Three-phase Contact Line Research Articles

Electrostatic Surface Charging by Water Dewetting.

Water dewetting generates static electricity. We reviewed historical experiments of this phenomenon, and we studied the charging of polymer slides and metal electrode supported polymer films withdrawn vertically from a pool of aqueous solutions. For pure water, charging was negative and surface charge densities increased with the speed of dewetting, which we explain by the thermally activated entrainment of nanometer-sized water droplets or clusters charged by unbalanced adsorbed electric double-layer ions. Surface charge densities increased for reduced polymer film thickness following a power law, which we explain by reduced discharge of the entrained water volumes. At low salinity c ≲ 10 μM, charging was proportional to electrokinetic interfacial charge densities: the negative charging was increased for alkaline solutions and for most salts at μM concentrations and the charge polarity was inversed to positive for a cationic surfactant, a salt with a highly positively charged cation, and for a strong acid at approximately pH 4. Charging was reduced again for c ≳ 100 μM, especially at high dewetting speeds and for chaotropic ions, which we explain by the entrainment of larger and more discharged droplets. We determined adsorption energies of the charged water clusters on the dewetted surface from thermally stimulated discharge of the charged polymer slides and we show that the surface charge distribution, imaged by charged toner powders and measured microscopically by Kelvin probe force microscopy, is a record of the dewetting process that provides spatial and kinetic information about the three-phase contact line motion.

Formation dynamics of the satellite droplet in the breakup of a symmetrical liquid bridge

Inkjet printing technology has played an irreplaceable role in life science, precision manufacturing, and other frontier fields in recent years. However, the further development of this technology is limited by the fact that its printing resolution is difficult to raise to a higher level. The emerging satellite droplet printing technology offers a new approach for inkjet printing to break through the bottleneck of printing resolution limitations. In this paper, a symmetrical satellite droplet printing strategy is proposed. The effects of the geometric parameters of the satellite droplet generating device, the physical properties of the ink, and the operating parameters on the liquid bridge breakup process and the size of the satellite droplet are systematically studied. The phase field method and adaptive mesh refinement strategy are applied to solve the two-dimensional symmetrical model. The results indicate that the length of the liquid bridge, the radius of the bridge, the viscosity of the ink, and the drainage velocity are all positively correlated with the satellite droplet size, while the surface tension coefficient has a negative correlation with the satellite droplet size. Furthermore, the three-phase contact line at the orifice end will slip toward the center if the initial radius of the liquid bridge is quite large. Based on these investigations and discussions, a corresponding effective working space for satellite droplet printing is obtained, which lays the foundation for the popularization and further development of satellite droplet printing technology.

О влиянии «гидрофобности» газовой фазы на образование флотокомплексов в процессах флотации

Introduction. A model of a three-phase system in which, as a result of hetero coagulation from a bulk liquid, its thin layer has formed, the surfaces of which separate the gas and condensed phases with different potentials, is a wetting film. The study of wetting films adds to the knowledge of the nature of the structure-induced surface forces acting in them, which serves to develop the theory of hetero coagulation and is of interest for solving various topical problems of the theory and practice of flotation. The purpose of the work is to study the influence of “hydrophobic” properties of the gas phase on the separation of minerals by flotation with a vapor-air mixture in flotation schemes with jet countercurrent flow of feed and rough concentrate. Materials and Methods. Methods and installations have been developed to investigate the temperature dependence of the equilibrium thickness of wetting films and wetting edge angles. Studies of wetting films are supplemented by measurements of induction time at adhesion of minerals to each other and to an air bubble on a specially designed installation. In-situ flotation experiments were performed on a sample of apatite-nepheline ores. Results. The temperature dependence of the equilibrium thickness of the wetting film has been revealed, which does not contradict the experimentally established decrease of the exponentially decreasing (non-oscillating) part of the cleavage pressure with increasing temperature. It is shown that the temperature dependence of the boundary angles formed by the wetting film on the hydrophobic and hydrophilic surface is multidirectional. The connection between the temperature dependence of the boundary angle and the temperature dependence of the spreading coefficient obtained from Young’s law and determined by multiplication of parameters characterizing the magnitude and long-range action of forces caused by the difference between the structure and properties of the liquid in the boundary layers and their values in the volume is shown. “Hydrophobicity” of the bubble is associated with a smaller range effect of structural repulsion forces compared to hydrophobic attraction forces. By measuring the induction time, it is shown that the “hydrophobicity” of air manifests itself in the difference in the stability of wetting (when hydrophobic and hydrophilic particles adhere to the air bubble) and symmetric (when particles of the same hydrophobicity/hydrophilicity adhere to each other) films as the temperature increases. Discussion. In the framework of the phonon mechanism of surface forces, the dynamic structure of the liquid in the boundary layers (the sign and magnitude of the phonon component of the bowing pressure) determines the selectivity of aggregation and completeness of particle extraction, as well as the stability of symmetric and wetting films from temperature. Conclusion. When discussing the stability of disperse systems, the concepts of additional (to dispersive (van der Waals) and ionic-electrostatic interactions) forces associated with the overlap of boundary layers of liquids with structure parameters changed compared to their bulk values are fruitfully used. Such differences are understood as static deviations of the structure and properties of the liquid induced by the surface. However, the main reason for changes in the stability of wetting films at increasing temperature may be the high sensitivity to temperature of the entire set of rotational and vibrational motions of atoms and molecules of the liquid, i. e., its dynamic structure and the associated phonon component of the wedging pressure. Resume. The results of the study can be used to improve the technological performance of ores enriched by flotation. Consideration of the influence of linear tension on the system with the line of threephase contact will be useful for revealing the peculiarities of flotation of micro-dispersions of minerals by the developed technology.

Distinction of Plasmonic Intrananoparticle and Internanoparticle Molecular Reaction Rates at the Three-Phase Contact Line of an Evaporating Sessile Droplet.

Molecular reactions on the surface of a plasmonic nanoparticle (intrananoparticle) and between nanoparticles (internanoparticle) may differ in kinetics, dynamics, and product selectivity. We report that the difficulty in distinguishing the kinetics in a dispersion medium could be overcome by probing the reactions at the three-phase contact line (TPCL) of an evaporating sessile droplet using surface-enhanced Raman spectroscopy (SERS). Thus, when an evaporating aqueous droplet on glass containing 4-aminothiophenol-stabilized Ag nanoparticles was monitored by SERS at the TPCL, dimerization into 4,4'-dimercaptoazobenzene followed two steps, each preceded by the loss of H-bonded water accordingly. On the basis of the results, we assigned the first step with a higher relative kinetic rate (∼3 times) to be an intrananoparticle reaction and the second one as an internanoparticle reaction. In D2O medium, the ratio of the rates was ∼1.8. The observed vibrational signatures of the losses of water molecules before reactions and product formations were accounted for by using density functional theoretical calculations.

Contact Angle Modulation: In Situ Polymer Deposition during Sessile Drop Evaporation.

The drying kinetics of a sessile drop on a solid surface are a widely studied phenomenon because of their relevance to various fields such as coating, printing, medical diagnostics, sensing, and microfluidic technology. Typically, the drop undergoes drying either at a constant contact radius (R) with a decrease in the three-phase contact angle or at a constant contact angle (θ) with a reduction in the radius with time. These two drying modes are referred to as CCR and CCA, respectively. It is not uncommon where both R and θ may decrease during drying, especially in the penultimate stage of drying. In this work, we report a scenario wherein the θ increases while R decreases during the drying process of an aqueous polymer solution on a high surface energy substrate. This behavior is observed across different polymer systems (such as poly(ethylene oxide) and polyvinyl pyrrolidine), varying molecular weights, and polymer concentrations. As the drop dries, the polymer gets deposited at the three-phase contact line, thus reducing the surface energy of the substrate and leading to an increase in the contact angle. The drop responds by attempting to reach a new equilibrium contact angle through slipping. The temporal increase in contact angle follows a power law scaling behavior. This study demonstrates an in situ modulation of contact angle facilitated by evaporation and polymer deposition, showcasing unconventional drying dynamics.

Modulation of wetting state switching of droplets on superhydrophobic microstructured surfaces by external electric field

HypothesisElectrowetting on conventional dielectrics requires direct fluid-electrode contact to generate strong electric fields at the three-phase contact line to modulate the wetting. Since the electric field alters wetting, the modulation of wetting can be achieved by applying an external electric field through insulated electrodes, preventing the liquid from contacting the electrodes. ExperimentA simple and efficient method for non-contact between the fluid and the electrode external electric field modulation of fluid wetting was proposed. The switching ability of droplets on microgroove surfaces from Cassie-Baxter to Wenzel wetting state under an external electric field was used to drive and quantify the relationship between wetting, contact angle, and the applied voltage. FindingsApplying an external electric field modulates the wetting of deionized water, ionic liquids, and high-viscosity liquids on microgrooves. The wetting degree of liquid can be controlled by adjusting the external voltage parameters. The finite element simulations revealed that the Maxwell force drove this process. The effects of substrate size and liquid properties on wetting behavior were also examined. Post-application cross-sectional imaging showed the formation of a conformal interface, highlighting the relevance of the proposed method in advanced adaptive shape fabrication and microfluidic control, among other applications.

Elastocapillary interaction for particles trapped at the isotropic-nematic liquid crystal interface.

We present numerical simulations on pairwise interactions between particles trapped at an isotropic-nematic liquid crystal (Iso-N) interface. The particles are subject to elastocapillary interactions arising from interfacial deformations and elastic distortions of the nematic phase. We use a recent model based on a phase-field approach [see Qiu etal., Phys. Rev. E 103, 022706 (2021)2470-004510.1103/PhysRevE.103.022706] to take into account the coupling between elastic and capillary phenomena. The pair potential is computed in a two-dimensional geometry for a range of particle separations and two anchoring configurations. The first configuration leads to the presence of an anchoring conflict at the three-phase contact line, whereas such a conflict does not exist for the second one. In the first case, the results show that significant interfacial deformations and downward particle displacements occur, resulting in sizable attractive capillary interactions able to overcome repulsive elastic forces at intermediate separations. The pair potential exhibits an equilibrium distance since elastic repulsions prevail at short range and prevent the clustering of particles. However, in the absence of any anchoring conflict, the interfacial deformations are very small and the capillary forces have a negligible contribution to the pair potential, which is fully repulsive and overwhelmed by elastic forces. These results suggest that the self-assembly properties of particles floating at Iso-N interfaces might be controlled by tuning anchoring conflicts.

Contact-angle hysteresis on rough surfaces: mechanical energy balance framework

Using as a starting point conservation of momentum, a multiphase mechanical energy balance equation is derived that accounts for multiple material phases and interfaces present within a moving control volume. This balance is applied to a control volume that is anchored to a three-phase contact line as it advances continuously over the surface of a rough and chemically homogeneous and inert solid. Using semi-quantitative models for the material behaviour occurring within the control volume, an order of magnitude analysis is performed to neglect insignificant terms, producing an equation for predicting contact-angle hysteresis from a knowledge of the interface dynamics occurring around the three-phase contact line. It is shown that the viscous energy dissipation that occurs during the ‘stick–slip’ motion of the three-phase contact line, being the cause of contact-angle hysteresis on rough surfaces, can be calculated from changes in intermediate equilibrium interface states. The balance is applied to the Wenzel, Cassie–Baxter and Fakir (super-hydrophobic) wetting states, showing for the Fakir case that significant dissipation occurs during both interface advance and recede, and relating these dissipations to interfacial area changes that occur around the ‘stick–slip’ events.

A Molecular Expression for "Line Tension".

"Line tension", a concept that features in an additional term to the Young's equation, was introduced to describe the size dependence of contact angles of nanodroplets on surfaces. Although this concept describes the observations in a succinct, elegant manner, theorists have long had misgivings about the physical interpretation of the phenomenon. Papers have been published that attempt to nail down its value, which is reportedly very small (∼10 pN) and evidently even the sign has been uncertain. Attempts to interpret it in a mechanical manner analogous to interfacial tension, i.e., due to the curvature of the three-phase contact line, have run into conceptual problems that require invocations of ever more complex models. In this work, we have used molecular simulations to systematically relate "line tension" to the additional free energy per unit length of the three-phase line and found no direct relation. However, when we rederived the Young's equation without ignoring the interfacial molecules, we found a physically satisfying explanation for the size dependence of the contact angle of nanodroplets without invoking the curvature of the three-phase contact line. The new model does not have the elegant form of the modified Young's equation, but each parameter in it has an unambiguous physical interpretation. An approximate form of this model, linearized in the inverse droplet radius, yields a quantity that is mathematically analogous to what is conventionally called "line tension", but unpacked at the molecular level, showing that it is unrelated to a restoring force associated with the curvature of the macroscopic three-phase contact line.

Morphological evolution of nano-droplets impinging on cylindrical wall: A molecular dynamics study

The impact of droplets on solid walls is the primary behavior in spray cooling, seawater desalination, self-cleaning, and other technological processes. Based on the molecular dynamics (MD) method, the morphological evolution characteristics of nanodroplets impinging on the copper cylinder wall are studied. The effects of droplet size, initial velocity, impact position, and wall wettability on nanodroplet dynamics are analyzed. The results indicate that a single nanodroplet impacting on a nanocylinder exhibits four distinct impact modes: spread-partially wrapped-deposition (SPD), spread-completely wrapped-deposition (SCD), spread-completely wrapped-splitting-deposition (SCSD), and spreading-partially wrapped-splitting-deposition (SPSD). The trend of the influence of initial velocity and droplet size on the impact mode is similar. As the initial velocity and droplet size increase, the droplet’s kinetic energy and inertia force increase, successively exhibiting the SPD, SCD, and SCSD modes. The trend of the influence of impact position and wall wettability on the droplet impact mode is similar. When the impact eccentricity distance is small, and the wall is highly hydrophilic, it exhibits the SCD mode. With increasing impact eccentricity and enhanced wall hydrophobicity, the adhesion force between the droplet and the cylinder wall decreases, making the droplet less likely to be captured and more prone to splitting, exhibiting the SPSD mode. The change in droplet centroid height and mean square displacement could predict whether the droplet undergoes a splitting mode, and its influence is most significant at the impact position. Constrained by the cylindrical wall, the droplet impacts radially and spreads primarily in that direction. With the enhancement of wall hydrophilicity, the migration region of the three-phase contact line expands, and the droplet spreading transforms into synchronous development along the radial and axial directions. The research results can enrich the dynamic mechanism of micro-nano scale droplet impact and provide potential guidance for optimizing relevant technologies.

Features of the contact angle hysteresis at the nanoscale: A molecular dynamics insight

Understanding the physics of a three-phase contact line between gas, liquid, and solid is important for numerous applications. At the macroscale, the response of a three-phase contact line to an external force action is often characterized by a contact angle hysteresis, and several models are presented in the literature for its description. Yet, there is still a need for more information about such model applications at the nanoscale. In this study, a molecular dynamics approach was used to investigate the shape of a liquid droplet under an external force for different wetting regimes. In addition, an analytic model for describing the droplet shape was developed. It gives us the possibility to evaluate the receding and advancing wetting angle accurately. With our modeling, we found that the interplay between capillary forces and viscous forces is crucial to characterize the droplet shape at the nanoscale. In this frame, the importance of the rolling movement of the interface between liquid and vapor was pointed out. We also demonstrate that in the range of the external forces when capillary forces are most significant compared to others, hysteresis is well described by the macroscale Cox–Voinov model.

Understanding the Role of Loss Modulus of Viscoelastic Substrates in the Evaporation Dynamics of Sessile Drops.

Viscoelastic properties of soft substrates play a crucial role in the evaporation dynamics of sessile drops. Recent studies have revealed that the modification of the viscoelastic properties of substrates changes the dynamics of the three-phase contact line, consequently affecting the evaporation behavior of sessile drops. Notably, these modifications occur without any noticeable changes to the substrate's wetting characteristics or surface topography. However, the individual role of storage (G') and loss (G″) moduli of substrates on drop evaporation dynamics remains unexplored. In this study, we investigate the evaporation dynamics of water drops on two groups of poly(dimethylsiloxane)-based viscoelastic substrates possessing either identical G' with varying G″ or identical G″ with varying G'. Our study reveals that on a substrate with constant shear modulus (G'), a reduction of an order of magnitude in loss modulus shifts the evaporation process from the constant contact radius mode to the constant contact angle mode. We hypothesize that this observed shift in behavior stems from the varying viscoelastic dissipation influenced by the plateau modulus and characteristic relaxation time of polymer gels. Our hypothesis is further supported from the observation that the evaporation process persists on the substrate with constant loss modulus (G″). Our study advances the current understanding of drop evaporation on soft substrates that may find potential applications involving soft composites, biological entities, tissue engineering, and wearable electronics.

Turning Non-Sticking Surface into Sticky Surface: Correlation between Surface Topography and Contact Angle Hysteresis.

We present a surface modification technique that turns CuNi foam films with a high contact angle and non-sticking property into a sticky surface. By decorating with mesh-like biaxially oriented polypropylene (BOPP) and adjusting the surface parameters, the surface exhibits water-retaining capability even when being held upside down. The wetting transition process of droplets falling on its surface were systematically studied using the finite element simulation method. It is found that the liquid filled the surface microstructure and curvy three-phase contact line. Moreover, we experimentally demonstrated that this surface can be further applied to capture underwater air bubbles.

Enhancement of the Rate of Surface Reactions by the Elastocapillary Effect.

We examined the effect of deformability of a solid substrate on the kinetics of a surface reaction that occurs between chemical species present in it and a liquid dispensed on it. In particular, we have dispensed aqueous solutions of gold and silver salt as sessile drops or as a liquid pool on a cross-linked film of poly(dimethylsiloxane) (PDMS). The PDMS surface contains organosilane (SiH), which reduces the salt, producing metallic nanoparticles at the solid-liquid interface. These experiments reveal that, for a sufficiently soft solid, the reaction proceeds about three times faster in the drop mode than in the pool mode. The reaction conditions in both cases remain exactly identical except that, for the drop, the vertical component of the liquid surface tension deforms the solid substrate at the three-phase contact line. We have estimated the solid-liquid and solid-air interfacial energy, which along with the surface energy of the liquid gives an estimate of excess free energy. This energy is found to be different for the drop and pool modes. By considering that this excess free energy decreases the activation energy barrier for the reaction, we have shown that the reaction rate constant in the drop mode should indeed exceed that in the pool mode by about three times.

Molecular Dynamics Study of the Microscopic Mechanical Balance at the Three-Phase Contact Line of Interfacial Nanobubble.

This study reveals the microscopic mechanical balance at the three-phase contact line (TPCL) of an interfacial nanobubble on a substrate with a wettability pattern using molecular dynamics simulations. The apparent contact angle was compared to that evaluated using Young's equation, in which the interfacial tensions were computed using a mechanical route. The comparison was conducted by changing the wettability of the substrate from hydrophilic to neutral while maintaining a hydrophobic region in the center of the substrate. When the wettability pattern pins the TPCL at the wettability boundary, the contact angle computed by Young's equation is larger than the apparent contact angle because a pinning force exists in the inward direction of the nanobubble. Conversely, on the surfaces where the wettability pattern does not pin the TPCL, the contact angle computed by Young's equation agrees with the apparent contact angle because the pinning force disappears. The distribution of principal stresses around the TPCL, which was visualized for the first time in this study, indicates that large compressive principal stresses exist between the liquid phase and the solid substrate interface, which pin the TPCL at the surface wettability boundary, and that the maximum principal stress occurs in the inward direction of the nanobubbles at the TPCL. The normalized pinning force estimated from the maximum principal stress is equivalent to that measured experimentally.

How Surface and Substrate Chemistry Affect Slide Electrification.

When water droplets move over a hydrophobic surface, they and the surface become oppositely charged by what is known as slide electrification. This effect can be used to generate electricity, but the physical and especially the chemical processes that cause droplet charging are still poorly understood. The most likely process is that at the base of the droplet, an electric double layer forms, and the interfacial charge remains on the surface behind the three-phase contact line. Here, we investigate the influence of the chemistry of surface (coating) and bulk (substrate) on the slide electrification. We measured the charge of a series of droplets sliding over hydrophobically coated (1-5 nm thickness) glass substrates. Within a series, the charge of the droplet decreases with the increasing droplet number and reaches a constant value after about 50 droplets (saturated state). We show that the charge of the first droplet depends on both coating and substrate chemistry. For a fully fluorinated or fully hydrogenated monolayer on glass, the influence of the substrate on the charge of the first droplet is negligible. In the saturated state, the chemistry of the substrate dominates. Charge separation can be considered as an acid base reaction between the ions of water and the surface. By exploiting the acidity (Pearson hardness) of elements such as aluminum, magnesium, or sodium, a positive saturated charge can be obtained by the counter charge remaining on the surface. With this knowledge, the droplet charge can be manipulated by the chemistry of the substrate.

Effect of viscosity on bubble spreading on flat solid surfaces

The behavior and dynamics of bubble spreading has a great impact on interfacial contact area and time, which is significant for the heat/mass transfer or separation efficiency. In this work, the dynamical behavior of bubble spreading especially the three-phase contact line (TPL) on solid flat surfaces in low viscous liquids was investigated. The results show that the final length of TPL on homogeneous solid surfaces tend to decrease with the increasing liquid viscosity. For heterogenous solid surfaces, TPL motion on non-stick coal surface is basically the same as that on homogeneous solid surfaces, whereas that on anthracite surface shows an anomalous morphology. By applying the power-law model, the fast and slow spreading stages of bubble on homogeneous surfaces show the universal exponent of b = 1/2 and b = 1/10, respectively. While the exponent for bubble spreading on heterogeneous surface is complicated due to the special surface physico-chemical properties.

Near-wall depletion and layering affect contact line friction of multicomponent liquids

The main causes of energy dissipation in micro- and nanoscale wetting are viscosity and liquid-solid friction localized in the three-phase contact line region. Theoretical models predict the contact line friction coefficient to correlate with the shear viscosity of the wetting fluid. Experiments conducted to investigate such correlation have not singled out a unique scaling law between the two coefficients. We perform molecular dynamics simulations of liquid water-glycerol droplets wetting silicalike surfaces, aimed to demystify the effect of viscosity on contact line friction. The viscosity of the fluid is tuned by changing the relative mass fraction of glycerol in the mixture and it is estimated both via equilibrium and nonequilibrium molecular dynamics simulations. Contact line friction is measured directly by inspecting the velocity of the moving contact line and the microscopic contact angle. It is found that the scaling between contact line friction and viscosity is sublinear, contrary to the prediction of molecular kinetic theory. The disagreement is explained by accounting for the depletion of glycerol in the near-wall region. A correction is proposed, based on multicomponent molecular kinetic theory and the definition of a rescaled interfacial friction coefficient. Published by the American Physical Society 2024

Water Impalement Resistance and Drag Reduction of the Superhydrophobic Surface with Hydrophilic Strips.

Superhydrophobic surfaces (SHS) offer versatile applications by trapping an air layer within microstructures, while water jet impact can destabilize this air layer and deactivate the functions of the SHS. The current work presents for the first time that introducing parallel hydrophilic strips to SHS (SHS-s) can simultaneously improve both water impalement resistance and drag reduction (DR). Compared with SHS, SHS-s demonstrates a 125% increase in the enduring time against the impact of water jet with velocity of 11.9 m/s and a 97% improvement in DR at a Reynolds number of 1.4 × 104. The key mechanism lies in the enhanced stability of the air layer due to air confinement by the adjacent three-phase contact lines. These lines not only impede air drainage through the surface microstructures during water jet impact, entrapping the air layer to resist water impalement, but also prevent air floating up due to buoyancy in Taylor-Couette flow, ensuring an even spread of the air layer all over the rotor, boosting DR. Moreover, failure modes of SHS under water jet impact are revealed to be related to air layer decay and surface structure destruction. This mass-producible structured surface holds the potential for widespread use in DR for hulls, autonomous underwater vehicles, and submarines.

Impact dynamics of water droplets on oil-covered dielectrowetting substrate: Effects of oil film thickness and surface wettability

Droplet impacting on solid or liquid film is a ubiquitous phenomenon in relevant processes such as spray cooling and inkjet printing on primer layers. In this study, the dynamics of water droplets impacting a solid substrate covered by a silicon oil film is investigated under the influences of the surface wettability of the dielectrowetting substrate (69.3°-117.4°) and the thickness of the silicon oil film (7.79–21.8 μm) at We=6.81. A phase diagram is established, which reflects the relationships between the impact dynamic behavior, equilibrium contact angle, and the oil film thickness. The maximum spreading factor βmax and maximum out-of-plane height Hmax/D0 for rebound of sub-droplet behaviors was smaller than 13 % and greater than 3 times than those droplet deposition behaviors, respectively. Finally, the retraction dynamics of the droplet after reaching its maximum spreading diameter is analyzed and discussed based on retraction rate γw=vr/Dmax=σw(cosθrmin-cosθeq)/fkDmax through the force balance at the three-phase contact line. Results of the study indicate that the surface wettability of the dielectrowetting substrate and thickness of the silicon oil film significantly affect the impact dynamics of water droplets on a solid substrate covered by the silicone oil film, especially in the retraction stage. This study sheds new light on controlling the dynamic impact of the droplets on silicon oil films, which is of importance to the control or optimization of processes such as inkjet printing on a primer layer.