The article identifies problems and threats to Ukraine’s employment sphere functioning, its labor force’ reproducing and using, which will remain relevant at various stages of the post-war revival, taking into account their influence on the implementation of the national economy’ competitiveness factors in the globalized world (needs for: the economic complex’ and its territorial subsystems’ diversification; accelerated development and clustering of innovative and knowledge-intensive types of activities; raising and fulfilling standards of productive employment, decent work and life quality). The effectiveness of the employment sphere’ functioning, which is based on the processes and results of the workforce’ reproduction and use, is one of the key factors of competitive businesses’ management, socium progress and social harmony in the conditions of neo- and post-industrial economic modes that have been spreading throughout the world and its macro-regions. The organization, the regulation priorities of the employment sphere, trends and problems of its functioning determine a multiplicative cluster of incentives and disincentives for the life quality in Ukraine in a number of its manifestations, among which, in particular, – the characteristics of the living environment (household, work), resource base, indicators and peculiarities of human resources’ reproduction and use that are of great importance for recovering from war losses and damages in Ukrainian post-war realities against the further globalization processes’ background. The above-mentioned factors, potentiated by established socially recognized practice and already achieved parameters of the life quality, outline long-term material and immaterial incentives and motivators of individual and community human development, parameters and processes of diversification of the national economy’ and the labor market’ territorial segments, and therefore – expectations and sustainability of positive post-war socioeconomic and, among other, demographic, professional and qualification, migration shifts.