Typical Mid-ocean Ridge Basalts Research Articles

The helium and carbon isotopic signature of Ocean island basalts: Insights from Fogo volcano (Cape Verde archipelago)

Fluid inclusions (FI) entrapped in phenocrysts carried by Ocean Island Basalts (OIB) contain key information on volatiles’ abundance and origin in their mantle sources. Here, we add new piece of knowledge to our understanding of volatile geochemistry in global OIB magmas, by presenting new noble gas (He-Ne-Ar) and carbon (C) isotope results for olivine- and clinopyroxene-hosted FI from enclaves, lavas, tephra and volcanic gas samples from Fogo, the only frequently active volcano at the Cape Verde archipelago (eastern Atlantic Ocean). FI, together with crater fumaroles, constrain the Fogo 3He/4He signature at 7.14–8.44 Rc/Ra (where RC is the air-corrected 3He/4He isotope ratio, and Ra is the same ratio in air), which is within the typical MORB (Mid-Ocean Ridge Basalt) mantle. The carbon isotopic ratio (δ13C vs. Pee Dee Belemnite) of CO2 in FI and fumaroles range from -6.04 to -4.41 ‰. We identify systematic variations of δ13C and He/Ar* with FI entrapment pressure (estimated from a combination of host mineral barometry and FI microthermometry), from which we develop a model for volatile degassing in the mantle-to-crustal magma storage system. The model predicts a crustal-like signature for carbon (δ13C of -0.4 ± 1.0 ‰) in primary melts formed by mantle melting at ∼2200 MPa (∼77 km) and a source He/Ar* ratio of 0.90–0.24, which are indicative of variably depleted mantle metasomatized by carbon enriched melts/fluids from a crustal component. We also use our results to characterise regional (in the Cape Verde and Canary archipelagos) and global trends in C and He isotope composition from OIB. From a comparison with the few other OIB localities for which δ13C are available, we propose that a carbon enriched crustal component could be recurrent at a global scale in OIB magmatism, although often masked by isotope fractionation during magmatic degassing. We additionally find that, at regional scale, He isotopes in OIB scale inversely correlate with the degree of partial melting of the mantle beneath individual islands’ (inferred from the La/Yb ratio of erupted basalts). More widely, our results corroborate previously established global relationships between OIB He isotopic signature, plume buoyancy flux and overlying plate velocity. In this interpretation, the MORB-like 3He/4He (8 ± 1 Ra) at Fogo reflects a combination of (i) low to medium magma productivity, (ii) relatively low plume buoyancy flux (∼1.1 Mg/s), and (iii) slow average velocity (∼3 cm/yr) of the overlying plate.

Coupled Geodynamical‐Geochemical Perspectives on the Generation and Composition of Mid‐Ocean Ridge Basalts

AbstractOwing to their abundance and relative availability on Earth's seafloor, mid‐ocean ridge basalts (MORBs) have a well‐defined chemical element budget, reflected by the low standard deviation associated with typical normal MORB (N‐MORB) composition. However, the exact mechanisms leading to magma differentiation and MORB generation remain debated, which hinders our ability to evaluate MORB parental magma composition. In this study, we leverage the predictive power of the BDD21 numerical framework to obtain a representative trace element budget of parental MORB magma and assess its ability to fractionate into the N‐MORB composition. Utilizing revised parameterizations for mineralogy, melting, and partitioning, we couple BDD21 with numerical simulations of a MOR system driven by seafloor spreading in which we track the evolution of partial melting, mineral modal abundances, and concentrations of incompatible elements. Parental magma compositions are determined once simulations reach a steady state, and magma chamber replenishment models are employed to predict the trace element budget of the erupted liquid. We explore a range of geophysical and geochemical parameters to evaluate their effect on computed trace element concentrations. Previous magma chamber replenishment models are extended to account for multiple crystallization events and melt‐crystal interaction. Modeling outcomes suggest that petrologically constrained fractionation of parental magma compositions obtained through BDD21 yields glass compositions compatible with the N‐MORB budget. Nevertheless, our results show a systematic underestimation of Sr concentration, indicating the presence of recycled oceanic crust in the MORB source region.

Concordance of V-in-olivine and Fe-XANES oxybarometry methods in mid-ocean ridge basalts

Oxygen fugacity (fO2) is a fundamental parameter controlling the behavior of redox-sensitive elements, as well as the speciation of degassing volatiles in igneous systems. Therefore, the average fO2 of typical mid-ocean ridge basalts (MORB) is important to constrain for models of atmospheric and mantle chemical evolution. Although there are several independent oxybarometry methods, in recent years, the Fe X-ray absorption near edge spectroscopy (Fe-XANES) oxybarometry of volcanic glasses has become the gold standard for evaluating the fO2 of modern lavas. Other oxybarometry methods, such as the V-in-olivine method, are useful for samples in which fresh glass is not preserved, but it is not clear whether the two methods give comparable results when applied to the same samples due to the lack of inter-calibration studies. Presented here are V-in-olivine oxybarometry data for eleven MORB lavas, eight of which have been previously characterized by Fe-XANES oxybarometry. The new data show that the V-in-olivine method is not applicable to MORB with glass containing <8.3 wt. % MgO, and that MORB with glass having MgO >8.3 wt. % have an fO2 averaging -0.28 ± 0.28 ΔFMQ, overlapping with the global Fe-XANES MORB average of -0.18 ± 0.16 ΔFMQ. It is therefore recommended that this oxybarometry technique only be applied to MORB with primitive (>8.3 wt. % MgO) glass. The lack of any systematic offset between the data from the two oxybarometers supports our previous conclusion that ocean island basalt sources (OIB) are more oxidized than average MORB, and that the majority of Archean komatiite sources record significantly lower fO2 than modern MORB.

Water in clinopyroxene from the 2021 Geldingadalir eruption of the Fagradalsfjall Fires, SW-Iceland

Water content plays a significant role in magma genesis, ascent rate, and, ultimately, in the style and intensity of volcanic eruptions, due to its control on the density, viscosity and melting behaviour of silicate melts. A reliable method for determining the pre-eruptive magmatic water content is to use phenocrysts of nominally anhydrous minerals (NAMs) which can preserve water as hydrogen configurations in structural defects. The advantage of this method is that eruptive changes such as water loss during magma degassing may be experimentally reconstructed and analysed by infrared spectroscopy. Applying this to clinopyroxene crystals (n=17) from lava samples (n=7) from April 2021 of the Geldingadalir eruption, SW-Iceland, reveals parental water contents of 0.69 ± 0.07 to 0.86 ± 0.09 wt. % H2O. These values are higher than those expected for typical mid-ocean ridge basalts (MORB 0.3–0.5 wt. % on average) indicating a significant plume (OIB) contribution to the magma source. Moreover, such water concentrations would imply that water saturation in the ascending Geldingadalir magmas was attained only at very shallow levels within the plumbing system. This could explain the at times pulsating behaviour within the uppermost conduit system as being the result of shallow episodic water vapour exsolution in addition to the deep-sourced CO2 flux.

Mid-Ordovician stratigraphy and volcanism in the Hølonda area, Scandinavian Caledonides: complex tectonomagmatic development following arc–continent collision near the Laurentian margin of Iapetus

The Hølonda area of the central Scandinavian Caledonides is a key for models of the Caledonian orogen owing to its Ordovician fauna of Laurentian affinity, now stranded on the Baltic side during opening of the North Atlantic. Here, we present a revised stratigraphic and tectonomagmatic model based on remapping, sedimentology, igneous geochemistry, Nd and Sr isotopes and geochronology. The Hølonda Group ( c. 470–461 Ma) reflects a transition from subaerial and shallow-marine deposition on a continental shelf to deeper-water sedimentation along a subsiding slope. Adakitic and mid-ocean ridge basalt type magmatism at c. 468 Ma was succeeded by benmoreitic–rhyolitic, shoshonitic, calc-alkaline and ultra-alkaline volcanism at c. 467–465 Ma. The complex magmatism followed arc–continent collision along a microcontinent outboard of Laurentia, associated with subduction polarity flip and slab rollback. This led to rifting and opening of a wide basin and its adjoining shelf on thickened orogenic lithosphere. Associated mantle upwelling and partial melting of depleted and variably metasomatized mantle occurred in a tectonomagmatic setting comparable with that of the central Mediterranean. The Hølonda–Ilfjellet setting is unique along the Caledonian–Appalachian orogen, possibly reflecting interaction with Laurentia-derived continental terranes at the northeastern end of the Taconian–Grampian orogenic tract. Supplementary material: Analytical data and supplementary figures are available at https://doi.org/10.6084/m9.figshare.c.6368922 Thematic collection: This article is part of the Caledonian Wilson cycle collection available at: https://www.lyellcollection.org/topic/collections/the-caledonian-wilson-cycle

Mantle helium in pore fluids of deep-sea sediments around the Azores archipelago

We present noble gas concentrations and helium isotope ratios measured in the pore fluids of two deep-sea sediment cores taken at the Azores Plateau. NeXe concentrations were used to estimate the atmospheric noble gas component within the pore fluids and to then determine the terrigenic helium component. The concentrations of terrigenic 3He indicate the presence of hydrothermal fluids and a mantle He component within the sediment pore space. At both sampling locations, the concentration of terrigenic helium increases with sediment depth. The observed concentration gradients suggest a diffusive transport of He through the sediments. The helium isotope ratio of the source of the terrigenic helium is characterized by a typical mid-ocean ridge basalt (MORB). These results support previous studies suggesting that the pelagic sediments surrounding the Azores host active hydrothermal systems.Our data indicate that the transport of terrigenic helium takes place diffusively over larger areas of the ocean floor, and that the concentration of terrigenic helium in the pelagic sediments increases towards the Mid-Atlantic Ridge and Terceira Rift.The data further suggests that in the Azores region the terrigenic noble gas component is only detectable in the sediment pore fluids and cannot be observed in the overlying bottom water. This highlights the potential of measuring noble gas concentrations and isotope ratios in the sediment column to identify hydrothermal activity in the ocean.

Off-rift Axis Channelized Melt and Lithospheric Metasomatism along Mid-ocean Ridges—A Case Study from Iceland on the Limits of Melt Channelling

AbstractMagmatism in Iceland is classically explained by the interaction of the mid-Atlantic ridge with the Iceland plume. The growth of Iceland through time is the result of volcanic activity at the rift axis. However, Holocene volcanism (0–11.5 ka) is not restricted to the rift zone (RZ) but also occurs off-axis, specifically in the western Snæfellsnes Volcanic Belt (SVB) and in the Southern Flank Zone (SFZ). The rift and off-axis postglacial volcanic zones are separated by a gap of ~60–80 km. While the volcanic activity of the SFZ seems correlated with the actual location of the Iceland plume, the plume relation to the SVB is uncertain. To address the origin and relationships between rift and off-rift magmas, we present new data from two transects perpendicular to the Reykjanes rift. The lavas in the SVB are characterized by transitional to alkaline compositions, with elevated incompatible trace element content. In contrast, the RZ volcanic rocks have tholeiitic compositions with trace element signatures slightly more enriched than Mid-Ocean Ridge Basalt (MORB). Rift and off-rift Iceland lavas are all characterized by positive Ba and Nb anomalies, particularly in alkaline rocks. Tholeiitic and alkaline lavas show distinct differentiation sequences, with the main difference being the delayed crystallization of plagioclase in the fractionating assemblage of alkaline magmas. We apply these sequences to calculate primary magma compositions, which are then used to constrain melting conditions. Geochemical modelling indicates that Iceland rift and off-rift magmas can be produced from a peridotitic mantle source if lithospheric processes are involved. We demonstrate that recycled crust in the form of pyroxenite is not required to generate Snæfellsnes alkaline lavas. The low solidus temperature and high productivity of pyroxenite favour early and more extensive melting producing primary magmas that are not sufficiently enriched in incompatible trace elements to explain the compositional variation of Snæfellsnes magmas. An alternative mechanism to involve pyroxenite in the source of Snæfellsnes lavas relates to the hybridization of recycled oceanic crust with peridotite, but such reacted pyroxenite requires specific compositions to reproduce the Ba and Nb anomalies. As an alternative, we suggest that Snæfellsnes alkaline lavas are the result of channelized low-degree melts produced on the periphery of the melting column at distances exceeding 65 km from the ridge axis. These melts accumulate and percolate into the lithosphere producing amphibole ± phlogopite-bearing hydrous cumulates. Incongruent melting of these cumulates via renewed magmatic activity and melt-peridotite reaction can reproduce the alkaline compositions observed in the SVB, including the Ba and Nb anomalies. Numerical simulations of melt extraction below mid-ocean ridges suggest that low-degree melts produced as far as ~65 km from the central ridge axis rise vertically to the base of the lithosphere and are then focussed towards the ridge axis in decompaction channels. We propose that these melts interact with hydrous cumulates previously formed during the development of decompaction channels at the lithosphere–asthenosphere boundary and acquire specific Ba and Nb anomalies. The mixing of these distal enriched melts with more depleted melts extracted from the central part of the melting regime explains the composition of RZ lavas. Alkaline lavas observed in the SFZ show numerous analogies with the Snæfellsnes magmas, suggesting that similar lithospheric processes control their chemistry. The high thermal regime in Iceland and thick lithosphere explains the difference between Icelandic tholeiite and typical MORB. Our results highlight the importance of mantle dynamics below mid-ocean ridges and lithospheric interaction to produce off-axis magmatism with enriched alkaline signatures.

Contrasting mechanisms and timescales of subduction and exhumation as recorded by Paleoproterozoic and late Paleozoic high-pressure granulites in the North China Craton

Abstract The North China Craton records multiple metamorphic events related to supercontinent assembly during the Paleoproterozoic, forming Columbia, and again during the late Paleozoic, forming Pangea. Here we show that the Paleoproterozoic high-pressure granulites (HPGs) formed from enriched mid-ocean ridge basalt protoliths and record a clockwise pressure-temperature-time (P–T–t) path with prograde metamorphism at 7.8–10.0 kbar and 780–820 °C, peak granulite-facies metamorphism at 12–12.3 kbar and ∼860–880 °C, and retrograde metamorphism at 8.7–9.1 kbar and 850–855 °C. Subduction initiated prior to 1.90 Ga, with final collision and orogeny at 1.88 Ga, followed by post-collision/exhumation at 1.80 Ga, defining a prolonged exhumation period (∼90 m.y.) that occurred at a slow velocity of ∼0.16 ± 0.08 mm/y. Late Paleozoic HPGs are normal mid-ocean ridge basalt type and record a near clockwise P–T–t path, with peak/post-peak amphibolitefacies metamorphism at 11.0–12.5 kbar and 860–890 °C, isothermal decompression to 7.2–7.5 kbar and 810–820 °C, and retrogression to 5.5–7.2 kbar and 805–850 °C. Subduction initiated earlier than ca. 340 Ma, exhumation and uplift initiated at 335–309 Ma and continued to 297–287 Ma. The exhumation was short-lived (∼50 m.y.) and relatively fast (0.38 ± 0.14 mm/y). When compared to granulite-facies metamorphism documented in many Paleoproterozoic HPGs, late Paleozoic HPGs appear to commonly form with an initial period of steep subduction leading to eclogite-facies metamorphism, with subsequent exhumation to middle/lower levels of the crust. Our results further reveal that the exhumation velocity for supercontinent collision was facilitated and duration shortened through time, and that the exhumation mechanism might have been controlled by subduction angle, compression pressure, and temperature.

Ocean crust accretion along a high-temperature detachment fault in the Oman ophiolite: A structural and petrological study of the Bahla massif

The Bahla massif exposes the lower crustal section of the Oman ophiolite located close to the thrust front of the Semail nappe. It is affected by intense faulting previously attributed to tectonic events that dismembered a classical ophiolitic sequence during or after the obduction. Here we show that most of this complexity is primary, inherited from syn-accretion tectonics. The crustal section is exposed in a 15 by 8 km tectonic enclave surrounded by mantle peridotite. Its northern boundary corresponds to a major, steeply dipping normal fault striking WNW-ESE, at low angle to the paleo-ridge axis. Movement along this fault was accommodated by intense plastic deformation of the crustal cumulates and adjacent mantle peridotites at temperature conditions ≥900 °C. The thickness of the deformed zone reaches several hundred meters. The flattening of the cumulate layering away from the fault is correlated to a decrease in the deformation intensity. Undeformed olivine-gabbro dykes cross-cut this “tectonic Moho” indicating that the tilting occurred before the end of the igneous activity. To the southwest, the crustal enclave is bounded by a NW-SE trending transtentional shear zone that was active in the amphibolite to greenschist facies and was intensely injected by syn- to post-kinematic gabbronorite and tonalite/trondhjemite dykes and plugs. The age of one felsic sample (95.214 ± 0.032 Ma, high-precision UPb zircon dating) is within error of the age of intrusive felsic intrusions into the mantle and lowermost axial crust from the length of the Oman ophiolite, which slightly post-dates the mean crystallization age of the Semail crust (V1 magmatism; 96.1–95.6 Ma). Other contacts are low temperature features including cataclastic faults, serpentine‑carbonate breccias and flat-lying décollements.Parent melts of the Bahla crustal cumulates were more siliceous and hydrous, i.e. more andesitic, than typical mid-ocean ridge basalt (MORB) as deduced from the frequent occurrence of early crystallizing orthopyroxene (opx) and late crystallizing amphibole. Some facies such as cumulate harzburgite and opx-troctolite have not been documented elsewhere in the Oman ophiolite and may be specific to the tectonic context in which the frontal massifs accreted. The chemical composition of the lower crustal cumulates can be accounted for by the hybridization in various proportions between MORB and a primitive andesite from a depleted source whose origin can be looked for in melts from a nascent subduction zone or from high temperature hydrothermal processes.The structure of the Bahla lower crustal section is reminiscent of the plutonic growth faults documented along present-day slow-spreading centres in both mid-ocean ridge and back arc settings. The distinctive characteristics of the Moho and lower crustal section in the Bahla massif are tentatively related to their position at the leading edge of the ophiolite, i.e. closer to the Arabian continental margin at the time of accretion than the massifs from the internal part of the ophiolite that have a more continuous and less deformed lower crust. It indicates that the style of crustal accretion may have changed during the opening of the oceanic basin from which the Oman ophiolite issued.

Origin of geochemically heterogeneous mid-ocean ridge basalts from the Macquarie Ridge Complex, SW Pacific

The Macquarie Ridge Complex (MRC), located at the Australian–Pacific plate boundary south of New Zealand, is a rugged bathymetric ridge comprising a series of submarine seamounts and Macquarie Island, the only subaerial portion of the complex. Mid-ocean ridge basalts (MORBs) from Macquarie Island show various enrichments in incompatible elements with compositions ranging from typical normal MORB to enriched MORB. However, these basalts have isotopic compositions trending towards a high μ-like (μ = 238U/204Pb; HIMU) mantle component, which is unusual for MORB-type rocks. The origin of this mantle signature is not understood, and it is unclear whether this isotopic signature is characteristic of the entire MRC or unique to Macquarie Island. Here we report new major and trace element abundances, and Sr, Nd, and Pb isotopes for samples from the MRC seamounts and from new sampling sites on Macquarie Island. The geochemical and isotopic data show that the entire MRC comprises normal to enriched MORB. Mixing modelling indicates that the heterogeneous isotopic signatures of the MRC basalts are not derived from contamination of the nearby Balleny mantle plume but have affinities with that of the Cenozoic Zealandia intraplate HIMU-like basalts. We propose that the heterogeneous geochemical signatures of the MRC basalts are derived from amphibole-bearing garnet pyroxenite veins, which is supported by the rare earth element partial melting modelling and strong correlations between Nd and Pb isotopic ratios vs La/Sm. We posit that the pyroxenite veins were generated in the oceanic lithospheric mantle, which was metasomatised by hydrous and carbonatitic fluids/melts derived either from delaminated, metasomatised Zealandia subcontinental lithosphere mantle, or from subducted material in the asthenosphere. The subducted material could be derived from ancient and/or recent subduction along the former east Gondwana margin.

Composition, crystallization conditions and genesis of sulfide-saturated parental melts of olivine-phyric rocks from Kamchatsky Mys (Kamchatka, Russia)

Sulfide liquids that immiscibly separate from silicate melts in different magmatic processes accumulate chalcophile metals and may represent important sources of the metals in Earth's crust for the formation of ore deposits. Sulfide phases commonly found in some primitive mid-ocean ridge basalts (MORB) may support the occurrence of sulfide immiscibility in the crust without requiring magma contamination and/or extensive fractionation. However, the records of incipient sulfide melts in equilibrium with primitive high-Mg olivine and Cr-spinel are scarce. Sulfide globules in olivine phenocrysts in picritic rocks of MORB-affinity at Kamchatsky Mys (Eastern Kamchatka, Russia) represent a well-documented example of natural immiscibility in primitive oceanic magmas. Our study examines the conditions of silicate-sulfide immiscibility in these magmas by reporting high precision data on the compositions of Cr-spinel and silicate melt inclusions, hosted in Mg-rich olivine (86.9–90 mol% Fo), which also contain globules of magmatic sulfide melt. Major and trace element contents of reconstructed parental silicate melts, redox conditions (ΔQFM = +0.1 ± 0.16 (1σ) log. units) and crystallization temperature (1200–1285 °C), as well as mantle potential temperatures (~1350 °C), correspond to typical MORB values. We show that nearly 50% of sulfur could be captured in daughter sulfide globules even in reheated melt inclusions, which could lead to a significant underestimation of sulfur content in reconstructed silicate melts. The saturation of these melts in sulfur appears to be unrelated to the effects of melt crystallization and crustal assimilation, so we discuss the reasons for the S variations in reconstructed melts and the influence of pressure and other parameters on the SCSS (Sulfur Content at Sulfide Saturation).

100 myr cycles of oceanic lithosphere generation in peri-Gondwana: Neoproterozoic–Devonian ophiolites from the NW African–Iberian margin of Gondwana and the Variscan Orogen

Abstract The Variscan Orogen in Iberia and the Anti-Atlas Mountains in Morocco contains a set of ophiolites formed between Neoproterozoic and Devonian times, during the complex evolution of the NW African–Iberian margin of Gondwana. During this time interval, the margin evolved from an active margin ( c. 750–500 Ma: the Reguibat–Avalonian–Cadomian arc) to the final collision with Laurussia in Devonian times to form Pangaea. In this context, one of the oldest recognized ophiolites is the Bou Azzer Ophiolite from the Anti-Atlas Mountains, dated at c. 697 Ma and containing two types of mafic rocks, the youngest of which has a boninitic composition. To the north, in the SW Iberian Massif, the Calzadilla Ophiolite contains mafic rocks also of boninitic composition dated at c. 598 Ma. Farther north, in the NW Iberian Massif, the Vila de Cruces Ophiolite is formed by a thick sequence of mafic rocks with an arc tholeiitic composition and minor alternations of tonalitic orthogneisses dated at c. 497 Ma. In the same region, the Bazar Ophiolite has a similar age of c. 495 Ma. Also in NW Iberia, there is a group of ophiolites with varied lithologies and dominant mafic rocks with arc tholeiitic composition (Careón, Purrido and Moeche ophiolites) dated at c. 395 Ma. The composition of all these peri-Gondwanan ophiolites is of supra-subduction zone type, showing no evidence of preserved mid-ocean ridge basalt type oceanic lithosphere. Consequently, these ophiolites were generated in the peri-Gondwanan realm during the opening of forearc or back-arc basins. Forearc oceanic lithosphere was promptly obducted or accreted to the volcanic arc, but the oceanic or transitional lithosphere generated in back-arc settings was preserved until the assembly of Pangaea. Based on the ages of the described ophiolites, the peri-Gondwanan realm has been a domain where the generation of oceanic or transitional lithosphere seems to have occurred at intervals of c. 100 myr. These regularly spaced time intervals may indicate cyclic events of mantle upwelling in the peri-Gondwanan mid-ocean ridges, with associated higher subduction rates at the peri-Gondwanan trenches and concomitant higher rates of partial melting in the mantle wedges involved. The origin of the apparent cyclicity for mantle upwelling in the peri-Gondwanan ocean ridges is unclear, but it could have possibly been related to episodic deep mantle convection. Cycles of more active deep mantle convection can explain episodic mantle upwelling, the transition from low- to fast-spreading type mid-ocean ridges and, finally, the dynamic context for the episodic generation of new supra-subduction zone type oceanic peri-Gondwanan lithosphere.

High fluxes of deep volatiles from ocean island volcanoes: Insights from El Hierro, Canary Islands

Abstract Basaltic volcanism contributes significant fluxes of volatiles (CO2, H2O, S, F, Cl) to the Earth’s surface environment. Quantifying volatile fluxes requires initial melt volatile concentrations to be determined, which can be accessed through crystal-hosted melt inclusions. However, melt inclusions in volatile-rich mafic alkaline basalts, such as those erupted at ocean islands, often trap partially degassed melts, meaning that magmatic volatile fluxes from these tectonic settings are often significantly underestimated. We have measured major, trace element and volatile concentrations in melt inclusions from a series of young ( 20 ka) basanites from El Hierro, Canary Islands. Our melt inclusions show some of the highest CO2 (up to 3600 ppm) and S (up to 4290 ppm) concentrations measured in ocean island basalts to date, in agreement with data from the recent 2011–2012 eruption. Volatile enrichment is observed in melt inclusions with crystallisation-controlled major element compositions and highly variable trace element ratios such as La/Yb. We use volatile-trace element ratios to calculate original magmatic CO2 contents up to 4.2 wt%, which indicates at least 65% of the original CO2 was degassed prior to melt inclusion trapping. The trace element contents and ratios of El Hierro magmas are best reproduced by 1–8% partial melting of a garnet lherzolite mantle source. Our projected CO2 (200–680 ppm) and S (265–450 ppm) concentrations for the source are consistent with upper estimates for primitive mantle. However, El Hierro magmas have elevated F/Nd and F/Cl in comparison with melts from a primitive mantle, indicating that the mantle must also contain a component enriched in F and other volatiles, most probably recycled oceanic lithosphere. Our modelled original magmatic CO2 contents indicates that, per mass unit, volatile fluxes from El Hierro magmas are up to two orders of magnitude greater than from typical mid-ocean ridge basalts and 1.5–7 times greater than from recent Icelandic eruptions, indicating large variability in the primary volatile content of magmas formed in different geodynamic settings, or even within different ocean islands. Our results highlight the importance of characterising mantle heterogeneity in order to accurately constrain both short- and long-term magmatic volatile emissions and fluxes from ocean island volcanoes.

Refractory chromitites recovered from the Eretria mine, East Othris massif (Greece): Implications for metallogeny and deformation of chromitites within the lithospheric mantle portion of a forearc-type ophiolite

The chrome ores of the abandoned Eretria mine of the East Othris ophiolite occur within a pervasively serpentinized and sheared harzburgite body. They consist of massive chromitites with mylonitic fabric in imbricate shaped pods. Modal analyses of these ores average at about 90–95% chromian spinel (Cr-spinel) and 5–10% secondary silicates. Chromian spinel compositions vary in Cr# [Cr/(Cr + Al) × 100] and Mg# [Mg/(Mg + Fe2+) × 100] from 44 to 62 and from 59 to 81, respectively. Trace element (Ti, Ni, V, Mn, Zn, Sc, Co and Ga) contents in Cr-spinel do not show significant variations from grain cores to grain boundaries. However, Cr-spinel compositions show depletions in Ti, Zn and Sc when compared to the composition of accessory Cr-spinel from typical mid-ocean ridge basalts (MORB). Mineral inclusions hosted in Cr-spinel comprise a range of (hydrous and anhydrous) silicate and base metal (BM) minerals occasionally intergrown with phosphate minerals and rare intermetallic compounds. A number of these inclusions have Cr-spinel rims with higher Cr# (63–68) than those of the enclosing Cr-spinel grains.The absence of dunite sheaths around chromitites is interpreted as an artifact of dunite structural obliteration during prolonged ductile shearing within harzburgite. The microtextural characteristics of a number of inclusions in Cr-spinel imply that they were initially fully molten. Furthermore, primary hydrosilicate (amphibole, phlogopite) inclusions in Cr-spinel indicate that chromitites crystallized from a water-bearing melt. Chromian spinel rims around silicate inclusions probably represent early crystals generated from a primitive magma produced by melting of a depleted mantle source.Geochemical calculations demonstrate that the parental melts of chromitites had intermediate affinity between MORB and arc-related magmas. Our preferred hypothesis for the genesis of the Eretria chromitites is that they were formed from a melt originated within the hydrated mantle wedge beneath a nascent forearc basin during subduction initiation.

Mantle Source and Magmatic Evolution of the Dying Spreading Ridge in the South China Sea

AbstractThe genesis of seamount chains along fossil spreading ridges reflects the mantle melting dynamics of dying spreading center. The South China Sea developed a seamount chain along its fossil ridge shortly after cessation of spreading. International Ocean Discovery Program Expedition 349 has recovered three volcanic layers, a shallow volcanic breccia layer and two deeper (upper and lower sections) basalt layers, at Site U1431 near the fossil ridge of the South China Sea. Despite the mid‐ocean ridge basalt (MORB)‐like geochemistry of the lower and upper section basalts, they show distinct geochemical differences that indicate a change of mantle source and a transition from spreading to intraplate volcanism. While the lower section basalts could reflect the last stage volcanism before the cessation of ridge spreading, the upper section basalts with whole‐rock MgO up to ~20 wt.% were formed by intraplate volcanism with significant olivine accumulation once the spreading center had become inactive. The MORB type basalts at Site U1431 have Hawaii‐like high olivine Ni and Fe/Mn and low olivine Ca and Mn and bulk‐rock low CaO that are distinctly different from normal global MORBs, suggesting an anomalous mantle source in lithology. We suggest that an eclogite‐/pyroxenite‐rich component, possibly sourced from the Hainan hot spot, played a fundamental role in the transition from spreading to intraplate volcanism of the dying spreading ridge of the South China Sea.

Rapid transition from continental breakup to igneous oceanic crust in the South China Sea

Continental breakup represents the successful process of rifting and thinning of the continental lithosphere, leading to plate rupture and initiation of oceanic crust formation. Magmatism during breakup seems to follow a path of either excessive, transient magmatism (magma-rich margins) or of igneous starvation (magma-poor margins). The latter type is characterized by extreme continental lithospheric extension and mantle exhumation prior to igneous oceanic crust formation. Discovery of magma-poor margins has raised fundamental questions about the onset of ocean-floor type magmatism, and has guided interpretation of seismic data across many rifted margins, including the highly extended northern South China Sea margin. Here we report International Ocean Discovery Program drilling data from the northern South China Sea margin, testing the magma-poor margin model outside the North Atlantic. Contrary to expectations, results show initiation of Mid-Ocean Ridge basalt type magmatism during breakup, with a narrow and rapid transition into igneous oceanic crust. Coring and seismic data suggest that fast lithospheric extension without mantle exhumation generated a margin structure between the two endmembers. Asthenospheric upwelling yielding Mid-Ocean Ridge basalt-type magmatism from normal-temperature mantle during final breakup is interpreted to reflect rapid rifting within thin pre-rift lithosphere.

Tectonic evolution of syn- to late-orogenic sedimentary–volcanic basins in the central Norwegian Caledonides

We present new structural, geochemical and U–Pb zircon data from syn- to late-orogenic sedimentary–volcanic basins in the southwestern part of the Trondheim Nappe Complex, central Norwegian Caledonides. In this area, a succession of enriched mid-ocean ridge basalt type metabasalt, jasper, ribbon chert with associated sandstone and conglomerate, and green siltstone is interpreted to represent volcanism and sedimentation in a hitherto little-known spreading-dominated tectonic environment. This environment is different from the suprasubduction-zone ophiolite setting dominating the Iapetus rock record elsewhere in the Scandinavian Caledonides. This volcanic and sedimentary succession was overturned and isoclinally folded in a pre-427 Ma orogenic phase. Post-427 Ma cross-bedded sandstones were deposited on the eroded surface of the previously deformed rocks, representing a rare example of a late Silurian or younger sedimentary basin within the Scandinavian Caledonides. The cross-bedded sandstones are intercalated with and/or overlain by post-427 Ma intermediate volcanic or subvolcanic rocks of calc-alkaline composition, representing a hitherto unknown volcanic phase within the Trondheim Nappe Complex and elsewhere within the Scandinavian Caledonides. Their particular geochemical signature could be the result of late-stage subduction-zone volcanism just prior to the onset of continent–continent collision between Baltica and Laurentia, or much younger post-collisional extensional melting with inherited subduction signatures. Supplementary material: A description of analytical methods and a table of geochronological data from LA-ICP-MS analysis of zircons are available at https://doi.org/10.6084/m9.figshare.c.3994605 .

Elemental and isotopic (Nd-Sr-O) geochemistry of eclogites from the Zamtyn-Nuruu area (SW Mongolia): Crustal contribution and relation to Neoproterozoic subduction-accretion events

We present the detailed mineralogical, geochemical (major and trace element), bulk Nd and Sr and mineral O isotope data for eclogites, associated orthogneisses and metasedimentary rocks from the recently discovered eclogite-bearing complex of the Zamtyn-Nuruu range (SW Mongolia). Trace element studies reveal the enrichment of eclogites with LILE and LREE relative to typical mid-ocean ridge basalts at similar levels of HREE and HFSE but without a clear arc-derived Nb minimum. The eclogites have relatively narrow range of mostly radiogenic εNd(T) values (+2.3 to +3.7 as back-calculated for 550 Ma) and model age TDM of 1.47–1.77 Ga at a wide range of initial 87Sr/86Sr ratio due to variable LILE mobilization in pre- or synmetamorphic processes. The geochemical and isotope data indicate the variably enriched MORB-like protolith for eclogites that have their variable composition through differentiation of precursor melts, slightly enriched mantle source and/or variable degree of crustal contamination. The mostly siliciclastic eclogite-hosting metasediments are likely derived from the intra-continental riftogenic basin, whereas the medium-pressure metapelites of the Maykhan Tsakhir formation originate from deeper passive margin sedimentation. Their Mesoproterozoic two-stage model age TDM−2ST of 1.49–1.63 Ga and crustal εNd(T) values (−3.5 to −5.3) significantly differ from the Zamtyn Nuruu complex rocks and indicate a mixed Nd source likely resembled from the juvenile Neoproteorozoic magmatism with depleted Nd signatures and the older Meso- or Paleoproterozoic crustal substrate. Contrastingly, eclogite-hosting gneisses exhibit the εNd(T) of the ancient crust (−12.9) and Paleoproterozoic model age TDM−2ST of 2.22 Ga. Both eclogites and metasediments evidently exhibit an input from the ancient crustal source that may be represented by orthogneisses of the Alag Khadny complex. Oxygen isotope data (δ18O of garnets mostly within +5.5 to +6.6) at high Fe3+/ΣFe ratio of bulk rocks (0.15–0.21) indicate variable but mostly limited interaction of precursor rocks with oceanic water, degassing at shallow crustal level or at the surface or relatively more oxidized (back-arc or subarc) mantle source. Considering the limited trace element evidence for the input from continental crust, generally elevated Fe3+/ΣFe for samples showing different retrograde alteration degrees, and no or limited δ18O evidence of pre-metamorphic interaction with oceanic water, we may suggest that primitive low-K tholeitic basalts close to T-MORB tholeites derived from a heterogeneously enriched mantle source of a rifted continental margin as precursor rocks for the studied eclogites. As a consequence of the geological structure and geochemical evidence, connection of rifting to the Rodinia break-up is proposed.

Compositional fingerprints of chromian spinel from the refractory chrome ores of Metalleion, Othris (Greece): Implications for metallogeny and deformation of chromitites within a “hot” oceanic fault zone

The chrome ores of the retired Metalleion mine of the Othris ophiolite are hosted in a small volume of a pervasively serpentinized, tabular harzburgite body. These ores have been studied to determine their geological mode of occurrence, mineralogy and chromian spinel (Cr-spinel) chemistry. The ores consist of massive chromitite (85–95% modal Cr-spinel) with mylonitic fabric in imbricate-shaped pods. Chromian spinel displays a limited range in Cr# [Cr/(Cr+Al)×100=53–63] and Mg# [Mg/(Mg+Fe2+)×100=59–73] and low TiO2 content (≤0.11wt%). Minor- (Ti, Ni, V, Mn and Zn) and trace-element (Sc, Co and Ga) concentrations do not show any significant variations from Cr-spinel cores to boundaries and were not considerably modified by post-magmatic processes. However, Cr-spinel compositions show slight enrichments in Zn and V, and depletions in Ti and Sc when compared to the composition of chromite from the East Pacific Rise mid-ocean ridge (MOR) basalts. The composition of Cr-spinel from the Metalleion chromitites is quite anomalous on a global perspective as these ores are not clearly associated to a suprasubduction zone (SSZ) or MOR chemistry.Field data indicate that the Metalleion chromitites lack remnant dunite envelopes due to prolonged shearing within the deforming harzburgite host and are constrained in location to a ductile-brittle shear zone that correlates with the transforming direction of the Domokos oceanic fault. Compositional data indicate that chromitites equilibrated with ambient harzburgite via a melt-peridotite interaction process followed by melt mixing. Geochemical calculations demonstrate that the parental magmas of the Metalleion chromitites had intermediate affinity between typical mid-ocean ridge basalts (MORB), island arc tholeiites (IAT) and boninites. We conclude that these melts originated within a hydrated and oxidized mantle wedge beneath an infant forearc basin connected by a transform fault to an active MOR.

High water content in primitive mid-ocean ridge basalt from Southwest Indian Ridge (51.56ºE): Implications for recycled hydrous component in the mantle

The Southwest Indian Ridge (SWIR) is an ultraslow spreading end-member of mid-ocean ridge system and is characterized by weak or even an absence of magmatism. The segment between Indomed (ITF) and Gallieni (GTF) transform faults in the SWIR, however, displays extremely magmatic accretion with an unusual thick crust (up to 9.5 km). Although H2O is present in trace amounts in the mantle, it has a strong influence on mantle melting and magmatism in the shallow crust. The mid-ocean ridge basalts (MORB) worldwide show strong variation in H2O contents, but with a nearly uniform H2O/Ce ratio. Regionally distinctive H2O contents and H2O/Ce ratios are inferred to be related to the H2O variation in the source and can be used to constrain the mantle heterogenity. In this study, we measured the H2O and trace elements of clinopyroxene phenocrysts from one basalt dredged from the ITF-GTF segment, SWIR (51.56°E). The estimated H2O content (1.3 wt.%±0.3 wt.%) in the primitive ITF-GTF basaltic melt is much higher than that in typical MORB samples, but similar to oceanic island basalts (OIB) and back-arc basalts (BABB). In addition, the calculated H2O/Ce ratio (1 672-4 990) are extremely high, bearing “arc-like” signature. This study provides evidence that arc-related hydrous components are involved in the mantle source beneath the ITF-GTF ridge segment. It further lends support to the hypothesis that the mantle beneath the central SWIR may have experienced an ancient hydrous melting event in an arc terrain prior to or during the closure of the Mozambique Ocean in the Neoproterozoic.