This paper focuses on the characteristic study of polymer matrix composites using a statistical approach, in terms of difference experimental and reflected to difference stacking sequence and orientation of composite lamination. Composite material, have an excellent characteristic and behavior, but with a difference application and materials used, it have a difference phenomenon occurred before the composite structure are collapsed. Therefore, in order to understand the characteristic of polymer matrix composites, it needs to investigate the phenomenon that influences the structure of composite lamination before failures. In this research, polymer matrix composites are produced using difference material and stacking sequence of lamination. The matrix used is thermoset epoxy and polyester resin with chopped strand mat (CSM) and woven roving (WR) as reinforcement materials. It has been produced using hand lay-up technique. The experimental work is carried out using the tension and flexural test accordance to ASTM-D3039 and D-D790 standard. By using a statistical approach, it can clearly show the differential between materials used with a characteristic of composite materials. It is noted, based on this investigation it also showed difference phenomenon failures and damage structure of polymer matrix composites with difference type of experimental.