Stratiform Copper Research Articles

Distribution and enrichment mechanism of rhenium in sediment-hosted stratiform copper deposits: A case study from the Tangdan deposit, SW China

Sediment-hosted stratiform copper (SSC) deposits are globally significant copper resources and contain critical metals such as Co, Re, and Ge. The Tangdan deposit, located in the Kangdian metallogenic belt within the western Yangtze block, is a prime example of SSC deposits in China. It comprises two types of ores: bedded ores with parallel bedding, and minor discordant vein-type high-grade ores. The sulfides in both types include chalcopyrite, bornite, chalcocite, tetrahedrite, digenite, and traces of galena and pyrite. Sulfides from vein-type ores show Re contents 10 to 100 times higher (0.01–1.67 ppm) than those in the bedded ores (0.06–0.27 ppm). However, the mechanism driving this disparity in Re content between ore types remains unclear. In the bedded ores, Re is preferentially partitioned into secondary digenite over primary sulfides such as chalcopyrite, bornite, chalcocite, and tetrahedrite. The relative Re enrichment in digenite is likely due to oxidization alteration, as Re is highly sensitive to oxygen fugacity. In contrast, Re in the vein-type ores predominantly associates with chalcocite, likely because of its high Mo content. Additionally, sulfides in vein-type ores typically have higher Zn, Mo, Sb, Re, and Pb concentrations than bedded ores. The δ34S values of Cu-sulfides in bedded ores range from +1.7 ‰ to +11.5 ‰, whereas those in vein-type ores span from −13.3 ‰ to −4.8 ‰. The sulfur isotope geothermometer for coprecipitated chalcopyrite and bornite indicates that the average formation temperature for vein-type ores is 364 °C. Based on trace elements, sulfur isotope, and formation temperature of sulfides, we propose that bedded and vein-type ores have different formation mechanisms. Copper and other ore-forming elements were leached from the source bed by low-temperature (171 °C), Re-poor basin brine, while marine sulfate provided reducing sulfur, triggering redox reactions that formed bedded ores. In contrast, vein-type ores accumulated Re through the interaction between high-temperature hydrothermal fluids (364 °C) and Re-rich carbonaceous slate. The continuous dissolution of dolostone in high-temperature fluids increases pH and promotes the precipitation of sulfides, ultimately leading to the formation of Re-rich vein-type ores. This model for Re migration and enrichment at the Tangdan deposit could have broader applications for SSC deposits globally and serves as an exploration guide for critical metals in SCC deposits.

Metallogenic model of sandstone-hosted copper deposits: a case study from the Paleogene in Jiashi area, northwestern China

Sandstone-hosted copper deposits, a type of Sediment-Hosted Stratiform Copper (SSC) deposits, are widely distributed globally. While economically viable deposits of SSC are relatively scarce, they account for approximately 30 % of the world's total discovered copper resources. However, there is still a lack of comprehensive and in-depth research into the depositional and metallogenic models of these deposits. The Jiashi area of the Tarim Basin in northwestern China, known for its economically significant Paleogene SSC deposit, lacks in-depth studies on metallogenic processes. To address this, field profile observations were conducted to analyze the sedimentary evolution, sequence stratigraphy, and tectonism of the Paleogene strata in the Jiashi area. Combined with elemental geochemical analysis of samples, the provenance of sediment, and the source of metallogenic materials, a robust metallogenic model was established. The results reveal the influence of provenance for the origin of Paleogene copper-rich strata. Sedimentary evolution played a crucial role in controlling the distribution of copper and sulfur elements, as well as the spatial arrangement of metallogenic beds. Additionally, nappe movement potentially generated faults, allowing upward movement of basin fluids, which played a crucial role in the formation of copper deposits within sandstone-hosted systems. Thus, this study offers a comprehensive analysis of the metallogenic processes involved in sandstone-hosted copper deposits, thereby contributing significant insights to the broader research on SSC deposits worldwide.

Biomarker signatures and depositional environment of ore-bearing black shale in the Luishia Cu–Co deposit, Democratic Republic of Congo: Implications for regional copper mineralization

The Central African Copperbelt is a globally important sediment-hosted stratiform copper cluster, with regional Cu–Co deposits controlled by Neoproterozoic rift basin. Ore formation in the Copperbelt involves multiple stages of mineralization during diagenesis, basin inversion, and collisional orogeny. Understanding the depositional environment of ore-hosting rocks is crucial for revealing the geological settings and pre-orogenic ore genesis. This paper presents a biomarker study focusing on the ore-bearing black shale in the Luishia Cu–Co deposit, Democratic Republic of Congo. The research investigates thermal maturity, source, and depositional environment of organic matter through rock organic carbon and pyrolysis analysis, chloroform bitumen “A” group component analysis, as well as saturated hydrocarbon gas chromatography-mass spectrometry (GC-MS) analysis. The results indicate significant thermal maturation of organic matter in Luishia black shale. Bacteria are identified as the primary source of organic matter followed by red algae and green algae. The sedimentary environment is characterized by a restricted rift basin under shallow marine conditions with a stratified water column. The processes of bacterial sulphate reduction (BSR) and thermochemical sulphate reduction (TSR) significantly influence the mineralization during diagenesis and basin inversion, respectively. Enhanced thermal maturity promotes methane generation which plays a role in reducing anhydrite and subsequently precipitating ore minerals. The findings have important implications for regional exploration strategies.

Analysis of the Possibility of Copper Recovery from Flotation Stratiform Copper Ore Tailings

ABSTRACT Flotation tailings produced at three concentrator plants operated by KGHM Polska Miedz SA (SW Poland) are all continuously deposited in the Zelazny Most Tailings Storage Facility. The aim of this study was to analyze the possibility of recovering copper from the stream of final tailings continually produced by the largest of the three KGHM concentrator plants. The tailings sample contained 0.25% of Cu and was characterized by a relatively fine grain size. The tests were performed for three narrow-range size fractions of the tailings sample: −0.040, 0.040–0.160 and +0.160 mm. The findings demonstrate that the coarse and fine fractions are the main carriers of copper-bearing minerals which can be recovered with satisfactory results, if the fractions are processed separately. The coarse grain fraction was milled and then floated in the presence of standard flotation reagents with satisfactory results. The fine fraction was floated in the presence of NaHS with a relatively good efficiency which requires further research. The presented results prove that copper losses in this material can be partially reduced already at the stage of the upgrading processes performed in the concentrator plant.

The role of supermountain belts and climatic controls on the genesis of copper deposits in the Kupferschiefer and the Central African Copperbelt

Sedimentary rock–hosted stratiform copper deposits are the world’s second largest source of copper and the largest source of cobalt, with about 73% of the copper occurring in two basins: the Katangan Basin (Central African Copperbelt) and the Permian Basin (Kupferschiefer). Why these two sedimentary basins are so highly endowed in copper is puzzling because sedimentary rock–hosted stratiform copper deposits have formed since the Paleoproterozoic and they all share remarkably similar ore mineralogy, host-rock characteristics and basin settings. We suggest that this discrepancy is due to the development of these two basins close to the bases of ~ 8000-km-long supermountain belts. The supermountain belts were instrumental in raising oxygen levels in Earth’s atmosphere, as well as providing a voluminous source of groundwater and a powerful and long-lived driver for the fluid-flow system. The elevated oxygen levels facilitated the diagenetic processes that converted copper-bearing labile minerals to amorphous iron-oxides and smectite and then in turn to hematite and illite. When oxidized brines flushed through the basin successions, the liberated copper was transported to units containing carbon-rich mudstone and the metals were deposited. For the Katangan Basin, development of the Transgondwanan supermountain belt along its margins between about 525 and 510 Ma explains the delay of several hundreds of millions of years between basin formation and mineralization in the Central African Copperbelt. In contrast, development of the Mid-Pangean supermountain belt formed penecontemporaneous with the Permian Basin explains the similarity in timing between basin formation and mineralization in the Kupferschiefer.

Fluid Flow, Alteration, and Timing of Cu-Ag Mineralization at the White Pine Sediment-Hosted Copper Deposit, Michigan, USA

Abstract White Pine, located in Michigan’s Upper Peninsula, is an archetypal sediment-hosted stratiform copper deposit. The Midcontinent rift system is one of only seven basins globally that host a giant sediment-hosted stratiform copper deposit. Despite many similarities with other deposits of this type, White Pine displays some important differences, including the late Mesoproterozoic age, a thick basalt sequence, an apparent lack of evaporites, and a lacustrine depositional setting. This study analyzes paleofluid flow related to the formation of White Pine and places a particular emphasis on structural and diagenetic fluid pathways. Most of the ore is located in a 30-m-wide zone spanning the Copper Harbor Formation red beds and the overlying Nonesuch Formation shales. Sedimentation of these units was accompanied by subtle synsedimentary faulting. Premineralization phases include calcite concretions and nodules, illite and hematite grain coatings, isopachous chlorite rims, emplacement of liquid petroleum (now pyrobitumen), and bleaching. Mineralization introduced native copper into the footwall sandstones and a zoned suite of native copper and sulfur-poor copper sulfide minerals across a migrating redox front in the overlying shales where copper minerals nucleated on authigenic and detrital chlorite grains. Postmineralization phases include quartz cement, calcite cement, and calcite veins that partially overlapped inversion of synsedimentary faults. Contrary to previous studies, we identified evidence for only one phase of mineralization. An Re-Os chalcocite age of 1067 ± 11 Ma places mineralization 11 to 17 m.y. after host-rock deposition. Sulfide δ34S values of –14.0 to 29.9‰ suggest an important contribution from sour gas and thermochemical sulfate reduction of seawater. Carbon (δ13C) and oxygen (δ18O) isotope compositions of five calcite generations range from –15.1 to –1.3‰ and 10.4 to 41.3‰, respectively, and record early meteoric pore water displaced by later seawater. White Pine is both a sediment-hosted stratiform copper deposit and a paleo-oil field. Synsedimentary faults controlled the sedimentological character of the upper Copper Harbor Formation, and together these imparted a strong control on fluid flow and later diagenetic processes. Early oxidized meteoric fluids were displaced by liquid petroleum and sour gas, which were in turn succeeded by metal-rich but sulfate-poor oxidized seawater. Burial compaction during deposition of the overlying Freda Formation drove fluids through White Pine due to its situation on a paleotopographic high near the basin margin. Mineralization occurred at ~125°C at depths of ~2.0 km and spanned incipient basin inversion related to the distal effects of Grenvillian orogenesis. The hightenor copper mineral assemblage is the product of an abundant supply of metal from basaltic volcanic detritus in the Copper Harbor Formation and low seawater sulfate concentrations in late Mesoproterozoic oceans. This demonstrates that viable sediment-hosted stratiform copper systems can form when a readily leachable metal source rock is present, even if hypersaline and sulfate-rich brines are not.

Controls on the Stratiform Copper Mineralization in the Western Syncline, Upper Peninsula, Michigan

The Western Syncline hosts reduced-facies, or Kupferschiefer-type, sedimentary rock-hosted stratiform Cu deposits (SSC) in the lowermost meters of the Nonesuch Formation, which is part of a thick section of clastic sedimentary rocks that comprise the upper fill of the Mesoproterozoic Midcontinent Rift of North America. Located in the Porcupine Mountains Cu district in Upper Peninsula, Michigan, these blind deposits were discovered in 1956, but are not yet developed, although recent renewed interest may result in near-term production. The deposits are distinguished by their relatively undeformed nature and lack of superposed hydrothermal events. Prior to lithification, chalcocite mineralization replaced diagenetic pyrite within two discrete tabular, albeit discontinuous, potential orebodies referred to as the lower Cu-bearing sequence (LCBS) and the upper Cu-bearing sequence (UCBS). The Top Cu Zone transgresses lithologic boundaries, suggesting that a limited volume of Cu-bearing fluids moved vertically upwards through the unlithified stratigraphy, since reductant pyritic rocks above this zone are essentially barren of Cu. The total Cu inventory that has a reasonable expectation of economic extraction is 3678 M lbs. of Cu with 15.3 M oz. of byproduct Ag. When a cutoff grade of 0.9% Cu over a minimum thickness of 2 m is applied to justify an underground room-and-pillar mine, the LCBS and UCBS are not continuous over the Western Syncline. Sedimentology is the first-order control of potential ore and its continuity; dark-gray shales and siltstones deposited under low-energy, anoxic conditions are preferred host rocks, whose thickness must be >2 m to be potential ore since host-rock thickness determines economic viability of extraction. Furthermore, stratigraphy influences the time constraints on mineralization as the lithification process impedes vertical permeability and thus the flow of Cu-bearing fluids upward through the unlithified section. Syn-sedimentary tectonic movements, likely along pre-existing buried faults, are a third-order control as the thickness of host rocks is enhanced under such conditions. Therefore, an understanding of the depositional and tectonic history throughout the Western Syncline is fundamental to understanding the limits of possible economic exploitation and to optimizing ore extraction.

Mineralization of the Liwu large-scale stratiform copper deposits in Sichuan Province, China: Constraints from fluid inclusions

The Liwu stratiform copper deposit is located in the NW Jianglang dome, western China. Current studies mainly focus on the genetic type and mineralization of this deposit. Detailed fluid inclusion characteristics of metallogenic period quartz veins were studied to reveal the ore-forming fluid features. Laser Raman analysis indicates that the ore-forming fluids is a H₂O-NaCl-CH₄ (-CO₂) system. Fluid inclusions microthermometry shows a homogenization temperature of 181–375°C and a salinity of 5.26%–16.99% for the disseminated-banded Cu-Zn mineralization; but a homogenization temperature of 142–343°C and a salinity of 5.41%–21.19% for the massive-veined Cu-Zn mineralization. These features suggest a medium–high temperature and a medium salinity for the ore-forming fluids. H-O isotopic data indicates that the ore-forming fluids were mainly from the metamorphic and magmatic water, plus minor formation water. And sulfur isotopic data indicates that sulfur was mainly derived from the formation and magmatic rocks. Metallogenesis of the disseminated-banded mineralization was mainly correlated with fluid mixing and water-rock reaction; whereas that of the massive-veined mineralization was mainly correlated with fluid boiling. The genetic type of the deposit is a medium-high temperature hydrothermal deposit related to magmatism and controlled by shear zones. This study is beneficial to understand the stratiform copper deposit.

Comparison of main and accompanying metals distribution patterns in newly documented deposits of the Northern Copper Belt in Poland

Three new world-class sediment-hosted stratiform copper deposits have recently been documented in SW Poland, in the deep parts of the Fore-Sudetic Monocline: Nowa Sól, Sulmierzyce North and Mozów. Along with the adjacent prognostic areas, these deposits form an extensive west–east-trending belt, distant from the well-known deposits of the Sieroszowice–Lubin area and referred to as the Northern Copper Belt. This major discovery was a result of an exploration program performed by the Canadian Miedzi Copper Corporation, which involved studies of archival data and the company's own drilling program. Investigation of the core material included microscopic observations of thin sections and chemical analyses using inductively coupled plasma (ICP) mass spectrometry and/or ICP optical emission spectrometry. The aim of this study was to compare available geochemical data from the documented deposits and determine the distribution patterns of the main and accompanying metals. Particular attention was paid to Cu, Ag, Pb, Zn, Co, Ni, Mo, V and Au. Each of the studied deposits is characterized by a different position of the ore mineralization in the lithological profile. Average concentrations of the analysed elements and their distribution in the ore series, both vertically and laterally, indicate that distinct mineralizing systems were responsible for the formation of each orebody. Among the main factors influencing metal distribution in the analysed deposits are: the spatial range of the epigenetic, oxidized Rote Fäule facies; composition and thickness of the source rocks for the mineralizing brines; and tectonics.

Textures, in situ trace element and sulfur isotope of pyrite from the sediment-hosted Cu–Co deposits in the Zhongtiao Mountains, Trans-North China Orogen: Implications for ore genesis

Sediment-hosted Cu–Co deposits in the Zhongtiao Mountains are hosted by the metasedimentary rocks of the Paleoproterozoic Zhongtiao Group in the southern part of the trans-North China orogen, North China Craton. The ore genesis is still disputed with proposed genetic models including metamorphosed sedimentary exhalative (M−SEDEX), metamorphosed sediment-hosted stratiform copper (M−SSC) and metamorphogenic mineralization type. Pyrite occurs as a ubiquitous mineral throughout all ore-forming stages and is ideal for clarifying this issue via the integration of in situ (LA–ICP–MS and EPMA) elemental and LA–MC-ICP–MS sulfur isotope composition analyses. Two main types of pyrite are identified based on petrographic and SEM observations: fine- to medium-grained, variably deformed and inclusion-rich Py1 (including Py1a and Py1b subtypes) in the disseminated–veinlet mineralization stage (S1), and coarse-grained, fractured Py2 (including Py2a and Py2b subtypes) in the fracture-controlled vein-type mineralization stage (S2, main ore stage). Deformed and inclusion-rich Py1a is overgrown by inclusion-poor Py1b, and nonporous Py2a is rimed by porous Py2b. Geochemical results show that the studied pyrite samples have considerable contents of Co (mean > 1000 ppm) and Ni (mean > 100 ppm). These features could be related to both the Co and Ni-rich sedimentary environment (e.g., a volcaniclastic-rich sulfidic marine) and metamorphic enrichment. The content of Se (mean > 200 ppm) in Py2 is significantly higher than that in Py1, indicating the extensive interaction of mineralizing fluids with Se-bearing graphite schist. LA–ICP–MS mapping and textural studies indicate the presence of coupled dissolution-reprecipitation (CDR) reactions that could lead to trace metal compositions (e.g., Co, Ni, Se, Pb, Bi) in the product phases (Py1b, Py2b) that differ from those of their parent phases (Py1a, Py2a). These variations were most likely controlled by fluid temperature and precipitation of specific minerals. The grain-scale chemical zoning of Py2a revealed by elemental mapping indicates fluctuating fluid parameters (e.g., temperature, fS2, and/or parent fluid compositions). The bimodal distributions in Py1 (10–14 ‰ and 18–24 ‰) are consistent with the inheritance of sulfur from sedimentary pyrite and the input of thermochemical sulfate reduction (TSR) -related sulfur from reworked evaporite sulfates in an increasingly open system. The relatively lighter and wider variation in δ34S values (3.2–22.4 ‰, mean = 15.1 ‰) of Py2 implies that the evolution of the ore fluid in S2 was far more complicated, probably as a result of fluid–rock interactions and fluid cooling. During this process, hydrothermal rims with lighter δ34S values (8.4 ‰) grew on older metamorphic pyrite cores with relatively heavier δ34S values (17.4–18.2 ‰). Chalcopyrite displays overlapping S isotopic compositions with pyrite from different mineralization stages, suggesting that copper sulfides inherited reduced sulfur from earlier formed pyrite. Cooling and fluid–rock interactions serve as the critical controls triggering Cu precipitation from the fluid. The combined textural and compositional data of pyrite and chalcopyrite are suggestive of a syn-orogenic copper deposit model, in which all the ore-grade copper was introduced during the Zhongtiao orogeny.

Co–Mn Mineralisations in the Ni Laterite Deposits of Loma Caribe (Dominican Republic) and Loma de Hierro (Venezuela)

Cobalt demand is increasing due to its key role in the transition to clean energies. Although the main Co ores are the sediment-hosted stratiform copper deposits of the Democratic Republic of the Congo, Co is also a by-product of Ni–Co laterite deposits, where Co extraction efficiency depends, among other factors, on the correct identification of Co-bearing minerals. In this paper, we reported a detailed study of the Co mineralisation in the Ni–Co laterite profiles of Loma Caribe (Dominican Republic) and Loma de Hierro (Venezuela). Cobalt is mainly associated with Mn-oxyhydroxide minerals, with a composition between Ni asbolane and lithiophorite, although a Co association with phyllosilicates has also been recorded in a Loma de Hierro deposit. In Loma Caribe, Co-bearing Mn-oxyhydroxide minerals mainly developed colloform aggregates, and globular to spherulitic grains, while in Loma de Hierro, they displayed banded colloform, fibrous or tabular textures. Most of the compositional analyses of Mn-oxyhydroxides yielded 20 and 40 wt.% Mn, with Ni and Co up to 16 and 10 wt.%, respectively. In both profiles, Mn-bearing minerals were mainly found in the transition from the oxide horizon to the saprolite, as observed in other laterite profiles in the world, where the precipitation of Mn-bearing minerals is enhanced because of the pore solution saturation and pH increase.

Geometallurgy of Cobalt Black Ores in the Katanga Copperbelt (Ruashi Cu-Co Deposit): A New Proposal for Enhancing Cobalt Recovery

Copper-cobalt deposits in the Central African Copperbelt belong to the Sediment-Hosted Stratiform Copper (SHSC) type and are situated in the Neoproterozoic Katanga Supergroup. This paper describes in detail the geology, geochemistry and hydrometallurgy of cobalt, with a special focus on the Black Ore Mineralised Zone (BOMZ) unit from the Ruashi Cu-Co deposit as a case study. Based on results from fieldwork and laboratory testing, it was concluded that the BOMZ consists of a succession of massive and stratified dolostones, which are weathered into carbonaceous clay dolostones and clays. The Lower “Calcaire à Minéreaux Noirs Formation” (Lower CMN Formation) consists of stratified and finely laminated dolostones, which are weathered at the surface into clayey to siliceous dolostones. The cobalt concentration in the weathering zone is due to supergene enrichment, a process that is linked to the formation of a cobalt cap. The ore consists of heterogenite associated with minor amounts of chrysocolla and malachite. Minor carrollite, chalcopyrite, chalcocite and bornite are present in unweathered fragments. The cobalt grade in both the BOMZ and Lower CMN decreases within depth while the copper grade increases. These grade changes reflect the variation in mineralogy with depth from heterogenite with minor amounts of malachite and chrysocolla to malachite, chrysocolla with traces of heterogenite, spherocobaltite, chalcocite, chalcopyrite, carrollite and bornite. Based on the Cu (100xAS Cu/TCu) and Co ratio (100 xAS Co/TCo), which is related to the ore mineralogy, oxide ores (Cu ratio ≥ 75%) and oxide dominant mixed ores (Cu ratio < 75%, containing the copper sulphide chalcocite) can be differentiated in both the BOMZ and Lower CMN. The absence of talc and the low concentration of Ni, Mn and Fe, on the one hand, and the high-grade Cu in the BOMZ, on the other hand, facilitate the hydrometallurgy of cobalt but require a specific processing. Consequently, the recovery of Co from the BOMZ requires the application of a processing method that is based on sulphuric acid (30 g/L) leaching under reducing conditions (300–350 mV) and the removal of impurities (Cu > 95% and Mn ≈ 99%) from the pregnant leach solution (PLS) by solvent extraction (SX) prior to the precipitation of cobalt as a high-grade hydroxide (40.5%). The sulphuric acid leaching of the BOMZ enabled achieving, after 8 h of magnetic stirring (500 rpm), a highest yield of 93% Co, with other major elements Mn (84%) and Cu (40%). The latter forms a main co-product of the Co exploitation. In contrast, the highest leaching yield for Fe remained smaller than 5%.

New perspective on trace element (Re, Ge, Ag) hosts in the Cu-Ag Kupferschiefer deposit, Poland: Insight from a LA-ICP-MS trace element study

The Kupferschiefer deposit in SW Poland provides an opportunity to study an ore system where besides factors such as temperature, salinity and pH, redox conditions play a major role in controlling trace element incorporation in sulphides. Chalcocite, djurleite, bornite, chalcopyrite, sphalerite, covellite and pyrite from the Cu-Ag deposit in the Lubin-Sieroszowice district were analysed with laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) to study the distribution of trace elements and to identify the main carriers of by-products such as silver and rhenium. Trace element anomalies are not only associated with certain minerals but also linked to specific mineralization styles. Chalcopyrite in epigenetic veins has significantly higher content of Ge, As and Sb while sulphides adjacent to hematitic “red spots” are enriched in redox sensitive elements: djurleite is enriched in V, Se, Re, Au, Hg and Tl, chalcopyrite in V, Se, Hg and Tl, and pyrite in Tl in comparison with bulk Cu-Ag mineralization. Elevated and substantially more variable data for V, Mn, Ni, Co, Ga, Mo, Sn in shale hosted sulphides can be attributed to submicron inclusions of Kupferschiefer silicate matrix which might skew low concentration values even if careful petrographic observations and precise spot selection are applied. Silver concentrations form a linear pattern from chalcocite/djurleite > bornite > chalcopyrite > sphalerite. Silver distribution in the deposit on a broad scale could be linked to the general Fe3+-Cu-Pb-Zn-Fe2+ zonation as well as mineral sequence (hematite-chalcocite-bornite-chalcopyrite-galena-sphalerite-pyrite) observed in the majority of sediment hosted stratiform copper deposits. Epigenetic sulphide-calcite veins associated with local faults and tectonic zones contain chalcopyrite exceptionally rich in germanium (up to 4806 μg/g of Ge) suggesting that the potential of Kupferschiefer Cu-Ag ores in terms of Ge grades and resources could be underestimated. The majority of analysed sulphides do not contain rhenium above detection limits (0.1 μg/g Re) with measurable quantities found almost exclusively in djurleite (up to 3.9 μg/g Re). This indicates that copper sulphides, in particular djurleite, could be a preferred host and an important carrier of rhenium in the deposit.

A critical comparison between the Fungurume 8 and 88 Cu-Co deposits, Central African Copperbelt

The Fungurume 88 deposit located in the Tenke-Fungurume Mining (TFM) district is situated in the northern extent of the Central African Copperbelt (CACB). It is an unusual sedimentary stratiform copper (SSC) deposit of this area, since it contains high-grade hypogene carrollite mineralization in the SD-1b subunit of the lower Shales Dolomitique (SD) Formation of the Mines Subgroup. These lithologies are normally regarded as being barren to poorly mineralized, here however, they boast cobalt concentrations as high as 3 wt% along with Cu concentrations in excess of 4 wt%. Detailed logging of drill core revealed that the sediments of the Fungurume 88 deposit which host the anomalous SD-1b mineralisation differ in both grainsize and mineralogy to the well-recognised Long Facies sediments exhibited by the majority of deposits in the TFM district - including the overlying Fungurume 8 deposit. Petrographic studies have revealed several distinct sulphide textures including the dominant disseminated style, stratiform style, bedding parallel jack veins and crosscutting veins. These sulphides also exhibit distinct trace element compositions suggesting several episodes of mineralization and support a multiphase hypogene Cu-Co model. The specific timings of the mineralisation events are constrained to an early phase (probably contemporaneous with diagenesis and early lithification) as well as a later phase associated with quartz-carbonate-sulphide veining and possibly linked to the regional brecciation event, and thus, in support of existing literature, indicate the presence of at least two mineralizing fluids. Host rock geochemistry obtained from SEM analyses together with LA-ICP-MS analyses on sulphide phases have helped to constrain the mineralizing process in the Fungurume 88 deposit by corroborating fluid-rock interaction, sulphide mineral paragenesis and trace element variation. Drill core assay data has also revealed prominent zonation and segregation between Cu and Co and the latter’s local enrichment observed in the SD-1b subunit. Metal zonation of this kind has also been described in some deposits of the Zambian copperbelt and are therefore used as a proxy here. The detailed petrographic analyses on the host rock shows that the sediments of the Fungurume 88 deposit potentially belong to the Kalumbwe, Menda or a geochemically similar deep marine sedimentary facies rather than the usual Long Facies. This lithological variation was likely the key ingredient, providing an optimal reducing environment or “trap site” for the precipitation of carrollite and other copper sulphides in the SD-1b subunit. These geological and geochemical observations provide insights into the genesis for the Fungurume 88 deposit, understood in a context of the regional geology and Cu-Co mineralisation throughout the greater Copperbelt. Moreover, it highlights that the northern apex of the Lufilian arc and the broader CACB hold vast exploration potential for similar deeper-water sub-basins which may host significant, and yet-undiscovered metal (notably Co) resources.

Geologic observations in the San Marcos area, Coahuila, Mexico: the case for sediment-hosted stratiform copper–silver mineralization in the Sabinas basin during the Laramide orogeny

The sediment-hosted stratiform copper–silver mineralization in the San Marcos area of Coahuila, northeastern Mexico occurs predominantly at an Early Cretaceous redox boundary between footwall siliciclastic red beds of the San Marcos Formation and hanging-wall carbonate strata of the Cupido Formation in the Sabinas basin. The hypogene mineralization is mainly present as chalcocite-group minerals, with additional bornite and chalcopyrite, and everywhere occurs in both disseminated and vein/veinlet forms. Supergene copper-bearing oxides (malachite, chalcanthite, azurite, chrysocolla) are, however, the dominant surface expression of the mineralization. Additional sediment-hosted stratiform copper–silver mineralization also occurs, albeit erratically, in lower strata of the Sabinas basin as well as in veins in basement granitoids, thus spanning ~3000 m of basin stratigraphy. Where best developed, the stratiform mineralization displays intense structural control proximal to the regional San Marcos fault system. This major bounding fault, regional in nature and with numerous periods of activity, controlled the evolution of the Sabinas basin. Structural controls on mineralization include stacked, shallow-angle, bedding-parallel, northeast-vergent thrust faults and associated drag folds, in addition to numerous, steeply-dipping, northeast-trending copper-bearing veins and veinlets. The mineralized veins and veinlets, and the bedding-parallel thrusts display mutually crosscutting relationships. These elements are all consistent and in harmony with a regional northeast-trending direction of horizontal shortening accompanying reverse motion of the San Marcos fault system. Inversion along the San Marcos fault system, and the entire Sabinas basin in the Paleogene from ~60 to 40 Ma, resulted from wholesale contractional deformation during the Laramide (Mexican) orogeny. Hence, emplacement of the sediment-hosted stratiform copper–silver mineralization at San Marcos, and elsewhere in the larger Coahuila region, is interpreted as a natural corollary of large-scale, metal-bearing fluid expulsion, migration, and precipitation resulting from orogenic shortening, lithostatic loading, and squeezing of the Sabinas basin during Mexican orogen construction. Although sedimentation of the host strata in the Sabinas basin took place in a pericratonic setting associated with the opening of the Gulf of Mexico, sediment-hosted stratiform copper-silver mineralization occurred during orogenic uplift and conversion of the original basin into an orogen-foreland pair, with similarities to some of the world´s largest sediment-hosted stratiform copper provinces.

Ore Minerals and Metal Distribution in Tailings of Sediment-Hosted Stratiform Copper Deposits from Poland and Kazakhstan

This study, carried out in tailings from two sediment-hosted stratiform copper deposits in the Lublin-Głogów Copper District in Poland (Kupferschiefer-type deposit) and Zhezkazgan (cupriferous sandstone-type deposit) in Kazakhstan, analysed the mineralogy of copper, zinc, and lead minerals as related to metal accumulation in sediments. Microscopic study in reflected light and SEM–EDS (Scanning Electron Microscope—Energy Dispersive Spectrometer) analysis, as well as chemical diversity in the used INAA (Instrumental Neutron Activation Analysis), ICP (Inductively Coupled Plasma), and AAS (Atomic Absorption Spectroscopy) methods in 35 samples from Kazakhstan and 35 from Poland were examined due to their diversity. In both tailing deposits in Kazakhstan and Poland, heavy fractions were dominated by copper sulphides: chalcopyrite (CuFeS2), bornite (Cu5FeS4). and chalcocite (Cu2S). Moreover, sphalerite, galena, and cerussite have been recognized as a carriers of Zn and Pb. Their geochemistry was dominated by Cu, showing a mean content of 2500 ppm, in both Poland and Kazakhstan. Zinc and lead also occurred, showing a content of approximately 200 ppm and 500 ppm in Poland, and 1500 ppm Zn and 2500 ppm Pb in Kazakhstan, respectively. Grain size analysis indicated that the dominant grain size in both districts corresponded to the silt and fine sands fractions. Copper, zinc and lead sulphides accumulated in fine fractions in tailings from Kazakhstan (in sandstones and quartz grains), and mainly in coarse fractions in Poland (within carbonates, sandstones, and black shales). Mineralogical and geochemical features should be taken into consideration when assessing potential metal sources of technogenic materials.

The prospecting strategy for a deep Cu-Ag ore deposit in Poland – An anatomy of success

The article presents the prospecting strategy implemented by Miedzi Copper Corporation in search for new Cu-Ag ore deposits of the Kupferschiefer type. Sediment-hosted stratiform copper deposits in Poland occur mostly in the Fore-Sudetic Monocline, in the contact zone between the continental red beds (Rotliegend) and Zechstein marine sediments. The ore-bearing series consists of white sandstone (Weissliegend), copper-bearing shale (Kupferschiefer) and carbonates (Zechstein Limestone). The southern-central part of the Fore-Sudetic Monocline is a well-known Lubin-Sieroszowice mining area, where mining operations are conducted at the depths up to 1300 m below surface. However, due to significant depletion of shallower reserves, deep Cu-Ag mineralisation have recently become a subject of interest. Several basic problems had to be resolved in order to reach for such deposits: finding indicators suggesting the presence of rich mineralisation; more precise identification of the current geothermal field in the area of the Fore-Sudetic Monocline; and the availability of modern technologies which would allow safe and economic operation of a deep underground mine. In 2011, Miedzi Copper Corporation initiated its exploration programme focused on deep Cu-Ag ore deposits, based on known prognostic areas in the vicinity of palaeorises and contacts between oxidised and reduced facies, as copper mineralization occurs at the rims of oxidised areas, on the reduced side of the redox boundary. Exploration programme has led to the documentation of three new deep deposits: Nowa Sól, Sulmierzyce North and Mozów, two of which were identified in areas previously described as prospective by the Polish Geological Institute.

On the timing and metallogenic implications of the sediment-hosted stratiform copper–silver mineralization in the Creston Formation (Belt-Purcell Supergroup), British Columbia, Canada

Sediment-hosted stratiform copper–silver mineralization is common in Middle Creston strata of southeastern British Columbia, a correlative lithostratigraphic unit of the Ravalli Group of western Montana. The Ravalli Group hosts the largest sediment-hosted stratiform copper–silver deposits of the Belt-Purcell Supergroup. Strata of the Belt-Purcell Supergroup accumulated between ~1540 and 1300 Ma in a pericratonic rift basin (Belt-Purcell basin) constructed over Archean and Paleoproterozoic blocks of Laurentia. The basin underwent several events of deformation and metamorphism at ~1380–1325 Ma (East Kootenay orogeny), ~1200–1000 Ma (Grenvillian), and 900–800 Ma (Goat River orogeny) prior to Meso-Cenozoic Cordilleran tectonism. U–Pb geochronology of detrital zircons from Middle Creston rocks define a maximum age of deposition of ~1470 Ma, in agreement with the established age range for the Belt-Purcell Supergroup in southeastern British Columbia. Molybdenite is locally part of the sediment-hosted stratiform copper–silver mineralization in the region, either as isolated grains within mineralized strata or in paragenetic sequence with the cupriferous sulfides. Re–Os geochronology on molybdenite reveals repetitive episodes of fluid flow through Middle Creston strata in the study area, with principal events at 1170–1140 and 1043–990 Ma. Paragenetically constrained molybdenite, in growth sequence with bornite and chalcocite, yields an age of 1043 ± 6 Ma. Hence, the fluid responsible for the sediment-hosted stratiform copper–silver mineralization in southeastern British Columbia permeated the host sequence ~440 m.yr. after its deposition, coincident with the Grenville-age metamorphic event at ~1200–1000 Ma. Such tectono-thermal activity extended along the western margin of Laurentia beyond the limits of the Belt-Purcell basin, and was a far-field response to orogen-scale collisions taking place off Laurentia during Rodinia assembly.

Base metal mineralization of the Kolyma terrain in Northeast Russia: Overview and genetic classification

Research subject. The Prikolyma terrain located in the Northeastern part ofRussia constitutes a long-lived Precambrian thrust-faulted structure hosting numerous Cu, Pb and Zn deposits of different types.Materials and methods. The mineralization of the terrain was examined during a course of research and exploration works over the 2007–2012. The rock geochemistry was studied using ICP-OES analysis at the Stuart Geochemistry and Essay laboratory (Moscow). The microprobe analysis of minerals was carried out at the facilities of the Far Eastern Branch of the Russian Academy of Sciences (Magadan) using a Camebax X-ray microanalyzer. The isotopic ratios of sulphur in sulphides were measured using a Finnigan MAT 253 isotope mass spectrometer.Results. The porphyry-copper deposit Nevidimka is represented by skarns and sulphide-quartz stockworks embedded in porphyry granites. The vein deposits Opyt and Glukhoye constitute sulphide-carbonate-quartz veins, the composition of which corresponds to copper-polymetallic ores of the peripheral parts of the copper-porphyry formation. These deposits feature a similar geochemistry and composition of sulphides and sulphur isotopes, which is characteristic of the Riphean complexes of the Prikolyma terrain. The stratiform Pb-Zn veins Nadezhda-3 and Khaya enclosed in Proterozoic dolomites represent parallel-bedding disseminated sulphides. The composition of these ores indicates their diagenetic origin. Tne stratiform copper deposit Oroyok is embedded in Proterozoic shales and can be referred to sediment-hosted copper deposits of a transgressive type.Conclusions. The diversity of Cu-Pb-Zn mineralization types in the Prikolyma terrain is established to have resulted from multiple cyclic changes of the geodynamic ore formation regime. During each such cycle, syngenetic mineralization was followed first by epigenetic and then by vein mineralization. The mobile, thrust-faulted structure caused repeated rejuvenation of ores, which inherited the geochemical features of hosting rocks.

Subaqueous debrites of the Grand ConglomÉrat Formation, Democratic Republic of Congo: A model for anomalously thick Neoproterozoic: “Glacial” diamictites

ABSTRACTVery thick (> 1 km) successions of matrix-supported conglomerates (diamictites) are a very distinctive component of many Neoproterozoic basins. Classically interpreted as glacially deposited sedimentary rocks, their thickness has been seen as requiring exceptional depositional conditions such as world-wide “panglacial” climates. The Neoproterozoic Grand Conglomérat Formation (GC) of Katanga Province, southeastern Democratic Republic of Congo, is a 1.8-km-thick diamictite succession hosting one of the world's largest stratiform copper deposits. Examination of more than 300 km of recently acquired large diameter (up to 4 inches, 10.2 cm) core identifies the diamictites of the GC as debrites that accumulated as part of a deep-water “mass-transport complex” in a tectonically active and volcanically influenced anoxic rift basin. Detailed sedimentological descriptions of debrite facies and their lateral and vertical variability permits new insights into processes of debris-flow formation and transport, and their wider paleoenvironmental and paleotectonic significance. A genetic model is herein presented that highlights the importance of slumping and subaqueous downslope mixing of basin-margin fan-delta gravels, fault breccias, volcanic debris from contemporaneous basaltic fissure eruptions with basinal muds, and the downslope ponding of flows in narrow fault-bounded depocenters. Preservation of such an exceptionally thick subaqueously deposited debrite-dominated mass transport complex lacking any evidence of shallow-water deposition, requires rapid subsidence. Any direct sedimentary evidence of a glacial influence on sedimentation in the wider basin hinterland (if present) has been destroyed and homogenized by mass flow. Indirect evidence of a cold-climate setting is possibly expressed as lonestones in laminated turbidite facies dropped by either glacial or seasonal ice, and by exceptionally rare scratched clasts that may have been striated subglacially. Descriptions and interpretations presented here provide clues to the origin of other unusually thick debrite and turbidite successions elsewhere in other Neoproterozoic basins; their primary paleoenvironmental significance is that they appear to record ponding and focusing of mass flows in narrow, rapidly subsiding fault-bounded depocenters, rather than any unique glacial paleoclimate.