The thermal buckling behavior of concrete annular sector plates reinforced with nanocomposites is investigated in this work. The thermal buckling issue is stated using mathematical modeling, taking into account the geometric linearity and material heterogeneity caused by the nanocomposite reinforcement. The governing differential equations that are obtained from the theoretical model are solved using the discrete singular convolution (DSC) technique. To generate accurate buckling load predictions, the DSC method’s great accuracy in handling complicated boundary conditions and discontinuities is used. Furthermore, using mathematical modeling to create extensive datasets, the research aims to train deep neural networks (DNNs) to anticipate thermal buckling reactions. These datasets provide a strong basis for DNN training as they include a wide range of factors, such as geometric configurations, loading situations, and material properties. By combining DNN predictions with DSC solutions, this unique technique for solving this difficult issue seeks to improve the accuracy and efficiency of thermal buckling analysis. The findings show how well sophisticated mathematical methods and machine learning models work together, opening the door to creative solutions for the design and analysis of concrete structures reinforced with nanocomposite under complicated stress.