Material Toughness Research Articles

Synthesis of Water-Soluble Polyethylene Glycol Fumarates for Biomedical Applications

Polyethylene glycol fumarate (PEGF) with controlled structural composition has been obtained for further synthesis of double network crosslinked hydrogels for biomedical applications. The copolymer has been synthesized by polycondensation reaction of fumaric acid and polyethylene glycol (PEG-600). Molecular weight of PEGF has been determined by gel permeation chromatography to be approximately 6000 Da with gel permeation chromatography. The polycondensation of fumaric acid and PEG-600 was studied throughout the reaction process. The structure of the reaction product has been evidenced using FTIR- and 1H NMR-spectroscopy. The quantitative ratios of the amount of –C=C– bonds and –COO groups to –C=O groups in the obtained PEGF have been estimated from IR-spectra for different synthesis time. The time-dependence of molar ratio of double bonds to methyl groups in PEGF has been obtained from corresponding 1H NMR-spectra. FTIR and 1H NMR-spectroscopy, both, demonstrate that after the end of reaction the unsaturated –C=C– double bonds remain in the structure of the macromonomer, that is essential for further preparation of cross-linked hydrogels. The addition of the tightly cross-linked network of polyvinyl alcohol leads to formation of highly tough biocompatible material for preparation of the artificial meniscus which can further be used as a solution n the treatment of diseases such as osteoarthritis.

Design of 3D printable boehmite alumina/thermally exfoliated reduced graphene oxide-based polymeric nanocomposites with high dielectric constant, mechanical and thermomechanical performance

In this study, melt-blending was employed to blend 80 wt% poly(lactic acid) and 20 wt% poly(ε-caprolactone) (80 %PLA/20 %PCL) with boehmite alumina-thermally exfoliated reduced graphene oxide (BA-TERGO) as nanofillers. Herein, we present a novel synergy effect of BA/TERGO particles on improving the dielectric constant while maintaining dielectric loss at lower magnitudes. Also, improving the thermomechanical properties of tough PLA/PCL nanocomposite through the incorporation of a dual-filer system strategy. Consequently, remarkable increase in dielectric constant was achieved for BA-TERGO/blend nanocomposite. In particular, the blend exhibited dielectric constant of about 2.91, while the BA-TERGO/blend nanocomposite exhibited dielectric constant of about 4.93 at a frequency of 2.0 ×106 Hz and a temperature of 190 ºC. On the other hand, tensile modulus of the BA-TERGO/blend nanocomposite increased from 1908.5 MPa to 2505.2 MPa and the tensile strength increased from 70.48 MPa to 96.3 MPa when compared to that of the neat blend. BA-blend and BA-TERGO/blend nanocomposites provided the improved storage modulus and thermal stability. This finding renders PLA-based biodegradable materials suitable for tough 3D printable material with potential for integrated circuits applications.

Study on tensile properties of copper/graphene/2D-SiC composite materials: A molecular dynamics simulation

Van der Waals heterostructures composed of graphene and 2D-SiC generally exhibit outstanding electrical and mechanical properties. However, these structures are prone to brittle failure during damage, which greatly limits their application in practical engineering. Conversely, copper-based composite materials have been discovered to significantly enhance material toughness. Therefore, a novel copper/graphene/2D-SiC composite material is designed and molecular dynamics simulation is performed to investigate its mechanical properties under uniaxial tension. The results show that these composite materials possess the advantages of both high strength and toughness due to the heterostructure layer and the copper layer. Further analysis of the deformation mechanism of the copper layer indicates that it is mainly attributed to short-range atomic slip and the generation of Shockley partial dislocations. The heterostructure layer can partially impede the propagation of dislocations, enhancing the overall tensile strength of the composite materials. After the copper layer enters the plastic flow state, the variation of bond lengths and bond angles suggests that the heterostructure layer bears the tensile load, and the 2D-SiC layer is more prone to fracture due to higher stiffness compared to the graphene layer. Additionally, the influence of temperature and strain rate on the tensile properties is investigated. It is observed that increasing temperature could gradually reduce the tensile strength of the composite materials while the strain rate, within a certain range, has little effect.

A Methodology to Assess Directional and Spatial Variations of Tensile and Fracture Properties in Fabricated Nuclear Components

In the present study, directional and spatial variations in the mechanical properties are calculated in two nuclear-grade materials. In practice, multiple ASTM standard specimens are tested to measure mechanical properties of any material. The variations obtained in the properties during the tests are generally neglected assuming such variations are due to experimental uncertainties. However, such variations may indicate some degree of anisotropy and spatial inhomogeneity in the material due to component fabrication. In the present study, multiple miniaturized tensile specimens are tested. These specimen materials are taken across the thickness and at different geometrical locations in the two manufactured nuclear-grade components. The experimental load versus displacement data of all the specimens are then used to evaluate stress-strain data and cohesive zone parameters. These parameters are determined for each tested specimen separately to gather variations over the geometries of the components. Subsequently, TPB specimens are analyzed employing these parameters to calculate variations in fracture initiation toughness over the geometry. The key findings of the present work include higher strengths in circumferential direction in comparison to the longitudinal direction for SA333 Gr6 steel. A new equation is developed to correlate the material toughness with the fracture toughness with a proportionality constant of 2.7778 for low-alloy carbon steels. The study showed that directional and spatial variations in Jini are less pronounced in 20MnMoNi55 compared to SA333Gr6 materials. This finding is crucial for safety analyses in nuclear components and indicates that this methodology can be applied more widely across different materials.

Interfacial structures and properties of sulfide-Fe matrix in steel: A first principles study

Fine sulfides can promote the refinement of microstructure and improve the strength and toughness of materials. The interface properties between sulfides and steel matrix are associated with this phenomenon. The first principles calculation combined with two-dimensional lattice mismatch and two-step nucleation theory is adopted to calculate the interface properties of TiS/bcc-Fe, TiS/fcc-Fe and TiS/MnS at the atomic level. The results show that TiS has a weak ability to promote the transition of austenite to intragranular ferrite (IGF) due to the low adhesion work value. And TiS needs to overcome energy barriers to induce the formation of IGF because the higher interface energy of TiS/bcc-Fe than TiS/fcc-Fe. The heterogeneous nucleation ability of TiS(001)/MnS(111) is stronger than that of TiS(001)/MnS(110), indicating that TiS is beneficial for improving the deformation performance of MnS without affecting the ability of MnS (110) surface to induce IGF nucleation for grain refinement. Based on the two-step nucleation theory, the structures and properties of TiS clusters are analyzed. The formation pathway of TiS/Fe interface can be described as: Tiatom + Satom + Featom → core (TiSn)–shell (fcc-Fe(111)) → core (TiS(001))–shell (fcc-Fe(110) + bcc-Fe(100)).

Effect of size and anisotropy on fracture process zone of coal: An experiment and numerical simulation

The size and properties of the fracture process zone (FPZ) have a significant impact on the fracture toughness of materials. Researching and understanding the characteristics of FPZ contribute to optimizing material performance and enhancing the reliability of engineering structures. In this study, the newly proposed modified semi circular bending (SCB) test method was used to carry out the pure mode I fracture test of coal samples with four sizes and four bedding angles, the development process of FPZ was obtained by using digital image correlation method, and the cohesive zone model considering the bedding plane was established. The influence of size and anisotropy on the development and size of FPZ was studied, and the influence mechanism of FPZ on the size effect and anisotropy of fracture toughness was revealed. The results show that the FPZ length of coal has obvious size effect and anisotropy. The FPZ length increases with the increasing specimen size, and increases first and then decreases with the increasing bedding angle. The FPZ relative length decreases with increasing specimen size, indicating that as the specimen size increases, the influence of specimen boundaries on PFZ gradually decreases, and the size effect of fracture toughness also gradually weakens. The competition between microcrack development driven by principal stress and microcrack development driven by bedding plane results in anisotropy in the development process of FPZ. The anisotropy of FPZ development process results in the anisotropy of FPZ length, fracture toughness and crack propagation path. The research findings can provide valuable guidance for the design of hydraulic fracturing in coal seams.

Kinetic Resolution Polymerization Enabled Chemical Synthesis of Perfectly Isotactic Polythioesters.

Isotactic polythioesters (PTEs) that are thioester analogs to natural polyhydroxyalkanoates (PHAs) have attracted growing attention due to their distinct properties. However, the development of chemically synthetic methods for preparing isotactic PTEs has long been an intricate endeavour. Herein, we report the successful synthesis of perfectly isotactic PTEs via stereocontrolled ring-opening polymerization. This binaphthalene-salen aluminium (SalBinam-Al) catalyst promoted a robust polymerization of rac-α-substituted-β-propiothiolactones (rac-BTL and rac-PTL) with highly kinetic resolution, affording perfectly isotactic P(BTL) and P(PTL) with Mn up to 276 kDa. Impressively, the isotactic P(BTL) formed a supramolecular stereocomplex with improved thermal property (Tm=204 °C). Ultimately, this kinetic resolution polymerization enabled the facile isolation of enantiopure (S)-BTL, which could efficiently convert to an important pharmaceutical building block (S)-2-benzyl-3-mercapto-propanoic acid. Isotactic P(PTL) served as a tough and ductile material comparable to the commercialized polyolefins. This synthetic system allowed to access of isotactic PTEs, establishing a powerful platform for the discovery of sustainable plastics.

Kinetic Resolution Polymerization Enabled Chemical Synthesis of Perfectly Isotactic Polythioesters

AbstractIsotactic polythioesters (PTEs) that are thioester analogs to natural polyhydroxyalkanoates (PHAs) have attracted growing attention due to their distinct properties. However, the development of chemically synthetic methods for preparing isotactic PTEs has long been an intricate endeavour. Herein, we report the successful synthesis of perfectly isotactic PTEs via stereocontrolled ring‐opening polymerization. This binaphthalene‐salen aluminium (SalBinam‐Al) catalyst promoted a robust polymerization of rac‐α‐substituted‐β‐propiothiolactones (rac‐BTL and rac‐PTL) with highly kinetic resolution, affording perfectly isotactic P(BTL) and P(PTL) with Mn up to 276 kDa. Impressively, the isotactic P(BTL) formed a supramolecular stereocomplex with improved thermal property (Tm=204 °C). Ultimately, this kinetic resolution polymerization enabled the facile isolation of enantiopure (S)‐BTL, which could efficiently convert to an important pharmaceutical building block (S)‐2‐benzyl‐3‐mercapto‐propanoic acid. Isotactic P(PTL) served as a tough and ductile material comparable to the commercialized polyolefins. This synthetic system allowed to access of isotactic PTEs, establishing a powerful platform for the discovery of sustainable plastics.

Ex Vivo Biomechanical Bone Testing of Pig Femur as an Experimental Model.

This study investigates the mechanical behavior of femur bones under loading conditions, focusing on the transition from elastic to plastic deformation and eventual fracture. The force-displacement curves reveal distinct phases of deformation, with an initial linear relationship indicating elastic behavior, followed by deviation from linearity marking the onset of plastic deformation. Fracture occurs beyond a critical load, leading to a sharp drop in the force-displacement curve. The maximum fracture force varies among specimens and is influenced by bone geometry, size, cross-sectional area, and cortical thickness. Post-failure analysis highlights additional insights into fracture mechanics and bone material toughness. Reinforcing bones with screws enhances their strength, which is evident in the higher fracture forces observed in force-displacement diagrams. Fixation procedures following fractures further increase bone strength. Comparing specimens with and without strengthening underscores the effectiveness of reinforcement methods in improving bone mechanical properties. After analyzing the results, it is evident that femur bones with reinforcement can withstand greater loads, and they can also absorb higher impact energies while remaining in the elastic deformation range and without suffering permanent plastic damage. This study provides valuable insights into bone biomechanics and the efficacy of reinforcement techniques in enhancing bone strength and fracture resistance.

Towards developing advanced CFRP with simultaneously enhanced fracture toughness and in‐plane properties via interleaving CNT/PEI hybrid veils

AbstractCarbon nanotube (CNT)‐polyetherimide (PEI) hybrid nanofibrous veils were prepared through the electrospinning process to function as an interlayer in carbon fiber reinforced polymer composites (CFRP), and the effects of the addition of the hybrid fiber veils on the interlaminar fracture properties and flexural properties of CFRP were investigated. The results showed that interleaving CNT/PEI hybrid veils can effectively avoid long‐troubled trade‐off between mode‐I interlaminar fracture toughness and in‐plane properties when using thermoplastic toughening materials. Specifically, the GIc value and flexural strength of the laminates were increased by as much as 86.2% and 14.3%, respectively when CNT content was reached up to 0.7 wt% in CNT/PEI hybrid veil. This method adopts ultra‐low PEI and CNT additions, and the limited quantity of these additives demonstrates a notably high interlaminar toughening efficiency while concurrently enhancing the strength, rendering it a promising strategy for both toughening and strengthening.Highlights PEI is used as a carrier to transport CNT to the CFRP interlaminar layers. PEI‐CNT hybrid fiber veils improve GIC and flexural strength of CFRP. PEI‐CNT hybrid fiber veils impede crack expansion through various mechanisms. This method adopts ultra‐low PEI and CNT additions.

Comparison of Mechanical Properties of Bulk NiAl-Re-Al2O3 Intermetallic Material Manufactured by Laser Powder Bed Fusion and Hot Pressing

AbstractThe low fracture toughness of NiAl at room temperature is one of the critical issues limiting its application in aircraft engines. It has been previously shown that a small addition of rhenium and alumina significantly improves the fracture toughness of hot-pressed NiAl. In this work, NiAl with an admixture of rhenium and alumina was produced by laser powder bed fusion additive technology (LPBF). The purpose was to compare the fracture toughness, bending strength, and microhardness of the NiAl-Re-Al2O3 material produced by LPBF and hot pressing (HP). Our results show that the LPBF material has lower fracture toughness and bending strength compared to its hot-pressed equivalent. Microcracks generated by thermal stresses during the LPBF process were the primary cause of this behavior. To improve the LPBF material, a post-processing by HP was applied. However, the fracture toughness of the (LPBF + HP) material remained at 50% of the KIC of the HP material. This study supports hot pressing as a suitable processing method for NiAl with rhenium and alumina additions. However, a hybrid approach combining LPBF and HP proved to be highly effective on the raw NiAl powder, resulting in superior fracture toughness of the final material compared to that consolidated by singular HP.

A Review on hydrogen embrittlement behavior of steel structures and measurement methods

Hydrogen can be found within metals under a variety of industrial and environmental conditions. Hydrogen-metal interactions can take place through hydrogen embrittlement, hydrogen sulfide corrosion, or hydrogen absorption. Steel and other metals that are exposed to hydrogen may experience a difficulty known as hydrogen embrittlement that affects their mechanical properties. The material's ductility and toughness may be reduced as a result of this phenomena, it also increasing the risk of brittle fracture. In steel, atomic hydrogen mainly diffuses into the microstructure of the steel, causing hydrogen embrittlement. Localized weakening of the bonds between the metal atoms might result from hydrogen atoms occupying interstitial positions in the metal lattice. Especially when under stress, this may lead to a more susceptible to fracture and cracking. Concerns with hydrogen embrittlement arise in sectors like aerospace and oil and gas that use high-strength steels. If not appropriately handled, it may result in catastrophic failures. Use of hydrogen-resistant alloys, appropriate heat treatments, and protection from conditions that promote hydrogen uptake are examples of preventive measures. This literature review paper covers the definition of hydrogen embrittlement (HE), mechanisms causing HE, measurement of hydrogen concentration and preventive measures that restrict hydrogen diffusion to the steel.

Static and dynamic fracture toughness of graphite materials with varying grain sizes

Graphite materials play critical roles as moderators, reflectors, and core structural components in high-temperature gas-cooled nuclear reactors. During the reactor operation, graphite materials may experience a variety of loads, including thermal, radiation, fatigue, and dynamic loads, potentially leading to crack initiation and propagation. Therefore, it is imperative to investigate their fracture properties. Despite this, there remains a paucity of comprehensive studies on the fracture toughness of graphite materials with varying grain sizes, particularly concerning dynamic fracture toughness. This study addresses this gap by employing a digital-image-correlation-based virtual extensometer to analyze crack propagation in graphite materials of different grain sizes, enabling precise measurement of crack propagation length and fracture toughness. Findings reveal that static fracture toughness increases with larger grain sizes, while under dynamic loading, smaller grain sizes exhibit greater fracture toughness. Additionally, dynamic fracture toughness shows a near-linear increase with impact speed. Scanning electron microscopy analysis of fracture surface morphology highlights the impact of grain size and impact speed on fracture toughness. Nuclear graphite specimens with larger grain sizes have more irregular grain and pore distributions, enhancing crack deflection and propagation resistance, thereby increasing fracture toughness. The observed loading rate dependence of dynamic fracture toughness is attributed to a gradual transition from intergranular to transgranular fracture modes with increasing impact speed.

Hierarchical looping results in extreme extensibility of silk fibre composites produced by Southern house spiders (Kukulcania hibernalis).

Spider silk is a tough and versatile biological material combining high tensile strength and extensibility through nanocomposite structure and its nonlinear elastic behaviour. Notably, spiders rarely use single silk fibres in isolation, but instead process them into more complex composites, such as silk fibre bundles, sheets and anchorages, involving a combination of spinneret, leg and body movements. While the material properties of single silk fibres have been extensively studied, the mechanical properties of silk composites and meta-structures are poorly understood and exhibit a hereto largely untapped potential for the bio-inspired design of novel fabrics with outstanding mechanical properties. In this study, we report on the tensile mechanics of the adhesive capture threads of the Southern house spider (Kukulcania hibernalis), which exhibit extreme extensibility, surpassing that of the viscid capture threads of orb weavers by up to tenfold. By combining high-resolution mechanical testing, microscopy and in silico experiments based on a hierarchical modified version of the Fibre Bundle Model, we demonstrate that extreme extensibility is based on a hierarchical loops-on-loops structure combining linear and coiled elements. The stepwise unravelling of the loops leads to the repeated fracture of the connected linear fibres, delaying terminal failure and enhancing energy absorption. This principle could be used to achieve tailored fabrics and materials that are able to sustain high deformation without failure.

To Monitor Fracture Behaviors in Four-Point Cyclic Bending Tests of Low-Activated High Alumina Concrete and Standard Concrete RC Beams Using Acoustic Emission Technique

In this study, acoustic emission monitory (AE) was used to observe and evaluate the mechanical behavior of two kinds of RC beam members, made of low-activation concrete and normal concrete, by general four-point bending test and cyclic four-point bending test. During the loading, acoustic emissions due to cracking, shearing, rubbing, de-bonding or interlocking could be monitored and recorded using a real-time high sampling rate DAQ system and proper sensors; besides, beam displacement, cracking situation and loading were also measured simultaneously. The experiment goals included: (1) to observe the damage mechanisms of the beams under bending test and their corresponding AE performance; and (2) to observe the material fracture and corresponding AE in the beams under the cyclic bending test of 0.5Hz (periodic dynamic condition). After experiments, the fracture history of the beam under general loading test could be revealed through the comparison for the chronicled AE signal density and load/strain data. The damage on beam under the cyclic test could be analysed through the chronological comparison for the cumulative sum of AE signal counts obtained for different test periods and stages. Both the irreversibility on fracture mechanism (affected by the Kaiser effect) and the “remainder toughness” could be discussed through the quantitative analysis on AE characteristics for two different beams. They might relate to the durability and toughness of material for beam.

On how pseudo-ductility modifies the translaminar fracture toughness of composites and the nominal strength of centre-cracked specimens

Among the efforts to revert the traditionally brittle characteristic of laminated composites, pseudo-ductility relies on utilising hybridisation to stimulate sub-critical damage mechanisms. However, how such pseudo-ductility would translate into an increase in material toughness or an improvement in the strength of the sub-components remains unclear. To elucidate this, we perform a numerical study departing from a parameterised pseudo-ductile model implemented in a finite element model. We use non-dimensional analysis to investigate the effect of the two most relevant parameters: pseudo-ductile strain (ɛd) and the ratio of ultimate strength to pseudo-ductile yield strength (σf/σy). We infer material toughness from the simulation of Compact Tension specimens, and it is shown to increase linearly with ɛd, and non-linearly with σf/σy but tends to a plateau. Then, the simulation of Centre Cracked scaled specimens reveal that the nominal strength increases on the elastic limit extreme (large specimens) but decreases below a given size.

Effect of the Atmospheric Plasma Treatment Parameters on the Surface and Mechanical Properties of Carbon Fabric.

The use of Atmospheric Pressure Plasma Jet (APPJ) technology for surface treatment of carbon fabrics is investigated to estimate the increase in the fracture toughness of carbon-fiber composite materials. Nitrogen and a nitrogen-hydrogen gas mixture were used to size the carbon fabrics by preliminarily optimizing the process parameters. The effects of the APPJ on the carbon fabrics were investigated by using optical and chemical characterizations. Optical Emission Spectroscopy, Fourier Transform Infrared-Attenuated Total Reflection, X-ray Photoelectron Spectroscopy and micro-Raman spectroscopy were adopted to assess the effectiveness of ablation and etching effects of the treatment, in terms of grafting of new functional groups and active sites. The treated samples showed an increase in chemical groups grafted onto the surfaces, and a change in carbon structure was influential in the case of chemical interaction with epoxy groups of the epoxy resin adopted. Flexural test, Double Cantilever Beam and End-Notched Flexure tests were then carried out to characterize the composite and evaluate the fracture toughness in Mode I and Mode II, respectively. N2/H2 specimens showed significant increases in GIC and GIIC, compared to the untreated specimens, and slight increases in Pmax at the first crack propagation.

Compact-tension-shear specimen for orthotropic materials in fracture toughness testing

Conducting Compact-Tension-Shear (CTS) tests emerges as a promising research methodology to determine the fracture toughness of orthotropic materials in mixed-mode I&II. However, the absence of pertinent fracture parameter solutions incorporating material orthotropy impedes the further application and standardization of CTS testing. Therefore, this study performed a systematic two-dimensional finite element analysis (FEA) on orthotropic CTS specimens to evaluate critical fracture parameters, including the normalized stress intensity factors (YI, YII) and compliance (u). First, the impacts of three commonly cited boundary conditions (BCs) of CTS models were investigated, revealing that the simplified or equivalent methods developed for isotropic CTS models are no longer applicable. Subsequently, the suitable CTS models were used to analysis the coupling effects of material orthotropy (λ, ρ), crack length ratios (a/W), and loading angles (β). Findings indicated that YI or u no longer exhibit a monotonic relationship with respect to a/W or β under strong orthotropy. The impact of λ and ρ on fracture parameters is equally significant across different geometries and loading conditions. Further, the impact of orthotropy on YII is relatively small, while the more affected YI may have a difference compared to isotropic results of over 80%. Finally, CTS tests were carried out on the unidirectional carbon fiber-reinforced epoxy resin composite measuring the fracture toughness in mixed-modes I&II. The obtained fracture parameter solutions were applied and validated during the process. The acquired results are poised to contribute to the advancement of fracture toughness testing standardization for orthotropic materials under mixed-mode loading.

On the intermolecular interactions and mechanical properties of polyvinyl alcohol/inositol supramolecular complexes

Hydrogen-bond (H-bond) cross-linking has recently been proven a promising strategy for simultaneously improving strength, toughness, and ductility of H-bonded polymers. However, there has been a lack of a fundamental understanding of how H-bond cross-linking works on a molecular level. To fill this knowledge gap, coarse-grained (CG) simulation provides a possibility because of its high computational efficiency and access to longer lengths and time scales. However, existing coarse-grained force fields and potential functions exhibit an inability to accurately describe H-bonded polymer systems. Herein, we report a modified CG model to understand the H-bond crosslinking effect of small molecules, inositol (IN) on polyvinyl alcohol (PVA), with reference to MARTINI 3.0 parameters and empirical data. The simulation results show that incorporating IN molecules results in a significant improvement in the strength, ductility, and toughness of PVA, which is in good agreement with experimental data. Moreover, the modified CG model establishes a close correlation between IN content, water content, tensile rate and glass transition, free volume, chain movement and mechanical properties of PVA. The results show that the yield strength of PVA initially increases and then decreases with the addition of IN. The maximum yield stress of PVA at IN-1.0 is approximately 155 MPa, representing a 33% increase compared to that of PVA. Additionally, the glass transition temperature (Tg) reaches 80.2 °C, ∼2.8 °C higher than that of pure PVA. This work develops a modified CG model for understanding intermolecular interactions and mechanical properties of H-bonded polymer systems on a molecular level. This understanding is expected to help expediate the material design and properties optimization of strong and tough polymeric materials.

IPP/HDPE blends compatibilized by a polyester: An unconventional concept to valuable products.

Polyolefins are the most widely used plastics accounting for a large fraction of the polymer waste stream. Although reusing polyolefins seems to be a logical choice, their recycling level remains disappointingly low. This is mainly due to the lack of large-scale availability of efficient and inexpensive compatibilizers for mixed polyolefin waste, typically consisting of high-density polyethylene (HDPE) and isotactic polypropylene (iPP) that, despite their similar chemical hydrocarbon structure, are immiscible. Here, we describe an unconventional approach of using polypentadecalactone, a straightforward and simple-to-produce aliphatic polyester, as a compatibilizer for iPP/HDPE blends, especially the brittle iPP-rich ones. The unexpectedly effective compatibilizer transforms brittle iPP/HDPE blends into unexpectedly tough materials that even outperform the reference HDPE and iPP materials. This simple approach creates opportunities for upcycling polymer waste into valuable products.