Nozières' exhaustion theory argues that the temperature for coherently screening of all local moments in Kondo lattice could be much lower than the temperature of single moment screening in case of insufficient conduction electrons. Experiments indicate that cerium based nickel pnictides CeNi2−δAs2(δ≈0.28) is an ideal material to exam such protracted Kondo screening. Using density functional theory plus dynamical mean-field theory, we found CeNi2As2 presents a transition from the local moment states to the coherent Kondo screening states under compression, accompanied by topological changes of the Fermi surface. Similar phase transition could be driven by chemical pressure via the isovalence As→P substitution. The derived coherent Kondo temperature Tcoh is much lower than the single-impurity Kondo temperature TK due to the diluted Ni-3d conduction electrons, indicating the protraction of Kondo screening in crystal. In contrast to structurally analogous layered iron pnictides, the electronic structures of the present systems show strong three-dimensionality.
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