Abstract
We present numerical simulations on pairwise interactions between particles trapped at an isotropic-nematic liquid crystal (Iso-N) interface. The particles are subject to elastocapillary interactions arising from interfacial deformations and elastic distortions of the nematic phase. We use a recent model based on a phase-field approach [see Qiu etal., Phys. Rev. E 103, 022706 (2021)2470-004510.1103/PhysRevE.103.022706] to take into account the coupling between elastic and capillary phenomena. The pair potential is computed in a two-dimensional geometry for a range of particle separations and two anchoring configurations. The first configuration leads to the presence of an anchoring conflict at the three-phase contact line, whereas such a conflict does not exist for the second one. In the first case, the results show that significant interfacial deformations and downward particle displacements occur, resulting in sizable attractive capillary interactions able to overcome repulsive elastic forces at intermediate separations. The pair potential exhibits an equilibrium distance since elastic repulsions prevail at short range and prevent the clustering of particles. However, in the absence of any anchoring conflict, the interfacial deformations are very small and the capillary forces have a negligible contribution to the pair potential, which is fully repulsive and overwhelmed by elastic forces. These results suggest that the self-assembly properties of particles floating at Iso-N interfaces might be controlled by tuning anchoring conflicts.
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