Ultra-low Switching Research Articles

Interfering Josephson diode effect in Ta2Pd3Te5 asymmetric edge interferometer

Edge states in topological systems have attracted great interest due to their robustness and linear dispersions. Here a superconducting-proximitized edge interferometer is engineered on a topological insulator Ta2Pd3Te5 with asymmetric edges to realize the interfering Josephson diode effect (JDE), which hosts many advantages, such as the high efficiency as much as 73% at tiny applied magnetic fields with an ultra-low switching power around picowatt. As an important element to induce such JDE, the second-order harmonic in the current-phase relation is also experimentally confirmed by half-integer Shapiro steps. The interfering JDE is also accompanied by the antisymmetric second harmonic transport, which indicates the corresponding asymmetry in the interferometer, as well as the polarity of JDE. This edge interferometer offers an effective method to enhance the performance of JDE, and boosts great potential applications for future superconducting quantum devices.

GeTe/MoTe2 Van der Waals Heterostructures: Enabling Ultralow Voltage Memristors for Nonvolatile Memory and Neuromorphic Computing Applications.

Advanced electronic semiconducting Van der Waals heterostructures (HSs) are promising candidates for exploring next-generation nanoelectronics owing to their exceptional electronic properties, which present the possibility of extending their functionalities to diverse potential applications. In this study, GeTe/MoTe2 HS are explored for nonvolatile memory and neuromorphic-computing applications. Sputter-deposited Ag/GeTe/MoTe2/Pt HS cross-point devices are fabricated, and they demonstrate memristor behavior at ultralow switching voltages (VSET: 0.15V and VRESET: -0.14V) with very low energy consumption (≈30 nJ), high memory window, long retention time (104 s), and excellent endurance (105 cycles). Resistive switching is achieved by adjusting the interface between the Ag top electrode and the heterojunction switching layer. Cross-sectional transmission electron microscope images and conductive atomic force microscopy analysis confirm the presence of a conducting filament in the heterojunction switching layer. Further, emulating various synaptic functions of a biological synapse reveals that GeTe/MoTe2 HS can be utilized for energy-efficient neuromorphic-computing applications. A multilayer perceptron is implemented using the synaptic weights of the Ag/GeTe/MoTe2/Pt HS device, revealing high pattern accuracy (81.3%). These results indicate that HS devices can be considered a potential solution for high-density memory and artificial intelligence applications.

A new type of pentagonal structure HgS2 monolayer with abundant active sites and low Gibbs free energy for photocatalytic water splitting

Discovery of new two-dimensional (2D) materials not only has important fundamental research significance but also has promising application prospects. Through systematic structure searching combined with density functional theory calculations and simulations, we predict a new 2D monolayer HgS2 material featuring with a previously unreported type of pentagonal structure with orthorhombic P21212 symmetry. The penta-HgS2 monolayer shows good thermal, thermodynamic, mechanical and dynamic stabilities, exhibiting ferroelastic phase transition with an ultralow switching energy barrier (about 1 meV/atom), high ultimate strength of 12 N/m, moderate indirect band gap of 2.25 eV. In addition, the penta-HgS2 monolayer shows significantly anisotropic carrier mobility with a large anisotropy ratio of 98.5 along the y direction. More importantly, the penta-HgS2 monolayer exhibits abundant catalytic active sites, low Gibbs free energy (ΔGH ranging from 0.656 to 1.687 eV) for hydrogen evolution reactions, excellent solar light absorption capacity (∼105 cm−1) with the solar-to-hydrogen efficiency reaching up to 11.83%. The excellent ultimate tensile ability and the ultralow ferroelastic phase transition energy barrier implies penta-HgS2 monolayer material can be used to manufacture flexible mechanical and nanoelectronic devices. The suitable band edge alignments, ultrahigh carrier mobility anisotropy, high catalytic activity and excellent visible light adsorption performance indicate that penta-HgS2 monolayer is a promising candidate photocatalyst for high-performance photocatalytic water splitting. The present work not only supplements a new member to the 2D pentagonal structure material family, but also points out its promising applications in nanoscale devices and photocatalytic hydrogen productions.

In-Plane Sliding Ferroelectricity Realized in Penta-PdSe2/Penta-PtSe2 van der Waals Heterostructure.

Different from conventional 2D sliding ferroelectrics with polarization switchable in the out-of-plane via interlayer sliding, we show the existence of in-plane sliding ferroelectricity in a bilayer of a pentagon-based van der Waals heterostructure formed by vertically stacking an experimentally synthesized penta-PdSe2 sheet and a crystal lattice well-matched penta-PtSe2 sheet. From the 128 sliding patterns, four stable configurations are found that exhibit in-plane sliding ferroelectricity with an ultralow polarization switching barrier of 1.91 meV/atom and a high ferroelectric polarization of ±17.11 × 10-10 C m-1. Following the ferroelectric transition among the stable sliding configurations, significant changes in carrier mobility, electrical conductivity, and second harmonic generation are identified. In particular, the ferroelectric stacking configurations are found to possess a negative Poisson's ratio, facilitating the experimental characterization of the sliding ferroelectric effect. This study demonstrates that pentagonal sheets can be used to realize 2D in-plane sliding ferroelectrics going beyond the existing ones.

Nonvolatile ferroelectric resistive switching in α-In2Se3(2H) ferroelectric semiconductor junctions

Emerging two-dimensional van der Waals (vdW) based ferroelectric semiconductor junctions (FSJs) are promising for low-power and high-density applications. In this work, we report the vdW α-In2Se3(2H) based FSJs of different metal-In2Se3 interfaces. All vertical devices emerge with the nonvolatile ferroelectric resistive switching behavior. The Cr/α-In2Se3(2H)/Au FSJs show a typical ferroelectric resistive switching behavior under ∼1.0 V applied voltage. The switching voltage of the Ag/α-In2Se3(2H)/Au FSJs could be further decreased from 1.0 V to 0.8 V because of Ag migrations and ferroelectric reversal. Further, by optimizing the metal-In2Se3 interfaces, the Ag/α-In2Se3(2H)/Pt FSJs exhibit the ultralow switching voltage (∼0.3 V), excellent endurance (>225 cycles) and retention (>1 × 104 s). The results suggest that vdW α-In2Se3(2H) ferroelectric has great potential for low-power memristive devices.

The fabrication of spin transfer torque-based magnetoresistive random access memory cell with ultra-low switching power

We conducted research on the integration technology of a spin transfer torque-based magnetoresistive random access memory (STT-MRAM) cell (one transistor, one magnetic tunnel junction – 1T-1MTJ) on an 8-inch process platform. By combining a 0.5 μm CMOS front end of line process and STT-MTJ back end of line process, a 1T-1MTJ device with an MTJ of approximately 80 nm is realized. The Resistance(R)-magnetic field(H) measurement reveals a coercive force of approximately 450 Oe for the MTJ. Nevertheless, the 1T-1MTJ device exhibits a critical switching current of 4.7 μA (from high to low resistance state) and 17.9 μA (from low to high resistance state), accompanied by corresponding critical switching voltages of 0.05 V and 0.16 V, respectively, which is extremely low in an STT-MRAM with dual CoFeB/MgO interface free layer. Our findings demonstrate the potential for application in ultra-low-power portable mobile devices and embedded systems.

Hydrogen-Driven Low-Temperature Topotactic Transition in Nanocomb Cobaltite for Ultralow Power Ionic-Magnetic Coupled Applications.

We reversibly control ferromagnetic-antiferromagnetic ordering in an insulating ground state by annealing tensile-strained LaCoO3 films in hydrogen. This ionic-magnetic coupling occurs due to the hydrogen-driven topotactic transition between perovskite LaCoO3 and brownmillerite La2Co2O5 at a lower temperature (125-200 °C) and within a shorter time (3-10 min) than the oxygen-driven effect (500 °C, tens of hours). The X-ray and optical spectroscopic analyses reveal that the transition results from hydrogen-driven filling of correlated electrons in the Co 3d-orbitals, which successively releases oxygen by destabilizing the CoO6 octahedra into CoO4 tetrahedra. The transition is accelerated by surface exchange, diffusion of hydrogen in and oxygen out through atomically ordered oxygen vacancy "nanocomb" stripes in the tensile-strained LaCoO3 films. Our ionic-magnetic coupling with fast operation, good reproducibility, and long-term stability is a proof-of-principle demonstration of high-performance ultralow power magnetic switching devices for sensors, energy, and artificial intelligence applications, which are keys for attaining carbon neutrality.

L10 FePd-based perpendicular magnetic tunnel junctions with 65% tunnel magnetoresistance and ultralow switching current density

L10 FePd is increasingly recognized as a potential candidate for magnetic tunnel junctions (MTJs), yet there remains room for enhancing device performance. In this work, we fabricated fully-integrated L10 FePd-based perpendicular MTJ devices and achieved a significant increase in tunnel magnetoresistance, reaching ∼65%, compared to the previous record of 25%. Notably, we observed bi-directional switching with a low switching current density of about 1.4 × 105 A/cm2, which outperforms the typical spin-transfer torque (STT) MTJ by about one order of magnitude. We propose two possible mechanisms to elucidate the switching process and associated device performance: (1) The voltage-controlled exchange coupling-driven switching of the bottom CoFeB layer; (2) The STT-driven switching of the exchange-coupled L10 FePd–CoFeB composite. While additional research is necessary, these findings may further advance the integration of L10 FePd into spintronic devices, potentially enabling low-energy memory and logic technologies.

High-temperature tolerant TaOX/HfO2 self-rectifying memristor array with robust retention and ultra-low switching energy

Due to the heat generation during operations in high-density three-dimensional (3D) integrated chips, a high-temperature tolerant and high-performance self-rectifying memristor (SRM) is a promising candidate for 3D integration. Here, we investigated the high-temperature characteristics of Ta/TaOX/HfO2/Pt SRMs with a 250 nm feature size in an 8 × 8 crossbar array (CBA). The SRMs exhibit high uniformity and can be operated repeatedly at Set (4 V/2 μs) and Reset (-2 V/1 μs) pulses for more than 104 cycles resulting in ultra-low switching energy (5.86 aJ for Set and 77.2 aJ for Reset). High yield of the array indicates the reliable preparation processes. Remarkably, the CBA is capable of stably resistive switching at high temperatures from 300 to 475 K. At 300 K, the SRM shows large nonlinearity (NL, ∼1.4 × 104) and rectification ratio (RR, ∼8.8 × 103) as well as high scalability (330 Mbit); at 475 K, the NL and RR of the SRM can still maintain above 400, and the scalability still reaches 71 Kbit. Moreover, our SRM passed a high-temperature retention test of over 5 × 104 s at 438 K. Segmented fittings of the I–V curves of the SRM at different temperatures were performed, concluding that large NL and RR attributed to the Schottky barriers at TaOX/HfO2 and Pt/HfO2 interfaces, respectively. Our work furnishes a feasible solution for high-density 3D integrated memristors in high-temperature application scenarios represented by automotive-grade chips.

Single Molecular Semi-Sliding Ferroelectricity/Multiferroicity.

In recent years, the unique mechanism of sliding ferroelectricity with ultralow switching barriers has been experimentally verified in a series of 2-dimensional (2D) materials. However, its practical applications are hindered by the low polarizations, the challenges in synthesis of ferroelectric phases limited in specific stacking configurations, and the low density for data storage since the switching process involves large-area simultaneous sliding of a whole layer. Herein, through first-principles calculations, we propose a type of semi-sliding ferroelectricity in the single metal porphyrin molecule intercalated in 2D bilayers. An enhanced vertical polarization can be formed independent on stacking configurations and switched via sliding of the molecule accompanied by the vertical displacements of its metal ion anchored from the upper layer to the lower layer. Such semi-sliding ferroelectricity enables each molecule to store 1 bit data independently, and the density for data storage can be greatly enhanced. When the bilayer exhibits intralayer ferromagnetism and interlayer antiferromagnetic coupling, a considerable difference in Curie temperature between 2 layers and a switchable net magnetization can be formed due to the vertical polarization. At a certain range of temperature, the exchange of paramagnetic-ferromagnetic phases between 2 layers is accompanied by ferroelectric switching, leading to a hitherto unreported type of multiferroic coupling that is long-sought for efficient "magnetic reading + electric writing".

Numerical analysis of an ultralow switching loss IGBT with super junction and blocking junction

In order to reduce the switching loss (ESW) and enhance the breakdown voltage (BV), in this paper, an insulated gate bipolar transistor with an internal blocking junction and super junction (SJBJ-IGBT) is proposed and investigated. By inserting P-pillar and N-pillar on both sides of the drift region, a drift area with auxiliary depletion function can be formed. The junction of the primary blocking layer (JPB) is located internally in the device’s drift region. The JPB is reverse biased and withstand the main E-field during device turn-off. Meanwhile, the JPB is surrounded by P-pillar and N-pillar, reducing the E-field(E-field) peak value of device, and making E-field distribution more uniform. Furthermore, during device turn-on, the reduction of the effective area of drift region makes it easier for the JPB side of the P-drift region to accumulate excess holes. So that the SJBJ-IGBT is easier to turn-on. The snapback phenomenon of SJBJ-IGBT is eliminated. Simulation results demonstrate that, under the same forward conduction voltage (VON) condition, the proposed device exhibits a significantly lower turn-on energy loss (EON) compared to the traditional super junction(SJ-IGBT), and is 44.5% lower than that of IPBJ-IGBT, while their turn-off energy losses (EOFF) are almost equivalent.Besides, the optimized E-field distribution in the SJBJ-IGBT shows 13.2% improvement of BV. Researching results can provide important reference for reducing the ESW of IGBT.

Laser-modulated formation of conduction path for the achievement of ultra-low switching voltage in resistive random-access memory (RRAM)

Energy saving is one of critical issues that must be seriously considered for the development of next-generation memory devices. In this study, an ultralow-power resistive random-access memory (RRAM) device is fabricated through use of a successful modulation of the AlOX layer by a laser treatment optimized for the energy saving in resistive switching (RS). The device shows not only multilevel memory properties but also a high on/off ratio (∼106), good endurance (300 cycles), and excellent retention (>104 s). Most importantly, the laser-modulated device achieves ultra-low set and reset voltages (0.06 V and −0.04 V), leading to a very low-power consumption. It was observed that the amorphous phase in the AlOX layer is transformed into the polycrystalline phase and a concentration gradient of oxygen vacancies is secured. The grain boundaries in the polycrystalline act as pathways to facilitate the movement of oxygen vacancies. Meanwhile, the concentration gradient accelerates the diffusion mobility of the oxygen vacancies. The highly potential application of the laser-modulation to the flexible RRAM devices has been demonstrated by a strong level of RS performance maintenance from a device fabricated using the polyethylene terephthalate (PET) substrate.

In Memory Energy Application for Electrochemical Random Access Memory

This work explores the innovative concept of a hybrid dual-behavior device, based on emerging nonvolatile memory technology, for both data retention and energy storage. Electrochemical random access memory (ECRAM) is considered a major candidate as next-generation memory, thanks to its promising performances in terms of scalability and CMOS process compatibility. In particular, three-terminal synaptic transistors (SynT) offer an ion conductor-gated control from which ion doping content can be monitored with high energy efficiency via redox reactions, thus decoupling write-read actions and improving the linearity of programming states for neuromorphic computing1. Its working mechanisms, based on faradaic processes, motivate the study on the feasibility of operating ECRAM also as energy storage element.To evaluate the energy capability, various electrochemical characterizations are presented. Cyclic voltammetry tests reveal that the cells behave as standard electrochemical storage elements when investigating the impact of the scan rate, maximum positive voltage, and area on the reduction peak. Storage capability amounts up to 1.5µAh.cm-2 have been obtained, two decades higher than deep trench capacitor existing solutions, while showing outstanding synaptic behavior: A nonvolatile conductance modulation (<75 nS) is achieved through reversible lithium intercalation into the channel, and synaptic functions, such as long-term potentiation/depression involve ultralow switching energy of 2 fJ μm−2. Moreover, this SynT shows excellent endurance (>105 weight updates) and recognition accuracy (>95% on the MNIST data test using crossbar simulations). Finally, design concepts are proposed, where ECRAM “in-memory energy” technology would be a newfangled approach to meet the needs of various emerging and standard applications.Reference Nguyen, N. et al. An Ultralow Power Li x TiO 2 -Based Synaptic Transistor for Scalable Neuromorphic Computing. Adv. Electron. Mater. 2200607, 2200607 (2022). Figure 1. Schematic view of the elaborated SynT, and corresponding dual energy and data storage properties: vertical gate stack is a nanobattery with energy storage function while lateral architecture allows for conductance modulation and data storage. Figure 1

Theoretical designs of low‐barrier ferroelectricity

AbstractFerroelectrics with electrically switchable spontaneous polarizations can be used for information storage, where a low switching barrier is favorable to reduce the energy cost and enhance the speed for data writing. Meanwhile their robustness at working temperature should be ensured, which is a challenge for the designs of low‐barrier ferroelectrics. Here we review several types of ferroelectric mechanisms that may render both low switching barriers and room‐temperature robustness, which have been theoretically proposed in previous studies. (1) The prediction of sliding ferroelectricity with ultralow switching barriers has been experimentally confirmed in a series of van der Waals layers, which may enable convenient electrical control of various physical properties in 2D materials, like magnetic, photovoltaic, valleytronic and topological properties. (2) Hydrogen‐bonded ferroelectricity spontaneously formed by head‐to‐tail chains can be switched by proton‐transfer crossing a low barrier, and a mechanism of ultra‐high piezoelectricity utilizing the specific features of hydrogen bonding has been proposed. (3) High‐ionicity ferroelectricity induced by covalent‐like ionic bondings may entail high polarizations and low barriers during switching, which is attributed to the features of long‐range Coulomb interaction, and the long ion‐displacements crossing unitcell may give rise to unconventional ferroelectricity with quantized polarizations even in crystals of non‐ferroelectric point groups. Those low‐barrier ferroelectric mechanisms may bring in both new physics and technological advances, which are to be further explored.This article is categorized under: Structure and Mechanism &gt; Computational Materials Science

Low-Power and Field-Free Perpendicular Magnetic Memory Driven by Topological Insulators.

Giant spin-orbit torque (SOT) from topological insulators (TIs) has great potential for low-power SOT-driven magnetic random-access memory (SOT-MRAM). In this work, a functional 3-terminal SOT-MRAM device is demonstrated by integrating the TI [(BiSb)2 Te3 ] with perpendicular magnetic tunnel junctions (pMTJs), where the tunneling magnetoresistance is employed for the effective reading method. An ultralow switching current density of 1.5 × 105 Acm-2 is achieved in the TI-pMTJ device at room temperature, which is 1-2 orders of magnitude lower than that in conventional heavy-metals-based systems, due to the high SOT efficiency θSH = 1.16 of (BiSb)2 Te3 . Furthermore, all-electrical field-free writing is realized by the synergistic effect of a small spin-transfer torque current during the SOT. The thermal stability factor (Δ = 66) shows the high retention time (>10 years) of the TI-pMTJ device. This work sheds light to the future low-power, high-density, and high-endurance/retention magnetic memory technology based on quantum materials.

Proton-mediated reversible switching of metastable ferroelectric phases with low operation voltages.

The exploration of ferroelectric phase transitions enables an in-depth understanding of ferroelectric switching and promising applications in information storage. However, controllably tuning the dynamics of ferroelectric phase transitions remains challenging owing to inaccessible hidden phases. Here, using protonic gating technology, we create a series of metastable ferroelectric phases and demonstrate their reversible transitions in layered ferroelectric α-In2Se3 transistors. By varying the gate bias, protons can be incrementally injected or extracted, achieving controllable tuning of the ferroelectric α-In2Se3 protonic dynamics across the channel and obtaining numerous intermediate phases. We unexpectedly discover that the gate tuning of α-In2Se3 protonation is volatile and the created phases remain polar. Their origin, revealed by first-principles calculations, is related to the formation of metastable hydrogen-stabilized α-In2Se3 phases. Furthermore, our approach enables ultralow gate voltage switching of different phases (below 0.4 volts). This work provides a possible avenue for accessing hidden phases in ferroelectric switching.

Solution-processed small-molecular organic memristor with a very low resistive switching set voltage of 0.38 V

Organic memristors are considered to be the next-generation storage element due to their unique advantages of flexibility, transparency, and good solution processability. In this Letter, a Zn-porphyrin based small-molecular organic memristor is prepared by spin-coating with an ultralow resistive switching set voltage of 0.38 V. It is found that the zinc atom in the porphyrin molecule plays a very important role in improving the resistance switching characteristics of organic memristors. By tracking the change in oxygen valence in the vertical dimension, we demonstrate that Zn atom located in the core of porphyrin helps to enhance the oxygen ion migration across the active layer, clearly revealing the memory mechanism of low-cost solution-processed Zn-porphyrin based small-molecular organic memristors. This organic memristor shows excellent memristive performance resulting from rational material design and appropriate device structure engineering.

A Survey of MRAM-Centric Computing: From Near Memory to In Memory

Conventional von Neumann architecture suffers from bottlenecks in computing performance and power consumption due to frequent data exchange between memory and processing units. To overcome this issue, research on novel computing architectures including near-memory computing (NMC) and in-memory computing (IMC) has been accelerated based on emerging nonvolatile memory devices. Among various potential candidates, spintronic-based magnetic random-access memory (MRAM) has come into a research and development hotspot by its ultralow switching energy, nonvolatility, and superior endurance. This paper outlines the background, trends, and challenges involved in the development of MRAM-centric computing, and highlights the recent prototypes and advances in applications based on MRAM-NMC and MRAM-IMC.

Numerical Analysis of an Ultralow Switching Loss IGBT With an Inner Primary Blocking Junction

To reduce switching loss, an insulated gate bipolar transistor (IGBT) with an inner primary blocking junction (IPBJ) is proposed and investigated. By inserting a P-drift between the N-drift and carrier storage (CS) layer, a primary blocking junction ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${J}_{\text {PB}}{)}$ </tex-math></inline-formula> of the P-drift/N-drift junction and a secondary blocking junction ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${J}_{\text {SB}}{)}$ </tex-math></inline-formula> of the P body/CS layer junction are formed. <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${J}_{\text {PB}}$ </tex-math></inline-formula> is in the inner of the drift region and supports most of the blocking voltage. This reduces the electric potential in the CS layer and hole density in the hole inversion layer around the trench gate during the turn-on transient. Consequently, its turn-on loss ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${E}_{\text {on}}{)}$ </tex-math></inline-formula> and electromagnetic interference (EMI) noise tradeoff relationship is improved. <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${J}_{\text {PB}}$ </tex-math></inline-formula> is forward-biased by the ON-state excess hole in the P-drift. Thus, no electric field ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${E}$ </tex-math></inline-formula> -field) builds in <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${J}_{\text {PB}}$ </tex-math></inline-formula> until the excess hole in the P-drift is swept out by the <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${E}$ </tex-math></inline-formula> -field extending from the reverse-biased <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${J}_{\text {SB}}$ </tex-math></inline-formula> to <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${J}_{\text {PB}}$ </tex-math></inline-formula> . Hence, with almost no excess hole in the P-drift, the <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${E}$ </tex-math></inline-formula> -field in <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${J}_{\text {PB}}$ </tex-math></inline-formula> can build fast in both the P-drift and N-drift directions. This reduces the collector voltage rising time, as well as turn-off loss ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${E}_{\text {off}}{)}$ </tex-math></inline-formula> . Simulation results show that, compared with the state-of-the-art carrier-stored trench-gate bipolar transistor (CSTBT), the proposed 650-V class silicon IPBJ-IGBT reduces <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${E}_{\text {off}}$ </tex-math></inline-formula> by 79.7% with the same ON-state voltage ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${V}_{\text {on}}{)}$ </tex-math></inline-formula> and reduces <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${E}_{\text {on}}$ </tex-math></inline-formula> by 77.9% with the same current overshoot ( <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${I}_{\text {peak}}{)}$ </tex-math></inline-formula> . Besides, with its <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">${E}$ </tex-math></inline-formula> -field and electric potential distribution optimized, the IPBJ-IGBT also improves its blocking characteristic, short-circuit withstand capability, and unclamped inductive switching performance.

Visual growth of nano-HOFs for low‐power memristive spiking neuromorphic system

Memristors showcasing progressive conductance modulation are now recognized as one of the most promising candidates to act like electronic synapses inside computer circuits, mimicking the behavior of neurons in the human brain. Recently, the concept of biomimic synapse devices based on organic materials has attracted enormous interest, nevertheless, largely limited by their poor electrical conductivity and charge transfer capacity. Here, 2D ribbon-structured hydrogen-bonded organic frameworks (Nano-HOFs) embedded with the transition metal nanoparticles are firstly grown under visual surveillance to serve as highly reliable memristive materials, where the localized surface plasmon resonance effect and enhanced charge-carrier transport are strongly confirmed. The HOFs@Au-based memristor presents gradient electrical conductances under continuous voltage sweep or pulse algorithms, thereby closely simulating the synaptic behaviors in biological neurons. The newly designed artificial synapses owns an ultra-low areal switching energy density (35.8 fJ µm−2) and maintains extremely stable synaptic functions even after being exposed to ambient conditions over 6 months without any encapsulation. Further brain-inspired cognitive systems are established to realize color coding and image cognition in a secure way. This work creates a precedent for developing highly viable Nano-HOFs materials to manipulate artificial synapse mimicking, prospective neuromorphic computing and intelligent cognition applications.