Ice Surface Research Articles

Overview of the Lost Meteorites of Antarctica field campaigns

AbstractThe Lost Meteorites of Antarctica project was the first UK‐led Antarctic meteorite recovery expedition. The project has successfully confirmed two new high‐density meteorite stranding zones in the Hutichison Icefield and Outer Recovery Icefields areas and investigated the geology of three previously unvisited Antarctic nunataks (Turner Nunatak, Pillinger Nunatak, Halliday Nunatak). The project undertook meteorite searching on the ice surface via skidoo reconnaissance and systematic searching and developed a novel pulse induction metal detection system to search for englacial iron‐rich meteorites trapped within the upper one meter of ice. In total, 121 meteorites have been recovered from the ice surface searching activities, which are now curated in the United Kingdom at the Natural History Museum London and are available for scientific analysis.

Performance characterization of a new, low-cost multi-GNSS instrument for the cryosphere

Abstract We developed a multi-frequency, multi-Global Navigation Satellite System (GNSS) positioning instrument optimized for autonomous applications in the cryosphere. At lower power requirements and a fraction of the cost and weight compared to commercially available options, this instrument simplifies field usage and associated logistics. In this paper, we assess several baseline aspects of performance in a polar environment relative to geodetic receivers commonly used for glaciological applications. Evaluations of precision and relative accuracy of positioning show millimeter to centimeter-level (‘geodetic-grade’) quality of this instrument, making it a competitive alternative for GNSS glaciological and geophysical applications such as monitoring surface elevation change and ice flow. An array of these instruments, tested in the field on the Greenland Ice Sheet, also demonstrated robustness throughout the polar winter and met power and reliability requirements.

Common origin of trapped volatiles in oxidized icy moons and comets

Following spacecraft encounters with comets 67P/C-G and 1P/Halley, it was surprising that O2, expected to be a very minor species in their comas, was observed to outgas at a few percent abundance during their ice sublimation phases. This challenged the direct connection suggested between comets and material in the interstellar medium (ISM), which exhibits a very low O2/H2O gas-phase abundance, leading to a number of papers suggesting novel sources for O2. Since these eccentrically orbiting comets have lost significant amounts of their evaporating surfaces over their lifetimes, the O2 observed must have been stably trapped down to significant depths in these primordial icy bodies. O2 was also seen in the coma by Rosetta, along with other volatiles, long after water ice sublimation began to subside. Here we note that the extensive observations of the icy satellites of Jupiter (Europa, Ganymede, and Callisto) exhibit radiolytic and outgassing processes that provide certain direct parallels to interpretations of recent comet observations. Given that O2 is consistently observed in the atmospheres of icy Jovian satellites, as well as stably trapped as ‘bubbles’ (Johnson and Jesser, 1997) in their water ice surfaces, their spectral observations can help constrain the environment in which Jupiter-family and Oort cloud comets formed given that the observed O2/H2O abundances at both types of comets and icy moons are nearly identical. Based on the approximate charged particle radiation required to produce the observed steady-state concentrations of O2, we suggest that comets likely formed in a far more energetic environment than the ISM. While grains can be irradiated for longer timescales in the neutral ISM, small grains are expected to erode before significant O2 formation and trapping occurs. Independent of celestial dynamics then, an unknown radiation source, may provide insight to the first population of oxidized water ice grains in the early solar system.

Assessment of rock glaciers and their water storage in Guokalariju, Tibetan Plateau

Abstract. Rock glaciers are important hydrological reserves in arid and semi-arid regions. Their activity states can indicate the existence of permafrost. To help further explore the development mechanisms of rock glaciers in semi-arid and humid transition regions, this paper provides a detailed rock glacier inventory of the Guokalariju (also known as Goikarla Rigyu) area of the Tibetan Plateau (TP) using a manual visual interpretation of Google Earth Pro remote sensing imagery. We also estimated the water volume equivalent (WVEQ) in the study area for the first time. Approximately 5057 rock glaciers were identified, covering a total area of ∼404.69 km2. Rock glaciers are unevenly distributed within the three sub-regions from west to east, with 80 % of them concentrated in the central region, where climatic and topographic conditions are most favorable. Under the same ground temperature conditions, increases in precipitation are conducive to rock glaciers forming at lower altitudes. Indeed, the lower limit of rock glaciers' mean altitude decreased eastward with increasing precipitation. Estimates of the water storage capacity of rock glaciers obtained by applying different methods varied considerably, but all showed the potential hydrological value of rock glaciers. The possible water storage in the subsurface ice of rock glacier permafrost was 1.32–3.60 km3. The ratio between the amount of subsurface ice stored in rock glaciers and surface ice stored in local glaciers falls within the range of 1:2.32 to 1:1.26, with an average ratio of 1:1.69. In the west region, where the climate is the driest, the water storage capacity of rock glaciers was estimated to be up to twice as large as that of the sub-region's glaciers. Changes in water resources and permafrost stability in the area where rock glaciers occur will have implications for regional water resource management, disaster prevention, and sustainable development strategies.

Dissociation of H2O2 on water surfaces (ice and water droplets).

OH radicals are an important constituent of the atmosphere. Therefore, all reactions that act as a source of OH radicals are important. It is known that photo-dissociation of H2O2 is an important source of OH radicals in the atmosphere. In the present study, using Born-Oppenheimer molecular dynamics simulations, we have shown that the H2O2 molecule can dissociate thermally on water droplets, as well as on the surface of ice, to form OH radicals. Furthermore, the dissociation of H2O2 was found to be very fast (less than 50 fs) on the ice surface compared with on the water droplets. We believe this route for the formation of OH radicals could be more critical than photo-dissociation, as it can take place both during the day and at night, but further studies with more sophisticated theoretical approaches or experiments are required to confirm this hypothesis.

Uptake of Ammonia by Ice Surfaces at Atmospheric Temperatures

We present an ambient pressure X-ray photoelectron spectroscopy investigation of the adsorption of ammonia on ice over the temperature range of −23 °C to −50 °C. Previous flow tube studies...

Influence of Pollution on the Composition Characteristic of an Arc on the Ice Surface

Influence of Pollution on the Composition Characteristic of an Arc on the Ice Surface

Intro in Ice properties and BIO-factor

Microorganisms could play a significant role in shaping the properties of ice. This overview examines the existing knowledge on the influence of microorganisms on ice, focusing on glacial, polar, and marine ice systems. The interaction between microorganisms and ice mechanics is complex and multifaceted. Studies have shown that microbial activity, including biofilm formation, enzymatic processes, and ice nucleation, can impact ice strength and int interaction with structures. Microbial colonization has been found to weaken ice structures, alter ice permeability, and influence ice deformation behavior. Additionally, microbial communities associated with ice surfaces have been shown to enhance ice adhesion and frictional properties. Understanding the role of microorganisms in ice mechanics is crucial for comprehending the dynamics of frozen environments and their response to environmental changes. Further research in this field will contribute to improved predictions of ice behavior and its implications for climate, engineering, and environmental processes.

In-depth exploration of catalytic sites on amorphous solid water: I. The astrosynthesis of aminomethanol.

Chemical processes taking place on ice-grain mantles are pivotal to the complex chemistry of interstellar environments. In this study, we conducted a comprehensive analysis of the catalytic effects of an amorphous solid water (ASW) surface on the reaction between ammonia (NH3) and formaldehyde (H2CO) to form aminomethanol (NH2CH2OH) using density functional theory. We identified potential catalytic sites based on the binding energy distribution of NH3 and H2CO reactants, on a set-of-clusters surface model composed of 22 water molecules and found a total of 14 reaction paths. Our results indicate that the catalytic sites can be categorized into four groups, depending on the interactions of the carbonyl oxygen and the amino group with the ice surface in the reactant complex. A detailed analysis of the reaction mechanism using Intrinsic Reaction Coordinate and reaction force analysis, revealed three distinct chemical events for this reaction: formation of the C-N bond, breaking of the N-H bond, and formation of the O-H hydroxyl bond. Depending on the type of catalytic site, these events can occur within a single, concerted, albeit asynchronous, step, or can be isolated in a step-wise mechanism, with the lowest overall transition state energy observed at 1.3 kcal mol-1. A key requirement for the low-energy mechanism is the presence of a pair of dangling OH bonds on the surface, found at 5% of the potential catalytic sites on an ASW porous surface.

A peek beneath the surface of Arctic sea ice

Sea ice ridges account for a large proportion of the overall Arctic sea ice volume, yet more attention in research has historically been focused on the thinner level ice. We spoke to Dr Mats Granskog and Dr Oliver Müller about their work in analysing samples from sea ice ridges collected during the MOSAiC polar expedition, with the aim of gaining deeper insights into their role.

Surface Reflectivity Variations of Global Navigation Satellite System Signals From a Mixed Ice and Water Surface

Surface Reflectivity Variations of Global Navigation Satellite System Signals From a Mixed Ice and Water Surface

Adhesion of impure ice on surfaces.

The undesirable buildup of ice can compromise the operational safety of ships in the Arctic to high-flying airplanes, thereby having a detrimental impact on modern life in cold climates. The obstinately strong adhesion between ice and most functional surfaces makes ice removal an energetically expensive and dangerous affair. Hence, over the past few decades, substantial efforts have been directed toward the development of passive ice-shedding surfaces. Conventionally, such research on ice adhesion has almost always been based on ice solidified from pure water. However, in all practical situations, freezing water has dissolved contaminants; ice adhesion studies of which have remained elusive thus far. Here, we cast light on the fundamental role played by various impurities (salt, surfactant, and solvent) commonly found in natural water bodies on the adhesion of ice on common structural materials. We elucidate how varying freezing temperature & contaminant concentration can significantly alter the resultant ice adhesion strength making it either super-slippery or fiercely adherent. The entrapment of impurities in ice changes with the rate of freezing and ensuing adhesion strength increases as the cooling temperature decreases. We discuss the possible role played by the in situ generated solute enriched liquid layer and the nanometric water-like disordered ice layer sandwiched between ice and the substrate behind these observations. Our work provides useful insights into the elementary nature of impure water-to-ice transformation and contributes to the knowledge base of various natural phenomena and rational design of a broad spectrum of anti-icing technologies for transportation, infrastructure, and energy systems.

A first-principles machine-learning force field for heterogeneous ice nucleation on microcline feldspar.

The formation of ice in the atmosphere affects precipitation and cloud properties, and plays a key role in the climate of our planet. Although ice can form directly from liquid water under deeply supercooled conditions, the presence of foreign particles can aid ice formation at much warmer temperatures. Over the past decade, experiments have highlighted the remarkable efficiency of feldspar minerals as ice nuclei compared to other particles present in the atmosphere. However, the exact mechanism of ice formation on feldspar surfaces has yet to be fully understood. Here, we develop a first-principles machine-learning model for the potential energy surface aimed at studying ice nucleation at microcline feldspar surfaces. The model is able to reproduce with high-fidelity the energies and forces derived from density-functional theory (DFT) based on the SCAN exchange and correlation functional. Our training set includes configurations of bulk supercooled water, hexagonal and cubic ice, microcline, and fully-hydroxylated feldspar surfaces exposed to a vacuum, liquid water, and ice. We apply the machine-learning force field to study different fully-hydroxylated terminations of the (100), (010), and (001) surfaces of microcline exposed to a vacuum. Our calculations suggest that terminations that do not minimize the number of broken bonds are preferred in a vacuum. We also study the structure of supercooled liquid water in contact with microcline surfaces, and find that water density correlations extend up to around 10 Å from the surfaces. Finally, we show that the force field maintains a high accuracy during the simulation of ice formation at microcline surfaces, even for large systems of around 30 000 atoms. Future work will be directed towards the calculation of nucleation free-energy barriers and rates using the force field developed herein, and understanding the role of different microcline surfaces in ice nucleation.

A modified Goldstein filter for interferogram denoising of interferometric imaging radar altimeter based on multiple quality-guided graphs.

Aiming at the characteristics that the signal noise ratio (SNR) gradually decreases from the near to far range of the swath, an adaptive phase filtering algorithm based on Goldstein filtering and combined with multiple quality-guided graphs was proposed. Firstly, the components used to determine the filtering parameters were obtained through residue density, pseudo-coherence coefficient and pseudo-SNR, the three quality-guided graphs. Then, the filter parameters were calculated by weighting the three components. Finally, the size of filtering window was determined according to the account of residues, and the interferometric phase noise was removed in frequency domain. Simulated data, TSX/TDX data and airborne interferometric imaging radar altimeter data were used to verify the performance of the new algorithm. Compared with the results of Goldstein filtering and its improved algorithms, the results showed that the proposed algorithm can effectively filter out phase noise while maintaining the edge characteristics of interferometric fringe. The section of filtering result can well match with the section of simulated pure interfeometric phase. Moreover, the algorithm proposed in this paper can effectively remove the noise in the interferogram of TSX/TDX sea ice data, and the residues' filtering rate was above 86%, which can effectively remove the phase residues of the sea ice surface while maintaining the characteristics of the sea ice edge. Experimental results showed that the new algorithm provides an effective phase noise filtering method for imaging radar altimeter data processing.

Influence of Surface Ice Roughness on the Aerodynamic Performance of Wind Turbines

Influence of Surface Ice Roughness on the Aerodynamic Performance of Wind Turbines

The Impact of Bare Ice Duration and Geo‐Topographical Factors on the Darkening of the Greenland Ice Sheet

AbstractDark (low albedo) surface ice on the Greenland Ice Sheet enhances melting and subsequent runoff, a major mass loss contributor during the ablation season. The accumulation of both biological (e.g., glacier ice algae) and abiotic (e.g., mineral dust) light‐absorbing particulates are important darkening factors, that are potentially influenced by the duration of snow‐free, bare ice (a phenological factor), and other geo‐topographical factors such as elevation, slope, aspect and the distance from the ice margin. Here, we present the first medium‐resolution (30 m) analysis of the phenological and geo‐topographical controls on the distribution of dark ice in SE and SW Greenland from statistical analysis of data derived from a harmonized satellite albedo product and ArcticDEM. The duration of bare ice primarily controls the distribution of dark surface ice, allowing for algae growth on inland ice surfaces in particular, whereas geo‐topographical factors are only secondary controls.

Determination of the Branching Ratio of CH3OH + OH Reaction on Water Ice Surface at 10 K

The CH3O and CH2OH radicals can be important precursors of complex organic molecules (COMs) in interstellar dust. The COMs presumably originating from these radicals were abundantly found in various astronomical objects. Because each radical leads to different types of COMs, determining the abundance ratio of CH3O to CH2OH is crucial for a better understanding of the chemical evolution into various COMs. Recent work suggested that the reaction between CH3OH and OH on ice dust plays an important role in forming CH3O and CH2OH radicals. However, quantitative details on the abundance of these radicals have not been presented to date. Herein, we experimentally determined the branching ratio (CH3O/CH2OH) resulting from the CH3OH + OH reaction on the water ice surface at 10 K to be 4.3 ± 0.6. Furthermore, the CH3O product in the reaction would participate in subsequent diffusive reactions even at a temperature as low as 10 K. This fact should provide critical information for COMs formation models in cold molecular clouds.

Reconstructions of Little Ice Age glaciers and climate in the Tanggula Mountains, Central Tibet Plateau

Mountain glaciers are one of the most sensitive indicators of climate change. Reconstructing past glacier extents provides valuable insights into the climate change for specific regions where instrumental records are not enough and even absent. In the paper we mapped the outlines for 691 Little Ice Age (LIA) glaciers in terms of prominent moraines beyond contemporary glaciers in the Tanggula Mountains, central Tibetan Plateau (TP). Based on these glacier outlines, we reconstructed the ice thicknesses and surfaces for the LIA glaciers in the region. Accordingly, we calculated the equilibrium-line altitudes (ELAs) for contemporary and LIA glaciers. By comparing the ELAs between the contemporary and LIA glaciers, we estimated the LIA summer temperature decreases in different subregions of the Tanggula Mountains. Since the LIA, the ELA have risen by 35.6 ± 18.8 m, 26.1 ± 17.6 m, and 63.1 ± 38.6 m in the respective western, central, and eastern subregions of the Tanggula Mountains. Assuming no change in precipitation, the LIA summer temperature would decrease by 0.22 ± 0.12 °C, 0.14 ± 0.09 °C, and 0.34 ± 0.21 °C in the three subregions, respectively. Moreover, glaciers in the western, central, and eastern subregions have lost 13.3%, 23.9%, and 42.8% of their area, 15.4%, 25.3%, and 39.6% of their length, and 20.8%, 39.0%, and 61.0% of their volume, respectively. By compiling the LIA ELA data from previous studies, we also estimated the LIA summer temperature changes for other regions of the TP. The LIA ELA and summer temperature changes relative to the present showed a decreasing trend from the edges towards the interior on the TP.

Enhancing the Efficiency of Ice-Resistant Materials in Asphalt Road Surfaces: A Comprehensive Performance Analysis

This study addresses the critical issue of traffic safety in winter, particularly focusing on the challenges posed by ice and snow on roads. Traditional methods of snow and ice removal are often labor-intensive, inefficient, and environmentally harmful. The objective is to develop a more effective solution for asphalt pavement deicing. Inspired by the anti-icing coating technology used in high-voltage conductors, this research develops an ice-suppressing material designed to reduce the adhesion between snow, ice, and pavement surfaces. The material’s performance is evaluated in terms of deicing efficiency, durability, adhesive properties, and its impact on pavement performance. Test results demonstrate that the developed ice-suppressing material significantly reduces the adhesion between the ice layer and the pavement, facilitating easier removal. This study concludes that the developed ice-suppressing material significantly enhances deicing efficiency on asphalt pavements. It exhibits strong hydrophobic properties, as evidenced by increased water droplet contact angles on coated surfaces (99.5° to 83.3°) compared to clean glass slides (39.2° to 29°). This hydrophobicity effectively reduces ice adhesion, decreasing tensile and shear strength of the ice layer by 38.2% and 63.6%, respectively. Additionally, the material demonstrates superior ice-melting capabilities in sub-zero temperatures, with coated ice cubes showing a higher mass reduction rate than uncoated ones. Importantly, its slow-release nature ensures sustained deicing performance over multiple cycles, maintaining effectiveness after seven test cycles. This study introduces an innovative ice-suppressing material that not only improves the efficiency and environmental impact of deicing methods but also contributes to enhancing road safety in winter conditions. The material’s novel composition and sustained effectiveness present a significant advancement in the field of winter road maintenance.

Remote sensing of ice albedo using harmonized Landsat and Sentinel 2 datasets: validation

ABSTRACT Albedo plays a key role in regulating the absorption of solar radiation within ice surfaces and hence strongly regulates the production of meltwater. A combination of Landsat and Sentinel 2 data provides the longest continuous medium resolution (10–30 m) earth surface observatory records. An albedo product (harmonized satellite albedo, hereafter HSA) has already been developed and validated for the Greenland Ice Sheet (GrIS), using harmonized Landsat 4–8 and Sentinel 2 datasets. In this paper, the HSA was validated for various Arctic and alpine glaciers and ice caps using in situ measurements. We determine the optimal spatial window size in point-to-pixel analysis, the best practices in evaluating remote sensing algorithms with groundtruth data, and cross sensor comparison of the Landsat 9 (L9) and Landsat 8 (L8) data. The impact of the spatial window size on measured ice surface homogeneity and albedo validation was analysed at both local and regional scales. Homogeneity statistics calculated from the grey-level co-occurrence matrix (GLCM) suggest that the ice surface becomes more homogeneous as the image resolution becomes coarser. The optimal spatial window size was found to be 90 m, based on maximizing the statistical and graphical measures while minimizing the root mean square error and bias. HSAs generally agree closely with in situ albedo measurements (e.g. Pearson’s R ranges from 0.68 to 0.92) across various Arctic and alpine glaciers and ice caps. Cross sensor differences between L9 and L8 are minor, and we suggest that no harmonization is necessary to add L9 to our HSA product.