed by NASA’s Jet Propulsion Laboratory to provide the first persistent quantum gas platform in the microgravity conditions of space. Within this unique environment, atom traps can be decompressed to arbitrarily weak confining potentials, producing a new regime of picokelvin temperatures and ultra-low densities. Further, the complete removal of these confining potential allows the free fall evolution of ultracold clouds to be observed on unprecedented timescales compared to earthbound instruments. This unique facility will enable novel ultracold atom research to be remotely performed by an international group of principle investigators with broad applications in fundamental physics and inertial sensing. Here, we describe the development and validation of critical CAL technologies, including demonstration of the first on-chip Bose–Einstein condensation (BEC) of 87Rb with microwave-based evaporation and the generation of ultracold dual-species quantum gas mixtures of 39K/87Rb and 41K/87Rb in an atom chip trap via sympathetic cooling.

Resonant spin exchange between heteronuclear atoms assisted by periodic driving

We propose a general scheme for inducing resonant exchange between spins or pseudo-spins of unmatched levels via periodic driving. The basic idea is illustrated for a system of two heteronuclear atoms, for which analytical results are provided for the effective spin exchange (SE) interaction strength. It is then applied to the mixture of 23Na and 87Rb atoms with a radio-frequency (rf) or microwave field near-resonant to the mismatched Zeeman level spacings. SE interaction engineered this way is applicable to ultracold quantum gas mixtures involving spinor Bose-Bose, Bose-Fermi, and Fermi-Fermi atoms.

Entanglement Induced Interactions in Binary Mixtures.

We establish a conceptual framework for the identification and the characterization of induced interactions in binary mixtures and reveal their intricate relation to entanglement between the components or species of the mixture. Exploiting an expansion in terms of the strength of the entanglement among the two species enables us to deduce an effective single-species description. In this way, we naturally incorporate the mutual feedback of the species and obtain induced interactions for both species which are effectively present among the particles of same type. Importantly, our approach incorporates few-body and inhomogeneous systems extending the scope of induced interactions where two particles interact via a bosonic bath-type environment. Employing the example of a one-dimensional ultracold Bose-Fermi mixture, we obtain induced Bose-Bose and Fermi-Fermi interactions with short-range attraction and long-range repulsion. With this, we show how beyond species mean-field physics visible in the two-body correlation functions can be understood via the induced interactions.

Production of ultracold Cs*Yb molecules by photoassociation

We report the production of ultracold heteronuclear Cs$^*$Yb molecules through one-photon photoassociation applied to an ultracold atomic mixture of Cs and Yb confined in an optical dipole trap. We use trap-loss spectroscopy to detect molecular states below the Cs($^{2}P_{1/2}$) + Yb($^{1}S_{0}$) asymptote. For $^{133}$Cs$^{174}$Yb, we observe 13 rovibrational states with binding energies up to $\sim$500 GHz. For each rovibrational state we observe two resonances associated with the Cs hyperfine structure and show that the hyperfine splitting in the diatomic molecule decreases for more deeply bound states. In addition, we produce ultracold fermionic $^{133}$Cs$^{173}$Yb and bosonic $^{133}$Cs$^{172}$Yb and $^{133}$Cs$^{170}$Yb molecules. From mass scaling, we determine the number of bound states supported by the 2(1/2) excited-state potential to be 154 or 155.

Reentrant Fulde-Ferrell-Larkin-Ovchinnikov superfluidity in the honeycomb lattice

We study superconducting properties of population-imbalanced ultracold Fermi mixtures in the honeycomb lattice that can be effectively described by the spin-imbalanced attractive Hubbard model in the presence of a Zeeman magnetic field. We use the mean-field theory approach to obtain ground state phase diagrams including some unconventional superconducting phases such as the Fulde--Ferrell--Larkin--Ovchinnikov (FFLO) phase. We show that this phase is characterized by atypical behaviour of the Cooper pairs total momentum in the external magnetic field. We show that the momentum changes its value as well as direction with change of the system parameters. We discuss the influence of van Hove singularities on the possibility of the reentrant FFLO phase occurrence, without a BCS precursor.