Typical Mid-ocean Ridge Basalts Research Articles

High water content in primitive mid-ocean ridge basalt from Southwest Indian Ridge (51.56ºE): Implications for recycled hydrous component in the mantle

The Southwest Indian Ridge (SWIR) is an ultraslow spreading end-member of mid-ocean ridge system and is characterized by weak or even an absence of magmatism. The segment between Indomed (ITF) and Gallieni (GTF) transform faults in the SWIR, however, displays extremely magmatic accretion with an unusual thick crust (up to 9.5 km). Although H2O is present in trace amounts in the mantle, it has a strong influence on mantle melting and magmatism in the shallow crust. The mid-ocean ridge basalts (MORB) worldwide show strong variation in H2O contents, but with a nearly uniform H2O/Ce ratio. Regionally distinctive H2O contents and H2O/Ce ratios are inferred to be related to the H2O variation in the source and can be used to constrain the mantle heterogenity. In this study, we measured the H2O and trace elements of clinopyroxene phenocrysts from one basalt dredged from the ITF-GTF segment, SWIR (51.56°E). The estimated H2O content (1.3 wt.%±0.3 wt.%) in the primitive ITF-GTF basaltic melt is much higher than that in typical MORB samples, but similar to oceanic island basalts (OIB) and back-arc basalts (BABB). In addition, the calculated H2O/Ce ratio (1 672-4 990) are extremely high, bearing “arc-like” signature. This study provides evidence that arc-related hydrous components are involved in the mantle source beneath the ITF-GTF ridge segment. It further lends support to the hypothesis that the mantle beneath the central SWIR may have experienced an ancient hydrous melting event in an arc terrain prior to or during the closure of the Mozambique Ocean in the Neoproterozoic.

Geochemistry and Sr–Nd isotope composition of Carboniferous volcanic rocks of the Jueluotage Orogenic Belt: implications for the tectonic evolution of Eastern Tianshan, China

ABSTRACTThe major and trace element, and Sr–Nd isotopic compositions of the Carboniferous Qi’eshan, Wutongwozi, and Yamansu volcanic rocks from the northern and southern parts of the Jueluotage Orogenic Belt in East Tianshan, China, were analysed to understand their genesis and geodynamic implications. The early Carboniferous Qi’eshan basalts are characterized by high Al2O3, with La/Sm (1.38–1.79) and Ba/La (27.06–58.76) values higher than those of typical normal mid-ocean ridge basalt. They are relatively enriched in large ion lithophile elements (LILE) and light rare earth elements (LREE), and depleted in high field strength elements. Overall, their initial Nd–Sr isotopic compositions are εNd(t) = (5.6–7.0) and Isr = 0.70397–0.70429, implying the magma originated from a mantle wedge source that was metasomatized by subduction-related fluids. In contrast, the late Carboniferous Wutongwozi basalts have lower Ba/La (4.86–12.82), La/Nb (0.87–2.45), and LILE concentrations. They have the isotopic characteristics of depleted asthenosphere, relatively high and heterogeneous εNd(t) (9.3–9.4), and high Isr (0.70471–0.70533). Thus, the late Carboniferous Wutongwozi basalts may have been derived from the partial melting of mantle sources during asthenospheric upwelling. The early Carboniferous Yamansu acid volcanic rocks are characterized by high Mg# (46–48) and Lu/Y (~0.15), and low K2O/Na2O (0.01–0.20), similar to M-type granites. However, their εNd(t) (5.0–5.5) and Isr (0.70642–0.70768) values are lower than those of depleted mantle, indicating they were contaminated by lower crustal material. The magma source originated from a mantle-derived magma that was contaminated by middle Tianshan massif in a continental margin arc setting. Based on the results and previous field-based studies, we conclude that the Carboniferous volcanics in the Jueluotage Orogenic Belt formed in a complex trench–arc–basin setting in the Kuguertage–Aqikuduke Suture Zone.

The deep distributions of helium isotopes, radiocarbon, and noble gases along the U.S. GEOTRACES East Pacific Zonal Transect (GP16)

We report the deep distributions of noble gases, helium isotopes, and radiocarbon measured during the U.S. GEOTRACES GP16 East Pacific Zonal Transect between 152 and 77°W at 12–15°S in the South Pacific. The dominant feature is an intense tongue of hydrothermal effluent that extends > 4000 km westward from the East Pacific Rise (EPR) at ~ 2500 m depth. The patterns reveal significant “downstream” variations in water mass structure, advection, and mixing that belie the simple perception of a continuous plume extending westward from the EPR. For example, one feature observed at 120°W, 14°S has tracer signatures that are consistent with a water mass originating from an area as much as 2000 km south of this section, suggesting a quasi-permanent northward flow on the western flank of the EPR. Helium isotope variations in the plume show a uniquely high 3He/4He source in the tongue compared with typical mid-ocean ridge basalts (MORB), consistent with the anomalously high ratios observed in MORB glasses from the EPR segment just south of this transect. The water column data also reveal that the background 3He/4He east of the EPR is significantly lower than values characteristic of MORB, suggesting an additional, more geographically distributed radiogenic 4He flux of order 107 mol/y into the deep Pacific. In the western end of the section, incoming bottom waters have relatively less hydrothermal hydrothermal helium, more radiocarbon, and more oxygen, as well as negative saturation anomalies for the heavy noble gases (Ar, Kr, and Xe). During the basin-scale upwelling of this water, diapycnal mixing serves to erase these negative anomalies. The relative magnitudes of the increases for the heavy noble gases (Ar, Kr, and Xe) are quantitatively consistent with this process. This leads us to estimate the relatively smaller effects on He and Ne saturations, which range from near zero to 0.2% and 0.3% respectively. With this information, we are able to refine our estimates of the magnitude of 3He and 4He excesses and the absolute 3He/4He ratio of non-atmospheric helium introduced into deep Pacific waters.

Enriched mid–ocean ridge basalt–type geochemistry of basalts and gabbros from the Nikoro Group, Tokoro Belt, Hokkaido, Japan

Enriched mid–ocean ridge basalt–type geochemistry of basalts and gabbros from the Nikoro Group, Tokoro Belt, Hokkaido, Japan

Möwe Bay Dykes, Northwestern Namibia: Geochemical and geochronological evidence for different mantle source regions during the Cretaceous opening of the South Atlantic

Dyke emplacement in the course of Paraná-Etendeka volcanism in northwestern Namibia has been considered as a short-lived event related to a specific magma source at approximately 135–130Ma. New geochemical, whole rock Sr-Nd-Pb isotope data and 40Ar/39Ar ages reveal that at least three geochemically and isotopically different tholeiitic dyke generations, with intrusion ages of 135.2±0.7, 124.1±0.8Ma and 113.0±0.5Ma, can be distinguished in the Möwe Bay area, Skeleton Coast of northwestern Namibia. Distinct mantle source components were identified in the petrogenesis of the various dyke generations. Magma composition of the two older dyke suites, both of which were emplaced in a tectonic setting dominated by E-W extension, evolved from a within-plate to an enriched mid-ocean ridge basalt type. Contamination by continental crust and/or lithospheric mantel is suggested by a high 238U/204Pb-value (=μ2) of 9.97, which is typical of the Kalahari Craton. The third dyke generation, which intruded in a tectonic regime dominated by SE-NW extension, corresponds to high-Ti ocean island-type basalt with unradiogenic isotopic compositions derived from a mantle source with a μ2-value of 9.35.The formation of the older dykes is attributed to the presence of a thermal anomaly in the upper sublithospheric mantle. This anomaly was most likely caused by the peripheral part of a mantle plume that impinged at the base of the lithosphere and caused erosion of the subcontinental mantle lithosphere and melting above the plume head. The initial break-up of SW Gondwana and the formation of early oceanic crust were most likely due to passive rather than active rifting. Continued plume upwelling facilitated by progressive thinning of SW-Gondwana crust led to the formation of the younger, c. 113Ma old dykes, which are chemically and isotopically identical to coeval rocks from the northeastern portion of the Walvis Ridge and thus are interpreted as onshore expressions of the Tristan-Gough plume head at that time. The difference in the dominant extension directions of the older and the younger dyke generations can be explained by rotation induced by the Aptian/Albian opening of the Equatorial Central Atlantic, accompanied by a substantial increase in the South Atlantic spreading rate.

Rifting under steam—How rift magmatism triggers methane venting from sedimentary basins

Abstract During opening of a new ocean, magma intrudes into the surrounding sedimentary basins. Heat provided by the intrusions matures the host rock, creating metamorphic aureoles potentially releasing large amounts of hydrocarbons. These hydrocarbons may migrate to the seafloor in hydrothermal vent complexes in sufficient volumes to trigger global warming, e.g., during the Paleocene-Eocene Thermal Maximum (PETM). Mound structures at the top of buried hydrothermal vent complexes observed in seismic data off Norway were previously interpreted as sediment volcanoes, and the amount of released hydrocarbon was estimated based on this interpretation. Here, we present new geophysical and geochemical data from the Gulf of California suggesting that such mound structures could in fact be edifices constructed by the growth of black smoker–type chimneys rather than sediment volcanoes. We have evidence for two buried and one active hydrothermal vent systems outside the rift axis. The active vent releases fluids of several hundred degrees Celsius containing abundant methane, mid-ocean ridge basalt–type helium, and precipitating solids up to 300 m high into the water column. Our observations challenge the idea that methane is emitted slowly from rift-related vents. The association of large amounts of methane with hydrothermal fluids that enter the water column at high pressure and temperature provides an efficient mechanism to transport hydrocarbons into the water column and atmosphere, lending support to the hypothesis that rapid climate change such as during the PETM can be triggered by magmatic intrusions into organic-rich sedimentary basins.

Geology of metamorphic rocks deriving from paleohydrothermal systems in the Mesoproterozoic Serra do Itaberaba Group, São Paulo State, southeastern Brazil

ABSTRACTIn the central portion of the Ribeira fold belt, southeastern Brazil, the Mesoproterozoic volcanosedimentary Serra do Itaberaba Group was deposited in an ocean basin having normal mid-ocean ridge basalt type basalts that evolved to a back-arc environment. This succession was affected by two medium-grade regional metamorphic events and a third low-grade retrometamorphic event. This geological map covers an area of approximately 16 km2, between 23°16′41.824″ and 23°18′47.744″ latitudes S, and 46°20′57.056″ and 46°23′18.933″ longitudes W, as a scale of 1:5000. It encompasses the metamorphic products of tectonically deformed paleohydrothermal systems that developed in a back-arc environment, which are spatially and genetically linked to small metamorphosed andesitic-rhyolitic bodies. These systems were responsible for lixiviation of Ca and alkali in deeper parts, carbonatization in shallower parts, and a first large chloritic alteration zone (CZ1) that was crosscut by small chloritic (CZ2), silicification, and advanced argillic alteration zones. The metamorphic products of CZ1 are cummingtonite/anthophyllite rocks, whereas those related to CZ2 are Mg-rich chloritites. The metamorphic products of silicification and advanced argillic alteration zones are rocks composed of quartz ± specularite and of corundum, margarite, sericite, tourmaline, rutile, and Ca-plagioclase, respectively. Those associated with Ca and alkali depletions are garnet-hornblende amphibolites, whereas those related to carbonatization zones are composed of diopside, hornblende, tremolite/actinolite, carbonate, clinozoisite/epidote, plagioclase, and quartz. Cummingtonite/anthopyllite rocks and Mg-rich chloritites are similar to those associated with metamorphosed Kuroko-type volcanogenic massive sulfide deposits, whereas rocks composed of corundum, margarite, sericite, tourmaline, rutile, and Ca-plagioclase are genetically associated with oceanic high-sulfidation magmatic-hydrothermal gold mineralization.

Petrogenesis and structure of oceanic crust in the Lau back-arc basin

Oceanic crust formed along spreading centers in the Lau back-arc basin exhibits a dramatic change in structure and composition with proximity to the nearby Tofua Arc. Results from recent seismic studies in the basin indicate that crust formed near the Tofua Arc is abnormally thick (8–9 km) and compositionally stratified, with a thick low-velocity (3.4–4.5 km/s) upper crust and an abnormally high-velocity (7.2–7.4+ km/s) lower crust (Arai and Dunn, 2014). Lava samples from this area show arc-like compositional enrichments and tend to be more vesicular and differentiated than typical mid-ocean ridge basalts, with an average MgO of ∼3.8 wt.%. We propose that slab-derived water entrained in the near-arc ridge system not only enhances mantle melting, as commonly proposed to explain high crustal production in back-arc environments, but also affects magmatic differentiation and crustal accretion processes. We present a petrologic model of Lau back-arc crustal formation that successfully predicts the unusual crustal stratification imaged in the near-arc regions of the Lau basin, as well as the highly fractionated basaltic andesites and andesites that erupt there. Results from phase equilibria modeling using MELTS indicate that the high water contents found in near-arc parental melts can lead to crystallization of an unusually mafic, high velocity cumulate layer. Best-fit model runs contain initial water contents of ∼0.5–1.0 wt.% H2O in the parental melts, and successfully reproduce geochemical trends of the erupted lavas while crystallizing a cumulate assemblage with calculated seismic velocities consistent with those observed in the near-arc lower crust. Modeled residual melts are also lower density than their dry equivalents, which aids in melt segregation from the cumulate layer. Low-density, water-rich residual melts can lead to the eruption of vesicular lavas that are unusually evolved for an oceanic spreading center.

Short Length Scale Oxygen Isotope Heterogeneity in the Icelandic Mantle: Evidence from Plagioclase Compositional Zones

Using a new high-resolution dataset, this study presents evidence for short length scale 18O/16O heterogeneity in the mantle source region of young (age ≲12 ka bp) Icelandic basalts. The dataset comprises secondary ion mass spectrometry determinations of 18O/16O in single compositional zones of plagioclase crystals from the primitive Borgarhraun flow in northern Iceland, along with trace and major element data from the same zones. The presence of mantle under Iceland with δ18O below typical mid-ocean ridge basalt (MORB) values of ∼5·5 ± 0·3‰ (VSMOW) has previously been disputed, because variability in δ18O in many Icelandic basalts is also known to be caused by the interaction of basaltic melts with crustal lithologies that have been altered by low-δ18O meteoric water. Primitive basalt flows, such as Borgarhraun, and their macrocrysts are the most likely candidates to retain a mantle δ18O signature. However, the role of crustal processes in generating the low δ18O in olivine crystals from these flows has not unequivocally been ruled out. By making intra-crystal analyses in Borgarhraun plagioclase it has been possible in this study to obtain a detailed record of the chemical and isotopic compositions of the melts that crystallized the plagioclase zones. The variability observed in trace element compositions of the early crystallized anorthitic plagioclase zones (80·9–89·4 mol % anorthite) is firstly shown to arise from melt compositional variability, and equilibrium melt concentrations of Sr, La and Y are then calculated from the crystal concentrations of these elements using carefully selected partition coefficients. The ranges of incompatible trace element ratios (La/Y, Sr/Y) in these equilibrium melts reflect a range of compositions of fractional mantle melts, a result that is in agreement with previous proposals for the cause of variability in trace element indices of Borgarhraun olivine-hosted melt inclusions and clinopyroxene compositional zones. Correlations observed between La/Y and Sr/Y in the melts in equilibrium with the Borgarhraun plagioclase zones and the δ18O of these zones therefore support the hypothesis that the mantle under Iceland is heterogeneous in 18O/16O. Such correlations have not previously been observed in intra-crystal data from Iceland, and provide strong evidence that mantle material with abnormally low δ18O may exist in the form of readily fusible heterogeneities alongside ambient mantle with MORB-like δ18O (≈+5·5‰) on a length scale of <100 km. The lowest δ18O of plagioclase that is attributed to a mantle origin in this study is 4·5 ± 0·4‰, equating to a melt equivalent value of 4·3 ± 0·5‰ or an olivine equivalent value of 3·8 ± 0·5‰.

Is the ‘Azores Hotspot’ a Wetspot? Insights from the Geochemistry of Fluid and Melt Inclusions in Olivine of Pico Basalts

The concept of an 'Azores mantle plume' has been widely debated, and the existence of an Azores hotspot questioned. In an effort to shed new light on this controversy, we present He isotope and major, trace and volatile element compositions for basaltic scoriae from five monogenetic cones emplaced along the fissure zone of Pico Island, the youngest island of the Azores archipelago. The bulk scoriae and lavas are moderately alkaline basalts, and their He isotope ratios, determined on olivine crystals, vary between 10*2 and 11*1 ± 0*1 Ra. In contrast, melt inclusions hosted in olivine (Fo76-83*5) span a large range of compositions (K2O = 0*7-1*7 wt %; Ce = 32-65 ppm; Nb = 21-94 ppm), which extends the compositional field of lavas erupted along the Pico fissure zone. This chemical evolution is predominantly controlled by polybaric fractional crystallization. Most melt inclusions share similar enrichments in large ion lithophile and light rare earth elements, and trace element ratios (La/Sm, La/Yb, Sr/Nd, Ta/Th, Zr/Y) with their bulk-rocks. Only a few of them differ in their lower contents of incompatible elements and La/Sm, Li/Ta and Na/K ratios, a feature that is ascribed to distinct conditions of melting. As a whole, the melt inclusions preserve high and variable volatile contents, and contain up to 1*8-2*0 wt % of H2O and 0*4 wt % of CO2. The total fluid pressures, retrieved from the dissolved CO2 and H2O concentrations, and the PCO2 from fluid inclusions, indicate magma ponding and crystallization at the crust-mantle boundary (ca. 18 km deep). The H2O/Cl and H2O/Ce ratios in the inferred parental undegassed basalts of the Pico fissure zone average 0*036 ± 0*006 and 259 ± 21, respectively. The latter value is significantly higher than that reported for typical mid-ocean ridge basalts from the southern Mid-Atlantic Ridge, but is similar to published ratios for submarine undegassed basalts from the Azores platform. Combining the calculated compositions of Pico primary magmas formed by low degrees of melting with recent geophysical data for the Azores, we propose a model for Azores magma generation involving the decompression melting of a water-enriched mantle domain (H2O = 680-570 ppm) with an estimated temperature excess of ≤120°C with respect to the Mid-Atlantic Ridge.

Depleted Basaltic Lavas from the Proto-Iceland Plume, Central East Greenland

New geochemical and isotopic data are presented for volumetrically minor, depleted low-Ti basalts that occur in the Plateau Basalt succession of central East Greenland (CEG), formed during the initial stages of opening of the North Atlantic at 55 Ma. The basalts have mid-ocean ridge basalt (MORB)-like geochemistry (e.g. depleted light rare earth elements) and are distinct from the high-Ti lavas that dominate the sequence. Rare earth element geochemistry implies derivation from a source more depleted than the typical MORB source, and suggests polybaric melting and contributions from both spinel- and garnet-facies mantle. The low-Ti basalts have Sr^Nd^ Pb^Hf isotopic characteristics that are similar to those of depleted magmas from Iceland (e.g. Theistareykir) and adjacent ridges (Kolbeinsey and Reykjanes) and distinct from global MORB (e.g. negative 207 Pb, and Hf and Nd isotope compositions that plot above the mantle reference line). Isotope and trace element data indicate the involvement of two depleted source components. One component has isotopic compositions similar to other depleted components identified in the North Atlantic and has high Rb/Zr and Ba/Nb. The second is isotopically less depleted with lower Rb/Zr and Ba/ Nb. Small degrees of crustal contamination (51%) by both amphibolitic and granulitic crust result in relatively large changes in isotopic composition (c .1 % lower for 206 Pb/ 204 Pb and 0·1% higher for 87 Sr/ 86 Sr depending on the contaminant). Negative Nb suggests a MORB affinity for the low-Ti magmas; however, they are distinguished from global normal (N)-MORB on the basis of vertical deviations from the Northern Hemisphere Reference Line (negative 207 Pb and positive 208 Pb), and relative enrichments in Ba, Sr and Pb. The isotopic compositions of the low-Ti CEG basalts suggest correlation with modern depleted components beneath Iceland and adjacent ridges, considered to be derived from upper mantle sources polluted by the Iceland plume. However, small positive Pb peaks when normalized to MORB, and lower Nb distinguish the CEG low-Ti basalts from depleted Icelandic compositions. The lower Nb (5 0) and 87 Sr/ 86 Sr, and suggestion of higher 206 Pb/ 204 Pb in crustally uncontaminated parental melts imply a closer affinity to compositions from the oceanic ridges surrounding Iceland (especially the Reykjanes Ridge), yet they are subtly distinct on the basis of available trace element data. We suggest that this depleted component was an integral part of the plume that melted primarily during the rapid lithospheric uplift and extension associated with continental break-up.

Geochemistry of basaltic lavas from the southern Lau Basin: input of compositionally variable subduction components

We present new major element, trace element, and Sr–Nd–Pb isotope data for 18 basaltic lavas and six glasses collected in situ from the Eastern Lau Spreading Centre (ELSC) and the Valu Fa Ridge (VFR). All lava samples are aphanitic and contain rare plagioclase and clinopyroxene microlites and microphenocrysts. The rocks are sub-alkaline and range from basalt and basaltic andesite to more differentiated andesite. In terms of trace element compositions, the samples are transitional between typical normal mid-ocean ridge basalt (MORB) and island arc basalt. Samples from the VFR have higher large ion lithophile element/high field strength element ratios (e.g. Ba/Nb) than the ELSC samples. VFR and ELSC Sr–Nd isotopic compositions plot between Indian MORB and Tonga arc lavas, but VFR samples have higher 87Sr/86Sr for a given 143Nd/144Nd ratio than ELSC analogues. The Pb isotopic composition of ELSC lavas is more Indian MORB-like, whereas that of VFR lavas is more Pacific MORB-like. Our new data, combined with literature data for the Central Lau Spreading Centre, indicate that the mantle beneath the ELSC and VFR spreading centres was originally of Pacific type in composition, but was displaced by Indian-type mantle as rifting propagated to the south. The mantle beneath the spreading centres also was variably affected by subduction-induced metasomatism, mainly by fluids released from the altered, subducting oceanic crust; the influence of these components is best seen in VFR lavas. To a first approximation, the effects of underflow on the composition and degree of partial melting of the mantle source of Lau spreading centre lavas inversely correlate with distance of the spreading centres from the Tonga arc. Superimposed on this general process, however, are the effects of the local geographic contrasts in the composition of subduction components. The latter have been transferred mainly by dehydration-generated fluids into the mantle beneath the Tonga supra-subduction zone.

Opening and evolution of the South China Sea constrained by studies on volcanic rocks: Preliminary results and a research design

The South China Sea (SCS) is characterized by abundant seamounts, which provide important information about the evolution of the SCS and related deep processes. Cenozoic volcanism in the SCS and its surroundings comprises three stages relative to the spreading of the SCS: pre-spreading (>32 Ma), syn-spreading (32-16 Ma), and post-spreading (<16 Ma). The pre-spreading magmatism predominantly occurs on the northern margin of the SCS and in South China coastal areas and shows a bi-modal affinity. The syn-spreading magmatic activity was very limited on the periphery of the SCS, but may be concentrated in the SCS. However, seafloor samples of this stage are not available yet because of overlying thick sedimentary deposits. Post-spreading magmatism is widespread in the central and southwest sub-basins of the SCS, Hainan Island, Leizhou Peninsula, Thailand, and Vietnam. These are mainly alkali basalts with subordinate tholeiites, and display OIB-type geochemical characteristics. The Dupal isotope anomaly and presence of high-magnesian olivine phenocrysts suggests their possible derivation from the Hainan mantle plume. The temporal and spatial distribution of Cenozoic volcanism in the SCS and its surroundings may be accounted for either by plate stress re-organization before and after SCS spreading, or by ridge suction of plume flow during opening of the SCS. If the latter is the case, the volcanic rocks within the SCS basin may not be typical mid-ocean ridge basalts (MORB). It remains puzzling, however, that the transition between the South China continental margin and the SCS basin does not have features typical of a volcanic rifted margin. Clearly, the relationship between mantle plume and SCS opening needs further evaluation. A better understanding of the link between deep processes and opening of the SCS not only requires enhanced studies on igneous petrogenesis, but also is heavily dependent on systematic sampling of seafloor rocks.

High-Pressure Tourmaline Formation and Fluid Activity in Fe–Ti-rich Eclogites from the Kreuzeck Mountains, Eastern Alps, Austria

A tourmaline-bearing eclogite from the Kreuzeck Mountains, Eastern Austria, is described in this study as part of an eclogite suite situated SE of theTauern Window.These rocks formed during Eoalpine high-P metamorphism of the Austroalpine basement. They have high and variable Fe, Ti, P, Zr and Sr contents and unlike other Eoalpine eclogites their Ti^V^Zr^P^Nb^Y systematics indicates a within-plate rather than mid-ocean ridge basalt type environment for the formation of their protoliths. Major and trace element variations are consistent with progressive differentiation of a mafic magma with Fe^Ti oxide and apatite as important igneous phases and with metasomatic addition of K and Sr. The eclogites

The H2O solubility of alkali basaltic melts: an experimental study

Experiments were conducted to determine the water solubility of alkali basalts from Etna, Stromboli and Vesuvius volcanoes, Italy. The basaltic melts were equilibrated at 1,200°C with pure water, under oxidized conditions, and at pressures ranging from 163 to 3,842 bars. Our results show that at pressures above 1 kbar, alkali basalts dissolve more water than typical mid-ocean ridge basalts (MORB). Combination of our data with those from previous studies allows the following simple empirical model for the water solubility of basalts of varying alkalinity and fO2 to be derived: $$ {\text{H}}_{ 2} {\text{O}}\left( {{\text{wt}}\% } \right) = {\text{ H}}_{ 2} {\text{O}}_{\text{MORB}} \left( {{\text{wt}}\% } \right) + \left( {5.84 \times 10^{ - 5} *{\text{P}} - 2.29 \times 10^{ - 2} } \right) \times \left( {{\text{Na}}_{2} {\text{O}} + {\text{K}}_{2} {\text{O}}} \right)\left( {{\text{wt}}\% } \right) + 4.67 \times 10^{ - 2} \times \Updelta {\text{NNO}} - 2.29 \times 10^{ - 1} $$ where H2OMORB is the water solubility at the calculated P, using the model of Dixon et al. (1995). This equation reproduces the existing database on water solubilities in basaltic melts to within 5%. Interpretation of the speciation data in the context of the glass transition theory shows that water speciation in basalt melts is severely modified during quench. At magmatic temperatures, more than 90% of dissolved water forms hydroxyl groups at all water contents, whilst in natural or synthetic glasses, the amount of molecular water is much larger. A regular solution model with an explicit temperature dependence reproduces well-observed water species. Derivation of the partial molar volume of molecular water using standard thermodynamic considerations yields values close to previous findings if room temperature water species are used. When high temperature species proportions are used, a negative partial molar volume is obtained for molecular water. Calculation of the partial molar volume of total water using H2O solubility data on basaltic melts at pressures above 1 kbar yields a value of 19 cm3/mol in reasonable agreement with estimates obtained from density measurements.

Rare gases in lavas from the ultraslow spreading Lena Trough, Arctic Ocean

Mid‐ocean ridge basalts (MORB) from the Arctic Ocean have been much less studied than those from the Indian, Atlantic, and Pacific due to the difficulty of access related to ice cover. In 2001 and 2004 the Arctic ridges (Gakkel Ridge and Lena Trough) were intensively sampled. In this study we present the first helium, neon, and argon concentrations and isotopic ratios in a suite of samples from the ultraslow spreading Lena Trough (∼0.75 cm/yr effective full rate). Central Lena Trough (CLT) lavas display 4He/3He between 89,710 and 97,530 (R/Ra between 7.4 and 8.1), similar to the mean MORB ratio of 90,000 ± 10,000 (R/Ra = 8 ± 1). In a three neon isotope diagram, the samples fall on the MORB line, without showing any excess of nucleogenic 21Ne. The 40Ar/36Ar ratios vary from 349 to 6964. CLT samples have a typical MORB He and Ne isotopic composition. Rare gases do not indicate any mantle heterogeneities or contribution of subcontinental lithospheric mantle, although this has been suggested previously on the basis of the Sr‐Nd and Pb isotopic systems. Based on noble gas systematics, a DUPAL‐like anomaly is not observed in the Arctic Ocean. We propose two possible models which reconcile the rare gases with these previous studies. The first is that the Lena Trough mantle has a marble cake structure with small‐scale heterogeneities (&lt;1 km), allowing rapid diffusion and homogenization of rare gases compared to elements such as Sr, Nd, and Pb. The second model proposes that the recycled component identified by other isotopic systems was fully degassed at a recent date. It would therefore have a negligible mass budget of rare gases compared to other isotopic systems. This would suggest that the mantle enrichment beneath Lena Trough was generated by rift‐forming processes and not by recycling.

Petrological and geochemical constraints on the origin of the Nehbandan ophiolitic complex (eastern Iran): Implication for the evolution of the Sistan Ocean

The Nehbandan ophiolite complex (NOC) crops out in the Sistan suture zone, which marks the boundary between the Lut and Afghan continental blocks. The NOC is composed of various ophiolitic lithotypes included in a tectono-sedimentary mélange, which are commonly interpreted as remnants of the oceanic lithosphere of the Sistan Ocean. Three different sequences (or associations) of ophiolitic rocks can be recognized in the NOC: (1) mantle peridotites consisting of clinopyroxene- (cpx-) rich harzburgites and depleted harzburgites; (2) olivine websterite–pyroxenite–gabbronorite sequence; (3) wehrlite–troctolite–cumulate gabbro–isotropic gabbro–basalt sequence. Petrographic observations, mineral chemistry, whole-rock chemistry, and rare earth element (REE) modelling carried out on the different rock associations led to the following conclusions: (1) the wehrlite–troctolite–cumulate gabbro–isotropic gabbro–basalt association represents a portion of oceanic crust generated in a mid-ocean ridge setting; (2) the cpx-rich harzburgites represent the residual mantle after 5–20% removal of mid-ocean ridge basalt-type (MORB) melt. This residual mantle was subsequently enriched in light REE (LREE) by subduction-derived fluids in a supra-subduction zone (SSZ) setting and it compositionally represents the typical mantle source for boninitic melts; (3) the olivine websterite–pyroxenite–gabbronorite association represents a portion of oceanic crust generated in an intra-oceanic arc setting; (4) the depleted harzburgites represent the residual mantle after 10–30% removal of boninitic melts in an intra-oceanic arc setting. The data presented in this paper provide new constraints for the tectonic evolution of the Iranian sector of the Neo-Tethys. In fact, in contrast with previous geodynamic models, the occurrence of SSZ ophiolites in the NOC implies that the phase of convergence between the Lut and Afghan blocks, which led to the closure of the Sistan Ocean, was accompanied by the development of an intra-oceanic arc setting.

Oceanic spreading center–generated basaltic crust and associated sulfidic and carbonate-rich hydrothermal deposits in the Archean (ca. 3 Ga), North Spirit Lake greenstone belt, Ontario, Canada

Detailed mapping of a portion of the North Spirit Lake greenstone belt reveals a basal basaltic volcanic unit (ca. 3 Ga) with a komatiitic component and strong major and trace element geochemical affinity with typical mid-ocean ridge basalts (e.g., N-MORB). The overlying transitional unit includes basaltic tuffs, which have close geochemical affinity to the underlying basalts, and to N-MORB. Interbedded with and overlying the tuffs is a thin, laterally continuous sulfide-rich unit with chert interbeds, which is in turn overlain by interbedded carbonate, chert, and iron-rich sedimentary rocks. The chemical sedimentary rocks of the transitional unit display rare-earth element (REE) patterns and positive Eu anomalies consistent with derivation from fluids associated with submarine hydrothermal vent fields. The sulfide unit is interpreted to represent proximal hydrothermal vent deposits derived from black smoker activity near a spreading center. The overlying carbonate and chert mounds and beds are interpreted as hydrothermal deposits formed at lower temperatures in a more distal setting relative to the spreading center. The carbonate deposits may have formed in an environment analogous to that of the Lost City hydrothermal field (Kelley et al., 2001), where abundant chimneys, dendrites, and beds of carbonate are produced ∼15 km from the mid-Atlantic rift axis. The basal volcanic unit consequently is interpreted as ocean-floor basalts formed at an Archean spreading center, with the basaltic tuffs representing the last volcanic emanations, and with the chemical sediments representing hydrothermal-vents deposits both proximal and distal to the spreading center. The capping siliciclastic unit likely is part of an accretionary wedge, possibly representing ocean closure after a protracted seafloor spreading episode. The sedimentary rocks were derived, in part, from a weathered tonalite-trondhjemite-granodiorite source. The supracrustal rocks of the North Spirit Lake greenstone belt provide an unusually clear window into some tectonic activity on the primitive Earth, including evidence for the existence of ocean-floor basalts, proximal and distal hydrothermal activity, and possibly a protracted cycle of ocean opening and destruction.

Subducted seamounts in an eclogite-facies ophiolite sequence: the Andean Raspas Complex, SW Ecuador

The metamorphic Raspas Complex of southwest Ecuador consists of high-pressure mafic, ultramafic, and sedimentary rocks. The Lu–Hf ages of a blueschist, a metapelite, and an eclogite overlap at around 130 Ma and date high-pressure garnet growth. Peak metamorphic conditions in the eclogites reached 1.8 GPa at 600°C, corresponding to a maximum burial depth of ~60 km. The geochemical signatures of the eclogites suggest that their protoliths were typical mid-ocean ridge basalts (MORB), whereas the blueschists exhibit seamount-like characteristics, and the eclogite-facies peridotites seem to represent depleted, MORB-source mantle. That these rocks were subjected to similar peak PT conditions contemporaneously suggests that they were subducted together as an essentially complete section within the slab. We suggest that this section became dismembered from the slab during burial at great depth—perhaps as a consequence of scraping off the seamounts. The spatially close association of MORB-type eclogite, seamount-type blueschist, serpentinized peridotite, and metasediments points to an exhumed high-pressure ophiolite sequence.

Deep mantle origin of kimberlite magmas revealed by neon isotopes

[1] We measured noble gases in olivines extracted from alteration-free samples of the Udachnaya-East kimberlite pipe, eastern Siberia. Neon isotope ratios indicate that the kimberlite has a less nucleogenic Ne signature than a typical mid-ocean ridge basalt (MORB) source, which is consistent with the less radiogenic 40Ar/36Ar ratio compared to MORB and subcontinental lithospheric mantle (SCLM) sources. Based on He-Ne systematics, the 3He/4He ratio of the plume source of the Udachnaya kimberlite pipe would be higher than 15 RA with the dominant He signature of the magma acquired by assimilation of SCLM and/or crustal material during magma ascent. Our results indicate that the source of the Udachnaya kimberlite has similar noble gas characteristics to those of ocean island basalts (OIBs). Its origin is therefore deeper than that of the MORB source mantle, and probably is the same as the OIB-source mantle.