Traditional Thermoelectric Materials Research Articles

High figure-of-merit for ZnO nanostructures by interfacing lowly-oxidized graphene quantum dots

Thermoelectric technology has potential for converting waste heat into electricity. Although traditional thermoelectric materials exhibit extremely high thermoelectric performances, their scarcity and toxicity limit their applications. Zinc oxide (ZnO) emerges as a promising alternative owing to its high thermal stability and relatively high Seebeck coefficient, while also being earth-abundant and nontoxic. However, its high thermal conductivity (>40 W m−1K−1) remains a challenge. In this study, we use a multi-step strategy to achieve a significantly high dimensionless figure-of-merit (zT) value of approximately 0.486 at 580 K (estimated value) by interfacing graphene quantum dots with 3D nanostructured ZnO. Here, we show the fabrication of graphene quantum dots interfaced 3D ZnO, yielding the highest zT value ever reported for ZnO counterparts; specifically, our experimental results indicate that the fabricated 3D GQD@ZnO exhibited a significantly low thermal conductivity of 0.785 W m−1K−1 (estimated value) and a remarkably high Seebeck coefficient of −\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$-$$\\end{document}556 μV K−1 at 580 K.

Strong electron-phonon coupling and high lattice thermal conductivity in half-Heusler thermoelectric materials.

Traditional half-Heusler thermoelectric materials, identified as 18-electron compounds, are characterized by the high power factor and the high lattice thermal conductivity. Interestingly, the emerging 19-electron half-Heusler compounds were also found to be promising thermoelectric materials, but with a 5-10 times lower lattice thermal conductivity. Since the two kinds of compounds have similar chemical and physical structures, such as TiCoSb and VCoSb, the large difference in lattice thermal conductivity is a puzzling question. Here, we present a theoretical study to clarify the lattice thermal transport in half-Heusler thermoelectric materials. Based on electronic band structure analysis, we show that the two transition-metal elements in half-Heusler compounds form the strong and direct d-d interaction that is responsible for the high lattice thermal conductivity of 18-electron compounds. In 19-electron half-Heusler compounds, however, the extra valence electron enters the d-d antibonding states, which significantly weakens the atomic bond strength, leading to a large decrease in the cohesive energy. The resulting softened acoustic phonons enhance the phonon-phonon scattering, and thus reduce the lattice thermal conductivity significantly. By constructing an artificial 18-e compound V0.5Sc0.5CoSb, it is proved that the one less electron relative to VCoSb increases the lattice thermal conductivity significantly.

2D MXene Interface Engineered Bismuth Telluride Thermoelectric Module with Improved Efficiency for Waste Heat Recovery

AbstractGraphene analog MXenes are the best options for interface engineering traditional thermoelectric materials. For the first time, a composite‐engineered TEG device composed of heavily doped bismuth and antimony telluride with incorporated Ti3C2Tx (MXene) nanoflakes is developed. Incorporated MXenes improved the electrical conductivity by carrier injection and reduces thermal conductivity by interfacial phonon scattering in both composites. The fabricated composite TEG device resulted in a maximum power of 1.14 mW and a power density of 6.1 mWcm−2. The fabricated composite TEG also demonstrates strong power generation stability and durability. Added MXenes improve the mechanical stability by employing a dispersion‐strengthening mechanism. Conclusively, the developed composite‐engineered TEG device is a facile and efficiency‐improving option for next‐generation bismuth telluride‐based commercial TEG devices.

First-Principles Investigation of Simultaneous Thermoelectric Power Generation and Active Cooling in a Bifunctional Semimetal ZrSeTe Janus Structure.

Traditional thermoelectric materials often face a trade-off between efficient power generation (high ZT) and cooling performance. Here, we explore the potential of achieving simultaneous thermoelectric power generation and cooling capability in the recently fabricated bulk ZrSeTe Janus structure using first-principles density functional theory (DFT). The layered ZrSeTe Janus structure exhibits a semimetal character with anisotropic transport properties along the in-plane and out-of-plane directions. Our DFT calculations, including the explicit calculation of relaxation time, reveal a maximum ZT of ~0.065 in the out-of-plane direction at 300 K which is one order of magnitude larger than that in the in-plane direction (ZT~0.006). Furthermore, the thermoelectric cooling performance is also investigated. The in-plane direction shows a cooling performance of 13 W/m·K and a coefficient of performance (COPmax) of ~90 with a temperature difference (ΔT) of 30 K, while the out-of-plane direction has a cooling performance of 2.5 W/m·K and COPmax of ~2.5. Thus, the out-of-plane current from the thermoelectric power generation can be utilized as an in-plane current source for active heat pumping. Consequently, we propose that the semimetal ZrSeTe Janus structure can display bifunctional thermoelectric properties for simultaneous thermoelectric power generation and active cooling.

Effects of substitutional doping CsSn0.75A0.25I3 (A=B, Sb) in the thermoelectric properties of the B-γ phase from first principles

Among hybrid and all-inorganic halide perovskites, CsSnI3 has stood out with moderate electrical conductivity and ultralow thermal conductivity. Nevertheless, the former is still low compared to values of traditional thermoelectric materials, this makes its applications scarce. Herein, we wish to present a DFT study combined with the application of the Boltzmann transport equation, to determine the effects of p and n-type substitutional doping in the lattice structure, electronic and thermoelectric properties of CsSn0.75A025I3 (A = B, Sb). Our calculations show that doping increases the thermoelectric power factor to 181.2 µW m−1 K−2 under Sb-doping, which represents a twofold value compared to 78.3 µW m−1 K−2 of the pristine lattice; under B-doping we obtained a value of 145.6 µW m−1 K−2. CsSnI3 has higher power factor upon n-type doping. Finally, yet importantly, we further examine the shifts in the Fermi level using the effective mass model framework. In doing so, our work predicts a performance enhancement by achieving a Fermi energy level close to the VBM, or CBM. Similarly, our work demonstrates that doping represents an effective way to improve the thermoelectric power factor of CsSnI3, this being attributed to the increase of charge carriers and the modification of the band structure.

Thermal shock fracture of honeycomb-based porous thermoelectric materials with non-Fourier heat conduction

Compared with dense thermoelectric materials (TEMs), the auxetic honeycomb porous TEMs can enhance mechanical performance and energy conversion efficiency. The Fourier heat conduction law becomes unavailable due to the thermal wave speed in the porous TEMs is limited. Considering the non-Fourier law, this paper analyzes the thermal shock fracture characteristics of the porous TEMs bonded to an elastic substrate. A theoretical model for the effects of non-Fourier heat conduction, thickness of TME, shape and dimensions of honeycomb cell on strength failure and fracture failure is proposed. The analysis demonstrates that the maximum thermal stresses in the porous TEMs are underestimated without considering the non-Fourier heat conduction. The stress level in the auxetic honeycomb-based TEMs is much smaller than that in the traditional honeycomb TEMs with the positive Poisson's ratio architecture. It is found that a thicker TEM, a bigger relative density and a larger length ratio of the horizontal to the inclined strut can result in a smaller thermal stress. Based on the strength and fracture criterions, the envelope of safety angle between the horizontal and the inclined strut is identified. The simplified expressions of the safety angle envelope versus the applied thermal load are given.

Dispersion of InSb Nanoinclusions in Cu3SbS4 for Improved Stability and Thermoelectric Efficiency

Thermoelectric‐based waste heat recovery requires efficient materials to replace conventional non‐eco‐friendly Te‐ and Pb‐based commercial devices. Ternary copper chalcogenide‐based famatinite (Cu3SbS4) compound is one of the practical substitutes for traditional thermoelectric materials. However, the pristine Cu3SbS4 inherits poor structural complexion, large thermal conductivity, and low power conversion efficiency. To develop high‐efficiency Cu3SbS4, InSb nanoinclusions are incorporated via high‐energy ball milling followed by the hot‐press densification method. Incorporating InSb nanoinclusions to lower thermal conductivity via phonon scattering while increasing the thermopower via a carrier energy filtering process. The thermoelectric performance (ZT) of ≈0.4 at 623 K is obtained in Cu3SbS4‐3 mol% InSb nanocomposite, which is ≈140% higher than pure Cu3SbS4. Both mechanical and thermal stability are improved by grain boundary hardening and dispersion strengthening. Thus, a facile nanostructured Cu3SbS4 with added InSb nanoinclusions is delivered as a highly efficient, eco‐friendly, structurally‐, thermally‐, and mechanically‐stable material for next‐generation thermoelectric generators.

Room temperature high thermoelectric performance of Bi-based full-Heusler compounds CsxRb[formula omitted]Bi with strong anharmonicity

Bismuth-based compounds have been identified as a class of promising candidates for the realization of high-performance thermoelectrics, derived from their exceptional electrical conductivity and intrinsic low lattice thermal conductivity κL. Here, we employed first-principles calculations, self-consistent phonon theory, and compressive sensing technique in conjunction with the Boltzmann transport equation to investigate the anharmonic thermoelectric properties of full-heusler bismuth compounds CsxRb3−xBi. As the Cs content increases, the κL of CsxRb3−xBi decreases due to impurity scattering effects, and then increases. Among them, at 300 K, Rb3Bi has the largest κL of 0.69 Wm−1K−1, while Cs2RbBi has the smallest κL of 0.45 Wm−1K−1, both of which are lower than the κL of traditional bismuth-based thermoelectric materials. The ultralow κL originates from the strong lattice anharmonicity. In addition, the coexistence of high dispersion and flat band edges leads to high thermoelectric power factor at optimal doping concentration. As a result, the largest thermoelectric figure of merit ZT values of 2.59 (4.19) at 300 (500) K were obtained for CsRb2Bi at optimal hole doping level. These findings suggest that CsxRb3−xBi compounds are superior for thermal management and thermoelectric applications.

Strategic Doping in Metal Halide Perovskites for Thermoelectrics

AbstractMetal halide perovskites (MHPs) have not only shown unique merits of ultralow thermal conductivity compared to traditional inorganic thermoelectric (TE) materials, but also featured superior Seebeck effect to organic semiconductors, thereby affording great prospect in TE field. However, their severely poor electrical conductivity significantly hinders TE applications, which results from the restrained doping efficiency due to the limited accommodation capability of heterogeneous dopants and the heavy compensation from interior defects in MHPs. Realizing high‐effectiveness electrical doping in MHPs becomes imperative yet remains extremely challenging. This Minireview is therefore intended to sort out the diversified doping strategies and highlight their underlying impacts on both thermal and electrical transportation in MHPs. These strategies are systematically classified into bulk and surface/interface doping as dictated by where the dopants are implemented while unravelling how they critically impact TE properties in distinctive means. A rational guideline is hence derived to strengthen electrical doping towards desirable perovskite TEs.

Enhanced thermoelectric properties of bismuth telluride (Bi2Te3) and multiwall carbon nanotube (MWCNT) composites

Solid solutions based on bismuth telluride are the traditional thermoelectric materials that are commercially utilized in the industry close to room temperature applications, where energy scavenging is a big challenge due to low quality and energy density. However, their broader applications are still limited due to low efficiency. The focus of the present work is to enhance the energy conversion efficiency of Bi2Te3 by mixing one-dimensional (1D) multiwall carbon nanotubes (MWCNTs) via facile powder processing by synergistically utilizing the nanostructuring and quantum confinement effects. Thus, different vol% of MWCNTs ranging from 0.5, 1.0, 1.5, and 2 were uniformly dispersed in a fine powder of Bi2Te3 that was ball milled from course Bi2Te3 in an inert environment. The coarse Bi2Te3 and fine composite powders were consolidated in a spark plasma-sintering furnace at ∼400 °C under uniaxial pressure of ∼40 MPa. Thermoelectric properties of Bi2Te3-based MWCNTs composites were evaluated in the temperature range from ∼300 to ∼525 K. The electrical conductivity of 1.5 vol% MWCNT composite has significantly enhanced from pristine Bi2Te3. This increase indicates that electrical transport dominantly involves a percolating network of MWCNTs. The concomitant increase in the Seebeck coefficient of 1.5 vol% Bi2Te3 composite suggests the enhanced energy-dependent scattering of charge carriers. Consequently, a substantially improved power factor is observed for the composite. The thermal conductivity of all the composites decreases, and considerable reduction is achieved for 0.5 vol% due to enhanced phonon scattering through nanostructuring and uniform distribution of the nanotubes. Hence, the significant decrease in thermal conductivity with improved power factor leads to substantial improvement in the thermoelectric figure of merit of 1.5 vol% Bi2Te3 composite from pristine Bi2Te3.

Flexible thermoelectrics: From energy harvesting to human–machine interaction

Thermoelectrics is the simplest technology applicable for direct energy conversion between heat and electricity. After over 60 years of fruitful research efforts, recent boom in flexible electronics has promoted the rapid development of flexible thermoelectrics with rising performances, discovery of new materials and concepts, unconventional device configuration, and emerging applications not possible for traditional thermoelectric (TE) semiconductors. In this Perspective, we first overview representative flexible TE materials, then discuss recent breakthroughs for flexible TE devices assembled from various types of TE materials employing different technical routes. They exhibit promising power generation and sensing performances, and aim for applications in wearable electronics, such as the power supply harvesting heat from body for low-power electronics, temperature sensors for tactile e-skin, and newly emerged application as a thermo-haptic device in an extended reality system.

Low lattice thermal conductivities and good thermoelectric performance of hexagonal antiperovskites X(Ba & Sr)3BiN with quartic anharmonicity.

Antiperovskites are a burgeoning class of semiconducting materials that showcase remarkable optoelectronic properties and catalytic properties. However, there has been limited research on their thermoelectric properties. Combining first-principles calculations, self-consistent phonon theory and the Boltzmann transport equation, we have discovered that the hexagonal antiperovskites X(Ba & Sr)3BiN exhibit strong quartic lattice anharmonicity, where the anharmonic vibrations of the light N atoms primarily affect the lattice thermal conductivity (κL) along the c-axis direction. As a result, the lattice thermal conductivities along the a(b)-axis direction are low. At 300 K, the κL values of Ba3BiN and Sr3BiN are only 1.27 W m-1 K-1 and 2.24 W m-1 K-1, respectively. Moreover, near the valence band maximum, the orbitals of the N atoms dominate. This dominance allows Sr3BiN to achieve high power factor under p-type doping, resulting in an impressive thermoelectric figure of merit (ZT) of 0.94 along the c-axis direction at 800 K. In the a(b)-axis direction, at 800 K, n-type doped Ba3BiN exhibits a ZT value of 1.47, surpassing that of traditional thermoelectric materials. Our research elucidates that the hexagonal antiperovskites X(Ba & Sr)3BiN represent a category of potential thermoelectric materials with pronounced anisotropy, low thermal conductivity, and high thermoelectric performance.

Adaptable and Wearable Thermocell Based on Stretchable Hydrogel for Body Heat Harvesting

AbstractThe application of traditional inorganic thermoelectric materials to wearable energy harvesters has been hindered by the rigid bulkiness, while flexible organic conductive polymers have been long troubled by their intrinsic low thermopower. An ideal solution that possesses the merits of the two thermoelectric materials is desperately needed for practical application. Here it is demonstrated that a polyacrylamide (PAAm)‐based ultra‐stretchable hydrogel can be selected as a superior candidate matrix for flexible and stretchable thermocells to adapt to the curved surface of the human body and deformation of the ankle. Fe(ClO4)3/Fe(ClO4)2 is selected as n‐type ion pair for their comparable thermoelectric performance to K3[Fe(CN)6]/K4[Fe(CN)6]. The p‐n pair hydrogel electrolytes show a voltage output of 29 mV and current output of 8.5 Am−2 with an average maximum power density of 0.66 mW K−2 m−2 for each p‐n cell (ΔT = 10 K). By integrating with the graphite paper electrode, a body‐conformal and portable thermocell device, employing the hydrogel electrolytes, is fabricated and reached a voltage output of 0.16 V with 14 pairs of p‐n cells (ΔT = 4.1 K). This commercially‐effective blueprint demonstrates the bright future of hydrogel‐based ionic thermocell in daily wearable scenarios.

Benny C. Chan

The traditional approach to teaching college chemistry, which includes in-class lectures and expectations of hours of individual study, often acts as a roadblock for underrepresented students seeking a career in science . Traditional thermoelectric materials, which include bismuth tellurides and selenides, can act like heat pumps in cooling systems when jolted by an electrical current. Benny C. Chan has applied his love of problem-solving to change the structures of both. Through an interdisciplinary approach to research, he has helped fill gaps in chemistry education as well as in the published crystal structures of thermoelectric compounds. Chan, an inorganic chemist and chair of the Chemistry Department at the College of New Jersey, studies how adding elements to bismuth telluride compounds might disrupt their structures and change their thermoelectric properties. Students in his lab have published the structures of a wide variety of chemical compounds, including organic compounds that had been overlooked

TRIANGULATION OF THE Cu-Sn-Se SYSTEM

Copper-containing compounds exhibit a wide range of properties, including thermoelectric, photoelectric, optical magnetic, superionic, superconducting, etc., which determines the areas of their practical use. In recent years, studies of complex copper selenides as promising thermoelectric (TE) materials have been actively carried out due to their advantages over traditional TE materials. Like binary Cu2Se, ternary selenides have low phonon thermal conductivity and high electrical conductivity and thermoelectric quality factor. Typically, copper-containing compounds belong to the p-type conductors and crystallize in four main structural types, among which phases with a diamond-like structure should be distinguished. Data on the nature of physicochemical interaction in the Cu – Sn – Se system are limited and contradictory. In view of this, it is important to carry out the triangulation of the ternary system Cu–Sn–Se, which is the first stage of the study of multicomponent systems.
 The investigated alloys of the Cu – Sn – Se system were obtained by fusing elementary components of high purity in vacuum quartz ampoules. The obtained alloys were investigated using X-ray powder diffraction (XRD) and differential thermal (DTA) analyzes. At the temperature of homogenizing annealing (170 ° С) there are seven binary Cu2Se, CuSe, CuSe2, Cu6Sn5, Cu3Sn, SnSe, SnSe2 and one ternary phase Cu2SnSe3 stable in the Cu – Sn – Se ternary system. The existence of the ternary phase of Cu2SnSe4 has not been confirmed, because the alloy corresponding to its stoichiometric composition is a mixture of Cu2SnSe3 and Se. To establish quasibinary sections of the Cu – Sn – Se system were performed the synthesis and phase analysis of only the significant points in the most informative areas. This ensures the establishment of the nature of the maximum number of quasibinary sections with a minimum number of syntheses. According to the results of phase analysis in combination with the literature data the triangulation of the Cu – Sn – Se system was carried out at 170 ° С. The quasibinarity of the Cu2Se – SnSe, Cu2Se – SnSe2, Cu2SnSe3 – Se, Cu2SnSe3 – SnSe, Cu6Sn5 – SnSe, Cu3Sn – SnSe, and Cu3Sn – Cu2Se sections was confirmed, and the quasibinarity of the Cu3Sn – Cu2Se was established at first.
 Keywords: triangulation; quasibinary section; phase analysis.

Thermoelectric characteristics of X_2YH_2 monolayers (X=Si, Ge; Y=P, As, Sb, Bi): a first-principles study

Ever since global warming emerged as a serious issue, the development of promising thermoelectric materials has been one of the main hot topics of material science. In this work, we provide an in-depth understanding of the thermoelectric properties of X_2YH_2 monolayers (X=Si, Ge; Y=P, As, Sb, Bi) using the density functional theory combined with the Boltzmann transport equation. The results indicate that the monolayers have very low lattice thermal conductivities in the range of 0.09−0.27 Wm^{-1}K^{-1} at room temperature, which are correlated with the atomic masses of primitive cells. Ge_2PH_2 and Si_2SbH_2 possess the highest mobilities for hole (1894 cm^2V^{-1}s^{-1}) and electron (1629 cm^2V^{-1}s^{-1}), respectively. Si_2BiH_2 shows the largest room-temperature figure of merit, ZT=2.85 in the n-type doping ( sim 3times 10^{12} cm^{-2}), which is predicted to reach 3.49 at 800 K. Additionally, Si_2SbH_2 and Si_2AsH_2 are found to have considerable ZT values above 2 at room temperature. Our findings suggest that the mentioned monolayers are more efficient than the traditional thermoelectric materials such as Bi_2Te_3 and stimulate experimental efforts for novel syntheses and applications.

A flexible thermoelectric film based on Bi2Te3for wearable applications

In recent years, with the development of the Internet of Things (IoT) and wearable technology, the research and exploration of thermoelectric materials have been greatly promoted. However, traditional thermoelectric materials are rigid and brittle. Thermoelectric devices made of these materials usually cannot be closely attached to the heat and cold sources that provide temperature differences, thus limiting the application of thermoelectric materials. Therefore, manufacturing new high-performance flexible thermoelectric devices is still a huge challenge. In this work, polyimide/copper (PI/Cu) substrate was deposited by electron deposition technology. The flexible thermoelectric thin film device was fabricated by bonding [Formula: see text]-type and [Formula: see text]-type bismuth telluride (Bi2Te[Formula: see text] slurries onto the PI/Cu substrate. Then, the PDMS film was coated on the device to make the device waterproof and oxidation resistant. The output voltage and maximum power of this device, at the temperature of 80 K, reach 97.5 mV and 60 uW, respectively. After 200 cycles of cyclic bending experiments, 90% high conductivity retention can be maintained. It demonstrates that the new flexible thermoelectric thin film has good flexibility and excellent stability. This work provides a simple method for the preparation of flexible thermoelectric thin films and opens up a new way for its application in the sensing equipment and wearable device of the IoT.

Comparison between the thermoelectric properties of new materials: The alloy of iron, vanadium, tungsten, and aluminum (Fe2V0.8W0.2Al) against an oxide such as NaCO2O4

An analysis of the thermoelectric characteristics of certain recently discovered materials is carried out in this investigation. The alloy of iron, vanadium, tungsten, and aluminum (Fe2V0.8W0.2Al) applied to a silicon crystal is compared to new inorganic thermoelectric materials, which are mosly oxides like NaCO2O4. For both materials, the thermoelectric effects, Seebeck effect, Peltier effect, Thomson effect, and Kelvin relations are described. The cooling rate’s influence on the energy balance is also assessed. The traditional thermoelectric materials provided are mostly made up of toxic, rare and/or expensive elements, which makes large-scale thermoelectric generator integration difficult. In recent decades, research has shifted toward the development of novel materials with a better price-to-performance ratio. Despite a low conversion yield, the family of oxides offers significant benefits in this respect, which are particularly evident at high temperatures. The findings of our study indicated that Fe2V0.8W0.2 applied to a silicon crystal has good thermoelectric characteristics. A sufficient merit factor was found in the new substance under investigation.

Integrated, Highly Flexible, and Tailorable Thermoelectric Type Temperature Detectors Based on a Continuous Carbon Nanotube Fiber.

As possible alternatives to traditional thermoelectric (TE) materials, carbon nanomaterials and their hybrid materials have great potential in the future application of flexible and lightweight temperature detection. In this work, an integrated, highly flexible, and tailorable TE temperature detector with high performance has been fabricated based on a continuous single-walled carbon nanotube (SWCNT) fiber. The detector consists of more than one pairs of thermocouples composed of p-type SWCNT fiber and n-type SWCNT hybrid fiber in situ doped by polyethylenimine. Due to the node contact mechanism of the detection, the sensitivity of the detector can be improved with the increase of the number of p-n thermocouples, independent of the length of the thermocouple. The temperature detection process of the detector has been studied in detail. In particular, the integrated and flexible detector can be divided into several sub-detectors easily by cutting, illustrating the prospect of large-scale preparation of this kind of novel temperature detectors. Its high flexibility ensures the detector to maintain excellent detection performance after 15000 bending circles. Furthermore, the as-designed TE type temperature detector demonstrates a great application promise for real-time temperature detection and temperature change sensing even in complex surface and harsh environment.

Wearable Electronics Based on the Gel Thermogalvanic Electrolyte for Self-Powered Human Health Monitoring.

There is always a temperature difference of more than 10 degrees between the human body, as a sustainable heat source, and the ambient temperature. Converting body heat into electricity that in turn is used to drive personal medical electronics is of significance in smart wearable medicine. To avoid the frangibility and complex preparation of traditional thermoelectric materials, we fabricated a gel electrolyte-based thermogalvanic generator with Fe3+/Fe2+ as a redox pair, which presents not only moderate thermoelectric performance but also excellent flexibility. With a micropore-widespread polyvinylidene fluoride diaphragm implanted in the gel, a thermal barrier was created between the two halves, effectively improving the Seebeck coefficient by reducing its thermal conductivity. Considering the superior temperature response of the gel, a self-powered body temperature monitoring system was established by conformally affixing it to the forehead. Meanwhile, the gel patch with a high specific heat capacity can effectively cool down fever patients. This work may offer a new train of thought for exploiting self-powered wearable medical electronics by scavenging low-grade body heat.