Effect Of Temperature Research Articles

An Insight into the Varying Effects of Different Cryogenic Temperatures on the Microstructure and the Thermal and Compressive Response of a Mg/SiO2 Nanocomposite

An Insight into the Varying Effects of Different Cryogenic Temperatures on the Microstructure and the Thermal and Compressive Response of a Mg/SiO2 Nanocomposite

Green adsorption of quinoline as basic N-compounds from liquid fuel using mesoporous and Fe-functionalized walnut shell-activated carbon

Removing nitrogenous compounds from liquid fuels is essential, and adsorption de-nitrogenation is a new process for this goal. This work has the purpose of investigating quinoline adsorption using Iron functionalized Activated carbon (IFAC) mesoporous nanocomposite. The mesoporous nanocomposite was synthesized in a one-step process by chemical activation of the walnut shell using Iron chloride as the activation and modification agent. The IFAC mesoporous nanocomposite was utilized to remove quinoline from isooctane as the liquid fuel via a discontinuous (batch) process by examining the effect of initial concentration, contact time, and temperature. The effect of contact time on the adsorption ability of IFAC for quinoline was well described by the pseudo-second-order model. The Langmuir model described the equilibrium manner of the process well, and the adsorbent could retain 344.82 mg/g of quinoline (37.37 mg N/g). The thermodynamic parameters show the endothermic (ΔH°= +30.070 kJ/mol) and spontaneity of the adsorption process. The regeneration experiments indicated that functionalized AC’s adsorption ability for quinoline adsorption decreased by 23% after five cycles. The obtained data indicate that the functionalization of activated carbon surface with iron particles leads to improving its adsorption ability toward N-containing compounds from liquid fuels.

Effect of Elevated Temperatures on Compressive Strength, Ultrasonic Pulse Velocity, and Transfer Properties of Metakaolin-Based Geopolymer Mortars

Effect of Elevated Temperatures on Compressive Strength, Ultrasonic Pulse Velocity, and Transfer Properties of Metakaolin-Based Geopolymer Mortars

Insight into adsorption behaviors of shale oil in kerogen slit by molecular dynamics

Shale oil is predominantly stored in organic nanopores, with kerogen playing a pivotal role in its adsorption. This study utilizes molecular dynamics (MD) simulations to quantitatively investigate the adsorption behavior of multi-component shale oil within kerogen slits. Unlike previous studies that focused on single-component hydrocarbon fluids and simplified kerogen models to graphene, this research employs an authentic kerogen structure and a multi-component shale oil model, incorporating the effects of surface roughness. The research analyzes the interaction mechanisms and distribution patterns of light, medium, and heavy components within the pores. Additionally, it examines the effects of temperature, pore size, and wall surface physical and chemical properties on shale oil adsorption. Results indicate that strong adsorption between asphaltene and kerogen significantly reduces the width of the kerogen slits, inhibiting the adsorption of lighter components. The study introduces the concept of effective radius for kerogen slits and provides a quantitative analysis of the adsorption capacity of kerogen surfaces. Different kerogen surface roughness and chemical properties were compared to understand their influence on shale oil adsorption. Key findings show that with increasing temperature, the distribution of hydrocarbons becomes more uniform, with medium components showing the most significant response. Surface roughness of kerogen affects the adsorption capacity, although the component proportions remain consistent, while different chemical property surfaces influence selective adsorption and the overall adsorption amount of shale oil components. This research offers a deeper understanding of shale oil adsorption mechanisms and provides valuable insights for optimizing shale oil extraction and utilization.

Effect of temperature and particle size on dielectric property of vanadium-titanium magnetite

The current body of research on microwave-assisted grinding of vanadium-titanium magnetite (VTM) predominantly focuses on the analysis of changes in particle size and dissociation degree of the grinding products. Nonetheless, the microwave heating mechanism of the ore remains inadequately explored. In this study, the dielectric property of VTM with different particle sizes were measured at a frequency of 2.45 GHz and temperatures ranging from ambient to 800 °C. The results indicate that the dielectric constants (ε′) and dielectric loss factors (ε″) of VTM increase with temperature. The loss tangent coefficients (tan δ) initially increase and then decrease, reaching a maximum value of 0.44 at approximately 500 °C. The values of dielectric property parameters increase as the particle size decreases. By calculating the penetration depth equation, it can be determined that the optimal particle size for uniform heating in microwave of VTM is approximately 15 ∼ 30 mm. The heating rate of the ore in the microwave field is divided into two stages. Initially, the heating rate is very fast due to the ore being a strong magnetic mineral. However, when the ore temperature reaches 500 °C, the tan δ of the ore decreases, leading to a decrease in the heating rate.

The effect of temperature on the sealability of bismuth–tin alloy plugs

Innovative solutions for plugging oil and gas wells are becoming increasingly important to ensure safe operations, save costs, and guarantee that the wells are sealed with a long-term perspective. Among these innovations, bismuth alloys have emerged as a potential sealing material, attracting attention for their distinctive properties. Despite the promising characteristics of bismuth alloys, comprehensive testing is required to fully understand their behavior and to validate their suitability as a sealing barrier. This study focuses on testing the sealability of eutectic bismuth-tin alloy plugs across a range of temperatures (23–120 °C). Examining this influence is crucial because bismuth alloys can be engineered to have specific melting points and characteristics, allowing them to respond effectively to the prevailing temperature conditions in the wellbore. To this end, the study employs an integrated approach, combining laboratory experiments and numerical simulations, to assess the performance of the plug under the influence of the variables pressure, temperature, and curing time through push-out tests. Preliminary results indicate that the sealing efficiency of the bismuth-tin alloy tends to increase over time at lower temperatures, whereas it decreases significantly as temperatures approach its melting point. Therefore, the eutectic bismuth-tin alloy can be employed safely as an environmental plug, but its applicability as a deep-set plug in high-temperature wells is questioned. In this case, selecting an alloy that has a higher melting point is recommended. This work not only underscores the necessity of understanding the thermodynamic influences on bismuth alloys but also sets the stage for future innovations in well sealing technologies, potentially establishing new industry standards.

Methanol electrooxidation performance of nickel-modified polyaniline thin films for direct methanol fuel cells

A metal–organic composite thin film composed of polyaniline (PANI) and Ni was prepared and characterized for methanol electrooxidation reaction. First, PANI thin films were electrodeposited on a fluorine-doped tin oxide (FTO) coated glass support in an aqueous acidic solution. Subsequently, the polymer film was modified with Ni particles (FTO/PANI-Ni) by chronoamperometric (CA) technique. The composite film was characterized by structural, morphological and electrocatalytic analyses. X-ray diffraction (XRD) results confirmed the crystallization of Ni according to the cubic structure. Scanning electron microscopy (SEM) images showed that the Ni nanoparticles were uniformly dispersed on the PANI surface. The electrocatalytic performance of the FTO/PANI-Ni composite electrode for the methanol electrooxidation reaction was investigated in 0.5 M KOH solution containing methanol using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and chronoamperometry (CA) techniques. The effects of temperature and methanol concentration on the methanol electrooxidation performance were also studied. The modified composite catalyst exhibited an electrochemically active surface area of 0.5235 cm2. The presence of Ni nanoparticles on the polymer surface promoted the adsorption of methanol molecules and facilitated the oxidation process, leading to higher current densities and better overall performance. The maximum current density was 14 mA cm-2 and the electrode maintain 68 % of its initial activity even after 200 cycles, indicating that the FTO/PANI-Ni electrode exhibited good stability. The high methanol oxidation performance of the composite electrode was associated with large real surface area, a possible synergistic effect between the polymer moleucles and Ni particles as well as high intrinsic activity of Ni for this process.

Effect of heat aging on pull-off strength of FRP epoxy bonded concrete: An experimental study and fire modelling

In this study, the bonding strengths of three different types of externally bonded composite systems were investigated under different environmental aging conditions at high temperatures, and the finite element model for a roof fire and concrete slab fire from above evaluated if the beams were externally reinforced with fiber-reinforced polymers (FRP). An FRP system is a structural reinforcement made of a type of fiber reinforcement fixed to a concrete surface through an epoxy adhesive. The bonding strength between the FRP and concrete substrates was measured using a pull-off test machine, as described in the EN 1542 standard. This study aims to determine the deterioration and negative effects of miscellaneous high temperatures on externally bonded FRPs used for strengthening civil structures. Epoxy-bonded carbon fiber-reinforced polymers (CFRP), glass fiber-reinforced polymers (GFRP), and basalt fiber-reinforced polymers (BFRP) were exposed to various temperatures of 23°C (control conditions), 70, 85, 100, 115, 130, and 150°C. Duratek® AV21 epoxy-based lamination system was used as an adhesive between the concrete and the FRP sheet. Three bonding failure modes (adhesive, cohesive, and substrate) were investigated for each test. The results were compared for three different types of FRPs under various temperatures, which is also significant research on the heat aging of the degradation process. The test results were also evaluated using finite element (FE) software modelling for roof and slab fires exposed from above, where the beams under the slab were reinforced with FRP systems. The test pull-off test results and FE model thermal analysis results were evaluated to obtain the temperature rise in the critical section of the concrete beam/slab in existing retrofitted buildings. The FE model results showed a critical temperature rise on the beam-slab corner connection as a result of the fire above the concrete slab. The duration of the FRP systems effectively bonded to the concrete beams located under different slab thicknesses and pull-off results were evaluated at elevated temperatures.

Residual strength and time to failure of bonded wooden lap joints at high temperatures and superimposed constant loading

ABSTRACT The study focused on the effect of high temperatures on wooden bond lines of single lap tensile shear specimens according to EN 302-1 made from beech wood at superimposed sustained mechanical loading. The quasi-duration of load (DOL) tests encompassed temperature levels of 160–232°C with specimens loaded at 30% of their mean shear strength at ambient temperature for 40 min. The investigations comprised one phenol resorcinol formaldehyde (PRF), two melamine urea formaldehyde (MUF) and three one-component polyurethane (1C-PUR) adhesives as well as solid wood reference specimens. Complementary ramp load tests were performed with specimens heated in unloaded state up to 250°C. The investigations revealed three highly differentiated adhesive DOL behaviours although showing a well comparable pure temperature-bound strength reduction effect at 200°C. PRF and one MUF showed little to no additional influence of applied load, while for two 1C-PUR brands a drastic impact on survival times and residual strength was revealed. One MUF and a special 1C-PUR forwarded results between both extremes. The investigations provide evidence that the assessment of the temperature behaviour of structural adhesives can be biased when relying exclusively on ramp load tests with specimens heated in unloaded state, and thus necessitates a superimposed load as present in realistic fire scenarios.

Research on the characteristics of hydrogen production by methanol steam reforming in a Fresnel lens concentrated tubular reactor

The methanol steam reforming process involves variable heat absorption along the flow direction, resulting in a non-uniform temperature within the reactor. To improve the hydrogen production performance, this paper introduces an innovative solar-driven reactor, the Fresnel Lens Concentrated Collector Tubular Reactor (FLCCTR), which matches solar energy collection with the endothermic reforming process through optimized design. The heat flux density on the reactor's inner wall was determined using the Monte Carlo method. Subsequently, a 3D model was developed that integrates flow, heat and mass transfer, along with reforming kinetics. This model assessed the effects of inlet flow rate, temperature, steam-to-methanol ratio, and heat flux density type on hydrogen production performance. Results indicate that the inlet flow rate significantly affects performance, with the reactor maintaining a minimal radial temperature difference of 3.554K. It also indicated that non-uniform heat flux reduces the temperature increase and CO output by 36.84% at the outlet.

Tree size partially mediates the influence of climate on fruit and seed production in Ricinodendron heudelotii (Baill.) Heckel

AbstractUnderstanding environmental drivers of fruit and seed production in wild edible fruit species is essential for their valorisation. Ricinodendron heudelotii is an oilseed plant whose kernels are particularly treasured in cosmetic and medical industries. This study assessed fruits and seeds production patterns of R. heudelotii. Data were collected for three consecutive years on 30 trees in the phytodistricts of Plateau, Pobè and South Borgou where it naturally occurs. Tree dbh, total height, crown diameter, number of fruits and seed mass were measured. Climatic data were obtained from NASA Power Database. Data were analysed using linear (seed mass) and generalised linear (number of fruits) mixed models and structural equation modelling. Fruit and seed production were significantly higher in the South‐Borgou phytodistrict (1433 ± 1144 fruits, 4.26 ± 3.39 kg of Dry matter per tree) and Plateau phytodistrict (1.66 ± 0.35 g DM/seed). Tree dbh further significantly mediated the effect of minimum temperature, and relative humidity on seed mass. Tree dbh, irradiance and dry season rainfall were identified as the best‐predictors of seed mass production (kg DM). These results improved current knowledge of the fruit and seed production of R. heudelotii and are of significant importance for the exploitation of the species.

Electrically‐Triggered Oblique Helicoidal Cholesterics with a Single‐Layer Architecture for Next‐Generation Full‐Color Reflective Displays

AbstractElectrically‐induced oblique helicoidal cholesterics (ChOH) are attractive for use in reflective displays due to tunable photonic band gap (PBG) in a broad spectral range and natural eye‐friendly feature. However, the lack of a stable liquid crystal (LC) material system with a wide temperature range and unknown driver architecture hinder the implementation of the ChOH‐based reflective displays. Here, a prototype for a full‐color reflective display device based on electrically‐tunable ChOH‐LC is demonstrated. In the comparison of ChOH‐S1, S2 and S3 samples, the electric‐field‐induced ChOH in the ChOH‐S3 exhibits intense Bragg reflection and a tunable PBG in the extended temperature range from 19.5 °C to 30 °C. Particularly, the resulting device exhibits a lower driving voltage and a relatively larger color gamut for the full‐color reflective displays. On this basis, the display patterns with variable colors are demonstrated via the direct addressing mode. Furthermore, a proof‐of‐concept of the full‐color reflective display is demonstrated with red‐green‐blue pixeled images serving as the active panels. Ultimately, by regulating the electric field strength dependent on the ambient temperature, a stable and vivid effect of the ChOH device on the actual environment is shown. This work provides valuable insight for the development of ChOH‐based reflective displays.

Species-specific differences and temperature-dependence of Na+/K+-ATPase in freshwater mussels Anodonta anatina and Unio tumidus (Bivalvia: Unionidae)

The predicted global warming of surface waters can be challenging to aquatic ectotherms like freshwater mussels. Especially animals in northern temperate latitudes may face and physiologically acclimate to significant stress from seasonal temperature fluctuations. Na+/K+-ATPase enzyme is one of the key mechanisms that allow mussels to cope with changing water temperatures. This enzyme plays a major role in osmoregulation, energy control, ion balance, metabolite transport and electrical excitability. Here, we experimentally studied the effects of temperature on Na+/K+-ATPase activity of gills in two freshwater mussel species, Anodonta anatina and Unio tumidus. The study animals were acclimated to three ambient temperatures (+4, +14, +24 °C) and Na+/K+-ATPase activity was measured at those temperatures for each acclimation group. Both species had their highest gill Na+/K+-ATPase activity at the highest acclimation temperature. Na+/K+-ATPase activity of gills exhibited species-specific differences, where it was higher in A. anatina than U. tumidus in all test groups at all test temperatures. Temperature dependence of Na+/K+-ATPase was confirmed in both species, being highest at temperatures between +4 and + 14 °C when Q10 values in the acclimation groups varied between 5.06 and 6.71. Our results underline the importance of Na+/K+-ATPase of gills for the freshwater mussels in warming waters. Because Na+/K+-ATPase is the driving force behind ciliary motion, our results also suggest that in warming waters A. anatina may be more tolerate at sustaining vigorous ciliary action (associated with elevated respiration rates and filter-feeding) than U. tumidus. Overall, our results indicate great flexibility of the mussel's physiological system as response to changing conditions.

Performance-Degradation Analysis of the Planetary Roller Screw Mechanism under Multi-Factor Coupling Effects

The performance-degradation pattern of the planetary roller screw mechanism (PRSM) is difficult to predict and evaluate due to a variety of factors. Load-carrying capacity, transmission accuracy, and efficiency are the main indicators for evaluating the performance of the PRSM. In this paper, a testing device for the comprehensive performance of the PRSM is designed by taking into account the coupling relationships among temperature rise, vibration, speed, and load. First, the functional design and error calibration of the testing device were conducted. Secondly, the PRSM designed in the supported project was taken as the research object to conduct degradation tests on its load-bearing capacity and transmission accuracy and analyze the changes in transmission efficiency. Third, the thread profile and wear condition were scanned and inspected using a universal tool microscope and an optical microscope. Finally, based on the monitoring module of the testing device, the vibration status during the PRSM testing process was collected in real time, laying a foundation for the subsequent assessment of the changes in the performance state of the PRSM. The test results reveal the law of performance degradation of the PRSM under the coupled effects of temperature, vibration, speed, and load.

Production of activated carbon from spent coffee grounds (SCG) for removal of hexavalent chromium from synthetic wastewater solutions

In this research, spent coffee grounds (SCG) are converted into a highly valuable porous adsorbent which removes chromium (VI) from wastewater with high efficiency. A set of nine Spent Coffee Ground Activated Carbon (SCG-AC) adsorbent samples were synthesized, by varying key parameters including pyrolysis temperature (400, 600 °C), pyrolysis duration (1 and 2 h), and the impregnation ratio of the activating agent, KOH (ranging from 0:1 to 2:1). Characterizations of these adsorbent samples were conducted by advanced analytical tools including SEM, EDX, XRD, FTIR, TGA, and BET. Furthermore, we carried out adsorption studies, exploring the effects of temperature and dosage variations. Additionally, point zero charge experiments and desorption studies were carried out to further understand the adsorption process. The outcomes of our investigation demonstrate the successful synthesis of these spent coffee ground-derived adsorbents, with a yield of up to 34%. Notably, these adsorbents exhibited high efficiency in extracting chromium (VI) from water, with removal efficiencies ranging from 75% to 100%. The adsorption isotherms revealed the Langmuir model to be the most fitting descriptor of the adsorption behavior. Moreover, a thermodynamics study revealed the process to be endothermic in nature which furthers our understanding of the underlying mechanisms. Importantly, our cost assessment shows the economic advantage of the synthesized adsorbent over commercial counterparts such as zeolite, making it a competitive choice for real-world applications. In summation, the study not only introduces an innovative and sustainable utilization of spent coffee grounds but also delivers an in-depth exploration of the synthesized adsorbent's ability in chromium (VI) removal. Our holistic approach, encompassing thorough experimentation, characterization, and economic evaluation, solidifies the significance of this research in tackling environmental concerns and propelling advancements in wastewater treatment methodologies.

Effects of Temperature on the Microbial Growth and Quality of Unsealed Dry Pet Food during Storage

Effects of Temperature on the Microbial Growth and Quality of Unsealed Dry Pet Food during Storage

Pyrolysis of wheat straw pellets in a pilot‐scale reactor: Effect of temperature and residence time

AbstractPyrolysis of two types of pellets (T1: 100% wheat straw, and T2: 70% wheat straw; 10% sawdust, 10% biochar, and 10% bentonite clay) was performed in a pilot‐scale reactor under a nitrogen environment at 20°C to 700°C. This was to investigate slow pyrolysis yields and gas composition as a function of temperature and residence time. The experimental data were obtained between 300°C and 600°C, with a residence time of 90 min, a nitrogen flow rate of 50 cm3/min, and a heating rate of 20°C/min. The results indicated that the maximum pyrolysis temperature is 605°C with a residence time of 55 min. The product analysis showed that the proportion of gas was higher than that of biochar and bio‐oil. The conversion efficiency increased with higher temperatures and varied between 66% and 76%. The results showed that carbon dioxide was the main component in the produced gas, and the maximum gas concentration was 63.6% at 300°C for T1. The higher temperature and longer residence time increased the syngas (CO + H2) composition for both T1 and T2 treatments. Nevertheless, the produced biochar had a high carbon content and retained a high calorific value, indicating slow pyrolysis is the ideal utilization route of wheat straw pellet biomass for biochar.

Effects of temperature gradient on functional fruit traits: an elevation-for-temperature approach

Fruit traits mediate animal-plant interactions and have to a large degree evolved to match the sensory capacities and morphology of their respective dispersers. At the same time, fruit traits are affected by local environmental factors, which may affect frugivore-plant trait match. Temperature has been identified as a major factor with a strong effect on the development of fruits, which is of serious concern because of the rising threat of global warming. Nonetheless, this primarily originates from studies on domesticated cultivars in often controlled environments. Little is known on the effect of rising temperatures on fruit traits of wild species and the implications this could have to seed dispersal networks, including downstream consequences to biodiversity and ecosystem functioning. In a case study of five plant species from eastern Madagascar, we addressed this using the elevation-for-temperature approach and examined whether a temperature gradient is systematically associated with variation in fruit traits relevant for animal foraging and fruit selection. We sampled across a gradient representing a temperature gradient of 1.5–2.6 °C, corresponding to IPCC projections. The results showed that in most cases there was no significant effect of temperature on the traits evaluated, although some species showed different effects, particularly fruit chemical profiles. This suggests that in these species warming within this range alone is not likely to drive substantial changes in dispersal networks. While no systemic effects were found, the results also indicate that the effect of temperature on fruit traits differs across species and may lead to mismatches in specific animal-plant interactions.

Effects of Temperature on the Microbial Growth and Quality of Unsealed Dry Pet Food during Storage

Effects of Temperature on the Microbial Growth and Quality of Unsealed Dry Pet Food during Storage

Effect of temperature on dynamic strain aging and intermediate temperature embrittlement of nickel-based alloy N06625

Due to its excellent mechanical properties and good corrosion resistance at low to intermediate temperatures, nickel-based alloy N06625 has gradually become an ideal material for high-temperature gas-cooled reactor evaporators in nuclear power plants. It is currently receiving more and more attention. In this work, the tensile test of nickel-based alloy N06625 was carried out at room temperature to 900℃. The dynamic strain aging (DSA) process and microstructure evolution were studied by electron back-scatter diffraction (EBSD). The dynamic strain aging and intermediate temperature embrittlement of nickel-based alloy N06625 in the temperature range 25–900℃ were systematically studied. The results show that the stress-strain curve exhibits a serrated shape at 200–700℃, and with the increase in temperature, the serrated type changes from type A to type A+B and type C. The type A and type (A+B) serrations are related to the diffusion of interstitial carbon atoms. The interaction between substitutional elements Cr and Mo and movable dislocations causes the type C serration. As the temperature increases, high-density dislocations accumulate at the grain boundaries, and the proportion of substructural grains increases. A brittle fracture occurs at 600–800℃. The fracture mechanism may be due to the stress concentration at the grain boundary caused by the appearance of micropore, which weakens the grain boundary's strength and promotes the grain boundary's early failure. The continuous increase of strain makes the micropore fuse and grow to form a crack source.