We present IR and UV photometry for a sample of brightest cluster galaxies (BCGs). The BCGs are from a heterogeneous but uniformly characterized sample, the Archive of Chandra Cluster Entropy Profile Tables (ACCEPT), of X-ray galaxy clusters from the Chandra X-ray telescope archive with published gas temperature, density, and entropy profiles. We use archival GALEX, Spitzer, and 2MASS observations to assemble spectral energy distributions (SEDs) and colors for BCGs. We find that while the SEDs of some BCGs follow the expectation of red, dust-free old stellar populations, many exhibit signatures of recent star formation in the form of excess UV or mid-IR emission, or both. We establish a mean near-UV to 2MASS K color of 6.59 \pm 0.34 for quiescent BCGs. We use this mean color to quantify the UV excess associated with star formation in the active BCGs. We use fits to a template of an evolved stellar population and library of starburst models and mid-IR star formation relations to estimate the obscured star formation rates. Many of the BCGs in X-ray clusters with low central gas entropy exhibit enhanced UV (38%) and mid-IR emission (43%), above that expected from an old stellar population. These excesses are consistent with on-going star formation activity in the BCG, star formation that appears to be enabled by the presence of high density, X-ray emitting gas in the the core of the cluster of galaxies. This hot, X-ray emitting gas may provide the enhanced ambient pressure and some of the fuel to trigger the star formation. This result is consistent with previous works that showed that BCGs in clusters with low central gas entropy host H{\alpha} emission-line nebulae and radio sources, while clusters with high central gas entropy exhibit none of these features. UV and mid-IR measurements combined provide a complete picture of unobscured and obscured star formation occurring in these systems.
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