We investigated the photoluminescence intensity and material gain values of GaN based laser structures with various well widths in the active layer by temperature dependent photoluminescence and optical gain measurements. The existence of two different nonradiative recombination channels can be demonstrated by temperature dependent photoluminescence measurements at low excitation densities. This results in two thermal activation energies which can be attributed to distinct activation processes. The influence of the nonradiative recombination is also reflected by the temperature dependence of the required material gain values.