Synchrotron Radiation Research Articles

Phase diagram of ruthenium characterized In Situ by synchrotron X-ray diffraction and Ab Initio simulations

In this work, an in situ characterization of the high-pressure and high-temperature phase diagram of ruthenium was carried out. This experiment was performed using a combination of laser-heated diamond anvil cell (LH-DAC) and X-ray diffraction (XRD) techniques at the beamline ID27 of the European Synchrotron Radiation Facility (ESRF). XRD patterns were collected in the range of 15 GPa to 110 GPa and from ambient temperature up to 6600 K. While the hcp-fcc transition, predicted to occur at elevated temperatures was not observed, this study has produced the first experimental observation of a solid–liquid phase transition of Ru at HP conditions. A P-V-T equation of state valid up to 100 GPa and 3000 K is reported.

3D hybrid fluid-particle jet simulations and the importance of synchrotron radiative losses

Relativistic jets in active galactic nuclei are known for their exceptional energy output, and imaging the synthetic synchrotron emission of numerical jet simulations is essential for a comparison with observed jet polarization emission. Through the use of 3D hybrid fluid-particle jet simulations (with the PLUTO code), we overcome some of the commonly made assumptions in relativistic magnetohydrodynamic (RMHD) simulations by using non-thermal particle attributes to account for the resulting synchrotron radiation. Polarized radiative transfer and ray-tracing (via the RADMC-3D code) highlight the differences in total intensity maps when (i) the jet is simulated purely with the RMHD approach, (ii) a jet tracer is considered in the RMHD approach, and (iii) a hybrid fluid-particle approach is used. The resulting emission maps were compared to the example of the radio galaxy Centaurus A. We applied the Lagrangian particle module implemented in the latest version of the PLUTO code. This new module contains a state-of-the-art algorithm for modeling diffusive shock acceleration and for accounting for radiative losses in RMHD jet simulations. The module implements the physical postulates missing in RMHD jet simulations by accounting for a cooled ambient medium and strengthening the central jet emission. We find a distinction between the innermost structure of the jet and the back-flowing material by mimicking the radio emission of the Seyfert II radio galaxy Centaurus\,A when considering an edge-brightened jet with an underlying purely toroidal magnetic field. We demonstrate the necessity of synchrotron cooling as well as the improvements gained when directly accounting for non-thermal synchrotron radiation via non-thermal particles.

Non-linear MHD modelling of transients in tokamaks: a review of recent advances with the JOREK code

Abstract Transient MHD events like edge localized modes (ELMs) or disruptions are a concern for magnetic confinement fusion power plants. Research with the MHD code JOREK towards understanding control of such instabilities is reviewed here. Experimental validation for unmitigated vertical displacement events (VDEs) progressed. The mechanism of vertical force mitigation by impurity injection was identified. Two-way eddy current coupling to CARIDDI was completed. Shattered pellet injection (SPI) was simulated in JET, KSTAR and ASDEX Upgrade (AUG) and ITER. Benign runaway electron (RE) beam termination in JET and ITER was studied. Coupling of kinetic REs to the MHD is ongoing and a virtual RE synchrotron radiation diagnostic was developed. Regarding pedestal physics, regimes devoid of large ELMs in AUG were simulated and predictive JT60-SA simulations are ongoing. For ELM suppression by resonant magnetic perturbations (RMPs), AUG, ITER and EAST simulations were performed. A free boundary RMP model was validated against experiments. Evidence for penetrated magnetic islands at the pedestal top based on AUG experiments and simulations was found. Simulations of the naturally ELM-free quiescent H-mode (QH) in AUG and HL-3 show external kink mode formation prevents pedestal build-up towards an ELM within windows of the edge safety factor. With kinetic neutral particles, high field side high density (HFSHD) formation in ITER was simulated and with kinetic impurities, tungsten transport in AUG RMP plasmas was studied. To capture turbulent transport, electro-static full-f PiC models for ion temperature gradient (ITG) and trapped electron modes (TEM) were established and benchmarked. Application to RMP plasmas shows enhanced turbulence in comparison to unperturbed states. Energetic particle (EP) interactions with MHD were studied. Flux-pumping that prevents the safety factor on axis from dropping below unity was simulated. First non-linear stellarator applications include current relaxation in l=2 stellarators, while verification for advanced stellarators progresses.

Multi-messenger signatures of delayed choked jets in tidal disruption events

Abstract Recent radio observations and coincident neutrino detections suggest that some tidal disruption events (TDEs) exhibit late-time activities, relative to the optical ehmission peak, and these may be due to delayed outflows launched from the central supermassive black hole. We investigate te possibility that jets launched with a time delay of days to months, interact with a debris that may expand outwards. We discuss the effects of the time delay and expansion velocity on the outcomes of jet breakout and collimation. We find that a jet with an isotropic-equivalent luminosity of ≲ 5 × 1045 erg/s is likely to be choked for a delay time of ∼3 months. We also study the observational signatures of such delayed choked jets. The jet-debris interaction preceding the breakout would lead to particle acceleration and the resulting synchrotron emission can be detected by current and near-future radio, optical and X-ray telescopes, and the expanding jet-driven debris could explain late-time radio emission. We discuss high-energy neutrino production in delayed choked jets, and the time delay can significantly alleviate the difficulty of the hidden jet scenario in explaining neutrino coincidences.

First Attempt at Photoionized Plasma Production with VUV Radiation in Synchrotron Light Source UVSOR-III

First Attempt at Photoionized Plasma Production with VUV Radiation in Synchrotron Light Source UVSOR-III

Analysis of the Structure of 14 Therapeutic Antibodies Using Circular Dichroism Spectroscopy.

Understanding the impact of the manufacturing environment on therapeutic monoclonal antibody (mAb) structures requires new process analytical technology. Here, we describe the creation of a new reference set for the circular dichroism (CD) spectra of mAbs. Data sets of the highest quality were collected by synchrotron radiation CD for 14 different mAbs in both native and acid-stressed states. Deconvolution of far-UV spectra for the mAb cohort identified two current reference sets (SP175 and SMP180) as assigning accurate secondary structures, irrespective of the analysis program employed. Scrutiny of spectra revealed significant variation in the far-UV and especially near-UV CD of the 14 mAbs. Two spectral features were found to be sensitive to changes in solution pH, i.e., the far-UV positive peak at 201-202 nm and the near-UV negative exciton couplet around 230-240 nm. The latter feature offers attractive possibilities for in-line CD-based monitoring of the mAb structure during manufacture.

Nucleation and growth behavior of primary Al11Ce3 intermetallic compounds during solidification in a hypereutectic Al–Ce alloy

In this study, the nucleation and growth mechanisms of Al11Ce3 intermetallic compounds (IMCs) in a hypereutectic Al–Ce alloy during solidification were investigated through synchrotron radiation X-ray real-time imaging. The results showed that Al11Ce3 IMCs nucleate and grow from the melt as the primary phase at the initial stage of solidification. Growth preferred orientations were observed in two opposite directions, resulting in an I-shaped growth pattern. Based on the minimum energy criterion, the morphology of Al11Ce3 IMCs displayed either hollow cubic tubes or grooves. The nucleation and growth rates of Al11Ce3 IMCs gradually decreased over time, owing to the variations in the Ce concentration in the melt and the undercooling. The nucleation and growth characteristics of Al11Ce3 IMCs can provide the theoretical basis for optimization on the performance of Al–Ce alloys.

Seeding Co Atoms on Size Effect‐Enabled V2C MXene for Kinetically Boosted Lithium–Sulfur Batteries

AbstractLithium‐sulfur (Li–S) batteries are facing a multitude of challenges, mainly pertaining to the sluggish sulfur redox kinetics and rampant lithium dendrite growth on the cathode and anode side, respectively. In this sense, MXene has shown conspicuous advantages in serving as a dual‐functional promotor for Li–S batteries throughout the morphologic engineering, but still suffers from poor electrocatalytic activity and insufficient lithophilic sites. Herein, atomically dispersed Co sites are seeded onto the size effect‐enabled V2C MXene spheres (Co‐VC), leading to the generation of unique coordination configurations and rich active sites. Electrochemical tests combined with synchrotron radiation X‐ray 3D nano‐computed tomography and theoretical calculations unravel that Co‐VC with optimal coordination environments simultaneously boost sulfur reaction kinetics and lithium nucleation. As a consequence, Li–S batteries with Co‐VC modified separator can sustain a stable operation over 700 cycles with negligible capacity decay at 1.0 C, and delivers an areal capacity of 9.0 mAh cm−2 and desired cyclic performance at a high sulfur loading of 7.6 mg cm−2 with a lean electrolyte dosage of 4.0 µL mgS−1 at 0.1 C. The work opens a new avenue for boosting atomic‐scale site design with the aid of 2D substrates toward pragmatic Li–S batteries.

Dynamics of JET runaway electron beams in D2-rich shattered pellet injection mitigation experiments

Abstract The publication provide further insights into the dynamics of JET runaway electron (RE) beams mitigated by D2-rich shattered pellet injection (SPI) (Reux et al 2022 Plasma Phys. Control. Fusion 64 034002). Multi-diagnostic analyses show that mechanisms causing continuous RE losses and energy transfer from hot electrons to cold background plasma can act before the SPI. After the SPI, measurements are compatible with a reduction of the maximum energy and pitch angle of the RE distribution while the population of supra-thermal electrons increases. The RE population growth is likely due to electron avalanche. Dark island-like pattern chains, characterised by an integer poloidal mode number and a certain minor radius, are identified in the JET RE beam synchrotron radiation videos. The synchrotron island dynamics is studied via a newly developed computer vision code (Sommariva and Silburn https://c4science.ch/source/pSpiPTV/). The radial motion of synchrotron island chains is found to be consistent with the most plausible time evolution of the radial current density profile compatible with both the RE synchrotron videos and the total RE current time trace. Similarly, correlations are identified between the temporal progression of the synchrotron islands poloidal rotation frequency and sudden MHD relaxation events. Loss-of-RE events probably caused by non-linear interactions between synchrotron islands are observed for the first time. Experimental evidences suggest that synchrotron islands are possibly related to the existence of magnetic islands which may lead to the development of new RE beam mitigation strategies.

The symbiotic recurrent nova V745 Sco at radio wavelengths

Abstract V745 Sco is a Galactic symbiotic recurrent nova with nova eruptions in 1937, 1989 and 2014. We study the behaviour of V745 Sco at radio wavelengths (0.6–37 GHz), covering both its 1989 and 2014 eruptions and informed by optical, X-ray, and γ-ray data. The radio light curves are synchrotron-dominated. Surprisingly, compared to expectations for synchrotron emission from explosive transients such as radio supernovae, the light curves spanning 0.6–37 GHz all peak around the same time (∼18–26 days after eruption) and with similar flux densities (5–9 mJy). We model the synchrotron light curves as interaction of the nova ejecta with the red giant wind, but find that simple spherically symmetric models with wind-like circumstellar material (CSM) cannot explain the radio light curve. Instead, we conclude that the shock suddenly breaks out of a dense CSM absorbing screen around 20 days after eruption, and then expands into a relatively low density wind ($\dot{M}_{out} \approx 10^{-9}-10^{-8}$ M⊙ yr−1 for vw = 10 km s−1) out to ∼1 year post-eruption. The dense, close-in CSM may be an equatorial density enhancement or a more spherical red giant wind with $\dot{M}_{in} \approx [5-10] \times 10^{-7}$ M⊙ yr−1, truncated beyond several × 1014 cm. The outer lower-density CSM would not be visible in typical radio observations of Type Ia supernovae: V745 Sco cannot be ruled out as a Type Ia progenitor based on CSM constraints alone. Complementary constraints from the free–free radio optical depth and the synchrotron luminosity imply the shock is efficient at accelerating relativistic electrons and amplifying magnetic fields, with εe and εB ≈ 0.01 − 0.1.

The theory of synchrotron radiation limited beams diffraction in single crystal in the Laue case

The features of the Bragg diffraction of coherent synchrotron radiation on the atomic lattice of a single crystal in the Laue geometry are studied theoretically, provided that the radiation beam is limited by a relatively large slit placed in front of the crystal. The method of numerical simulation is used and dependences of the intensity distribution are obtained for various thicknesses of the crystal. It is shown that the slit edges introduce inhomogeneous intensity distortions inside the Bormann triangles with an angle of 2θB, where θB is the Bragg angle. In the area where the triangles intersect, the intensity distribution is similar to that for diffraction by a slit in air at a certain (large) distance. An equation for the correspondence between the distance and the thickness of the crystal is obtained, which describes well the results of numerical calculations.

X-ray-based technologies in emerging fuel cell research

The workshop titled `X-ray-based technologies in emerging fuel cell research', organized by Vivian Stojanoff from Brookhaven National Laboratory (BNL) and Narayanasami Sukumar from Cornell University/Advanced Photon Source-Northeastern Collaborative Access Team, was a notable segment of the National Synchrotron Light Source II and Center for Functional Nanomaterials Users' Meeting held 13–17 May 2024. This one-day event, on 13 May 2024, at BNL in New York, aimed to bring together researchers, beamline scientists, management and developers to propel fuel cell technology forward using model systems inspired by natural photosynthesis and redox enzymes. This summary encapsulates the key discussions, advancements and future implications of the workshop.

Micro to macro scale anatomical analysis of the human hippocampal arteries with synchrotron hierarchical phase-contrast tomography.

To date, no non-invasive imaging modality has been employed to profile the structural intricacies of the hippocampal arterial microvasculature in humans. We hypothesised that synchrotron-based imaging of the human hippocampus would enable precise characterisation of the arterial microvasculature. Two preserved human brains from, a 69-year-old female and a 63-year-old male body donors were imaged using hierarchical phase-contrast tomography (HiP-CT) with synchrotron radiation at multiple voxel resolutions from 25.08μm down to 2.45μm. Subsequent manual and semi-automatic artery segmentation were performed followed by morphometric analyses. These data were compared to published data from alternative methodologies. HiP-CT made it possible to segment in context the arterial architecture of the human hippocampus. Our analysis identified anterior, medial and posterior hippocampal arteries arising from the P2 segment of the posterior cerebral artery on the image slices. We mapped arterial branches with external diameters greater than 50 μm in the hippocampal region. We visualised vascular asymmetry and quantified arterial structures with diameters as small as 7 μm. Through the application of HiP-CT, we have provided the first imaging visualisation and quantification of the arterial system of the human hippocampus at high resolution in the context of whole brain imaging. Our results bridge the gap between anatomical and histological scales.

Galactic Stellar Black Hole Binaries: Spin Effects on Jet Emissions of High-Energy Gamma-Rays

In the last few decades, galactic stellar black hole X-ray binary systems (BHXRBs) have aroused intense observational and theoretical research efforts specifically focusing on their multi-messenger emissions (radio waves, X-rays, γ-rays, neutrinos, etc.). In this work, we investigate jet emissions of high-energy neutrinos and gamma-rays created through several hadronic and leptonic processes taking place within the jets. We pay special attention to the effect of the black hole’s spin (Kerr black holes) on the differential fluxes of photons originating from synchrotron emission and inverse Compton scattering and specifically on their absorption due to the accretion disk’s black-body radiation. The black hole’s spin (dimensionless spin parameter a*) enters into the calculations through the radius of the innermost circular orbit around the black hole, the RISCO parameter, assumed to be the inner radius of the accretion disk, which determines its optical depth τdisk. In our results, the differential photon fluxes after the absorption effect are depicted as a function of the photon energy in the range 1GeV ≤E≤103GeV. It is worth noting that when the black holes’ spin (α*) increases, the differential photon flux becomes significantly lower.

IAEA fostering of the development and applications of nuclear analytical techniques for Heritage Science

The IAEA Physics Section is strongly involved in the development and utilization of accelerator-based analytical techniques, which are powerful tools for the characterization of cultural and natural heritage objects and materials. Various activities are carried out with the purpose to build capacity, strengthen capabilities, transfer knowledge and foster networking in the field of heritage science. In addition, access to different X-ray fluorescence spectrometers and other analytical techniques is provided at the Nuclear Science and Instrumentation Laboratory (part of the IAEA Physics Section), and access to ion beam accelerators and synchrotron light is facilitated thanks to collaborations with Ruđer Bošković Institute (RBI) in Croatia and the Elettra Sincrotrone facility in Italy, respectively. Member States are also supported on their Research and Development programmes, as well as through the technical cooperation projects. This paper aims to provide a broad overview about how the IAEA Physics Section is engaged in the field of heritage science, promoting the safe, reliable, and effective use of ion beam, X-ray and neutron-based techniques for the characterization and preservation of cultural and natural heritage through its global networks and partners.

In situ synchrotron X-ray diffraction study: Phase evolution in transition zone of TiAl/Ti2AlNb dual alloy fabricated by laser-directed energy deposition

The phase evolution in the transition zone (TZ) of TiAl/Ti2AlNb dual alloy during laser-directed energy deposition (L-DED) process was investigated using in situ synchrotron radiation X-ray diffraction. The as-solidified microstructure of the TZ forms through the following phase transitions: Liquid→ Liquid + β/B2 →β/B2→ β/B2 + α2. Thermal cycles promote the β/B2 to α2 phase transition with the α2 phase precipitates from the (011) plane of the β/B2 matrix during this transition. The phase transition sequence of the TZ during the first thermal cycle is: β/B2 + α2 → β/B2 → β/B2 + α2. The second thermal cycle leads to a partial transformation of β/B2 phase to α2 phase. The TZ experiences no phase transition from the third thermal cycle. This study provides a comprehensive understanding of the phase formation mechanism in the TZ of L-DEDed TiAl/Ti2AlNb dual alloys.

Microplastics in the Olfactory Bulb of the Human Brain

Microplastic (MP) pollution is an emerging environmental and health concern. While MPs have been detected in various human tissues, their presence in the human brain has not been documented, raising important questions about potential neurotoxic effects and the mechanisms by which MPs might reach brain tissues. To determine the presence of MPs in the human olfactory bulb and to analyze their characteristics such as size, morphology, color, and polymeric composition. This case series study used a cross-sectional design involving the analysis of olfactory bulb tissues obtained from deceased individuals during routine coroner autopsies. The sampling procedures were conducted at São Paulo City Death Verification Service, with laboratory analysis carried out at the Brazilian Synchrotron Light Laboratory (LNLS). Participants included 15 adult individuals who had been residents of São Paulo for more than 5 years and underwent coroner autopsies. Exclusion criteria included previous neurosurgical interventions. Data analysis was performed in April 2024. The primary exposure assessed was the presence of MPs in the olfactory bulb, analyzed through direct tissue examination and digested tissue filtration followed by micro-Fourier transform infrared spectroscopy. The main outcomes were the identification and characterization of MPs within the olfactory bulb, including their size, morphology, color, and polymeric composition. The median age of the 15 deceased individuals was 69.5 years, ranging from 33 to 100 years, with 12 males and 3 females. MPs were detected in the olfactory bulbs of 8 out of 15 individuals. A total of 16 synthetic polymer particles and fibers were identified, with 75% being particles and 25% being fibers. The most common polymer detected was polypropylene (43.8%). Sizes of MPs ranged from 5.5 μm to 26.4 μm for particles, and the mean fiber length was 21.4 μm. Polymeric materials were absent in procedural blank and negative control filters, indicating minimal contamination risk. This case series provides evidence of MPs found in the human olfactory bulb, suggesting a potential pathway for the translocation of MPs to the brain. The findings underscore the need for further research on the health implications of MP exposure, particularly concerning neurotoxicity and the potential for MPs to bypass the blood-brain barrier.

Observation of ferroelectric domains in BaTiO3 by synchrotron radiation X-ray diffraction topography

X-ray diffraction topography was used to observe two distinct ferroelectric domains in BaTiO3. The use of highly-parallel X-rays and a high-resolution detector with approximately 200 nm resolution enabled us to successfully characterize two distinct domains, each with sizes of the order of 10 μm. Along with the local rocking curve of the bulk crystal, we generated width maps corresponding to crystal properties including defects and, strain. This information is beneficial for understanding domain behavior, and the measurement system can be expected to become a powerful tool for in situ measurements of processes requiring domain control.

Synchrotron radiation Fourier-transform infrared absorption measurements on the single-crystal dinaphtho[2,3-b:2′,3′-f]thieno[3,2-b]thiophene

The strong coupling of charge carriers with molecular vibrations is one essential characteristic of organic semiconductor materials as molecular solids. To address this question, fundamental solid-state properties of each molecular species are demanded not only for the electronic states but also for the vibrational characteristics. In the present study, Fourier-transform infrared absorption measurements were performed on single-crystal samples of dinaphtho[2,3-b:2′,3′-f]thieno[3,2-b]thiophene (DNTT) by using a linearly polarized synchrotron radiation light source. Molecular vibrational modes in a wavenumber range of 200–1600 cm−1 were reasonably assigned, and the Davydov splittings of several vibrational modes were resolved demonstrating intermolecular couplings of two DNTT molecules in the unit cell.

A versatile steel belt casting equipment for in situ synchrotron radiation x-ray scattering measurement of polymer films.

A steel belt casting equipment, weighing approximately ∼6-7 tons and measuring ∼5m in length, has been designed and developed for simulating the industrial processing of polymer films and being combined with synchrotron radiation in situ x-ray scattering measurements. Through modification of its modules, it is feasible to implement two distinct film casting modes, namely the wet and the dry casting processes. The speed of a steel belt can span from 0.5 to 8 m/min. The highest experimental temperature and drying wind speed are 300 °C and 6m/s, respectively. All film casting parameters, such as extrusion speed, distance between die and steel belt, casting speed, temperature, and wind speed, can be adjusted independently. Especially, the control accuracy of the temperature and casting rate can reach ±0.1 °C and ±0.01 m/min, respectively. The feasibility of this equipment has been validated through in situ x-ray scattering tests at the BL10U1 industrial beamline of the Shanghai synchrotron radiation facility. With the assistance of this equipment, the understanding of the physical mechanism behind the film casting process should be improved so that the development of advanced functional polymer films.