Temperature-dependent Curves Research Articles

Low-Temperature Growth of Centimeter-Sized 2D PdSe2 by Self-Limiting Liquid-Phase Edge Epitaxy.

Two-dimensional (2D) PdSe2 atomic crystals hold great potential for optoelectronic applications due to their bipolar electrical characteristics, tunable bandgap, high electron mobility, and exceptional air stability. Nevertheless, the scalable synthesis of large-area, high-quality 2D PdSe2 crystals using chemical vapor deposition (CVD) remains a significant challenge. Here, we present a self-limiting liquid-phase edge-epitaxy (SLE) low-temperature growth method to achieve high-quality, centimeter-sized PdSe2 films with single-crystal domain areas exceeding 30 μm. The SLE growth mechanism, clarified by theoretical calculations and time-of-flight secondary ion mass spectrometry (ToF-SIMS), reveals that hydrogen ions on the precursor surface inhibit vertical growth while promoting lateral growth. The as-grown PdSe2 few-layer exhibits a surface roughness of 1.20 nm and an average conductivity of 1.67 × 10-6 S/m, demonstrating their smoothness and uniformity. Temperature-dependent electrical measurements and transfer characteristic curves confirm the orthorhombic PdSe2's bipolar semiconductor behavior. The photodetector based on few-layer PdSe2 films exhibit excellent optoelectronic performance in the 405-1650 nm wavelength range, achieving a responsivity of 6262.37 A W-1, a detectivity of ∼1012 Jones under 1064 nm illumination, and a fast response time of 37.1 μs, making them highly suitable for broadband photodetection applications. This work provides valuable insights into the scalable synthesis of PdSe2 few-layers and establishes a foundation for the development of PdSe2-based integrated functional devices.

From layered 2D carbon to 3D tetrahedral allotropes C12 and C18 with physical properties related to diamond: Crystal chemistry and DFT investigations

Mechanisms of changes from 2D to 3D (D = dimensionality) involving 2D C(sp2) trigonal paving to C(sp3) tetrahedral stacking are proposed through puckering of the 2D layers on one hand and interlayer insertion of extra C on the other hand. Such transformations, led to 3D hexagonal C12 and C18 allotropes respectively characterized by lon and bac topologies. Using density functional theory DFT calculations, the two allotropes were found cohesive and stable both mechanically (elastic properties) and dynamically (phonons). Comparisons of the physical properties with known uni C6 were established letting identify ranges of large Vickers hardness: HV (uni C6) = 89 GPa, HV (lon C12) = 97 GPa, and HV (bac C18) = 70 GPa. Whilst C6 was identified with acoustic phonons instability, C12 and C18 were found stable dynamically throughout the acoustic and optic frequency ranges. Furthering on the thermal properties the allotropes were characterized with a temperature dependence curve of the specific heat CV close to experimental data of diamond with best fit for novel C18. The electronic band structures reveal a small band gap of 1 eV for uni C6 and larger direct band gap of 3 eV for the two other 3D allotropes. Such modulations of the electronic and physical properties should open scopes of carbon research.

Photoluminescence properties of Mn2+-activated red-emitting phosphors with superior thermal stability for backlighting display applications

The red-emitting phosphors, Na2Mg1-x(PO3)4:xMn2+ with concentrations ranging from 0.01 to 0.11, have been successfully synthesized using a simple solid-state method. The as-synthesized phosphors are crystallized in an orthorhombic structure. The luminescence mechanism of Mn2+ ions in Na2Mg(PO3)4 lattice has been deeply explained using the Tanabe-Sugano (T-S) energy level diagram for the d5 electron configuration. The typical photoluminescent emission (PL) and photoluminescent excitation (PLE) spectra were measured. Several excitation peaks in the spectral range of 250–550 nm on the PLE spectrum and a strong emission peak at 613 nm indicate that the as-synthesized phosphors can be effectively excited using ultraviolet (UV) and near-UV LED chips. Several photometric characteristics were measured, such as the Commission International de'LEclarirage (CIE) chromaticity coordinate (x, y), color purity (CP), and correlated color temperature (CCT), corresponding to the concentration-dependent PL spectra. Furthermore, the thermal stability of the Na2Mg1-x(PO3)4:xMn2+ phosphors was investigated through temperature-dependent PL spectra and decay curves from 10 to 500 K. All results confirm that the as-synthesized red-emitting phosphors exhibit excellent thermal stability, which are attractive characteristics for white light emitting diodes (W-LEDs) applications.

Modelling and Analysis of Inhomogeneous Back-to-Back Schottky Junction Diode

Back-to-back Schottky diode (BBSD) is a simple device structure made from Schottky junctions that can be applied in various applications. In modelling and simulating the BBSD, the inhomogeneity of the barrier height at the Schottky interface should be considered. This paper presents device models and simulation result of an inhomogeneous BBSD. Two device models with different current spreading condition are considered. The distribution of the inhomogeneous barrier height is represented by Gaussian distribution. All the computation was done using Python programming software. When the standard deviation of the barrier height increases, the apparent barrier height that influence the electrical characteristic decreased. This is consistent with the reported experimental data. Device model that considers full current spreading showed 37.8% reduction of apparent barrier height at standard deviation of 100 meV. This is greater that the model with no current spreading. The ideality factor showed correlation with the standard deviation of barrier height, particularly when no current spreading is considered. At standard deviation of 100 meV, the ideality factor increased 2.6 %. The obtained non-unity ideality factor is associated to the significant fluctuation in the barrier height. The computed temperature-dependent current curves also showed good agreement with the reported experimental results. The device model can be a convenient tool to investigate the device operation and to validate the method used for extraction of Schottky barrier parameters.

Brightening dark excitons in inorganic halide perovskites by local symmetry breaking

Thermally activated delayed fluorescence (TADF) phenomenon, defined as thermal activation of triplet dark-state excitons into singlet state excitons through reverse intersystem crossing (RISC), has become a prevalent principle for designing organic-based electro-/photo-luminescent molecules. However, activating dark excitons in inorganic metal halide perovskites (MHPs) still remains challenging. Herein, we report an efficient strategy of doping-induced local symmetry breaking to brighten dark excitons in inorganic halide perovskite Cs2ZrCl6, which result in a 500 % enhancement of low-temperature luminescence emission. Lattice symmetry breaking confirmed by the X-ray absorption spectroscopy measurements could disturb the local coordination environment at the Zr site. The singlet-triplet energy gap (ΔEST) fitted from temperature-dependent photoluminescence decay curves decreases from 0.087 to 0.071 eV, thus reducing up-conversion barrier of dark excitons. Theoretical calculation indicates large spatial separation of charge density favorable for enhanced TADF emission. Furthermore, a flexible X-ray scintillator screen with poly (dimethylsiloxane) as the matrix could obtain high-quality X-ray imaging with a 14 lp mm−1 resolution. This work gives insights into improving photoemission of inorganic MHPs via brightening dark excitons.

Comparative Evaluation of Falling Weight Deflectometer, Traffic Speed Deflectometer and Rapid Pavement Tester in Deflection Measurement

This study intends to compare deflections obtained from traffic speed deflection devices (TSDDs) with the deflections of the falling weight deflectometer (FWD). For this purpose, deflections were measured on five sections of three roads in the Norwegian road network using traffic speed deflectometer (TSD) and rapid pavement tester (Raptor). Deflections were also measured using FWD at three different temperatures and the curves of FWD deflections versus temperature (FWD temperature-dependent deflection curves) were obtained. These curves were used to correct the effect of temperature difference. It was shown that both TSD and Raptor have the potential to detect structural deficiencies; however, TSD had better consistency with FWD with regard to deflection values and deflection basin parameters. A refinement was then made to make the Raptor data more consistent with FWD data. Calculating bearing capacity before and after refinement revealed that refining Raptor data can substantially increase the consistency between Raptor and FWD.

Strain and orientation modulated optoelectronic properties of La-doped SrSnO3 epitaxial films

We have studied the structural, electrical, and optical properties of La0.05Sr0.95SnO3 thin films, which exhibited a strong dependence upon the substrate’s orientation and strain. X-ray diffraction results show that the LSSO films grow epitaxially on (001) and (011)-oriented LaAlO3 substrates, and the in-plane compressive strain decreases gradually upon increasing film thickness. Room-temperature resistivity varies from 4.23 (13.0) to 1.37 (4.76) mΩ cm as the film thickness increases for (001) orientation ((011) orientation). Temperature dependent resistivity curves of all the samples show a metal–semiconductor transition (MST), which can be explained by the electron–electron interactions below MST rather than weak localization. Both reducing the in-plane compressive strain and transferring the orientation from (011) to (001) can drive the MST point shifts toward lower temperature, indicative of the enhancement of the metallic transport in the films. The band gap increases upon increasing film thickness due to Burstein-Moss effect. The charge distributions of Sn and O from density functional theory (DFT) calculations illustrate that (001)-plane has a better conductivity. Furthermore, our DFT results also demonstrate that decreasing the in-plane strain will lead to a smaller electron effective mass, thus the increased carrier mobility can be obtained. These comprehensive investigations advance our knowledge of the optoelectronic characteristics and provide valuable insights for future research in related transparent materials.

Broad temperature range with stable permittivity and low dielectric loss in (1–2x)Na0.5Bi0.5TiO3-xNaNbO3-xGdFeO3 system

High-temperature capacitors have garnered increasing attention in current research due to the inability of commercially available capacitors to meet the evolving industry demands. In this study, a Na0.5Bi0.5TiO3 based ternary system, denoted as [(1–2x)(Na0.5Bi0.5TiO3) -x(NaNbO3) -x(GdFeO3): x=0.01–0.09], was synthesised through solid-state reaction route. The influence of NaNbO3 and GdFeO3 on phase structure, dielectric, and ferroelectric properties are investigated. A fall of polar R3c phase % from X-ray refinement studies, diminishing macroscopic polarization, increasing breakdown strength, and flattening of temperature-dependent dielectric permittivity curves are perceived with the increase of substituent concentration. Temperature stable permittivity of (1–2x)(Na0.5Bi0.5TiO3) -x(NaNbO3) -x(GdFeO3) calculated ε'r/ε'r [250℃] at 1, 10, 100, 500 kHz with 10 % tolerance. Remarkably, (Δε′/ε′250°C ≤ ± 10 %) with x = 0.07 and 0.09 showed stable permittivity in the wide temperature range of (30°C to 600°C) at 500 kHz and a minimal dielectric loss (tan δ ≤ 0.01) measured at 250°C makes it a promising candidate for high-temperature dielectric capacitor applications.

Adjustment in phonon scattering through doping to boosting the Near-IR photoresponse performance of p-type SnSe nanosheets

As a p-type semiconductor, layered SnSe has attracted more and more attention because of its great potential application in the field of optoelectronics. However, the strong phonon scattering caused by abundant intrinsic vacancy defects dramatically reduces the performance of carrier transport. It is significant to effectively compensate for the intrinsic defects and reduce the phonon scattering for photodetection materials. In this letter, a novel and simple method is used to reduce the scattering and thus improve the detector performance. The inhibition effect of doping on phonon scattering is systematically studied by experiments and theoretical calculations. The Bi-doped SnSe photodetector exhibits great responsivities of 2.13 A W−1 (447 nm), 1.35 A W−1 (655 nm) and 1.91 A W−1 (980 nm) at 5 V, which are about 2∼3 folds better than those of the undoped device. Furthermore, for the Bi-doped SnSe photodetector, the Ion/Ioff are about 46.7, 20.3 and 30.3 for 447 nm, 655 nm and 980 nm, respectively, which are much higher than those of the SnSe photodetector. The photoluminescence and absorption are performed to confirm the bandgap and defects energy level. Meanwhile, the temperature-dependent current-voltage curves measurement is utilized to prove that the enhancement in response performance is because of the decrease in intensity of phonon scattering, which is attributed to the reduction of scattering centers and the weakening of the effect of vacancy defects on the structural translational asymmetry. All these results evidently illustrate that adjustment in phonon scattering is an effective way to achieve high-performance SnSe photodetectors.

Modelling the Response of Timber Beams Under Fire

A fundamental requirement for analysing timber structures under fire is to consider the degradation of material properties with temperature. Therefore, the objective of this study is to propose a model that accounts for the variation of the thermo-physical properties, the development of char, and its evolution with temperature. This model integrates a sequential coupling of heat transfer analysis with structural response. The degradation of the material properties is accounted for through the regulatory approach recommended in Eurocode 5. The stress analysis employs an elasto-plastic model with nonlinear isotropic hardening. Implementation of the model is achieved within the Abaqus suite of finite element software using external subroutines. The model's predictions align well with experimental data, accurately reproducing both thermal and structural responses. Specifically, the model accurately predicts temperature profiles, displacements, and the depth of the charred layer, which initiates above 300 °C. Additionally, for rectangular sections, it was observed that exposure of all faces to fire results in a non-rectangular residual section. Furthermore, employing the temperature-dependent thermal property curves suggested by EC5 yields satisfactory results when predicting the fire resistance of softwood timber structures.

1- and 2-Tetrazolylacetonitrile as Versatile Ligands for Laser Ignitable Energetic Coordination Compounds.

1- and 2-Tetrazolylacetonitrile (1- and 2-TAN) have been synthesized by the reaction of chloroacetonitrile with 1H-tetrazole under basic conditions. They further were reacted with sodium azide in the presence of zinc(II) chloride to form 5-((1H-tetrazol-1-yl)methyl)-1H-tetrazole (1-HTMT) and 5-((2H-tetrazol-2-yl)methyl)-1H-tetrazole (2-HTMT). The nitrogen-rich compounds have been applied as ligands for Energetic Coordination Compounds (ECCs) and show interesting coordinative behavior due to different bridging modes. The structural variability of the compounds has been proved by low-temperature X-ray analysis. The ECCs were analyzed for their sensitivities to provide information about the safety of handling and their capability to serve as primary explosives in detonator setups to replace the commonly used lead styphnate and azide. All colored ECCs were evaluated for their ignitability by laser initiation in translucent polycarbonate primer caps. In addition, the spin-crossover characteristics of [Fe(1-TAN)6](ClO4)2 were highlighted by the measurement of the temperature-dependent susceptibility curve.

A three-mode temperature sensing based on UC luminescence of Er:PbF2 crystal

Optical temperature sensor, especially the temperature sensor made based on fluorescence intensity ratio (FIR) technology, have numerous applications in temperature detection. However, most of these sensing materials are phosphors, which still face challenges in maintaining their chemical stability. In contrast, crystal materials exhibit superior thermal stability and fluorescence stability. The temperature sensing characteristics of Er: PbF2 single crystal material were studied by the three modes temperature dependence curve. Excellent relative sensitivity and absolute sensitivity were obtained on FIR between two non-thermally coupled energy levels (non-TCEL: I(4F9/2)/I(4S3/2)) and two thermally coupled energy levels (TCEL: I(2H11/2)/I(4S3/2), and I(4S3/2)/I(4S3/2)) of Er3+ ions when excited by a 980 nm LD. Futhermore, with the increase of temperature, the luminescence emission color of the Er: PbF2 single crystal varied from green to yellow-orange. These discoveries suggest that the Er: PbF2 single crystal could serve as an excellent sensing medium for optical temperature sensors.

Enhancement of localized superconductivity in BaFe2As2 films via Co-ion implantation

In this study, we present a novel approach to localized superconductivity induction in BaFe2As2 films via targeted implantation of cobalt (Co) ions. Primarily, our study focuses on the systematic distribution of Co ions and the subsequent evolution of superconducting properties in Co-ion-implanted BaFe2As2 films. Our observations show that Co-ion distribution in the films is congruent with the results of analytical methodologies employed in the semiconductor industry, as confirmed via transmission electron microscopy imaging. The temperature-dependent resistivity curves reveal the concurrent presence of superconducting and non-superconducting regions. Moreover, the superconducting domain demonstrates the typical diamagnetic behavior intrinsic in superconductors. Importantly, Co-ion concentrations of ∼1020 cm−3 can be achieved by finely tuning the beam energy and ion dose. This concentration is instrumental in establishing an effective superconducting percolation pathway within the films.

Design of Unplasticized Polyamide 12 Oilfield Line Pipe Based on Published Regression Curves and ASTM F3524

The long-term strength of unplasticized polyamide 12 (PA-U12) has been characterized using standard methods for plastic pressure pipe during the qualification process for use in buried piping systems for natural gas delivery operating at low ambient temperatures, usually less than 20 to 30°C at pressures previously served only by steel pipe. The high strength characteristics of the material also made it interesting as a steel substitute for buried and above-ground industrial pressure pipe applications. So far, typical geometries are diameters up to 6 inch (162 mm) with wall thicknesses up to DR9. Assuming a design factor of 0.63 applied to the PPI TR-4 listed HDB, DR9 PA-U12 pipes have a maximum pressure at 23°C of 496 psig (3.4 MPa), although design pressures will typically be lower. These industrial systems can operate at much higher temperatures, up to ~ 50°C for above-ground installations in pipe supports or up to ~ 65°C for surface-laid oilfield pipes. Design engineers need the temperature dependent strength curves to properly design a thermoplastic pressure piping system. Therefore, the regression curves have been extended by LTHS tests up to 120°C. Corresponding test durations enabled to define the location of knees with determination of second branches. These branches are caused by hydrolytic degradation of the polymer resulting in brittleness of the polyamide after long times at elevated temperature in sufficiently wet environments or services. The first appearance of a knee is at 60° C and approximately 44 years. This paper describes various standards to which PA-U line pipe and materials must conform, and the development of standardized, temperature dependent, long-term strength reference curves for PA-U12 pressure pipe, including the transition from ductile to brittle behavior at long times and high temperatures. These curves have been standardized first in DVS and followed by ISO based on the combined LTHS data of pipes made from two different PA-U12 180 compounds and one PA-U11 180 compound. An example of a typical PA-U12 180 pipe design is presented, applying chemical resistance derating factors for oil and gas applications in the design process. Short Summary: Oilfield pipeline design engineers need temperature dependent strength curves to properly design a thermoplastic pressure piping system for use at temperatures often far above the typical range for natural gas distribution. Therefore, LTHS regression curves have been experimentally developed at temperatures up to 120°C to define the location of knees and characterization of second branches. In this paper we describe various standards to which PA-U line pipe and materials must conform, and the development of standardized, temperature dependent, long-term strength reference curves for PA-U12 pressure pipe, including the transition from ductile to brittle behavior at long times and high temperatures. These curves have been standardized in ISO and DVS and apply to both PA-U12 and PA-U11 [1,2]. For PA-U12 line pipe we also present an example for a typical pipe design, where chemical resistance derating factors are applied for oil and gas applications in the design process.

Re-dissolution of precipitates in reactor pressure vessel steels evaluated by internal friction technique

The re-dissolution process of Mn-Si-rich precipitates in Fe-1.0 %Mn-0.4 %Ni-0.2 %Si (wt.%) reactor pressure vessel (RPV) model steel was assessed using the internal friction (IF) technique. A relaxation IF peak (P1), corresponding to grain boundary relaxation, was observed near 600 °C in the temperature-dependent IF curve of the as-received sample. After long-term aging at 600 °C, a significant suppression of the P1 was observed due to the extensive precipitation of Mn-Si-rich precipitates. Upon further annealing at 700–800 °C, the P1 gradually recovered with increasing annealing temperature, indicating the gradual dissolution of Mn-Si-rich precipitates along the grain boundaries. This phenomenon was consistent with transmission electron microscopy experimental results.

Fission yeast spindle dynamics and chromosome segregation fidelity show distinct thermosensitivity.

Cellular processes rely on proteins with temperature-dependent stability and activity. While thermosensitivity in biological networks is well-explored, the effect of temperature on complex mechanochemical assemblies, like the spindle, is rarely studied. We examined fission yeast spindle dynamics and chromosome segregation from 15⁰C to 40⁰C. Our findings reveal that these parameters follow U-shaped temperature-dependent curves but reach their minima at different temperatures. Specifically, spindle dynamics peak around 35⁰C, whereas chromosome segregation defects are minimized at 25⁰C. This suggests a scenario in which mitotic errors are tolerated to expedite rapid cell cycle progression.

The Cold-Brittleness Regularities of Low-Activation Ferritic-Martensitic Steel EK-181

The behavior of the EK-181 low-activation ferritic-martensitic reactor steel (Fe–12Cr–2W–V–Ta–B) in the states with different levels of strength and plastic properties after traditional heat treatment (THT) and after high-temperature thermomechanical treatment (HTMT) in the temperature range from −196 to 25 °C, including the range of its cold brittleness (ductile–brittle transition temperature, DBTT) is studied. The investigations are carried out using non-destructive acoustic methods (internal friction, elasticity) and transmission and scanning electron microscopy methods. It is found that the curves of temperature dependence of internal friction (the vibration decrement) of EK-181 steel after THT and HTMT are similar to those of its impact strength. Below the ductile–brittle transition temperature, it is characterized by a low level of dislocation internal friction. The temperature dependence curves of the steel elastic modulus increase monotonically with the decreasing temperature. In this case, the value of Young’s modulus is structure-sensitive. A modification of the microstructure of EK-181 steel as a result of HTMT causes its elastic modulus to increase, compared to that after THT, over the entire temperature range under study. The electron microscopic studies of the steel microstructure evolution near the fracture surface of the impact samples (in the region of dynamic crack propagation) in the temperature range from −196 to 100 °C reveal the traces of plastic deformation (increased dislocation density, fragmentation of the martensitic structure) at all of the temperatures under study, including those below the cold brittleness threshold of EK-181 steel.

Melting Behavior and Densities of K2B2OF6 Melts Containing KReO4

Methods of simultaneous thermal analysis (differential scanning calorimetry, thermogravimetry) and an analysis of cooling curves were used to study the melting of K2B2OF6–(0–15 wt. %) KReO4 melts. The synthesis of K2B2OF6 was performed by alloying KF, KBF4, and B2O3 components. The liquidus temperature dependence on the content of potassium perrhenate in the K2B2OF6–(0–15 wt. %) KReO4 melts was determined. It was found that the addition of up to 6 wt. % KReO4 caused an increase in the melt liquidus temperature to 733 K. Further increases in potassium perrhenate did not change the temperature of the primary crystallization (733 ± 5 K) of the K2B2OF6–KReO4 melt. This fact testifies to the presence of the monotectic reaction. It was found that the relative loss of mass of the K2B2OF6–(0–15 wt. %) KReO4 melts did not exceed 2.1%. The delamination of the K2B2OF6–KReO4 melt was revealed according to the values of the primary crystallization temperatures (liquidus temperatures) in different layers of the melt. The density of the K2B2OF6–KReO4 melts as a function of potassium perrhenate content (0–15 wt. %) was investigated at 628–933 K. The temperature dependence of the K2B2OF6–KReO4 melts’ densities was recorded. They are presented as linear functions. The curves of the density temperature dependence of the K2B2OF6–KReO4 melts were used to determine the critical temperatures, i.e., the boundaries of the miscibility gap. The miscibility gap of the K2B2OF6–KReO4 melts is limited to 1 wt. % and 15 wt. % KReO4 content.

Temperature- and frequency-dependent magnetic susceptibility on archaeological ceramics of the Tlatilca culture (Mexico City): A pilot study towards an archaeointensity approach

Temperature-dependent susceptibility curves are commonly used in archaeointensity studies to identify changes in the magnetic mineralogy of archaeological ceramics. In this pilot study, we investigated the low- and high-temperature thermomagnetic behavior and frequency-dependent susceptibility of eight ceramics from a Tlatilca culture archaeological site in Mexico City, after heating them at five different temperatures (from 120 to 440 °C). Our objective is to establish a correlation between the thermomagnetic behavior and the parameters that determine the magnetic grain-size and magnetic domain in similar style of ceramics from different occupations of the site. Our findings show that superparamagnetic grains (SP) degrade with increasing reheating temperature in ceramics, and we conclude that this behavior is related to details in artifact processing, such as the use of pastillage to represent headdresses, and an important aspect to consider when working with samples for archaeointensity procedures.

A potential growth thermal index for estimating juvenile Atlantic salmon (Salmo salar) size-at-age across geographical scales.

We present a potential growth thermal index (PGTI) and assess its correlation with juvenile Atlantic salmon Salmo salar fork length data collected near the end of the growth season in a range of latitudinal locations and geographic scales (watershed, regional, continental) across the American north-east. The PGTI is based on two components: a water temperature-dependent growth curve and a water temperature time series continuously describing the thermal environment preceding fish sampling. Testing various shapes and characteristics of the temperature-growth curve against fish length data revealed strong positive correlations for all combinations. PGTI warming, calculated only from the beginning of the growth season until maximum summer temperature is reached, consistently performed well in explaining fish size-at-age across the latitudinal gradient and the three geographic scales that were considered. Varying thermal contrasts created by repeat subsampling of the dataset showed that fish length is better explained by the level of thermal contrast within the dataset than the geographical scale of analysis. A simple generalized linear model using a log link function with PGTI warming, fish density and water discharge as predictors explained 87% of the variance of size-at-age of 0+ and 1+ juvenile Atlantic salmon.