Corrosion Resistance Of Steel Research Articles

Rust Prevention Property of a New Organic Inhibitor under Different Conditions.

The corrosion resistance properties of a new type of environmentally-friendly organic inhibitor containing amino ketone molecules are presented in this paper. To evaluate the prevention effect of the inhibitor on corrosion of reinforcement, the electrochemical characteristics of steels in the simulated concrete pore solution (SPS) were investigated under varied conditions of the relevant parameters, including concentrations of the inhibitor and NaCl, pH value, and temperature. The inhibition efficiency of the material was characterized through electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, and the weight loss of steels. The results reveal a significant improvement in the corrosion resistance of steels with the inhibitor. A maximum resistance value of 89.07% was achieved at an inhibitor concentration of 4%. Moreover, the new organic inhibitor exhibited good corrosion protection capability for steels under different NaCl concentrations. Its inhibition efficiency was determined to be 65.62, 80.06, and 66.30% at NaCl concentrations of 2, 3.5 and 5%, respectively. On the other hand, it was found that an alkaline environment was favorable for an enhanced corrosion prevention effect, and an optimal pH value of 11.3 was observed in this work. Besides, the inhibition efficiencies at different temperatures showed a trend of 25 > 35 > 40 > 20 > 30 °C, with a maximum value of 81.32% at 25 °C. The above results suggest that the new organic material has high potential to be used as an eco-friendly and long-term durable inhibitor for steel corrosion prevention under complex conditions.

Experimental Investigation of Producer Gas Effects on Coated Pipelines in Biomass Downdraft Gasifier System

Abstract This research examines the performance of epoxy, ceramic, and graphene coatings on stainless steel 316 in a producer gas environment, focusing on corrosion and erosion resistance. This research aimed to identify the most effective coating for applications in harsh gasification environments. In this research, various analyses, including microstructural examination, hardness and weight measurements, FESEM analysis, and EDAX analysis, were conducted to evaluate the performance of the coatings. The producer gas was passed on to all the coated samples for a period of 100 hours. The significant findings include the superior corrosion and erosion resistance of ceramic-coated stainless steel, as evidenced by low weight fluctuations, maintained hardness levels, and elemental stability. Graphene coatings exhibit high hardness but increased porosity, raising concerns about durability, while epoxy coatings are vulnerable to gas-induced structural alterations. The inclusion rating analysis underscored the ceramic coatings' ability to preserve consistent material properties. Overall, ceramic coatings have emerged as the preferred option for gasification environments due to their structural resilience, inclusion integrity, and elemental stability. Considering the inclusion integrity, mechanical strength, weight stability, and elemental stability, ceramic-coated stainless steel 316 samples exhibit better resistance toward producer gas influence. This research contributes valuable insights for material selection in applications exposed to harsh gasification environments, emphasizing the importance of coating selection for long-term durability and performance.

Enhancing the corrosion resistance of high Mo S31254 super austenitic stainless steel using grain boundary engineering

Super austenitic stainless steel (SASSs) with a high Mo content exhibit excellent resistance to intergranular corrosion (IGC), Its mechanical properties mainly depend on solid solution strengthening. Meanwhile, grain boundary engineering (GBE) can simultaneously improve the corrosion resistance and mechanical properties of Mo-rich austenitic stainless steel using the resistance to IGC of Mo. However, recrystallization annealing is extremely difficult due to the sensitive precipitation of Cr-rich and Mo-rich precipitations in SASSs. Therefore, this study explores the effect of large deformation, high temperature, and short-time annealing on the corrosion resistance of SASSs. The results show that a recrystallized organization with an average grain size of 13.3 μm was prepared by 50% cold rolling deformation and 2min high-temperature short-time annealing at 1150 °C. The highest percentage of Σ3 GBs is about 34%, the percentage of other low-energy GBs is relatively low (only about 6%), and the rest are random high-angle grain boundaries (RHAGBs), which account for about 60%. It can be seen the corrosion resistance of random GBs after GBE treatment is superior to that of solution treatment. Meanwhile, medium-temperature aging improved the resistance to IGC of SASSs, especially after aging at 450 ℃, a small amount of Mo is enriched along the GBs, which promotes the formation of Cr2O3 and Mo-rich oxides in the passivation film and improves the corrosion resistance. The above results provide guidance for improving the corrosion resistance of Mo-rich austenitic stainless steels.

Essential role of Si in enhancing corrosion resistance of high strength low alloy steels in marine environment

High strength low alloy steels are extensively applied in marine engineering structures (cross-sea bridge, ocean platform, etc), which are usually subjected to severe corrosion in marine atmosphere. In this work, the corrosion behaviors of 550MPa-grade high strength low alloy marine steels with varied Si content were studied in simulated marine atmosphere. Results show the increase of Si could significantly facilitate the formation of α-FeOOH and enrichment of Cr and Cu in inner rust layer, making the rust layer compact and cation-selective. Si and Cr can be co-enriched in inner rust layer to form mixed or complex oxides with amorphous network structure, which could greatly improve the compactness and stability of rust layer and thereby enhance the corrosion resistance of low alloy steel.

Effect of Ca-Mg microalloying on corrosion behavior and corrosion resistance of low alloy steel in the marine atmospheric environment

The effect of Ca-Mg microalloying on corrosion behavior of Al deoxidized low alloy steel in the simulated tropical marine atmospheric environments was investigated. The addition improves microstructural characteristics, increasing the corrosion potential by 70±10mV and decreasing the corrosion rate from 1.66mm/y to 1.57mm/y over time. Furthermore, the addition of Ca-Mg has been observed to modify the morphological attributes, population density, dimensional parameters, and electrochemical properties of the prevalent inclusions. This modification is instrumental in shifting the underlying mechanisms that contribute to localized corrosion, which is often precipitated by these inclusions in the steel matrix.

Enhanced Long-Term Corrosion Resistance of 316L Stainless Steel by Multilayer Amorphous Carbon Coatings.

Diamond-like carbon (DLC) coatings are effective in protecting the key components of marine equipment and can greatly improve their short-term performance (1.5~4.5 h). However, the lack of investigation into their long-term (more than 200 h) performance cannot meet the service life requirements of marine equipment. Here, three multilayered DLC coatings, namely Ti/DLC, TiCx/DLC, and Ti-TiCx/DLC, were prepared, and their long-term corrosion resistance was investigated. Results showed that the corrosion current density of all DLC coatings was reduced by 1-2 orders of magnitude compared with bare 316L stainless steel (316Lss). Moreover, under long-term (63 days) immersion in a 3.5 wt.% NaCl solution, all DLC coatings could provide excellent long-term corrosion protection for 316Lss, and Ti-TiCx/DLC depicted the best corrosion resistance; the polarization resistances remained at ~3.0 × 107 Ω·cm2 after immersion for 63 days, with more interfaces to hinder the penetration of the corrosive media. Meanwhile, during neutral salt spray (3000 h), the corrosion resistance of Ti/DLC and TiCx/DLC coatings showed a certain degree of improvement because the insoluble corrosion products at the defects blocked the subsequent corrosion. This study can provide a route to designing amorphous carbon protective coatings for long-term marine applications in different environments.

Dissolution and redistribution behavior of Cu-rich phase: Implications for corrosion resistance in Cu-bearing duplex stainless steel in chloride media

In this study, the dissolution and redistribution behaviors of the Cu-rich phases were investigated to determine their effect on the corrosion resistance of Cu-bearing 2205 duplex stainless steels. This investigation revealed the presence of Cu-rich phases with varying precipitation modes in ferrite and austenite, as well as a decrease in corrosion resistance as their size increased. The Cu-rich precipitate was preferentially dissolved compared to the steel matrix. A corrosion-product layer was formed on the surface of the alloy. The Volta potential difference between the Cu-bearing corrosion products and the matrix was lower than that between the Cu-rich phase and the matrix. This reduction in the potential difference enhanced the corrosion/passive film stability and improved the corrosion resistance of the alloy.

Enhanced corrosion resistance of 9Cr alloy steel via Al alloying in simulated harsh marine atmosphere

The corrosion behaviors of Cr9Ni1 and Cr9Ni1Al in simulated harsh marine atmosphere were studied by dry-wet cyclic test (DWCT). Scanning electron microscopy (SEM), energy disperse spectroscopy (EDS) and electron probe microanalyzer (EPMA) were used to observe the cross-section morphology of rust layer. The composition of corrosion products were analyzed through X-ray diffractometer (XRD) and X-Photoelectron spectroscope (XPS). Electrochemical impedance spectroscopy (EIS) was used to determine the electrochemical properties of rusted samples. The results show that the corrosion rate of both 9Cr alloy steels increases continuously during the initial corrosion process of 576 h, which can be understood from α/γ*>1 of the rust layer and the acidification caused by increased CrO3. Interestingly, the addition of 0.7% Al reduced the corrosion rate of 9Cr steel by more than 26%. Al not only generates Al2O3 and Al(OH)3 enriched in the whole rust layer, but also optimizes the rust layer in terms of the Cr distribution, composition of Cr-containing compounds, and α-FeOOH content. Importantly, it is proposed that Al alloying weakens acidification through reducing CrO3 content and partial dissolution of the generated Al(OH)3.

Fabrication of High Corrosion Resistant Stainless Steel Containing Mo-rich Grain

Fabrication of High Corrosion Resistant Stainless Steel Containing Mo-rich Grain

Durability properties and steel corrosion resistance of reinforced concrete using fly ash and ground granulated blast furnace slag as partial replacements for sand and cement

Durability properties and steel corrosion resistance of reinforced concrete using fly ash and ground granulated blast furnace slag as partial replacements for sand and cement

Preparation of Superhydrophobic Coating on X80 Steel and Its Corrosion Resistance in Oilfield Produced Water.

Corrosion is an unavoidable issue that steel encounters during service; however, the generic methods employed for corrosion prevention often need high cost or preparation conditions. In this study, a facile chemical replacement deposition method was proposed to realize an anticorrosion superhydrophobic coating on a X80 steel surface. The growth mechanism of the rough structure and its impact on the wettability of the superhydrophobic coating were analyzed. The superhydrophobic coating, deposited for 50 s and modified for 30 min, achieved optimal electrochemical properties and a maximum water contact angle. The immersion test, in the saturated CO2 oilfield produced water, demonstrated the better corrosion resistance of superhydrophobic coating than X80 steel. Correspondingly, a kinetic corrosion model was established to analyze the anticorrosion mechanism. In summary, this method significantly improves the corrosion resistance of X80 steel and is attractive for other industrial fields.

Study on the Effect of Microstructure and Inclusions on Corrosion Resistance of Low-N 25Cr-Type Duplex Stainless Steel via Additive Manufacturing.

Duplex stainless steels are widely used in many fields due to their excellent corrosion resistance and mechanical properties. However, it is a challenge to achieve duplex microstructure and excellent properties through additive manufacturing. In this work, a 0.09% N 25Cr-type duplex stainless steel was prepared by additive manufacturing (AM) and heat treatment, and its corrosion resistance was investigated. The results show that, compared with S32750 duplex stainless steel prepared by a conventional process, the combination value of film resistance and charge transfer resistance of AM duplex stainless steel was increased by 3.2-5.5 times and the pitting potential was increased by more than 100 mV. The disappearance of residual thermal stress and the reasonable distribution of Cr and N elements in the two phases are the reasons for the improvement of the corrosion resistance of AM duplex stainless steel after heat treatment. In addition, the extremely high purity of AM duplex stainless steel with no visible inclusions resulted in a higher corrosion resistance exhibited at lower pitting-resistance-equivalent number values.

STUDYING THE INHIBITORY PROPERTIES OF KETOXIMES IN HYDROGEN SULFIDE-CONTAINING ENVIRONMENTS

The creation and development of technology for the production of highly effective environmentally friendly inhibitors is an important area for modern low-tonnage chemistry and the oil and gas industry. The application of the principles of «green chemistry» and circulation economics in this matter makes it possible to reduce the cost of production of inhibitory compositions by using waste or excess production of organic compounds as raw materials. One of these classes of compounds are ketones and their derivatives, the production of which is common in small- and large-tonnage chemical enterprises. Poorly studied ketone derivatives are ketoximes, a product of the interaction of ketones and amino compounds; an important advantage in the context of studying the inhibitory properties of ketoximes is the presence in their structure of the functional group C=N –OH with electronegative N, O atoms and a double bond at the same time, which have good solubility in water, are nontoxic and biodegradable. Selected compounds, in particular butanone oxime (methyl ethyl ketoxime), which is a fairly common organic compound used in industry to inhibit the polymerization process. The effect of a number of ketoximes (with a C4 chain length) on the corrosion resistance of carbon steel in an imitation of NACE formation water saturated with carbon dioxide and hydrogen sulfide has been studied. The influence of medium temperature and exposure time on inhibitory properties has been established. The influence of the «structure – property», kinetic and physico-chemical parameters of interaction, as well as the mechanism of adsorption on the metal surface are investigated.

ВЛИЯНИЕ ОЗОНА НА КОРРОЗИОННОЕ ПОВЕДЕНИЕ МЕТАЛЛОВ И СПЛАВОВ

Research on the effect of ozone treatment on metal corrosion is presented in the article. The results of experiments on changes in the state of metals and steels when they are in aggressive environments in the presence of ozone are analyzed. In most cases, the ozone-air mixture has a negative effect on various metals and welded joints, increasing the rate of corrosion. Considering that recently the popularity of ozone technologies in all industries has been steadily growing, the massive use of ozone in agriculture is a matter of time. Therefore, there is a need to conduct research aimed at studying the corrosion resistance of various steels and alloys used in the agricultural sector. It has been analytically established that one of the most accessible alloying elements resistant to ozone treatment is chromium. However, its content in steel grades Steel 08kp, Steel 45, 45X, Steel 60S2, which are most widely used in agricultural engineering, ranges from 0.1 to 1.1%. This chromium content may be insufficient and therefore similar studies need to be carried out. It was established that the most common Steel 08kp showed sufficient resistance to aggressive environments in the presence of ozone as a result of the experiment, quite comparable with more expensive alloys. At the same time, the introduction of ozone into a solution of 70% acetic acid reduced the weight loss per unit area of steel grades Steel 08kp, Steel 45, 45X, Steel 60S2 by 2...7 times. This suggests that ozone blocks metal atoms and prevents exposure to aggressive environments.

High-velocity oxy-fuel and high-velocity air fuel sprayed WC-Co-Cr coatings on solution-treated 21-4N steel for slurry and corrosion resistance

This study aims to fabricate WC-Co-Cr coatings on the solution-treated 21-4N steel utilizing high-velocity oxy-fuel (HVOF) and high-velocity air fuel (HVAF) techniques. The microstructure, hardness, surface quality, porosity, slurry erosion, and corrosion resistance of HVOF and HVAF coatings on solution-treated 21-4N steel were investigated and compared. The HVAF sprayed WC-Co-Cr coating exhibited dense structure, more hardness (1582 HV), greater fracture toughness (5.69 MPa m1/2), less decarburization, and lower porosity (0.97 %) as compared to HVOF sprayed coating. Further, slurry jet erosion tests and electrochemical corrosion tests provide a comprehensive evaluation of the coating’s performance under erosive and corrosive conditions. Eventually, the conclusive results of the study affirm the exceptional performance of the high-velocity air fuel sprayed WC-Co-Cr coating, demonstrating its superiority in both erosion and corrosion resistance compared to the high-velocity oxygen fuel sprayed coating.

Trisodium phosphate-loaded magnesium‑aluminum layered double hydroxides/oxidized-multiwalled carbon nanotubes self-assembled 2D-nanohybrid for designing a multifunctional smart epoxy nanocomposite

In this study, a hybrid nanomaterial based on layered double hydroxides (LDH) and multi-walled carbon nanotubes (MWCN) was fabricated using a co-precipitation method. Trisodium phosphate (TP) was loaded into the designed nanocarrier to enhance the corrosion resistance of mild steel in 3.5 wt% NaCl media. Fourier transform infrared (FT-IR) spectroscopy, Raman, and X-ray diffraction (XRD) analyses were carried out to investigate the magnesium‑aluminum layered double hydroxides/oxidized-multiwalled carbon nanotubes (Mg-AL-LDH/O-MWCN) structure and morphology before and after loading of trisodium phosphate. Furthermore, the nanocarrier inhibition capability was evaluated through electrochemical impedance spectroscopy (EIS), polarization, and field emission-scanning electron microscopy (FE-SEM) techniques. Electrochemical impedance spectroscopy (EIS) was also employed to estimate the anticorrosion properties of the epoxy coating loaded with TP-LDH/O-MWCN. The EIS evaluation of the intact coating revealed the impedance at the lowest frequency (|Z|0.01 Hz) of about 109 Ω.cm2 after 42 days of immersion for the trisodium phosphate-layered double hydroxides/oxidized-multi-walled carbon nanotubes@epoxy (TP-LDH/O-MWCN@EP) sample and the lowest value of breakpoint frequency was obtained for this sample (fb = 0.063 Hz). These findings prove the trisodium phosphate-layered double hydroxides/oxidized-multi-walled carbon nanotubes (TP-LDH/O-MWCN) particles' effectiveness in the epoxy coating water/ion barrier function enhancement. EIS results indicated the enhancement of the charge transfer resistance (Rct) of the scratched coatings, from 65.97 kΩ.cm2 for the pure epoxy (EP) sample to 94.87 kΩ.cm2 for the trisodium phosphate-layered double hydroxides/oxidized-multi-walled carbon nanotubes@epoxy (TP-LDH/O-MWCN@EP) sample, revealing the self-repairing behavior of the designed coating. In addition, the adhesion properties of the samples coated with LDH/O-MWCN@EP and TP-LDH/O-MWCN@EP were studied by pull-off and cathodic disbonding tests, leading to a 33% reduction in adhesion loss and a 52.23% reduction in the diameter of cathodic delamination. The tensile test conducted on the samples indicated an increase in the ultimate tensile strength (σUTS), elongation break (Ɛb), and toughness values by 188%, 223%, and 800%, respectively, in comparison with the pure epoxy (EP) sample.

A new study on the corrosion inhibition mechanism of green walnut husk extract as an agricultural waste for steel protection in HCl solution

In this study, green walnut husk (GWH) extract was explored as a cost-effective (waste-agricultural) and eco-friendly inhibitor to increase the corrosion resistance of carbon steel in a 1 M HCl solution. Electrochemical impedance spectroscopy, weight change, and potentiodynamic polarization (PDP) tests were utilized to examine the electrochemical behavior of steel substrates with and without the inhibitor. Atomic force microscopy (AFM), field emission scanning microscopy, Fourier-transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) were performed to analyze corroded surface structures with and without the inhibitor. This inhibitor was found to be 27–82 % efficient in increasing the corrosion resistance of the steel substrates. When the temperature of the solution was increased from 303 to 323 K, the retardation coefficient decreased due to the physical adsorption of GWH molecules on the surface. The results indicated that GWH acted as a mixed inhibitor, and its adsorption on the surface followed the Langmuir model. AFM measurements showed that the roughness of corroded surfaces decreased by approximately 22 % when the GWH concentration was at its optimum level of 400 ppm. Thermodynamic studies displayed a decrease in the corrosion reaction's activation energy of about 25 %. FTIR and XRD patterns of corroded surfaces represented that hydrated iron chloride was the dominant corrosion product. Furthermore, the results provided insight into the GWH adsorption mechanism.

Influence of compound layer on the corrosion resistance of low alloy steel in a 3.5% NaCl solution

Samples of AISI 4140 low alloy steel were nitrided at different conditions by using plasma nitriding. The optical microscopy observation and x-ray diffraction analysis showed that a 3 ∼ 12 μm thick compound layer composed of ε-Fe2–3N and γ′-Fe4N was formed on the surface after nitriding treatments. The corrosion behavior was evaluated by measuring the anodic polarization curves in a 3.5% NaCl solution along with the observation of corroded surfaces and cross-sectional morphologies using optical and scanning electron microscope. The results indicated that the corrosion resistance of low alloy steel was significantly enhanced through the formation of compound layer. The thickness of compound layer was one important factor in determining its corrosion resistance.

Performance of Austenitic High-Nitrogen Steels under Gross Slip Fretting Corrosion in Bovine Serum.

Modular artificial hip joints are a clinical standard today. However, the release of wear products from the head-taper interface, which includes wear particles in the nm size range, as well as metal ions, have raised concerns. Depending on the loading of such taper joints, a wide variety of different mechanisms have been found by retrieval analyses. From these, this paper concentrates on analyzing the contribution of gross slip fretting corrosion at ultra-mild wear rates using a bovine calf serum solution (BCS) as the lubricant. The parameters were chosen based on biomechanical considerations, producing wear rates of some ng/m wear path. In parallel, the evolution of tribomaterial (third bodies) was analyzed as to its constituents and generation rates. It has already been shown earlier that, by an advantageous combination of wear mechanisms and submechanisms, certain constituents of the tribomaterial remain inside the contact area and act like extreme-pressure lubricant additives. For the known wear and corrosion resistance of austenitic high-nitrogen steels (AHNSs), which outperform CoCrMo alloys even under inflammatory conditions, we hypothesized that such steels will generate ultra-mild wear rates under gross slip fretting. While testing AHNSs against commercially available biomedical-grade materials of CoCrMo and TiAlV alloys, as well as zirconia-toughened alumina (ZTA) and against itself, it was found that AHNSs in combination with a Ti6Al4V alloy generated the smallest wear rate under gross slip fretting corrosion. This paper then discusses the wear behavior on the basis of ex situ analyses of the worn surfaces as to the acting wear mechanisms and submechanisms, as well as to the tribological reaction products.

ULTRASONIC-ASSISTED ELECTRODEPOSITION OF CoMo/Al2O3 COMPOSITE COATING ON THE SURFACE OF STEEL AND ITS CORROSION RESISTANCE IN SIMULATED SEWAGE WATER

The ultrasonic is applied during the electrodeposition process of CoMo/Al2O3 composite coating on 10# steel to enhance its corrosion resistance in simulated sewage water. The influence of ultrasonic power on the thickness, roughness, chemical composition, surface morphology, and corrosion resistance of the composite coating is investigated. In an aqueous solution, a co-deposition of cobalt and molybdenum can be induced to form CoMo alloy coating. The Al2O3 nanoparticles are incorporated into CoMo alloy to form CoMo/Al2O3 composite coating. When the ultrasonic power increases from 0[Formula: see text]W to 100 W, the electrodeposition rate of the composite coating increases from 63.25[Formula: see text]mg/h to 153.73[Formula: see text]mg/h, and the thickness of the composite coating also increases from 15.6[Formula: see text][Formula: see text]m to 28.1[Formula: see text][Formula: see text]m. The surface roughness of composite coating electrodeposited without ultrasonic is about 0.436[Formula: see text][Formula: see text]m. The CoMo/Al2O3 composite coating electrodeposited at 100[Formula: see text]W ultrasonic power exhibits the smallest surface roughness of 0.193[Formula: see text][Formula: see text]m and presents a denser surface morphology composed of 74.4% Co, 10.3% Mo, and 15.3% Al, resulting in better corrosion resistance with the smallest corrosion current density of only 9.7[Formula: see text][Formula: see text]A/cm2. However, when the ultrasonic power is 150[Formula: see text]W, the intense hydrogen evolution on the surface of the cathode reduces the density of the coating surface, which leads to the deterioration of corrosion resistance.