Temperature Gradient Research Articles

Open-pit post-blast dust cloud lightning

Lightning has been observed in dust clouds following open-pit blasting. It is proposed that the occurrence of this phenomenon is related to the physical composition and characterization of the mineral fines that comprise the bulk of the dust cloud. Silicate minerals, which are susceptible to fine fracturing during blasting, generate the initial charge. This is further enhanced by collisions and friction during the turbulent upcast in the post-blast dust cloud. Varying size fractions result in different rates at which these particles drop out of suspension and create a secondary temperature gradient. This results in the creation of two charged zones and increases the potential of developing a discharge in the form of lightning. The ideal prevailing meteorological conditions need to be windless to minimize the effect of particle dissipation and have sufficient moisture to enhance the potential of generating lightning.

Vacuum-Boosting Precise Synthetic Control of Highly Bright Solid-State Carbon Quantum Dots Enables Efficient Light Emitting Diodes.

Carbon quantum dots (C-dots) have emerged as efficient fluorescent materials for solid-state lighting devices. However, it is still a challenge to obtain highly bright solid-state C-dots because of the aggregation caused quenching. Compared to the encapsulation of as-prepared C-dots in matrices, one-step preparation of C-dots/matrix complex is a good method to obtain highly bright solid-state C-dots, which is still quite limited. Here, an efficient and controllable vacuum-boosting gradient heating approach is demonstrated for in situ synthesis of a stable and efficient C-dots/matrix complex. The addition of boric acid strongly bonded with urea, promoting the selectivity of the reaction between citric acid and urea. Benefiting from the high reaction selectivity and spatial-confinement growth of C-dots in porous matrices, in situ synthesize C-dots bonded can synthesized dominantly with a crosslinked octa-cyclic compound, biuret and cyanuric acid (triuret). The obtained C-dots/matrix complex exhibited bright green emission with a quantum yield as high as 90% and excellent thermal and photo stability. As a proof-of-concept, the as-prepared C-dots are used for the fabrication of white light-emitting diodes (LEDs) with a color rendering index of 84 and luminous efficiency of 88.14lm W-1, showing great potential for applications in LEDs.

DIGIT: An In Situ Experiment for Studying the Diffusion of Water and Solutes under Thermal Gradient in the Toarcian Clay Rock at the Tournemire Underground Research Laboratory: Part 1—Goals, Scoping Calculations, Installation and First Results under Unheated Conditions

DIGIT: An In Situ Experiment for Studying the Diffusion of Water and Solutes under Thermal Gradient in the Toarcian Clay Rock at the Tournemire Underground Research Laboratory: Part 1—Goals, Scoping Calculations, Installation and First Results under Unheated Conditions

Potential impacts of reduced winter Kara Sea ice on the dipole pattern of cold surge frequency over the tropical western Pacific

The impact of Arctic Sea ice melting on weather and climate extremes in the Northern Hemisphere has garnered widespread attention. Existing research has convincingly demonstrated the importance of this impact in mid-high latitudes, while its influence in areas beyond remains controversial. This study reveals the indirect influence of Kara Sea ice reduction on cold surge (CS) over the tropical western Pacific (TWP), with the East Asian jet stream serving as the connecting link. The leading mode of CSs over the TWP exhibits a zonal dipole characteristic, which is associated with cyclonic anomaly over the Philippine Sea. The enhanced cyclonic anomaly is caused by strengthened and northward-moved subtropical East Asian jet stream and weakened polar jet stream, which can lead to more CSs over the South China Sea and fewer CSs over the Philippine Sea. Such variations in the jet stream are contributed by the facilitated atmospheric blockings west of the Ural Mountains, which suppressed the circumpolar westerly winds and increased meridional temperature gradient in Northeast Asia. The connection between atmospheric blockings and Kara Sea ice can be confirmed through local vertical energy exchange. Simulations of the atmospheric response to the forcing of decreased Kara Sea ice support the proposed connection. Although there is no statistically significant correlation between tropical CSs and Kara Sea ice, this study highlights the potential impacts of Arctic climate change signal on weather and climate extremes over tropical regions.

Definition of a thermal conductivity map for geothermal purposes

The use of geothermal energy is spreading globally due to its many advantages, especially for heating and cooling. The correct design of a geothermal system requires knowledge of the parameters of the subsoil rocks, and particularly the thermal conductivity (k), which is the intrinsic ability of a material to transfer thermal energy as a result of a temperature gradient. A thermal conductivity map of the geological formations is time-consuming to produce, but can be of great help when selecting the location of a low-enthalpy geothermal installation, resulting in significant savings and an increase in the efficiency of that installation. The preferred option for determining k is an in situ thermal response test, but laboratory methods may be an alternative if it is not available or affordable. In this work, the needle thermal probe method has been used to measure the k of representative outcropping rocks in Oviedo (NW Spain), since it allows to obtain a rapid determination, its cost is comparatively low and it can be implemented in a portable device. 162 measurements have been carried out on a total of 27 samples, ranging from 0.2 (clay) to 5.4 W m−1 K−1 (quartzite). A relationship has been found between the k of the rocks and their characteristics, such as mineralogy, anisotropy or geological age and a thermal conductivity map was created.

Target Tracking Two Degrees of Freedom State Feedback Control for Continuous Flow Microfluidic Chips Temperature Controller

Microfluidic chips represent a cutting-edge technology for manipulating fluids within micrometer-scale spaces and are gradually becoming a new favorite platform in life science research. Precise and fast zonal temperature control is essential for accelerating biological experiments. However, current multi-channel temperature controllers typically rely on multiple channel sets to achieve single set-point control, which results in discrepancies between the fluid temperature distribution and sensor temperature due to the distributed temperature field in the fluid channel. To estimate the actual temperature and implement gradient temperature control, this paper introduces an extension of the target tracking (TT) two degrees of freedom (2DOF) state feedback control (SFC) method, followed by a presentation of simulation and experimental results. Through comparisons with an enhanced PID system in both simulation and experimentation, the paper demonstrates an 8.96% reduction in the maximum temperature difference across different regions and a 27.89% decrease in the time taken to reach various temperatures. This solution effectively addresses the existing challenges in temperature control for microfluidic chips, offering a more precise and stable control within the desired temperature range.

Metabolic plasticity drives mismatches in physiological traits between prey and predator

Metabolic rate, the rate of energy use, underpins key ecological traits of organisms, from development and locomotion to interaction rates between individuals. In a warming world, the temperature-dependence of metabolic rate is anticipated to shift predator-prey dynamics. Yet, there is little real-world evidence on the effects of warming on trophic interactions. We measured the respiration rates of aquatic larvae of three insect species from populations experiencing a natural temperature gradient in a large-scale mesocosm experiment. Using a mechanistic model we predicted the effects of warming on these taxa’s predator-prey interaction rates. We found that species-specific differences in metabolic plasticity lead to mismatches in the temperature-dependence of their relative velocities, resulting in altered predator-prey interaction rates. This study underscores the role of metabolic plasticity at the species level in modifying trophic interactions and proposes a mechanistic modelling approach that allows an efficient, high-throughput estimation of climate change threats across species pairs.

Microwave heating-assisted chemical looping dry reforming of methane

Chemical looping dry reforming of methane (CLDRM) offers a sustainable pathway to convert methane (CH4) and carbon dioxide (CO2) to syngas, i.e., a mixture of hydrogen (H2) and carbon monoxide (CO). However, carbon deposition caused by high gas temperature remains a crucial challenge for the CLDRM. We proposed microwave (MW) heating-assisted CLDRM to leverage the selective heating feature of MWs to create a thermal gradient between solid and gas phases. This thermal gradient, i.e., a higher solid temperature than the gas temperature, can promote desired reduction and oxidation (redox) reactions, while suppressing undesired gas phase reactions, in particular, CH4 decomposition. At bulk temperature of 800 °C, the MW heating-assisted CLDRM achieved a maximum CH4 conversion of 97% and H2/CO ratio of around 2. Compared to the conventionally heated CLDRM, the MW heating increased the redox extents of magnetite (the oxygen carrier) by 2.5 and 1.5 times, respectively, and suppressed carbon deposition.

Impact of variable viscosity, thermal conductivity, and Soret–Dufour effects on MHD radiative heat transfer in thin reactive liquid films past an unsteady permeable expandable sheet

AbstractSignificance of magnetohydrodynamic effect on a viscous (temperature‐dependent) and chemically reactive thin fluid film flow past an unsteady permeable stretchable plate with Soret–Dufour effects, nonlinear thermal radiative, and suction under the action of a convective type of boundary condition is analyzed. The problem consists of nonlinear governing basic equations that are highly nonlinear due to the existence of nonlinear thermal radiative terms in the energy equation. Analytical solutions are challenging to achieve for such types of problems, so a numerical scheme adopts the numerical solution. Computed solutions indicate that decreasing the Dufour number (and simultaneously increasing the Soret number) enhances heat flux, whereas the reverse trend is estimated for the concentration gradient field. The influence of magnetization indicates a decrement in the thin liquid film velocity distribution, whereas an increment is observed in temperature and solutal gradient profiles. Further, an enhancement in thermoradiative values focuses on decreasing the heat flux profiles, whereas a decreasing trend is determined in the solutal gradient by incrementing the Schmidt number. The variations of the velocity field, temperature, and concentration gradients are shown for the unsteady parameter lying in the range [0.8, 1.4]. Similarly, the range of different parameters utilized are [0.0, 1.0], [0.0, 2.0], [0.8, 1.5], [0.5, 2.0], [0.0, 1.0], [0.2, 3.0], [1.0, 2.0], [0.0, 3.0], [0.4, 1.0], and [0.4, 1.0]. The novelty of the present study lies in its analysis of complex fluid dynamics phenomena and their implications for various industrial processes and engineering applications, including coating processes, heat exchangers, microfluidics, and biomedical engineering. The insights gained from the study can contribute to developing more efficient and innovative research in these areas. Further, we have compared the present results with those available in the literature under some special cases and found them to be in excellent agreement.

Integrated internal-external thermal modeling for packed pebble beds

In this study, an integrated external-internal thermal DEM model is introduced in a GPU environment. The external model considers contact conduction and radiation, exhibiting accuracy validated against effective thermal conductivity (ETC) under packed bed conditions. The effective radiation range for a mono-sized packed bed is determined to be 3.5rp, providing accurate predictions of ETC. The internal model integrates FDM-based discretization to solve heat generation, heat conduction and thermal expansion. The model well predicts the temperature gradient of a sphere with partial heat generation. Additionally, preliminary analysis is conducted on the postulated heat generation of packed beds under a complete coolant-loss condition. The results reveal that fission-induced expansion may impact local porosity variations exceeding 2.5%. It is also observed that internally homogeneous models may overestimate heat transfer in packed beds, critical for safety. The model's accuracy and feasibility are demonstrated, providing insights for future research.

Pyrolysis of shenmu coal to prepare blue-coke used as reductant

Blue-coke is a form of granular char prepared by medium-low temperature pyrolysis of low-rank coal. As a reductant, it has been widely used in calcium carbide production, ferroalloy, copper pyro refining, and ferrosilicon production in China due to the abundant reserves of raw coal and its excellent performance. However, there is little research on the pyrolysis process of granular coal to produce blue-coke and its characteristics as a reductant. Thus, the effects of pyrolysis temperature, heating rate, particle size and holding time at the final temperature on blue-coke preparation were investigated in a rotary kiln reactor. The quality index of blue-coke as a reductant and its properties, including the element composition, surface function groups, carbon forms, reactivity and lower heating value under different pyrolysis temperatures, were analyzed in detail. It is demonstrated that the pyrolysis temperature had a more significant impact on the quality of blue-coke compared to other pyrolysis conditions. With the rise of pyrolysis temperature, the blue-coke’s C/O and C/H increased. With the particle size and heating rate increased, the temperature gradients developed within the granular coal during the pyrolysis process led to the volatile release shifting to higher temperature zone and more secondary reaction occurrence. Nevertheless, the secondary reaction was restrained in the rotary kiln with good heat and mass transfer. The indexes of blue-cokes as reductants were met by the chars produced at temperatures from 550 oC to 750 oC with a holding time 60 min at this temperature and a heating rate of 10 oC/min. As the key index of blue-coke, the electrical resistivity decreased with the increase of pyrolysis temperature. It was found to be closely related to the removal of H and O heteroatom at the pyrolysis temperature below 700 °C. While at the higher temperature, the development of graphitized carbon structure took a major role on it. Nonetheless, the crystallite sizes of the blue-coke obtained under this low temperature pyrolysis were small and the carbon forms were turbostratic. These resulted in the blue-coke's high combustion reactivity, which would gradually decline with the rise of pyrolysis temperature.

Numerical investigation of CH4/H2/air micro-mixing combustion flow in a micro gas turbine combustor with different head-end structures

In order to investigate the premixed combustion characteristics of CH4/H2/air in a micro-mixing combustor, the effects of different micro-mixing head-ends (HE1, HE2, HE3) and hydrogen mixing ratios on the temperature distribution, heat transfer process, emission characteristic, flames shape are analyzed. The results show that compared with swirl head-end combustion, the micro-mixing combustion performance is better. Among the three head-ends, HE3 has the best combustion characteristics and stable flames. The temperature distribution in the high-temperature zone is uniform, and low-temperature zone is concentrated near the jet, which can suppress the flashback. The velocity and temperature gradient near the central axis of jet streams show a strong synergistic effect. The flames are plume shaped and flames stability is mainly influenced by the H2 combustion process. Increasing the jet diameter, decreasing the jet spacing and increasing the hydrogen mixing ratio all contribute to the flames stability, but these three methods can stabilize the flames by affecting fluid Reynolds number, interaction between small flames and combustion rate, respectively. Moreover, small jet diameter and high hydrogen mixing ratio can reduce OTDF, which contributes to improve outlet temperature uniformity.

In situ observation and reduction of hot-cracks in laser additive manufacturing

Cracking during Laser Additive Manufacturing is a problem for many higher-strength aluminium alloys, including AA6061. Here, we used a pulsed laser with ramp-down power modulation to improve the cracking resistance by about 50% compared to the use of a rectangular pulsed laser. Using synchrotron in situ X-ray imaging at 100,000 images s−1, ground truth data was obtained about changes in melt pool geometry, solidification rate, and thermal gradients were calculated. An analytical hot cracking model was developed to show that these changes lead to a decreased hot tear susceptibility. Therefore, laser pulse modulation can be an effective tool to reduce crack susceptibility of alloys. More fundamentally, the results demonstrate that modifying thermal conditions provides a pathway to crack elimination in LAM and the model established in our study sets the foundation for further complex laser manipulation in modifying the printability and resulting mechanical properties of hard-to-process alloys in Laser Additive Manufacturing.

Internal temperature estimation for lithium-ion batteries through distributed equivalent circuit network model

Lithium-ion cells experience significant internal thermal gradients during operation, with a direct impact on their safety, performance, cost and lifetime. The estimation of the internal temperature of cells is therefore particularly important. In this work, a 3D distributed electro-thermal model for internal temperature estimation is developed for a cylindrical cell (LG M50T, NMC811). The model is parameterized and comprehensively validated against experimental data for 21700 cells, including direct core temperature measurements. Multiple types of electrical load are considered, including constant current discharge, pulse discharge, drive cycle and instant discharge/charge switching. The developed model is used to estimate core temperature based on surface temperature measurement. The predictions are shown to have good accuracy at relatively low computational cost. We show that the widely adopted two-node lumped thermal estimation model is increasingly inaccurate for more aggressive discharges, when thermal gradients become higher. Compared to the standard two-node model, the distributed equivalent circuit network model predicts the effects of detailed internal cell structure (electrode, current collector, metal can and tab) and distributed internal heat generation. The results are of immediate interest to cell manufacturers and battery pack designers, while the modelling and parameterization framework is a useful tool for energy storage systems design.

Microstructural and mechanistic insights into the Tension–Compression asymmetry of rapidly solidified Fe–Cr alloys: A phase field and strain gradient plasticity study

Rapid solidification in Additively Manufactured (AM) metallic materials results in the development of significant microscale internal stresses, which are attributed to the printing induced dislocation substructures. The resulting backstress due to the Geometrically Necessary Dislocations (GNDs) is responsible for the observed Tension–Compression (TC) asymmetry. We propose a combined Phase Field (PF)-Strain Gradient J2 Plasticity (SGP) framework to investigate the TC asymmetry in such microstructures. The proposed PF model is an extension of Kobayashi’s dendritic growth framework, modified to account for the orientation-based anisotropy and multi-grain interaction effects. The SGP model has consideration for anisotropic temperature-dependent elasticity, dislocation strengthening, solid solution strengthening, along with GND-induced directional backstress. This model is employed to predict the solute segregation, dislocation substructure and backstress development during solidification and the post-solidification anisotropic mechanical properties in terms of the TC asymmetry of rapidly solidified Fe–Cr alloys. It is observed that higher thermal gradients (and hence, cooling rates) lead to higher magnitudes of solute segregation, GND density, and backstress. This also correlates with a corresponding increase in the predicted TC asymmetry. The results presented in this study point to the microstructural factors, such as dislocation substructure and solute segregation, and mechanistic factors, such as backstress, which may contribute to the development of TC asymmetry in rapidly solidified microstructures.

Interfacial delamination mechanism of thermal barrier coatings with real microstructure considering gradient thermal and growth strains based on the fracture phase field

The interface of atmospheric plasma spray (APS) thermal barrier coatings (TBCs) is highly irregular and rough, while their microstructure is porous and extremely uneven. This complexity leads to intricate patterns during the growth of thermally grown oxide (TGO), the distribution and evolution of the generated stress, as well as the initiation and expansion of cracks. Along these lines, in this work, a phase-field theory considering both the thermal gradient strain and TGO growth was established to thoroughly investigate the interface oxidation cracking in TBCs. More specifically, a two-dimensional geometric model of APS TBCs was established, incorporating real interface morphology and microstructure. Numerical simulations and experiments were also conducted to study the temperature and stress distribution, as well as the underlying mechanism of interface cracking during the service of TBCs. The results indicated that at high temperatures, the bottom temperature of the top coating (TC) layer with a porosity of 3.1% and a thickness of 200 μm was approximately 5 °C lower than that of the TC layer without porosity. Compared to the ideal model without pores, the model considering the real microstructure, with the presence of microcracks in the TC, makes it easier for the normal stress in the TGO at the peak region to be released. The inter-lamella cracks (Type A) in the TC near the peaks initiated earliest, followed by the creation of inter-lamella cracks at other locations, accompanied by the appearance of lamella-fracture cracks (Type B), inter-lamella to interfacial cracks (Type C), inter-lamella to TGO cracks (Type D), and internal TGO cracks (Type E). The coalescence of all these types of cracks will ultimately lead to coating failure.

Local temperature evaluation of Si ribbon under a temperature gradient by Kelvin-probe force microscopy

Local temperature evaluation of Si ribbon under a temperature gradient by Kelvin-probe force microscopy

Ultralight air-filled hollow yarn fabrics for efficient thermal insulation and its heat and mass transfer mechanism

Fibrous thermal insulating materials rely on retaining stationary air in their porous structure for effective insulation. However, hollow fibers lose their insulation when turned into textiles due to compression. In this study, we developed connected knitted loop sheaths to create stable hollow yarns. This direct formation allowed immediate use in fabric weaving, avoiding flattening during spinning. Comprehensive experimental analyses examined hollowness, porosity, mass density, and thermal resistance of air-filled hollow (AFH11AFH: air-filled hollow.) yarn fabrics. Results showed remarkable hollowness (41.62%) and porosity (87.509%), effectively trapping stagnant air and enhancing insulation while maintaining a lightweight structure. Computational Fluid Dynamics (CFD) revealed that minor temperature gradients and negligible airflow within the hollow structure minimized heat transfer, resulting in superior thermal insulation performance. These insights aid in designing textiles with hollow yarns for desired insulation and thermal comfort.

Simulation of thermal field in mass concrete with cooling pipes based on the isogeometric analysis method

As the water pipe cooling system is widely applied to controlling temperature in mass concrete structures, the precise simulation of the temperature field in mass concrete with cooling pipes embedded is meaningful. This paper presents an isogeometric analysis (IGA) with NURBS for heat transfer in mass concrete with consideration of the cooling pipe. The proposed method not only achieves the same level of accuracy with fewer nodes but also eliminates the time-consuming process of mesh in the traditional FEM. The coarsest parameter space which depicts small pipe and large concrete precisely is constructed to create an efficient model for numerical computation. In addition, the unique k-refinement in IGA is supposed to be the most appropriate encryption mechanism, and the knot insertion vector for effective refinement is calculated by considering the characteristics of temperature gradient distribution around the cooling pipes. In addition, a different calculation parameter has been discussed to show the stability and flexibility of the IGA. The obtained numerical results demonstrate the accuracy and efficiency of the proposed scheme in the simulation of transient temperature fields in concrete structures with cooling systems.

Experimental and Numerical Investigation of Single-Phase Liquid Cooling for Heterogeneous Integration Multichip Module

Abstract The variety of new electronic packaging technologies has grown significantly over the last 20 years as a result of market demands for higher device performance at lower costs and in less space. Those demands have pushed for heterogeneous packaging, where computer chips with different stack heights are closely packed, creating nonuniform heat flux and temperature and additional challenges for thermal management. Without implementing an appropriate thermal management strategy for heterogeneous packages, large temperature gradients can be observed within the package, which would increase the thermal stresses on the chip and raise reliability issues. To mimic this real-life scenario of such packaging, an experimental setup was designed and built. The design of the new experimental setup consists of four identical 1.2 cm × 1.2 cm ceramic heaters, each of which is connected to a separate power supply and can reach a heat flux of 140 W/cm2. Accordingly, this mock package is capable of delivering different power levels to mimic different multicore microprocessor conditions. To give the heater the ability to move precisely in the x-, y-, and z-directions, each heater is mounted to an XYZ linear stage. Deionized water (DI) was used as the working fluid, and a pin-fin heat sink was used to run the initial steady-state tests on the experimental rig. The tests showed how different flow rates at a constant fluid temperature and input power affect the temperatures of the heaters and the thermohydraulic performance of the heat sink. In addition, a three-dimensional numerical model has been developed and validated with experimental data in terms of heat sink pressure drop and the temperatures of the heaters.