Stratified Water Research Articles

Computationally characterizing the diffusive boundary layer in lakes and reservoirs

PurposeHypolimnetic hypoxia has become increasingly prevalent in stratified water bodies in recent decades due to climate change. One primary sink of dissolved oxygen (DO) is sediment oxygen uptake (JO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${J}_{{O}_{2}}$$\\end{document}). On the water side of the sediment–water interface (SWI), JO2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${J}_{{O}_{2}}$$\\end{document} is controlled by a diffusive boundary layer (DBL), a millimeter-scale layer where molecular diffusion is the primary transport mechanism. In previous studies, the DBL was determined by visual inspection, which is subjective and time-consuming.Material and methodsIn this study, a computational procedure is proposed to determine the SWI and DBL objectively and automatically. The procedure was evaluated for more than 300 DO profiles in the sediment of three eutrophic water bodies spanning gradients of depth and surface area. Synthetic DO profiles were modeled based on sediment characteristics estimated by laboratory experiments. The procedure was further verified adopting the synthetic profiles.Results and discussionThe procedure, which was evaluated for both measured and synthetic DO profiles, determined the SWI and DBL well for both steady and non-steady state DO profiles. A negative relationship between DBL thickness and aeration rates was observed, which agrees with existing literatures.ConclusionsThe procedure is recommended for future studies involving characterizing DBL to improve efficiency and consistency.

Prandtl number effects on extreme mixing events in forced stratified turbulence

Relatively strongly stratified turbulent flows tend to self-organise into a ‘layered anisotropic stratified turbulence’ (LAST) regime, characterised by relatively deep and well-mixed density ‘layers’ separated by relatively thin ‘interfaces’ of enhanced density gradient. Understanding the associated mixing dynamics is a central problem in geophysical fluid dynamics. It is challenging to study LAST mixing, as it is associated with Reynolds numbers $Re := UL/\nu \gg 1$ and Froude numbers $Fr :=(2{\rm \pi} U)/(L N) \ll 1$ ( $U$ and $L$ being characteristic velocity and length scales, $\nu$ the kinematic viscosity and $N$ the buoyancy frequency). Since a sufficiently large dynamic range (largely) unaffected by stratification and viscosity is required, it is also necessary for the buoyancy Reynolds number $Re_{b} := \epsilon /(\nu N^{2}) \gg 1$ , where $\epsilon$ is the (appropriately volume-averaged) turbulent kinetic energy dissipation rate. This requirement is exacerbated for oceanically relevant flows, as the Prandtl number $Pr := \nu /\kappa = {O}(10)$ in thermally stratified water (where $\kappa$ is the thermal diffusivity), thus leading (potentially) to even finer density field structures. We report here on four forced fully resolved direct numerical simulations of stratified turbulence at various Froude ( $Fr=0.5, 2$ ) and Prandtl ( $Pr=1, 7$ ) numbers forced so that $Re_{b}=50$ , with resolutions up to $30\,240 \times 30\,240 \times 3780$ . We find that, as $Pr$ increases, emergent ‘interfaces’ become finer and their contribution to bulk mixing characteristics decreases at the expense of the small-scale density structures populating the well-mixed ‘layers’. However, extreme mixing events (as quantified by significantly elevated local destruction rates of buoyancy variance $\chi _0$ ) are always preferentially found in the (statically stable) interfaces, irrespective of the value of $Pr$ .

First evidence of sexual dimorphism in olfactory organs of deep-sea lanternfishes (Myctophidae).

Finding a mate is of the utmost importance for organisms, and the traits associated with successfully finding one can be under strong selective pressures. In habitats where biomass and population density is often low, like the enormous open spaces of the deep sea, animals have evolved many adaptations for finding mates. One convergent adaptation seen in many deep-sea fishes is sexual dimorphism in olfactory organs, where, relative to body size, males have evolved greatly enlarged olfactory organs compared to females. Females are known to give off chemical cues such as pheromones, and these chemical stimuli can traverse long distances in the stable, stratified water of the deep sea and be picked up by the olfactory organs of males. This adaptation is believed to help males in multiple lineages of fishes find mates in deep-sea habitats. In this study, we describe the first morphological evidence of sexual dimorphism in the olfactory organs of lanternfishes (Myctophidae) in the genus Loweina. Lanternfishes are one of the most abundant vertebrates in the deep sea and are hypothesized to use visual signals from bioluminescence for mate recognition or mate detection. Bioluminescent cues that are readily visible at distances as far as 10 m in the aphotic deep sea are likely important for high population density lanternfish species that have high mate encounter rates. In contrast, myctophids found in lower density environments where species encounter rates are lower, like those in Loweina, likely benefit from longer-range chemical or olfactory cues for finding and identifying mates.

Mechanism of organic phosphorus transformation and its impact on the primary production in a deep oligotrophic plateau lake during stratification

Global warming is leading to extended stratification in deep lakes, which may exacerbate phosphorus (P) limitation in the upper waters. Conversion of labile dissolved organic P (DOP) is a possible adaptive strategy to maintain primary production. To test this, the spatiotemporal distributions of various soluble P fractions and phosphomonesterase (PME)/phosphodiesterase (PDE) activities were investigated in Lake Fuxian during the stratification period and the transition capacity of organic P and its impact on primary productivity were evaluated. The results indicated that the DOP concentration (mean 0.20 ± 0.05 μmol L−1) was significantly higher than that of dissolved inorganic P (DIP) (mean 0.08 ± 0.03 μmol L−1) in the epilimnion and metalimnion, which were predominantly composed of orthophosphate monoester (monoester-P) and orthophosphate diesters (diester-P). The low ratio of diester-P / monoester-P and high activities of PME and PDE indicate DOP mineralization in the epilimnion and metalimnion. We detected a DIP threshold of approximately 0.19 μmol L−1, corresponding to the highest total PME activity in the lake. Meta-analysis further demonstrated that DIP thresholds of PME activities were prevalent in oligotrophic (0.19 μmol L−1) and mesotrophic (0.74 μmol L−1) inland waters. In contrast to the phosphate-sensitive phosphatase PME, dissolved PDE was expressed independent of phosphate availability and its activity invariably correlated with chlorophyll a, suggesting the involvement of phytoplankton in DOP utilization. This study provides important field evidence for the DOP transformation processes and the strategy for maintaining primary productivity in P-deficient scenarios, which contributes to the understanding of P cycles and the mechanisms of system adaptation to future long-term P limitations in stratified waters.

Missing Argo Float Profiles in Highly Stratified Waters of the Amazon River Plume

Abstract In the western tropical Atlantic Ocean close to the Amazon plume, a large loss rate of Argo-float profiles took place, that is, instances of profiles that should have happened but were not transmitted. We find that APEX and SOLO floats were not ascending to the surface in the presence of low surface practical salinity, typically on the order of 32.5 or less, because of limitations on the surface buoyancy range for those floats. This results in an overall loss of profiles from these floats that is on the order of 6% averaged over the year, with a peak of 12% in July. We also find aborted descents/incorrect grounding detections for ARVOR/PROVOR floats when surface salinity is low and the descending float reaches a strong halocline (2.6% of all the profiles in the June–August season). Altogether, the whole Argo set includes a maximum loss rate of roughly 6% in July. We find a pattern of loss that fits the surface salinity seasonal cycle and the occurrence of low surface salinity investigated from a high-resolution daily satellite salinity product in 2010–21. The agreement is even better when considering surface density instead of surface salinity, with the temperature contribution to density inducing a shift in the maximum occurrence of these events by 1 month relative to the cycle of very low salinity events. Because of changes in the float technology, the loss rate that targets the lowest surface salinities was very large until 2010, with an overall decrease afterward. Significance Statement In the western tropical Atlantic Ocean, some Argo floats were not able to ascend or descend with very low surface salinity, because of buoyancy limitations for some float types and false bottom detection on others. In this region, for surface practical salinity smaller than 32.5, this resulted in a loss of close to one-half of the Argo profiles during the last 20 years. Altogether, this undersampling of the lowest surface salinities by Argo floats modifies the upper-ocean salinity seasonal cycle, as well as longer-term trends portrayed in Argo data–based products. Furthermore, in this region, care must be taken when validating satellite salinity data with Argo data or when adjusting satellite sea surface salinity data to in situ data products.

Surface Heat Fluxes Drive a Two‐Phase Response in Southern Ocean Mode Water Stratification

AbstractSubantarctic mode waters have low stratification and are formed through subduction from thick winter mixed layers in the Southern Ocean. To investigate how surface forcing affects the stratification in mode water formation regions in the Southern Ocean, a set of adjoint sensitivity experiments are conducted. The objective function is the annual‐average stratification over the mode water formation region, which is evaluated from potential temperature and salinity adjoint sensitivity experiments. The analysis of impacts, from the product of sensitivities and forcing variability, identifies the separate effects of the wind stress, heat flux, and freshwater flux, revealing that the dominant control on stratification is from surface heat fluxes, as well as a smaller effect from zonal wind stress. The adjoint sensitivities of stratification to surface heat flux reveal a surprising change in sign over 2 years lead time: surface cooling leads to the expected initial local decrease in stratification, but there is a delayed response leading to an increase in stratification. This delayed response in stratification involves effective atmospheric damping of the surface thermal contribution, so that eventually the oppositely‐signed advective haline contribution dominates. This two‐phase response of stratification is found to hold over mode water formation regions in the South Indian and Southeast Pacific sectors of the Southern Ocean, where there are strong advective flows linked to the Antarctic Circumpolar Current.

North Atlantic Temperature Change Across the Eocene‐Oligocene Transition From Clumped Isotopes

AbstractThe Eocene‐Oligocene transition (EOT) (∼34 Ma) is marked by the rapid development of a semi‐permanent Antarctic ice‐sheet, as indicated by ice‐rafted debris and a 1–1.5‰ increase in deep sea δ18O. Proxy reconstructions indicate a drop in atmospheric CO2 and global cooling. How these changes affected surface ocean temperatures in the North Atlantic and ocean water stratification remains poorly constrained. In this study, we apply clumped‐isotope thermometry to well‐preserved planktonic foraminifera, that are associated with lower mixed‐layer to subthermocline dwelling depths from the drift sediments at international ocean discovery program Site 1411, Newfoundland, across four intervals bracketing the EOT. The thermocline/lower mixed‐layer dwelling foraminifera record a cooling of 1.9 ± 3.5 K (mean ± 95% CI) across the EOT. While the cooling amplitude is similar to previous sea surface temperature (SST) reconstructions, absolute temperatures (Eocene 20.0 ± 2.9°C, Oligocene 18.0 ± 2.2°C) appear colder than previous organic proxy reconstructions for the northernmost Atlantic extrapolated to this location. We discuss seasonal bias, recording depth, and appropriate consideration of paleolatitudes, all of which complicate the comparison between SST reconstructions and model output. Our subthermocline dwelling foraminifera record a larger cooling across the EOT (Eocene 19.0 ± 3.5°C, Oligocene 13.0 ± 3.2°C, cooling of 5.5 ± 4.6 K) than foraminifera from the thermocline/lower mixed‐layer, consistent with global cooling and an increase in ocean stratification which may be related to the onset or intensification of the Atlantic meridional overturning circulation.

Climate Variability and Glacier Dynamics Linked to Fjord Productivity Changes Over the Last ca. 3300 Years in Nuup Kangerlua, Southwest Greenland

AbstractGreenlandic fjords, located between the ice sheet and the ocean, are dynamic systems that can sustain highly variable levels of primary productivity and are sensitive to climate change. In our current climate trajectory, meltwater discharge is expected to significantly increase but its long‐term effects on fjord productivity are still poorly constrained. Paleo‐archives can offer valuable insights into long‐term effects. Here, we present two marine sediment core records from Nuup Kangerlua, Southwest Greenland. Our goal is to better understand to what extent, and on what time‐scales, climate fluctuations and associated glacier dynamic changes have impacted fjord productivity over the past ca. 3300 years. Our multiproxy records include diatom fluxes and assemblage composition, sediment biogeochemistry, and grain‐size distribution. Our study reveals that fjord productivity is tightly linked to regional climate variability; relatively higher productivity levels coincided with mild climate periods whereas the climate cooling of the last millennium led to a decrease in productivity. The diatom records suggest that lower productivity is associated with shorter or less intense summer blooms, increased sea‐ice cover and/or a stratified water column. Diatom assemblages demonstrate cold sea‐surface conditions around 1600 CE that might be linked to local advance of glaciers. Cold conditions and decreasing productivity culminated at 1850 CE, when glaciers in the fjord retreated and high glacial meltwater discharge would have altered the fjord hydrography, likely leading to limited nutrient availability. Our long‐term records support the idea that changing climate and cryosphere conditions have a non‐linear impact on the productivity of Greenlandic fjords.

Early Cretaceous climatic influences on organic matter enrichment in lacustrine shales: Insights from the Liupanshan Basin of northwestern China

Organic-rich petroleum source rocks are widespread in Early Cretaceous strata, but the related paleoclimatic conditions are still uncertain. Aptian-Albian lacustrine sediments from the Liwaxia and Madongshan formations in the Liupanshan Basin of northwestern China provide vital material to reveal correlations between the Early Cretaceous paleoclimate and the formation of organic-rich lacustrine shales. Outcrop samples were analyzed for total organic carbon (TOC), C/N ratio, CaCO3 content, lipid biomarkers, and compound-specific n-alkane carbon isotopes. Results show that organic matter (OM) of the Liwaxia Formation was mainly sourced from lacustrine plankton and deposited in a weakly stratified and suboxic water column under a hot and arid climate. Organic matter in the lower part of the Madongshan Formation was derived from a mixture of aquatic organisms and higher plants under a warm and humid climate; plant carbon sources were widely available, and the water column was strongly saline, stratified, and anoxic. Elevated temperatures and a less humid climate accompanied the deposition of the upper part of the Madongshan Formation. Higher plants were the primary OM source, and the carbon source became limited. The water column was hypersaline and stratified, and the bottom water was less anoxic. Abrupt changes in the OM inputs and depositional environments documented in the Madongshan Formation were ascribed to global climatic variations. A warm and humid climate during the Aptian-Albian transition enhances continental nutrient inputs and promotes the formation of reduced water conditions, which directly controls the formation of the coeval organic-rich shales in lacustrine basins in China.

Simultaneous sensing profiles of beam attenuation coefficient and volume scattering function at 180° using a single-photon underwater elastic-Raman lidar.

Lidar has emerged as a promising technique for vertically profiling optical parameters in water. The application of single-photon technology has enabled the development of compact oceanic lidar systems, facilitating their deployment underwater. This is crucial for conducting ocean observations that are free from interference at the air-sea interface. However, simultaneous inversion of the volume scattering function at 180° at 532 nm (βm) and the lidar attenuation coefficient at 532 nm (K l i d a r m) from the elastic backscattered signals remains challenging, especially in the case of near-field signals affected by the geometric overlap factor (GOF). To address this challenge, this work proposes adding a Raman channel, obtaining Raman backscattered profiles using single-photon detection. By normalizing the elastic backscattered signals with the Raman signals, the sensitivity of the normalized signal to variations in the lidar attenuation coefficient is significantly reduced. This allows for the application of a perturbation method to invert βm and subsequently obtain the K l i d a r m. Moreover, the influence of GOF and fluctuations in laser power on the inversion can be reduced. To further improve the accuracy of the inversion algorithm for stratified water bodies, an iterative algorithm is proposed. Additionally, since the optical telescope of the lidar adopts a small aperture and narrow field of view design, K l i d a r m tends to the beam attenuation coefficient at 532 nm (cm). Using Monte Carlo simulation, a relationship between cm and K l i d a r m is established, allowing cm derivation from K l i d a r m. Finally, the feasibility of the algorithm is verified through inversion error analysis. The robustness of the lidar system and the effectiveness of the algorithm are validated through a preliminary experiment conducted in a water tank. These results demonstrate that the lidar can accurately profile optical parameters of water, contributing to the study of particulate organic carbon (POC) in the ocean.

Understanding the Mechanisms and Implications of the First Flush in Mine Pools: Insights from Field Studies in Europe’s Deepest Metal Mine and Analogue Modelling

The chemical composition of mine water discharged from flooded underground mines typically improves over time. This phenomenon is called first flush and can be described by a characteristic curve. Shortly after the mine water begins to discharge, water constituent concentrations rise and then fall in an almost exponential curve, improving water quality over time. In this study, the change in mine water quality was investigated throughout the mine water body. This mine water body commonly consists of different water bodies with individual densities, resulting in mine water stratification. Anthropogenic disturbance of the mine water body can disrupt this stratification and also the positive effect of the first flush. To better understand and predict the first flush, the first flush was simulated experimentally using an analogue model of a flooded underground mine, the Agricola Model Mine. The results were compared with field studies to help understanding and predicting the change in mine water quality. Overall, the results suggest that the first flush occurs throughout the mine water body, making it similar to a chemical reactor. This better understanding of the process can lead to more effective mine water management and design of mine water treatment facilities.Graphical

Effects of storm runoff on the spatial-temporal variation and stratified water quality in Biliuhe Reservoir, a drinking water reservoir.

Stormflow runoff is an important non-point source of pollution in drinking water reservoirs. Storm runoff is usually very turbid and contains a high concentration of organic matter, therefore affecting water quality when it enters reservoirs. In order to investigate the impact of storm runoff on spatial-temporal variation and stratification of water quality during this rainstorm event, the inflow process of the storm runoff was studied through a combination of field investigation and simulation using the Delft3D-Flow model. Water samples were collected from Biliuhe Reservoir at four different periods: before storm runoff, storm runoff flood peak period, 1week after storm runoff, and 5weeks after storm runoff. The results showed that the input of storm runoff resulted in a significant increase in the nitrogen (N) and phosphorus (P) in the reservoir water, especially in the reservoir entrance. The concentrations of total nitrogen (TN) and total phosphorus (TP) gradually decreased after the flood peak period; however, the average concentrations of TN and TP in the entire reservoir remained higher than those before the storm runoff levels for an extended duration. The storm runoff will greatly contribute to the contamination of water quality in a reservoir, and the water quality cannot be quickly restored by self-purification in the short term. During the flood peak period, under the influence of density current, the electrical conductivity (EC) and turbidity increased significantly in the water depth of 10-15m, so that the reservoir water had obvious stratification between 10 and 15m. The form of pollutants in storm runoff was mostly in particle phosphorus. Total particulate phosphorus (TPP) concentration was 0.015 ± 0.011mg/L, accounting for 44.12% of total phosphorus (TP) concentration in storm runoff flood peak period. The process of a rainstorm caused runoff, which carried high levels of turbidity, particulate phosphorus, and organic matter. The storm runoff disrupts the stratification of the reservoir water. In terms of vertical distribution, the turbidity in the reservoir area increased to 73.75 NTU. Therefore, the occurrence of significant turbidity density flow in the reservoir is frequently accompanied by intense rainfall events. Gaining insights into the impact of storm runoff on the vertical distribution of reservoir turbidity can help managers in selecting an appropriate inlet height to mitigate high turbidity outflow.

Water stratification alters phytoplankton assemblages in scallop farming waters of the North Yellow Sea in China

As evaluation indicators of the primary productivity, the phytoplankton biomass and community structure are of great significance to the fishery industry, which can be driven by ocean currents, nutrients and water stratification. In the present study, the characteristics of phytoplankton assemblages in different water layers of a typical Yesso scallop farming area in Zhangzi Island, the North Yellow Sea were investigated from March 2021 to January 2022. According to the vertical distribution of temperature, water stratification was observed from June to August (stratification period), and disappeared in March, October and the following January with vertical homogeneity (mixing period). 18S rRNA gene sequencing results revealed that Pyrrophyta was the most dominant phylum during the sampling period, with high gene proportions in the stratification (63.36%) and mixing periods (77.35%). The gene proportion of Bacillariophyta in the stratification period was 5.44%, which was significantly lower than that in the mixing period of 8.93% (p < 0.05). Moreover, Pseudo-nitzschia, a toxin-producing taxon affiliated with Bacillariophyta, exhibited a significantly higher proportion in the stratification period than in the mixing period. During the stratification period, a number of toxin-producing taxa such as Pseudo-nitzschia and Karlodinium were enriched in the bottom layer, which was 1.29-fold and 1.37-fold of that in the surface layer, respectively. Redundancy analysis showed that phosphate and water temperature were major environmental factors driving the vertical distribution of phytoplankton assemblages. The phosphate (0.11 μM) and silicate (2.09 μM) concentrations in the surface layer approached the minimum threshold for phytoplankton growth, and the stoichiometric limitation of phosphate was detected in the surface and middle layers. Collectively, these results indicated that the decreased proportion ratio of Bacillariophyta to Pyrrophyta and unfavorable community composition of Bacillariophyta for scallops were observed during summer, which might result from the phosphate limitation driven by water stratification. The results will further our understanding of the dynamics of phytoplankton communities under the background of intensifying ocean stratification and provide ecological guidance for mollusc mariculture.

Assessment of the danger of the release of deep hydrogen sulfide from the Black Sea to the surface

The relevance of this study is due to the fact that the Black Sea is the largest body of water with a hydrogen sulfide zone. The proven reserves of hydrogen sulfide in the water column of the Black Sea amount to five billion tons. In terms of volume, this corresponds to 3.5 trillion cubic meters. At the same time, a mixture of hydrogen sulfide with air is explosive starting with a concentration of hydrogen sulfide in the air of 50 g/ m3. In addition, hydrogen sulfide is toxic, since it is a nerve gas, deadly already at 1 g/ m3. It is of interest to assess the possibility of the release of hydrogen sulfide waters of the sea to the surface with their subsequent degassing, as well as the consequences of increasing the concentration of hydrogen sulfide in surface waters and in the air for coastal areas. The distribution of hydrogen sulfide in the Black Sea is well studied. Especially a lot of measurement data was obtained for the top layer at a depth of 1000 m. Data on the concentration of hydrogen sulfide at depths from 1000 m to 2000 m is significantly less for technical reasons. The maximum concentration of hydrogen sulfide in the sea is reached at depths above 1500 m. A numerical assessment of the consequences of the release of deep waters to the surface has been obtained. It is shown that the concentration of hydrogen sulfide in the air will not exceed 1 g/m3, which is almost two orders of magnitude less than the explosive concentration. The balance estimates of oxygen and hydrogen sulfide fluxes in the Black Sea are considered in connection with forecasts of a rise in the boundary of the hydrogen sulfide zone. It is shown that the rise of the boundary is a consequence of the imbalance of these flows, however, the amount of net hydrogen sulfide production cannot be estimated accurately enough. With an accuracy of estimates of the fluxes themselves of 20-30%, the resulting increase in the amount of hydrogen sulfide per year is a statistically insignificant amount. The release of hydrogen sulfide to the surface in the foreseeable future is possible if the stratification of waters is disrupted by mechanical intervention.

The Structure and Dynamics of an Estuarine Tidal Intrusion Front

AbstractTidal intrusion fronts are surface convergences that occur at constrictions in estuaries during the flood tide, separating incoming higher‐salinity water from lower‐salinity, stratified estuarine water. Previous observations of tidal intrusion fronts describe a V‐shaped planform, with the apex of the V pointing into the estuary, however the significance of this structure has not been previously explained. Observations near the mouth of the James River estuary during the flood tide reveal the development of a quasi‐steady, V‐shaped front. Considering a reference frame oriented normal to the front, the velocity and density structure are consistent with gravity‐current dynamics, but the oblique orientation of the front relative to the impinging flow indicates strong, along‐front shear, which results from vorticity produced by flow separation at the lateral boundaries as well as topographic torque from upstream. The combination of convergence and along‐front shear leads to enhanced mixing, as revealed by acoustic backscatter images of shear instability and persistent subcritical gradient Richardson number in the frontal zone. Oblique fronts such as this tidal intrusion front are common features of estuaries, and they play an important role in vertical exchange due to subduction and mixing of surface water.

Research and Application of the Fourth Generation Stratified Water Injection Technology in Daqing Oilfield

Stratified water injection is the most important characteristic technology in Daqing oilfield development, providing technical support for efficient oilfield development. With the oilfield entering the ultra-high water cut stage, the remaining oil is highly dispersed, the oil-water relationship is complex, the qualified rate of water injection decreases rapidly, and the difficulty of stabilizing oil and controlling water is increasing. In order to solve the contradiction between the increasing workload of water injection well testing and the limited testing team, and mee t the needs of oilfield precision development, the cable-controlled layered water injection technology has been developed. In this technology, the pressure monitoring system, flow monitoring system and flow control system are placed in the preset cable intelligent water distributor. At the office end, the technicians send control instructions on the server software, and send them to the ground control box through the oilfield production wireless network. The cable carrier technology is used to transmit the instructions to the intelligent water distributor through the cable, so as to achieve real-time communication, obtain the downhole layering parameter information, and control the downhole layering injection volume. Ten intelligent injection technology demonstration areas have been built to verify the process adaptability under different development contradictions. The cable-controlled layered water injection technology improves the proportion of water absorption thickness, effectively controls the water cut rise rate and natural decline rate, and has obvious oil increase effect, promoting the digital transformation and intelligent development of the oilfield.

Compatibility assessment of thermal energy storage integration into industrial heat supply and recovery systems

Thermal energy storage (TES) systems can be used for recovering industrial waste heat and increasing energy efficiency, especially when coupled to batch thermal processes. Stratified water thermal storage tanks are the preferred technology for low-temperature applications, while molten salts are commonly used in medium and high-temperature applications with large storage capacities. No clear consensus exists on the appropriate TES technology for different industrial demands characteristics and their respective heat supply systems for medium and high-temperature applications. The present study analyzes several industrial sectors and their thermal processes, analyzing their temperature ranges, heat demands, and available TES technologies, which are classified by their operational conditions. The study presents two novel indicators for a preliminar compatibility assessment between TES and industrial sectors: a temperature compatibility indicator and exergy efficiency for TES and thermal processes. The results show that low and medium-temperature applications such as food, chemical, or textile industries exhibit high compatibilities with water (over 64%), high-temperature PCM (over 61%), and solid-state TES (100%), whereas molten salts and chemical looping demonstrate lower compatibility (below 24%). The exergy analysis for industrial cases shows that a lower temperature operating range for a TES induces low exergy efficiency. Regarding this scenario, high-temperature cPCM reaches efficiencies of over 44% for mid and high-temperature processes. Conversely, solid-state TES emerges as the most viable option for integration in high-temperature industries, exhibiting an efficiency of 62% with minimal exergy losses. The indicators defined in this study can be used for an early evaluation of TES integration in industrial applications, thus promoting emerging technologies selection through a quantitative comparison of the compatibility metrics.

Lower Jurassic (Pliensbachian–Toarcian) marine paleoenvironment in Western Europe: sedimentology, geochemistry and organic petrology of the wells Mainzholzen and Wickensen, Hils Syncline, Lower Saxony Basin

AbstractOver the past few decades, Toarcian (Early Jurassic) black shale deposits of NW Europe have been extensively studied, and the possible global and regional mechanisms for their regional variation have been discussed. In this context, the black shales of the Northwest German Basin are still sparsely studied with regard to their palaeo-depositional history. This study aims to understand the connection between regional and global influences on the widespread Early Toarcian oceanic anoxic event by examining two wells covering the Upper Pliensbachian to Upper Toarcian sediments in the Northwestern German Basin. The core intervals were analysed using a multidisciplinary approach, including geochemistry, biostratigraphy and organic petrography. Marine palaeoenvironmental changes were reconstructed, and sediment sequences were stratigraphically classified to allow a supra-regional stratigraphic correlation. The results reveal complex interactions between sea level changes, climate warming, basin confinement, and Tethys–Arctic connectivity resulting in the Toarcian black shale deposition. Upper Pliensbachian sediments were deposited under terrigenous influence, shallow water depths, and predominantly oxic bottom water conditions. The deposition of black shale is characterized by algal organic material input and anoxic bottom water conditions. Strong correlations between water stratification, anoxia, and bioproductivity suggest that global warming and intensification of monsoonal rainfall, continental weathering, and increasing freshwater and nutrient inputs were the main factors controlling the formation of black shales. Prolonged deposition of OM-rich sediments in the NWGB may be related to intensified monsoonal precipitation in northern Europe and enhanced Tethys–Arctic connectivity at the serpentinum–bifrons transition. Graphical Abstract

Dominant nitrogen metabolisms of a warm, seasonally anoxic freshwater ecosystem revealed using genome resolved metatranscriptomics.

Nitrogen (N) availability is one of the principal drivers of primary productivity across aquatic ecosystems. However, the microbial communities and emergent metabolisms that govern N cycling in tropical lakes are both distinct from and poorly understood relative to those found in temperate lakes. This latitudinal difference is largely due to the warm (>20°C) temperatures of tropical lake anoxic hypolimnions (deepest portion of a stratified water column), which result in unique anaerobic metabolisms operating without the temperature constraints found in lakes at temperate latitudes. As such, tropical hypolimnions provide a platform for exploring microbial membership and functional diversity. To better understand N metabolism in warm anoxic waters, we combined measurements of geochemistry and water column thermophysical structure with genome-resolved metatranscriptomic analyses of the water column microbiome in Lake Yojoa, Honduras. We sampled above and below the oxycline in June 2021, when the water column was stratified, and again at the same depths and locations in January 2022, when the water column was mixed. We identified 335 different lineages and significantly different microbiome membership between seasons and, when stratified, between depths. Notably, nrfA (indicative of dissimilatory nitrate reduction to ammonium) was upregulated relative to other N metabolism genes in the June hypolimnion. This work highlights the taxonomic and functional diversity of microbial communities in warm and anoxic inland waters, providing insight into the contemporary microbial ecology of tropical ecosystems as well as inland waters at higher latitudes as water columns continue to warm in the face of global change.IMPORTANCEIn aquatic ecosystems where primary productivity is limited by nitrogen (N), whether continuously, seasonally, or in concert with additional nutrient limitations, increased inorganic N availability can reshape ecosystem structure and function, potentially resulting in eutrophication and even harmful algal blooms. Whereas microbial metabolic processes such as mineralization and dissimilatory nitrate reduction to ammonium increase inorganic N availability, denitrification removes bioavailable N from the ecosystem. Therefore, understanding these key microbial mechanisms is critical to the sustainable management and environmental stewardship of inland freshwater resources. This study identifies and characterizes these crucial metabolisms in a warm, seasonally anoxic ecosystem. Results are contextualized by an ecological understanding of the study system derived from a multi-year continuous monitoring effort. This unique data set is the first of its kind in this largely understudied ecosystem (tropical lakes) and also provides insight into microbiome function and associated taxa in warm, anoxic freshwaters.

A volatile sulfur sink aids in reconciling the sulfur isotope mass balance of closed basin lakes

Sedimentary rocks from the early Eocene Green River Formation comprise the largest known lacustrine oil shale deposits, contain remarkably well-preserved fossils, and provide a unique record of climate evolution across the Early Eocene Climate Optimum, a period of high atmospheric CO2. The depositional environment of these intermountain lakes spanned from relatively fresh and fluvially influenced to expanded and stratified saline closed basin lakes under the influence of the Laramide orogeny and alternating humid and arid climatic conditions. As the surface area of the lakes expanded, alkalinity and salinity increased, with depositional cycles that linked to evaporative cycles and marked by an increasing abundance of organic matter-rich shales (TOC > 10 wt%). Simultaneously, an intriguing 20 ‰ positive shift in the sulfur isotope composition of sulfide minerals and organic sulfur is observed. Given that this trend cannot be simply explained by a change in the source of sulfate delivered to the basin, the evolution of biogeochemical sulfur cycling and the balance of fluxes in response to basin evolution remain unresolved. Here, we combine the sulfur isotope compositions of pyrite, organic sulfur, and carbonate-associated sulfate and molecular proxies of euxinia in samples from the Uinta basin's depocenter. We find that organic matter-rich sediments reflect deposition in a stratified water column with enhanced burial of pyrite and sulfurized organic matter, while organic-lean facies present evidence of, at least transiently, euxinic conditions reaching the photic zone during arid conditions presumably because of evaporation. As the lake became both saline-stratified and euxinic, we observe that δ34S values of all measured sulfur-bearing sedimentary proxies increase and evolve along a 1:1 line, a trend independent of facies that we interpret as reflecting a sulfate-limited system despite saline conditions. The isotopic mass balance of sulfur fluxes implies the existence of a sink of sulfur depleted in 34S that is spatially decoupled from burial in the depocenter. Modeling sulfur biogeochemical processes in a saline stratified lake system allows us to estimate that at least 50 % of the sulfur entering the lake could have been lost from the upper part of the euxinic water column where the fractionation factor imparted by microbial sulfate reduction is expressed. We propose that the overall isotopic enrichment of the system was caused by H2S degassing during arid climate intervals, presumably enhanced by transient water column mixing events. Further, episodic intrusion of euxinic bottom waters into the upper part of the water column might have triggered mass fish and plankton mortality, consequently facilitating the formation of these exceptionally fossiliferous and organic matter-rich rocks. Our study finds that volatile outgassing may be an underappreciated mechanism for the sulfur mass balance of stratified lacustrine systems.