Synchrotron Radiation Research Articles

In situ/Operando Synchrotron Radiation Analytical Techniques for CO2/CO Reduction Reaction: From Atomic Scales to Mesoscales

AbstractElectrocatalytic carbon dioxide/carbon monoxide reduction reaction (CO(2)RR) has emerged as a prospective and appealing strategy to realize carbon neutrality for manufacturing sustainable chemical products. Developing highly active electrocatalysts and stable devices has been demonstrated as effective approach to enhance the conversion efficiency of CO(2)RR. In order to rationally design electrocatalysts and devices, a comprehensive understanding of the intrinsic structure evolution within catalysts and micro‐environment change around electrode interface, particularly under operation conditions, is indispensable. Synchrotron radiation has been recognized as a versatile characterization platform, garnering widespread attention owing to its high brightness, elevated flux, excellent directivity, strong polarization and exceptional stability. This review systematically introduces the applications of synchrotron radiation technologies classified by radiation sources with varying wavelengths in CO(2)RR. By virtue of in situ/operando synchrotron radiationanalytical techniques, we also summarize relevant dynamic evolution processes from electronic structure, atomic configuration, molecular adsorption, crystal lattice and devices, spanning scales from the angstrom to the micrometer. The merits and limitations of diverse synchrotron characterization techniques are summarized, and their applicable scenarios in CO(2)RR are further presented. On the basis of the state‐of‐the‐art fourth‐generation synchrotron facilities, a perspective for further deeper understanding of the CO(2)RR process using synchrotron radiation analytical techniques is proposed.

Luminescence of CsLa1-хCeхSiS4 thiosilicate solid solution: From STE to Ce3+ emission

A series of single crystals of CsLa1-хСехSiS4 monophasic solid solution (x = 0–1) has been obtained for the first time by high-temperature flux synthesis. Methods of XRD and chemical analysis, absorption and low-temperature (from T = 5 K) luminescent spectroscopy were used. The results of the band scheme calculating using density functional theory correlate with spectroscopy data. One non-elementary d → f emission band of Ce3+ ions is observed in the region of 520 nm in the luminescence spectra at room temperature at any value of the x parameter. The luminescence decay kinetics of Ce3+ ions upon excitation by a pulsed electron beam, X-ray synchrotron radiation or intracenter photoexcitation is characterized by a nanosecond component. As the parameter x increases, the decay time is reduced from 132 ns (x = 0.005) to 0.88 ns (x = 1). The luminescence decay kinetics upon photoexcitation at x = 0.005–0.12 is characterized by monoexponential decay with τ = 31.4 ± 0.2 ns. Concentration quenching of the Ce3+ ion photoluminescence is not observed up to the value of the parameter x = 0.12; it only appears at x = 1. The anomalously short decay time of the Ce3+ ions luminescence in CsCeSiS4 upon both X-ray excitation and photoexcitation is associated with concentration quenching.At temperature 5 K, new intense bands at 408 and 688 nm in addition to the Ce3+ emission band observed in the photoluminescence spectra of nominally pure CsLaSiS4 or at the lowest parameter value x = 0.005. These bands correspond to the luminescence of self-trapped excitons (STE) and defects. With increasing x parameter, the STE emission band is reabsorbed by the absorption of Ce3+ ions and is quenched due to the resonance energy transfer STE → Ce3+ center. Thermoluminescence glow curves of CsLa1-xCexSiS4 irradiated with X-ray at T = 90 K are characterized by several low temperature intense peaks, which indicates a high concentration of charge carrier traps.

Investigation of crystalline and band alignment properties of NiO/GaN and Ni0.5Co0.5O/GaN heterojunctions using synchrotron radiation based techniques

Epitaxial layers of NiO and Ni0.5Co0.5O have been deposited on GaN templates using RF magnetron sputtering deposition technique. The epitaxial relationship in out-of-plane and in-plane directions for NiO and Ni0.5Co0.5O layers with respect to GaN is [111]NiO(Ni0.5Co0.5O)∥[0001]GaN and [1̅10]NiO(Ni0.5Co0.5O)∥[1̅21̅0]GaN, respectively. The epi-layers are found to have two triangular domain structures oriented along [111] direction with an in-plane rotation of 60° with respect to each other. Photoelectron spectroscopy (PES) has been used to determine the valence band offset (∆EV) and the band alignment at the heterojunctions (HJs). The ∆EV at NiO/GaN and Ni0.5Co0.5O/GaN HJs are 1.2 ± 0.2 eV and 1.8 ± 0.2 eV, respectively. The conduction band offsets (∆EC) have also been estimated using the determined values of optical band gap (NiO: Eg = ∼ 3.5 eV; Ni0.5Co0.5O: Eg = ∼ 3.3 eV) from optical transmission measurements. The values of ∆EC are found to be 1.5 ± 0.2 eV and 1.9 ± 0.2 eV at NiO/GaN and Ni0.5Co0.5O/GaN HJs, respectively. A type-II band alignment is observed at both the HJs. Higher values of valence band and conduction band offsets are observed at Ni0.5Co0.5O/GaN HJ in comparison to NiO/GaN. These experimentally determined values of band offsets can be used to design wide band gap HJ based devices like photodetectors, where higher values of band off-set at the Ni0.5Co0.5O/GaN HJ can be utilized to confine the carriers.

Modelling the galaxy radio continuum from star formation and active galactic nuclei in the Shark semi-analytic model

Abstract We present a model of radio continuum emission associated with star formation (SF) and active galactic nuclei (AGN) implemented in the Shark semi-analytic model of galaxy formation. SF emission includes free-free and synchrotron emission, which depend on the free-electron density and the rate of core-collapse supernovae with a minor contribution from supernova remnants, respectively. AGN emission is modelled based on the jet production rate, which depends on the black hole mass, accretion rate and spin, and includes synchrotron self-absorption. Shark reproduces radio luminosity functions (RLFs) at $1.4\, \rm GHz$ and $150\, \rm MHz$ for 0 ≤ z ≤ 4, and scaling relations between radio luminosity, star formation rate and infrared luminosity of galaxies in the local and distant universe in good agreement with observations. The model also reproduces observed number counts of radio sources from 150 MHz to 8.4 GHz to within a factor of two on average, though larger discrepancies are seen at the very bright fluxes at higher frequencies. We use this model to understand how the radio continuum emission from radio-quiet AGNs can affect the measured RLFs of galaxies. We find current methods to exclude AGNs from observational samples result in large fractions of radio-quiet AGNs contaminating the ‘star-forming galaxies’ selection and a brighter end to the resulting RLFs.We investigate how this effects the infrared-radio correlation (IRRC) and show that AGN contamination can lead to evolution of the IRRC with redshift. Without this contamination our model predicts a redshift- and stellar mass-independent IRRC, except at the dwarf-galaxy regime.

Vacuum chambers for Swiss Light Source arcs

The vacuum chambers for diffraction limited storage ring differ from the previous storage rings generation in three main aspects: the cross-section dimension, which is divided by a factor of 2 or more to fit smaller magnet apertures; the material, which includes much more copper for heat dissipation and to limit resistive wakefields; the coating of the inner surface with a nonevaporable getter (NEG) to ensure good pumping level despite low conductance. This paper gives a detailed description of the vacuum chambers’ design used in the arc section of SLS 2.0, starting with conceptual design choices based among others on synchrotron radiation heat and wakefield considerations. The particular case of the main bending magnet vacuum chamber is explained in detail from design to manufacturing, including the development of an appropriate NEG coating procedure. Finally, the overall assembly of a 17 m long arc, its activation to reach pressure in the 10−11 mbar range followed by transport and installation into the magnets is presented. This validates the choice of activation for an arc vessel made out of copper, with wall thicknesses as small as 1 mm and with less than 0.5 mm clearance to magnet poles. Published by the American Physical Society 2024

Existence of density inhomogeneity of liquid Te associated with liquid-liquid phase transition.

We performed small-angle X-ray scattering measurements of liquid Te using a synchrotron radiation facility and observed maximum scattering intensity near 620 K in the supercooled region (melting temperature 723 K). This indicates that density inhomogeneity exists in liquid Te, and the fact that this temperature coincides with the temperature at which the specific heat, sound velocity, and thermal expansion coefficient reach their maxima means that this density inhomogeneity is the cause of these thermodynamic anomalies. The thermodynamic anomalies in liquid Te had already been shown in the 1980s to be comprehensively explained by the inhomogeneity associated with the continuous liquid-liquid phase transition (LLT), but direct experimental evidence for the existence of the inhomogeneity had not been obtained. The present results, together with those already obtained for mixture systems (Te-Se, Te-Ge), indicate the existence of inhomogeneity associated with LLT in liquid Te systems, and strongly support the model. Recently, similarmaximum scattering intensity has also been observed in supercooled liquid water, which exhibits thermodynamic anomalies similar to those of Te, indicating the universality of the inhomogeneous model or LLT scenario to explain the thermodynamics of such "anomalous liquids". Further development of the LLT scenario is expected in near future.&#xD.

Synchrotron x-ray spectra characterisation for radiation therapy applications at the ESRF - ID17 biomedical beamline

Objective. Radiation therapy requires reliable dosimetry protocols to deliver successful treatments with high accuracy and precision. In this context, accurate knowledge of the beam’s energy spectra is mandatory. The goal of this study was to validate the synchrotron x-ray spectrum of the ID17 beamline at the European Synchrotron Radiation Facility (ESRF). The modification of the synchrotron storage ring and beamline in recent years necessitates a new characterisation of the radiation spectra of the ID17 beamline. The validated spectra will be a starting point for possible future clinical applications. Approach. The half value layer method was used to measure the attenuation of the x-ray spectrum in Al and Cu. Experimental data was validated against theoretical data produced using OASYS; an in-house developed software for calculating beamline spectra. Two different spectral configurations, ‘conventional’ and ‘clinical’, were investigated. The characterised spectra were used to perform dosimetric validation of depth dose profiles measured in a water-equivalent phantom. The dose profile was measured using two different detectors and compared with calculations generated using two different Monte Carlo algorithms. Main results. The results showed good agreement between measured and predicted half value layers, with differences of less than 1% in most cases. Excellent dosimetric agreement to within 3% was obtained, an agreement that satisfies the requirements in conventional radiotherapy for approvable treatment planning. Significance. Accurate spectra have been defined and validated for the ESRF—ID17 Biomedical beamline. The validated spectra can be used as input for future dosimetric studies and treatment planning systems in the context of preclinical studies and possible future clinical trials.

DEVILS/MIGHTEE/GAMA/DINGO: The impact of SFR timescales on the SFR-radio luminosity correlation

Abstract The tight relationship between infrared luminosity (LTIR) and 1.4 GHz radio continuum luminosity (L1.4 GHz) has proven useful for understanding star formation free from dust obscuration. Infrared emission in star-forming galaxies typically arises from recently formed, dust-enshrouded stars, whereas radio synchrotron emission is expected from subsequent supernovae. By leveraging the wealth of ancillary far-ultraviolet – far-infrared photometry from the Deep Extragalactic VIsible Legacy Survey (DEVILS) and Galaxy and Mass Assembly (GAMA) surveys, combined with 1.4 GHz observations from the MeerKAT International GHz Tiered Extragalactic Exploration (MIGHTEE) survey and Deep Investigation of Neutral Gas Origins (DINGO) projects, we investigate the impact of timescale differences between far-ultraviolet – far-infrared and radio-derived star formation rate (SFR) tracers. We examine how the SED-derived star formation histories (SFH) of galaxies can be used to explain discrepancies in these SFR tracers, which are sensitive to different timescales. Galaxies exhibiting an increasing SFH have systematically higher LTIR and SED-derived SFRs than predicted from their 1.4 GHz radio luminosity. This indicates that insufficient time has passed for subsequent supernovae-driven radio emission to accumulate. We show that backtracking the SFR(t) of galaxies along their SED-derived SFHs to a time several hundred megayears prior to their observed epoch will both linearise the SFR-L1.4 GHz relation and reduce the overall scatter. The minimum scatter in the SFR(t)-L1.4 GHz is reached at 200 – 300 Myr prior, consistent with theoretical predictions for the timescales required to disperse the cosmic ray electrons responsible for the synchrotron emission.

Photoionization and Dissociative Photoionization of Acetaldehyde in the 10.0-13.7 eV Range by Synchrotron Photoelectron Photoion Coincidence Spectroscopy.

Photoionization and dissociative photoionization of acetaldehyde (CH3CHO) in the 10.0-13.7 eV energy range are studied by using synchrotron radiation double imaging photoelectron photoion coincidence spectroscopy (i2PEPICO). The X2A' and A2A" electronic states of CH3CHO+ as well as the Franck-Condon gap region between these two states have been populated with several vibrational sequences and assigned in the high-resolution slow photoelectron spectrum (SPES). The adiabatic ionization energies (AIEs) of the X2A' and A2A" states are measured at 10.228±0.006 and 12.52±0.05 eV, respectively. The present results show that the X2A' state is a stable state while the A2A" state is fully dissociative to produce CH3CO+, CHO+ and CH4 + fragment ions. The 0 K appearance energies (AE0K) of CH3CO+ and CHO+ fragment ions are determined through the modeling of the breakdown diagram, i. e., AE0K(CH3CO+)=10.89±0.01 eV (including a reverse barrier of ~0.19 eV) and AE0K(CHO+)=11.54±0.05 eV. In addition, the dissociation mechanisms of CH3CHO+ including statistical dissociation, direct bond breaking and isomerization are discussed with the support of the calculated dissociation limits and transition state energies.

Crystal structures of two new high-pressure oxynitrides with composition SnGe4N4O4, from single-crystal electron diffraction.

SnGe4N4O4 was synthesized at high pressure (16 and 20 GPa) and high temperature (1200 and 1500°C) in a large-volume press. Powder X-ray diffraction experiments using synchrotron radiation indicate that the derived samples are mixtures of known and unknown phases. However, the powder X-ray diffraction patterns are not sufficient for structural characterization. Transmission electron microscopy studies reveal crystals of several hundreds of nanometres in size with different chemical composition. Among them, crystals of a previously unknown phase with stoichiometry SnGe4N4O4 were detected and investigated using automated diffraction tomography (ADT), a three-dimensional electron diffraction method. Via ADT, the crystal structure could be determined from single nanocrystals in space group P63mc, exhibiting a nolanite-type structure. This was confirmed by density functional theory calculations and atomic resolution scanning transmission electron microscopy images. In one of the syntheses runs a rhombohedral 6R polytype of SnGe4N4O4 could be found together with the nolanite-type SnGe4N4O4. The structure of this polymorph was solved as well using ADT.

Efficient catalytic degradation of carbamazepine using single-atom Ru-NiFe-LDH: Role of 1O2 and selective degradation

The targeted elimination of stubborn organic pollutants is crucial for human health and ecosystem well-being. Thanks to its exceptional efficiency and other benefits, peroxymonosulfate offers extensive potential for water treatment. However, realizing the practical application of this technology hinges on creating a high-efficiency catalyst. This study presents the fabrication of a monoatomic Ru catalyst through a straightforward hydrothermal approach. Synchrotron radiation and spherical electron microscopy were used to confirm the binding of monoatomic Ru to the NiFe-LDH (Layered Double Hydroxide, LDH) surface. Using a catalyst containing 0.77 wt% of single-atom Ru, 20 mg/L of Carbamazepine (CBZ) could be eliminated within 25 mins. With this, an impressive pseudo-first-order reaction rate constant of 0.118 min−1 was attained. The feasibility of the catalyst was evaluated in a column experimental reactor. The removal rate of 0.5 g of catalyst in wastewater containing 20 mg/L CBZ reached 100 %, demonstrating sustained operation for 720 mins. Ru-LDH/PMS system preferentially degrades carbamazepine, ciprofloxacin and other pollutants. This may be related to the structure and HOMO value of the pollutants and the active factors stimulated by Ru-LDH. Through a range of probe reactions and spectral analysis, it was determined that 1O2 played a pivotal role in pollutant degradation, closely linked to the presence of Ru.

Characterization of selected additive manufacturing materials for synchrotron monochromatic imaging and broad-beam radiotherapy at the Australian synchrotron- imaging and medical beamline.

This study aims to characterize radiological properties of selected additive manufacturing (AM) materials utilizing both material extrusion and vat photopolymerization technologies. Monochromatic synchrotron X-ray images and synchrotron treatment beam dosimetry were acquired at the hutch 3B of the Australian synchrotron - imaging and medical beamline (AS-IMBL).
Approach: Eight energies from 30 keV up to 65 keV were used to acquire the attenuation coefficients of the AM materials. Comparison of theoretical, and experimental attenuation data of AM materials and standard solid water for MV linac was performed. Broad-beam dosimetry experiment through attenuated dose measurement and a Geant4 Monte Carlo simulation were done for the studied materials to investigate its attenuation properties specific for a 4 tesla wiggler field with varying synchrotron radiation beam qualities.
Main results: PLA plus matches attenuation coefficients of both soft tissue and brain tissue, while ABS, ASA, and Draft resin have close equivalence to adipose tissue. Lastly, PLA, CPE plus, TPU, and White resins are promising substitute materials for breast tissue. For broad-beam experiment and simulation, many of the studied materials were able to simulate RMI457 SolidWater and bolus within +/-10% for the three synchrotron beam qualities. These results are useful in fabricating phantoms for synchrotron and other related medical radiation applications such as orthovoltage treatments. 
Significance and conclusion: These 3D printing materials were studied as potential substitutes for selected tissues such as breast tissue, adipose tissue, soft-tissue, and brain tissue useful in fabricating 3D printed phantoms for synchrotron imaging, therapy, and orthovoltage applications. Fabricating customizable heterogeneous anthropomorphic phantoms (e.g. breast, head, thorax) and pre-clinical animal phantoms (e.g. rodents, canine) for synchrotron imaging and radiotherapy using AM can be done based on the results of this study.

Nonminimally coupled scalar field in Schwarzschild–de Sitter spacetime: Geodesic synchrotron radiation

Nonminimally coupled scalar field in Schwarzschild–de Sitter spacetime: Geodesic synchrotron radiation

Synchrotron radiation x-ray topography applied to nitride semiconductor crystals

Gallium nitride (GaN) and aluminum nitride (AlN), as examples of third-generation semiconductors, have attracted significant interest due to their remarkable physical attributes, including a wide bandgap, high breakdown voltage, exceptional chemical stability, and high thermal conductivity. These characteristics render GaN and AlN highly promising for use in power and (opto)-electronic devices. Consequently, there is a growing demand for high-quality GaN and AlN crystals on the centimeter scale. As the dislocation density in these materials decreases, the need for a reliable method of dislocation characterization becomes more pressing. Synchrotron radiation x-ray topography (SR-XRT) has emerged as a superior, nondestructive technique for the precise characterization of crystal defects. This review briefly introduced the principle of XRT, and its application in the analysis of dislocations in GaN and AlN crystals is summarized. By examining the relationship between the SR-XRT image contrast and the Burgers vectors of dislocations, it is possible to categorize wafer dislocations and determine the magnitude and direction of Burgers vectors. Additionally, SR-XRT facilitates the analysis of interactions between dislocations in GaN and AlN crystals. These analyses are instrumental in advancing the development of superior crystals. This review concludes with a discussion of the current challenges faced by SR-XRT and a projection of its future applications in characterizing third-generation semiconductor crystal materials. This review offers significant guidance for the characterization of nitride crystal defects using SR-XRT.

Regular relations of the composition, structure and properties of crystals of hydrogen-containing compounds

Research subject. Crystals of hydrogen-containing compounds belonging to the superprotonic family. Aim. To obtain knowledge about regular relations between composition, atomic structure, real structure and physical properties of materials, with the purpose of elucidating processes occurring in condensed state and forming the basis for modification of known or obtaining new compounds. Materials and methods. Experimental data were obtained using a set of complementary physical methods, including structural analysis using X-rays, synchrotron radiation and neutrons, optical microscopy, and atomic force microscopy. Results. Experimental data on the atomic structure, real structure, and physical properties of superprotonic crystals, including systems of hydrogen bonds and their changes, were obtained. Conclusions. The physical properties of superprotonic crystals are significantly affected by hydrogen bonding systems and their changes, primarily by the formation of dynamically disordered hydrogen bonds with energetically equivalent positions of hydrogen atoms. When carrying out diagnostics of crystalline samples, account should be taken of their real structure, including the structure of surface layers and the presence of crystallization water. These factors may affect the measured physical parameters, the boundaries of existence of phases, the formation of a multiphase state under variations in temperature.

X-ray emission from large scale jets of AGNs at high redshifts

The limited angular resolution of the existing telescopes, operating in radio, optical and X-ray wavebands, hinder the study on multi-spectral component (MSC) emissions from the large scale jet of AGNs. This is particularly strenuous for the sources located at high redshifts. Though a few of them were resolved in radio-optical wavebands, their X-ray counterparts have been rarely discovered. This poses a bigger challenge in understanding their emission mechanism. At high redshifts, the X-ray emission from the large scale jets are generally interpreted as inverse-Compton scattering of cosmic microwave background photons (IC/CMB), due to the increase in CMB photon density. However, recent Fermi γ-ray flux upper limit estimates on two high redshift (z>3.5) AGN jets (J1510+5702 and J1421-0643), question the validity of the IC/CMB model. Here, we propose a model by considering the advection of electrons from the sites of particle acceleration (Rahman et al., 2022), to interpret the MSC emission from these sources. We show that observed radio/optical/X-ray emissions can be explained by the synchrotron emission from the advected and accelerated electron distribution. We also show that the IC/CMB spectrum of this composite electron distribution satisfies the constraints drawn from Fermi observations.

Preliminary Analysis of Beam Position Monitor Accuracy

Preliminary Analysis of Beam Position Monitor Accuracy

Direct Work Function Measurement Using In-situ APXPS and Its Application on Copper Oxidation Process.

The work function (WF) measurement plays a critical role in engineering energy materials and energy devices. However, the ultra-high vacuum (UHV) environments of photoemission method limit the practical application for absolute work function measurements of materials, especially under complex working conditions. To understand the energy level of materials under complex chemical environments, the in-situ measurements of work function is necessary in complex metal/semiconductor system for various application. In this paper, we describe the utilization of ambient pressure X-ray photoemission spectroscopy (APXPS) with utilization of low photon energy X-ray for absolute WF measurements at BL02B of the Shanghai Synchrotron Radiation Facility. We herein present the WF measurement during oxygen adsorption on Pt(111) and oxidation of Cu(111) in ambient oxygen environment as demonstration of the APXPS capability for WF measurement. After oxygen chemisorption on Pt and formation of Cu2O, the WF will increase. This is due to charge transfer from metal to chemisorbed oxygen atoms. After the formation of bulk Cu2O and CuO, the WF value almost remain at ~5.5 eV. We believe the direct measurement of absolute work function via APXPS could help bridge the gap between the physical properties and the surface chemical species for metal/semiconductor materials.

Peculiarities in XPS spectra of Sn/SiO2 layers as an effect of surface charge

X-ray photoelectron spectroscopy based on synchrotron radiation was used to investigate the composition of the observed SnO2-x/Sn:SiO2-x thin layer grown by organometallic chemical vapour deposition on single-crystalline silicon wafer with additional argon ions etching treatment. Due to the formation of a thermodynamic anomaly during in situ layer growth, an efficient oxygen exchange between silicon and tin oxide phases occurs. The present study addresses the effect of localized surface charging and its influence on the obtained XPS core level spectra. We found that due to the high electrical conductivity of metallic tin and the direct coupling of tin particles to the silicon wafer, the XPS Sn 3d5/2 core level spectrum is not affected by the surface charge compared to the highly charged dielectric silicon oxide matrix, as observed for the XPS O 1 s and Si 2p core level spectra. Our results show that the core level spectra of Si 2p and O 1 s are shifted up to 3 eV due to the presence of uncompensated positive charge on the surface of the silica matrix. These results provide insight into the influence of surface charge effects on the analysis of conductor/insulator composite materials and contribute to the application of Sn-based materials in various application concepts related to energy and surface functionalization.

Associating LOFAR Galactic Faraday structures with the warm neutral medium

Faraday tomography observations with the Low Frequency Array (LOFAR) have unveiled a remarkable network of structures in polarized synchrotron emission at high Galactic latitudes. The observed correlation between LOFAR structures, dust polarization, and emission suggests a connection to the neutral interstellar medium (ISM). We investigated this relationship by estimating the rotation measure (RM) of the warm neutral (partially ionized) medium (WNM) in the local ISM. Our work combines UV spectroscopy from FUSE and dust polarization observations from with LOFAR data. We derived electron column densities from UV absorption spectra toward nine background stars, within the field of published data from the LOFAR two-meter sky survey. The associated RMs were estimated using a local magnetic field model fitted to the dust polarization data of A comparison with Faraday spectra at the position of the stars suggests that LOFAR structures delineate a slab of magnetized WNM and synchrotron emission, located ahead of the bulk of the warm ionized medium. This conclusion establishes an astrophysical framework for exploring the link between Faraday structures and the dynamics of the magnetized multiphase ISM. It will be possible to test it on a larger sample of stars when maps from the full northern sky survey of LOFAR become available.