Effect Of Surface Electric Field Research Articles

Point Calculation Detection System Based on In Suit Convolution Transistor for Clinical Diagnosis of Heart Disease

AbstractElectrocardiograph signals reflect the current state of the heart and have great significance to the clinical diagnosis of the heart. Convolutional neural networks perform excellently in electrocardiograph pattern recognition. However, CNNs processing ECG signals need to convert them from 1D to 2D, leading to additional circuit and time costs in hardware. Here, a convolution organic transistor (COT) is proposed for monitoring the ECG with CNNs. Based on the surface electric field effect and trap effect, COT can directly process 1D ECG data without complex preprocessing. It can complete the convolution calculation of ECG signals ≈20 000 times per second in theory and reduce the number of devices by 83% compared to conventional arrays. Further, actual ECG signals are measured and input into the COT, which can initially recognize the type of ECG abnormality. Finally, a point calculation detection system is established with 96.2% recognition accuracy in the five‐heartbeat classification task by combining the 1D CNN.

The application of C/Sb composite multilayer films on fast flexible phase change memory

In this paper, the phase transformation properties of C/Sb composite multilayer films based on flexible substrates were studied. After different times of bending, the flexible films can still achieve amorphous to crystalline phase transition, but the crystalline resistance increases to different degrees. When the bending times are less than 15000 times, the deformation makes the grain fine, the surface of the film tends to be flat, the surface electric field effect is weakened, and the resistance drift is reduced. When the bending times are higher than 15000 times, cracks begin to appear in the film, and the cracks’ depth and width increase with the bending times. The distribution of C and Sb elements at the crack was analyzed by scanning electronic microscope energy spectrum. The phase change memory device of C/Sb composite multilayer film based on flexible PEEK substrate has been made, and the rapid reversible resistance transition (∼10 ns) in various complex states has been successfully achieved. This research provides a new idea for flexible information storage.

Facile design of surface electric field driven tourmaline/g-C3N4 layered stacked photocatalysts with enhanced photocatalytic activity for antibiotic removal

In the field of photocatalysis, Graphitic carbon nitride (g-C3N4) has received a lot of attention for its superior functionality and benefits. However, it suffers from the fatal defect of low charge separation efficiency, which is well addressed by tourmaline's self-contained surface electric field. In this work, tourmaline/g-C3N4 (T/CN) composites were successfully synthesized. Due to its surface electric field effect, tourmaline and g-C3N4 are stacked on top of each other. It makes its specific surface area increase greatly and more active sites are exposed. Additionally, the rapid separation of photogenerated electron holes under the action of electric field promotes the photocatalytic reaction. T/CN exhibited excellent photocatalytic performance under visible light, with 99.9% Tetracycline (TC 50 mg L−1) removal after 30 min. Compared to tourmaline (0.0160 min−1) and g-C3N4 (0.0230 min−1), the T/CN composite's reaction rate constant (0.1754 min−1) was 11.0 and 7.6 times higher. A series of characterizations also determined the structural properties and catalytic performance of the T/CN composites, which were found to have a larger specific surface area, narrower band gap, and higher charge separation efficiency compared to the monomer. In addition, the toxicity of tetracycline intermediates and their degradative pathways were investigated, and the toxicity of the intermediates was found to be reduced. Given the quenching experiments and active substance determination, it was also found that h+ and ·O2− play a major role. This work provides more inspiration for photocatalytic material performance research as well as green innovation for environmental management.

High-Performance GaN Vertical Schottky Barrier Diode With Self-Alignment Trench Structure

In this work, high-performance GaN vertical Schottky barrier diodes (SBDs) are successfully fabricated on the GaN-on-GaN substrate by using the self-alignment trench structure and argon (Ar) ion implantation. The fabricated diodes achieve a high current ON/ OFF ratio of 10 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">8</sup> and high breakdown voltage (BV) of 656 V due to the reduced surface electric field effect. Besides, the temperature-dependent reverse leakage characteristics show that two Poole–Frenkel emission (PFE) processes dominate the carrier transport. This work shows great potential of the self-alignment trench structure in fabricating GaN vertical SBDs to improve the BV with simply fabrication process.

Evolution of spheroidal dust in electrically active sub-stellar atmospheres

Context. Understanding the source of sub-stellar polarimetric observations in the optical and near-infrared is key to characterizing sub-stellar objects and developing potential diagnostics for determining properties of their atmospheres. Differential scattering from a population of aligned, non-spherical dust grains is a potential source of polarization that could be used to determine geometric properties of the dust clouds. Aims. This paper addresses the problem of the spheroidal growth of dust grains in electrically activated sub-stellar atmospheres. It presents the novel application of a mechanism whereby non-spherical, elongated dust grains can be grown via plasma deposition as a consequence of the surface electric field effects of charged dust grains. Methods. We numerically solve the differential equations governing the spheroidal growth of charged dust grains via plasma deposition as a result of surface electric field effects in order to determine how the dust eccentricity and the dust particle eccentricity distribution function evolve with time. From these results, we determine the effect of spheroidal dust on the observed linear polarization. Results. Numerical solutions show that e ≈ 0.94 defines a watershed eccentricity, where the eccentricity of grains with an initial eccentricity less than (greater than) this value decreases (increases) and spherical (spheroidal) growth occurs. This produces a characteristic bimodal eccentricity distribution function yielding a fractional change in the observed linear polarization of up to ≈0.1 corresponding to dust grains of maximal eccentricity at wavelengths of ≈1 μm, consistent with the near infrared observational window. Order of magnitude calculations indicate that a population of aligned, spheroidal dust grains can produce degrees of polarization P ≈ 𝒪(10−2 − 1%) consistent with observed polarization signatures. Conclusions. The results presented here are relevant to the growth of non-spherical, irregularly shaped dust grains of general geometry where non-uniform surface electric field effects of charged dust grains are significant. The model described in this paper may also be applicable to polarization from galactic dust and dust growth in magnetically confined plasmas.

Graphene-Assisted Antioxidation of Tungsten Disulfide Monolayers: Substrate and Electric-Field Effect.

Transition metal dichalcogenides (TMDs) have emerged as promising materials to complement graphene for advanced optoelectronics. However, irreversible degradation of chemical vapor deposition-grown monolayer TMDs via oxidation under ambient conditions limits applications of TMD-based devices. Here, the growth of oxidation-resistant tungsten disulfide (WS2 ) monolayers on graphene is demonstrated, and the mechanism of oxidation of WS2 on SiO2 , graphene/SiO2 , and on graphene suspended in air is elucidated. While WS2 on a SiO2 substrate begins oxidation within weeks, epitaxially grown WS2 on suspended graphene does not show any sign of oxidation, attributed to the screening effect of surface electric field caused by the substrate. The control of a local oxidation of WS2 on a SiO2 substrate by a local electric field created using an atomic force microscope tip is also demonstrated.

Experimental investigation on the effect of surface electric field in the growth of tungsten nano-tendril morphology due to low energy helium irradiation

The mechanisms responsible for and controlling the growth of tungsten nano-tendrils (or “fuzz”) under low-energy helium plasma exposure remain unclear. For the first time in nano-tendril experiments, the plasma sheath-produced electric field and the helium (He) ion energy have been decoupled, showing that the sheath electric field has little impact on nano-tendril growth, eliminating a possible cause for tendril growth. The well-established necessary growth conditions for W fuzz were maintained with He ion flux density ΓHe > 1021 He m−2 s−1, surface temperature Ts = 1273 K, He ion energy EHe = 64 eV, and He ion fluence ΦHe > 1024 He m−2. A grid is situated between the tungsten sample and plasma, with the grid and sample potentials independently controlled in order to control the electric field at the surface of the sample while maintaining the same incident He ion energy to the surface. A calculation of the potential profile in the drift space between the grid and sample was used to account for space charge and calculate the electric field at the surface of the sample. Tungsten fuzz formed at all electric fields tested, even near zero electric field. Also, the depth of the resulting W fuzz layer was unaltered by the electric field when compared to the calculated depth determined from an empirical growth model. The conclusion is that the sheath electric field is not necessary to cause the changes in surface morphology.

Controlled calcite nucleation on polarized calcite single crystal substrates in the presence of polyacrylic acid

We studied theoretically and experimentally the effects of the surface electric field generated by polarization and polyacrylic acid (PAA) additives on the heterogeneous nucleation of calcite on the calcite single crystal substrates with (10.4), (10.0) and (00.1) orientations. A set of “in-situ” experiments with optical microscopy was performed to determine the waiting time of CaCO3 nucleation, defined as the time interval between the onset of the diffusion of CO2 and the appearance of the first visible precipitation. Calcite was nucleated on the oriented calcite substrates through diffusion of NH3 and CO2 gas from a solid ammonium carbonate into calcium chloride solutions. A theoretical analysis showed that the surface electric field of the polarized calcite substrate decrease the activation energy for nucleation and consequently promotes nucleation. Experimentally, the surface electric field and PAA addition were found to decrease both contact angles and waiting times, and as a result, promote the heterogeneous nucleation. Combined effect of PAA and surface electric field further reduced contact angles and waiting times regardless of orientation differences of the calcite substrates. The cooperation acts remarkably on N-surface of the respective calcite substrates. The results were explained by the Cassie׳s equation, a classical heterogeneous nucleation theory under a surface electric field, and matching of the charged sites on the PAA chain with the ion arrangement on the calcite substrate.

Metal‐nanoparticle‐coating‐induced enhancement and weakening of resonant Raman scattering in ZnO: effect of surface electric field

Effects of Ag and Ti nanoparticle coatings on resonant Raman scattering in various ZnO thin films are presented. The longitudinal optical (LO) phonons, irrespective of the ZnO quality, exhibit an enhancement and a weakening by the Ag and Ti nanoparticle coatings, respectively. The enhancement (weakening) is always accompanied by a reduced (an increased) intensity ratio of the second to first‐order LO phonons, which can be associated with changes in the electron‐phonon coupling strength in the probed area of ZnO. Angle‐resolved X‐ray photoelectron spectroscopy provides evidence for the bending of the surface energy bands and their changes induced by the metal coatings. The effect of metal nanoparticle coatings on the Raman scattering of ZnO is thus attributed to the changes in the surface electric field. Copyright © 2011 John Wiley &amp; Sons, Ltd.

Influence of Polar Tourmaline Substrates on the Growth of ZnO Nanoplates

Nanoplate-shaped ZnO thin film was achieved by the ultrasonic spray pyrolysis technique,using polar(0001) tourmaline wafers as the growing substrates.The as-prepared nanoplates were cross-linked and upright-standing.XRD and Raman tests revealed the hexagonal structure of wurtzite.The electron probe microanalysis and Mssbauer spectroscope were utilized to explore the chemical composition and the fine structures of Fe ions in tourmaline substrates.The plate-like growth of ZnO nanocrystals are related to the surface electric field effect of tourmaline crystals.With the variation of Fe ions contents,valence states and occupation characters,the ratio of thickness to diameter of the ZnO nanoplates decreases with the increase of the intrinsic dipole moments along the c axis and the strengthening of surface electric field effect in tourmaline crystals.

Guiding Effect of Surface Electric Field of Collector on Deposited Electrospinning Fibers

Collecting the fiber mats with uniform characteristics is a current technological bottleneck to industrial application (e.g. filter media, nano-sensors, separators of Li-ion batteries etc.). This paper provides a promising industrial method for collecting uniform fiber mats in large area. The simulation results demonstrated that different collection targets had different surface electric field distribution. The experiments gave a result that thinner and more uniform fibers were collected when using a specific spherical-hat target uniform surface electric field distribution, and the thickness of fiber mats was more uniform as well. The paper presents that the collector's surface electric field has great effect on the electrospinning fibers arrived at the collector, and higher electric field intensity can guide the orientation of the deposited electrospinning fibers.

Design Criteria of High-Voltage Lateral RESURF JFETs on 4H-SiC

Integrated power electronics on SiC have great potential in future power electronics applications. In this paper, a novel vertical channel lateral junction field-effect transistor structure with reduced surface electric field effect is proposed for the first time on 4 H-SiC to address existing challenges in lateral power devices on SiC. Based on an experimentally proven channel design, the detailed design procedure of such a device has been investigated. Design criteria to optimize device forward blocking as well as conduction characteristics are studied. Parameter tolerance and design windows are discussed considering practical issues in device fabrication. Designs that will lead to an optimized tradeoff between device breakdown voltage and specific on-resistance are shown. With an 8-/spl mu/m-long drift region, a 1535-V breakdown voltage and 3.24 m/spl Omega//spl middot/cm/sup 2/ specific on-resistance can be achieved. This represents a figure-of-merit of 737 MW/cm/sup 2/, about 100 times higher than that of the best normally off lateral power devices reported in the literature. The proposed device can be an attractive candidate for power integrated circuit on SiC.

Potentiometric titrations of Bacillus subtilis cells to low pH and a comparison of modeling approaches

To provide constraints on the speciation of bacterial surface functional groups, we have conducted potentiometric titrations using the gram-positive aerobic species Bacillus subtilis, covering the pH range 2.1 to 9.8. Titration experiments were conducted using an auto-titrator assembly, with the bacteria suspended in fixed ionic strength (0.01 to 0.3 M) NaClO 4 solutions. We observed significant adsorption of protons over the entire pH range of this study, including to the lowest pH values examined, indicating that proton saturation of the cell wall did not occur under any of the conditions of the experiments. Ionic strength, over the range studied here, did not have a significant effect on the observed buffering behavior relative to experimental uncertainty. Electrophoretic mobility measurements indicate that the cell wall is negatively charged, even under the lowest pH conditions studied. These experimental results necessitate a definition of the zero proton condition such that the total proton concentration at the pH of suspension is offset to account for the negative bacterial surface charge that tends towards neutrality at pH <2. The buffering intensity of the bacterial suspensions reveals a wide spread of apparent pKa values. This spread was modeled using three significantly different approaches: a Non-Electrostatic Model, a Constant Capacitance Model, and a Langmuir-Freundlich Model. The approaches differ in the manner in which they treat the surface electric field effects, and in whether they treat the proton-active sites as discrete functional groups or as continuous distributions of related sites. Each type of model tested, however, provides an excellent fit to the experimental data, indicating that titration data alone are insufficient for characterizing the molecular-scale reactions that occur on the bacterial surface. Spectroscopic data on the molecular-scale properties of the bacterial surface are required to differentiate between the underlying mechanisms of proton adsorption inherent in these models. The applicability and underlying conceptual foundation of each model is discussed in the context of our current knowledge of the structure of bacterial cell walls.

The impact of ionic strength on the adsorption of protons, Pb, Cd, and Sr onto the surfaces of Gram negative bacteria: testing non-electrostatic, diffuse, and triple-layer models

Bacterial surface adsorption reactions are influenced by electric field effects caused by changes in ionic strength; however, existing datasets are too sparse to definitively constrain these differences or to determine the best way to account for them using thermodynamic models. In this study, we examine the ionic strength dependence of proton and metal adsorption onto the surfaces of Pseudomonas mendocina and Pseudomonas putida by conducting proton, Cd(II), Pb(II), and Sr(II) adsorption experiments over the ionic strength range of 0.001 to 0.6 M. Chosen experimental results are thermodynamically modeled using a non-electrostatic approach, a diffuse layer model (DLM), and a triple-layer model (TLM). The results demonstrate that bacterial surface electric field effects are negligible for proton, Cd, and Pb adsorption onto P. putida and P. mendocina, and that the discrete site non-electrostatic model developed in this study is adequate for describing these reactions. The extent of Sr adsorption is influenced by changes in the bacterial surface electric field; however, the non-electrostatic model better describes Sr adsorption behavior than the DLM or TLM. The DLM and TLM greatly overpredict the effect of the electric field for all adsorption reactions at all ionic strengths tested.

Effect of surface electric field on the anchoring of nematic liquid crystals

We analyse the influence of adsorbed ions and the resulting surface electric field and its gradient on the anchoring properties of nematics with ionic conductivity. We take into account two physical mechanisms for the coupling of the nematic director with the surface electric field: (i) the dielectric anisotropy and (ii) the coupling of the quadrupolar component of the flexoelectric coefficient with the field gradient. It is shown that for sufficiently large fields near saturated coverage of the adsorbed ions, there can be a spontaneous curvature distortion in the cell even when the anchoring energy is infinitely strong. We also discuss the director distortion when the anchoring energy of the surface is finite.

Direct observation of ferroelectric domains in MOCVD-grown PbTiO3 thin films by means of transmission electron microscopy

Transmission electron microscopic observations of domain structures have been made on the PbTiO3 ferroelectric thin films prepared on (100) NaCl by metalorganic chemical vapor deposition (MOCVD). Both single-domain and alternating 90[ddot] a-a and a-c domain configurations were observed in the as-deposited thin films. 180 domain boundaries were also detected in the films which can compensate the polarization charges in grain boundaries. Domain formation in closely-packed polycrystalline thin films was different from that in free crystallites without boundary clamping. Domain width was found to decrease with decreasing grain size and domain splitting cannot be observed in ultrafine grains less than about 40 nm. An interesting phenomenon of polar microregions was also observed and attributed to the effect of surface electric field arising from electron irradiation during the observations.

Effect of surface electric field on the gate capacitance of metal-oxide-semiconductor structures of ternary semiconductors

An attempt is made to derive a generalized expression for the gate capacitance of metal-oxide-semiconductor structures of ternary semiconductors without any approximations of weak or strong electric field limits. It is found, taking n-channel layers on p-type Hg1−xCdxTe as an example, that the same capacitance increases with increasing surface field and the approximated results overestimate the numerical values for both limits. The theoretical formulation is in good agreement with the experimental observation as reported elsewhere, and the corresponding well-known results for n-channel inversion layers on parabolic semiconductors are also obtained from the expressions derived.