Introduction: For the Navier-Stokes equation, one of the most essential tasks should be to study its completeness of the complex nonlinear systems. Also, its nature and physical practical applications would be depth explored. Moreover, as one of the routes to chaos, this equation with an external force has been investigated numerically in 1989. Recently, some information is worth noting that when the high symmetry was imposed on the velocity field, the complex nonlinear motions should occur even lead to the chaos phenomenon. However, most of the published papers are based on theoretical studies and rarely deal with the above results, which lost of the match between them and the integrity of the scientific system.Methods: This study analyzed the molecular distillation process in detail based on the basic theory of nonlinear chaotic systems. Then, the mathematical model for the process of molecular distillation with one brushless DC motor (BLDCM) is built and named the Molecular-Distillation-Navier-Stokes (MDNS) equation. Also, its complex and potentially chaotic behaviors and chaotic processes are first discovered and demonstrated, such as chaotic attractors, chaotic co-attractors, phase portraits, time-domain waveforms, Lyapunov exponent spectrums, Poincare maps, the bifurcation diagrams, and so on.Results: The good agreement among theoretical analysis, simulation and experimental results verifies the practicability and flexibility of the configured model.Discussion: The related conclusions have supplemented and improved the theoretical system for the Navier Stokes equations. Also, it reflects the significance in molecular distillation processes. Meanwhile, the novel research direction for the fields of the chaotic nonlinear and complex industrial systems have been explored and discovered.