This work presents a numerical study of a skimming flow regime in a stepped spillway structure, which is a complex two-phase flow with self-aeration phenomenon. The numerical models employed consist in a hybrid approach capable of switching between interface resolving and interface modelling closures on a local level, and a state-of-the-art volume-of-fluid (VOF) method. A new switch criterion for the hybrid approach is proposed, allowing calculations on irregular grid cells. A detached eddy simulation (DES) turbulence model is selected in order to directly resolve the turbulent flow structures triggering the onset of self-aeration. The main flow properties computed in the non-aerated and aerated region are confronted with experimental measurements. Compared to the VOF method, the hybrid approach provides an overall better prediction of time-averaged air concentration, highlighting the positive outcome of modelling sub-grid interface structures.