The air voids present in concrete were evaluated as a 2D spatial point process. The characteristic distance between the points was defined using the nearest neighbor distance function and resulted to be very similar to the spacing factor, which has been used for long. This similarity was discussed by comparing the cubic lattice structure of the air voids associated to the point process model and the spacing factor. Due to the random air-void distribution within the cement paste matrix, a method to estimate the characteristic distance by simulation was also proposed. The characteristics of the random point patterns were consistent with the air-void structures assumed for the spacing factor. Hence, the characteristic distance could be used as a quality parameter instead of the spacing factor and the point process statistics was a useful evaluating method for air-void distribution in concrete.