Spray Process Research Articles

Effects of PEMFC cooling channel insulation coating on heat transfer and electrical discharge characteristics of nanofluid coolants

Nanofluids have high thermal conductivity and electrical conductivity, and there is a problem of electrical discharge when used as a coolant in proton exchange membrane fuel cell (PEMFC). In this study, the compact Al2O3 insulating coating was prepared by supersonic plasma spray processing technology and evenly coated in the cooling channel. The electrical discharge effect and heat transfer enhancement ability of three coolants, namely deionized water, Al2O3 nanofluid and graphene nanofluid, were studied when applied in the electrically active atmosphere of PEMFC. The results show that, the graphene nanofluid has the best heat transfer performance before insulation coating integration, but the dispersion of solid nanoparticles in the base fluid leads to a higher pressure drop, with an increase of 6.7%. When the voltage is 200 V, the leakage current of Al2O3 nanofluid and graphene nanofluid is up to 16 mA and 33 mA respectively. After insulation coating integration, the index of uniform temperature (IUT) and maximum temperature of graphene nanofluids further decrease, while the pressure drop increases by 7.0%. The leakage current of all three coolants at different voltages and Re numbers decrease to 0, indicating a significant improvement in the insulation performance of PEMFC cooling channel. In addition, dimensionless evaluation parameter ε for the applicability of heat transfer fluids were proposed from the perspectives of work and energy. Within the pump power range of 0.0065 W ∼ 0.0325 W, the ε of graphene nanofluids with insulating coating is always lower than Al2O3 nanofluid. At the pump power of 0.014 W, the ε of graphene nanofluids with insulating coating is 0.76, which has the best coolant applicability when applied in the electrically active atmosphere of PEMFC.

Implementasi Sistem Otomatisasi Monitoring Suhu, Kelembapan, dan Amonia pada Kandang Ayam Petelur Menggunakan Metode Fuzzy

The increase in demand for egg consumption and the high chicken population in Indonesia has not been matched by the maintenance of good chicken coops, this has led to a decrease in the quality of eggs produced. Then an automation system is needed in the chicken coop to control temperature, humidity and ammonia levels. Automatic control is by spraying cooling water and prebiotic liquids. The time in the spraying process is calculated using the fuzzy method to determine the spraying decision. The spraying data on the system is compared with manual fuzzy calculations using confusion matrix calculations to get the accuracy value of spraying on the system. The calculation results show that although the precission in water spraying and prebiotic watering reaches 100%, the recall is still low. This shows that improvements are still needed to improve the accuracy of the tool. However, this automation system still has the potential to assist laying hen farmers in optimizing the cage environment, maintaining the health of laying hens, and increasing productivity effectively and efficiently. With this system, it is hoped that the quality of life and welfare of laying hens can be improved, as well as help farmers manage cages more efficiently.

Improvement of the durability of thermal barrier coating by pre-oxidation

To suppress thermally grown oxides (TGO) in thermal barrier coatings (TBCs), the effect of pre-oxidation treatment was investigated for different thermal spray processes, such as high-velocity oxy-fuel spraying (HVOF) and low-pressure plasma spray (LPPS). A pre-oxidation treatment was applied before or after the top coat processing. When the pre-oxidation treatment was applied before top coat processing, TGO growth was suppressed during isothermal oxidation compared to when pre-oxidation was applied after the top coat process. Thermal spray processing did not affect the TGO growth behavior.

A sensitive CsBr/Cs3Bi2Br3I6 heterostructure perovskite gas sensor for H2S detection at room temperature with high stability

In this paper, a new all inorganic lead-free perovskite gas sensor based on CsBr/Cs3Bi2Br3I6 composite was prepared to detect low concentrations H2S gas at room temperature (23 ℃). A two-step method of evaporation and subsequent spraying process was adopted, which makes the vertical growing Cs3Bi2Br3I6 nanoplates uniformly coating on the surface of the CsBr microspheres and forming a heterogeneous structure based conductive path way. The gas sensing test results indicate that the sensor shows good selectivity and reliable repeatability for H2S detection with long-term stability over 60 days, and the lowest concentration detected is 0.5 ppm. The sensor shows satisfactory stability in the range of relative humidity from 44 to 83 %. The in-situ diffuse reflectance infrared Fourier transformations spectroscopy (DRIFTs) results confirm the formation and enhancement process of SO asymmetric telescopic vibration peak due to the introduction of H2S gas, supporting the synergistic mechanism of adsorption-desorption and dynamic defect passivation.

Cost-Effective Milled Silicon and Exfoliated Graphene Anode for High-Performance Li-Ion Batteries

Lithium-ion batteries play a significant role in modern electronics and electric vehicles. However, current lithium-ion battery chemistries are unable to satisfy the increasingly heightened expectations regarding energy demand and reliability. To boost the overall energy density while ensuring the safety of Li batteries, researchers have focused on developing the battery materials [1]. Silicon has an ultrahigh theoretical capacity and has been regarded as the best choice for next-generation lithium-ion battery anodes, but it also suffers from dramatic expansion during cycling [2]. Hence mitigating volume expansion is one of the main challenges towards developing a successful Si based anodes. Herein, a facile air-controlled electrospray method to directly deposit silicon/graphene (Si/Gr) onto current collectors was described. This method is inspired by an electrospinning process and possesses all the advantages that electrospinning has such as low cost, easy scaling up, and simultaneous solvent evaporation during the spraying process. Cost-effective silicon/graphene (Si/Gr) composite electrodes have been investigated for the multiple benefits of Gr in providing mechanical integrity to buffer the silicon volume expansion while maintaining electronic contact with Si to provide a Li-ion transport pathway and to form a uniform solid electrolyte interface (SEI) layer. Our results revealed a superior battery performance including a capacity of 1000 mAh/g at 2C rates and minor capacity loss during long cycling. The details of synthesis, characterization, and lithium-ion battery results of the hybrid anodes will be presented.

Automated Production of Catalyst Coated Membranes for PEM Water Electrolysis Using a Direct Ultra-Sonic Spray Coating Approach

The production of green hydrogen through polymer electrolyte water electrolysis (PEMWE) has attracted attention in recent years for its potential to enable the widespread use of green hydrogen [1, 2]. This technology particularly impacts important sectors of today’s society such as the agricultural and mobility sectors. Among the different components of an electrolysis cell, the membrane electrode assembly (MEA) is regarded as the most important component for its operation, since it is where the water-splitting reaction takes place. For this reason, the choice of materials and production approach play a highly important role to optimize its lifetime, performance, and cost [3]. Within this context, the MEA production via ultra-sonic spray coating has been lately gaining relevance due to its potential to yield high-activity electrode layers with a low catalyst loading.Conventionally, electrodes for PEMWE have been fabricated using other catalyst deposition techniques such as the doctor blade, airbrush spray coating or rod coating on a separate substrate, which is then transferred onto the membrane via hot pressing. However, the shortcomings of these approaches which include an additional hot press step were recently reported, particularly due to the complexity associated with electrodes with low catalyst loadings due to their sensitivity towards mechanical stress [1, 4]. On the other hand, effective approaches involving a direct ink deposition onto the membrane using ultra-sonic spray coating have been long reported for fuel cell applications [5, 6].In this work, we take the approach of direct ink deposition via ultra-sonic spray coating to produce iridium based MEAs for PEMWE. Furthermore, the dependency of the MEA electrochemical activity on the process and material choice are studied in an iterative manner. Of particular interest for this study is the material transfer rate from the catalyst ink to the membrane, the reproducibility of the developed spray coating process and the variation of materials used for the MEA fabrication. The spray process was performed with an ultra-sonic spray nozzle attached to an automized 3-axis rig and coupled with a syringe pump. The fabricated MEAs were characterized using a single cell setup with an active area of 4 cm2. The results of the first generation of the fabricated MEAs show that the material ratios in ink composition play an important role in the ink flowability through the piping which carries the ink to the ultra-sonic nozzle. Furthermore, this behavior has a direct and strong influence on the final composition of the catalyst layer, which consequently directly affects the cell performance.

Performance Enhancement of Nickel Manganese Cobalt Oxide Cathodic Material for Solid-State Battery Technology by Surface Engineering

Batteries as any other electronic devices are affected by parasitic phenomena including physical processes and chemical reactions occurring within the battery materials as well as their interfaces. The phenomena lead to degradation in performance, impose operation restrictions and potentially make devices unsafe.Solid-state, lithium-metal-based, batteries show promise to meet electric vehicle market requirements, but technical challenges to overcome rapid degradation and cost-effective processing remains. Cathode/electrolyte interfacial side reactions can lead to passivating layer formation, thus increasing cell resistance, unwanted additional overvoltage, and ultimately capacity loss. These phenomena are exacerbated in solid-to-solid contact between solid state electrolytes, active materials, and electronic conductive agents. Therefore, electrode manufacturing design is required to mitigate these issues.Within this work we have evaluated Spray Drying (SD) and Atomic Layer Deposition (ALD) coating processes to engineer the cathode/ electrolyte interface of SSBs, thus improving performance and overall cell cycle life. Cathode materials coating is utilised as an effective strategy to mitigate the degradation of the interface. SD is classically utilised in the food and pharma industries, and it has recently been expanded to include the synthesis/shaping of battery electrode materials as a versatile and robust methodology that can be easily scaled up. ALD is a widely exploited technique in the semiconductor (SC) industry based on self-limiting chemical reactions to deposit stoichiometrically-fixed, defect-free and nanometric-thick materials on surfaces. As such, the application of ALD to coat powders in the battery community is innovative and currently under development.Cathodic materials such as NMC (Nickel Manganese Cobalt Oxides) have been investigated, as the need for improving the capacity retention is strong for high-content (>80%) nickel cathodes. Indeed, ALD utilised to coat NMC powder provides a nanometric thick layer of a dielectric but ionic conductive metal oxide. Optimisation of aluminium oxide shell on a core of polycrystalline high nickel material has been investigated with surface engineering. In parallel, we have been exploring the benefit of SD to create an NMC811 powder showing a decorated structure using two different approaches. Indeed, we have either used preformed metal oxide nanoparticles dispersed in an NMC suspension or synthesised a metal oxide layer on top of the NMC in-situ by a chemical reaction during the spray process.Morphological and chemical characterisation of the products have been crucial to develop the coating processes. Electrochemical Impedance Spectroscopy (EIS) probed the engineered cathode/ electrolyte interface within half- and full-coin cell configuration. Rate performance and long-term cycling evaluation has driven the design of an oxide-based lithium metal solid state battery.Alumina coated powder NMC showed longer capacity retention than raw materials when tested in coin cell batteries. The cells were assembled using thin lithium metal anode, Lithium-Lanthanum Zirconium Oxide (LLZO) electrolyte, and surface-engineered NMC811 supported by aluminium current collector. Key words:Surface Engineering, Coatings, Solid-State Batteries (SSB), Spray Dry, Atomic Layer Deposition (ALD), Preformed Nanoparticles, Nickel Manganese Cobalt Oxide (NMC), NMC811, Lithium Lanthanum Zirconium Oxide (LLZO), Interfaces.

Low-pressure plasma sprayed dense scandia-stabilized zirconia electrolyte and its effect on SOFC performance

The plasma spraying process has been proven capable of fabricating high-performance metal-supported solid oxide fuel cells (MS-SOFCs), and the critical technology is to prepare dense MS-SOFC electrolytes. Usually, very low-pressure plasma spraying (<1000 Pa) is adopted as it can significantly improve the electrolyte density and air tightness. However, at the same time, it also has the disadvantages of low deposition efficiency and high cost. This paper explores whether it is possible to prepare dense MS-SOFC electrolytes under low-pressure conditions (1000–10000 Pa) with ideal deposition efficiency and cost. Specifically, 4000 Pa and 7000 Pa were chosen to prepare scandia-stabilized zirconia (ScSZ) electrolytes. The effects of spraying pressure and distance on the electrolyte microstructure and cell electrochemical performance were investigated. It was found that the electrolyte prepared at a pressure of 4000 Pa and a spraying distance of 325 mm had the lowest porosity of 3.28%. Meanwhile, the cell exhibited the best electrochemical performance with an open circuit voltage of 1.008 V and a maximum power density of 970 mW/cm2 at 800 °C.

Machine learning based spray process quantification

Droplet size distribution and liquid loading are two of the most important properties to characterise spray processes. For example, nitrogen oxide (NOx) formation of liquid fuel-operated combustion systems is dominated by mixture homogenisation that is heavily dependent on atomization. While phase Doppler interferometry (PDI) is the technique of choice to measure droplet size distribution, shadowgraphy enables the detection of liquid bodies of arbitrary shape, e.g. ligaments, and thus can be used to delineate primary atomization. For this purpose, a data analysis tool is developed that enables a quantitative description of droplet size and the primary break-up process simultaneously. In this context, machine learning-based (ML) object detection provides a generally applicable approach that is used here to characterise a pressure swirl water spray. The deep neural networks are trained using synthetic training data with physics-informed domain randomisation. Two different network architectures (namely Mask R-CNN and SparseInst), backbones (ResNet50 and ResNet101) and several different training approaches are evaluated. The inference accuracy of the ML models is validated against PDI measurements in terms of droplet size distribution. The best-performing ML model provides a robust detection method for a wide range of measurement conditions. The validated ML model is used to characterise the primary break-up to delineate the effect of aerodynamic forces on the atomization of a hollow cone pressure swirl spray in high momentum gaseous co-flow. The results show the largest and most deformed liquid bodies away from the centre line in regions of high co-flow velocity.

Evolution of microstructure and mechanical properties of cold spray additive manufactured aluminum deposit on copper substrate

The microstructure and mechanical properties of cold sprayed aluminum coatings on copper substrates were studied in this paper. The impact and deposition mechanisms of single and multiple particles during cold spraying were investigated using finite element modeling. The results of single particle model show that the maximum equivalent plastic strain is located at the contact surface between particle and substrate, decreasing from the jet site to the center of particles, and the equivalent plastic strain at the top of particles is almost zero. The results of multi-particle model show that the regions with large equivalent plastic strain include the contact surface between particle and substrate and the region between particles. The experimental results show that particle deposition has a significant impact on compaction during the spraying process. When the spraying distance is set to a fixed value of 30 mm, and the gas pressure is 2.2 MPa, 2.6 MPa, 3.0 MPa and 3.4 MPa, the coating porosity is always stable at about 1 %. The bonding strength of coating increases with the increase of gas pressure. When the gas pressure increases from 2.2 MPa to 3.4 MPa, the coating bonding strength has increased by 142.0 %, and the maximum value of bonding strength between the coating and the substrate is 16.9 MPa. When the gas pressure is 3.4 MPa with the gas preheating temperature of 300 °C, and the spraying distance is 20 mm, 30 mm and 40 mm, the coating porosity is 1.74 %, 0.95 % and 1.21 %, respectively. The maximum value of bonding strength between the coating and the substrate is 21.3 MPa under the spraying distance of 30 mm.

Machine learning model of acoustic signatures: Towards digitalised thermal spray manufacturing

Thermal spraying, an important industrial surface manufacturing process in sectors such as aerospace, energy and biomedical, remains a skill intensive process often involving multiple trial runs impacting the yield. The core research challenge in digitalisation of thermal spraying process lies in instrumenting the manufacturing platform as the process includes harsh conditions, including UV Rays, high-plasma temperature, dusty chemical environment, and spray booth inaccessibility. This paper introduces a novel application of machine learning to the acoustic emission spectra of thermal spraying. By transitioning from the amplitude-time domain to a Fourier-transformed frequency-time domain, it is possible to predict anomalies in real-time, a crucial step towards sustainable material and manufacturing digitalization. Our experimental results also indicate that this method is suitable for industrial applications by generating useful data that can be used to develop Visual Geometry Group (VGG) transfer learning models to overcome the traditional limitations of convoluted neural networks (CNN).

INVESTIGATION OF THE PROCESS OF ELECTRIC ARC METALIZATION OF COATINGS FROM STEEL 30KhGSA

The article considers the electric arc metallization technological modes of steel 30KhGSA wires, which affect thestructure formation and properties ofcoatings.Electric arc spraying was carried out using an SX-600 electric arc metallizer. The properties and characteristics of the resulting coatings depend on several plating parameters such as wire feed speed, voltage, and amperage. The coating structure was studied by electron microscopy and metallographic analysis. The coating has a layered structure, which consists of frozen convective metal flows, micro-welded small metal particles and oxides. The results of the study show that an increase in the wire feed speed during metallization leads to an increase in the resulting coating thickness per unit time. On the surface of steel 45, depending on the selected mode, coatings were formedfromsteel30KhGSAwithathicknessintherangefrom50μmto370μm.Ithasbeenestablishedthat when electric arc metallization coatings are sprayed with 30KhGSA wire, the microhardness of the surface layer increases by a factor of 2 relative to the microhardness of 45 steel. Based on studies investigating the impact of various factors in the electric arc spraying process on the formation of coating structures and properties, it can be deduced that utilizing electric arc metallization on steel 30KhGSA substrates allows for the production of coatings with enhanced hardness.

Fabrication and Characterization of Plasma Sprayed TiO2 and Li4Ti5O12 Materials as All Active Material Lithium-Ion Battery Electrodes

Two strategies to increase battery energy density at the cell level are to increase electrode thickness and to reduce the amount of inactive electrode constituents. All active material (AAM) electrodes provide a route to achieve both of those aims toward high areal capacity electrodes. AAM electrodes are often fabricated using hydraulic compression processes followed by thermal treatment; however, additive manufacturing routes could provide opportunities for more time-efficient and geometry-flexible electrode fabrication. One possible route for additive manufacturing of AAM electrodes would be to employ plasma spray as a direct additive manufacturing technology, and AAM electrode fabrication using plasma spray will be the focus of the work herein. TiO2 and Li4Ti5O12 (LTO) powders were deposited onto stainless steel substrates via plasma spray processing to produce AAM battery electrodes, and evaluated with regards to material and electrochemical properties. The TiO2 electrodes delivered low electrochemical capacity, &lt;12 mAh g−1, which was attributed to limitations of the initial feed powder. LTO plasma sprayed AAM electrodes had much higher capacity and were comparable in total capacity at a low rate of discharge to composite electrodes fabricated using the same raw powder feed material. LTO material and electrochemical properties were sensitive to the plasma spray conditions, suggesting that tuning the material microstructure and electrochemical properties is possible by controlling the plasma spray deposition parameters.

A Survey Paper on Comparative Study of Autonomous Pesticide Spraying Robot

This survey focuses on creating a smart farming solution that combines autonomous pesticide spraying and crop harvesting, all controlled through a user-friendly Android application. In simpler terms, it aims to develop a robot that can take care of two crucial tasks on the farm automatically. This innovative technology is designed to enhance efficiency in agriculture by automating the application of pesticides and the harvesting of crops. The Robot will be equipped with advanced features, such as autonomous navigation, allowing it to move around the farm independently. This not only saves time for farmers but also ensures that the pesticide spraying and harvesting processes are carried out with precision. The integration with an Android application adds a user-friendly interface for farmers to control and monitor the robot. The project envisions a sustainable and technology-driven approach to farming, reducing the manual labor required for pesticide application and crop harvesting. With the help of robot, farmers can expect increased productivity, improved crop yields, and a more streamlined farming experience. This project aligns with the goal of advancing agricultural practices by incorporating automation for the benefit of farmers and the overall farming ecosystem

Layer structure formation induced by in-situ deposit surface temperature under different scanning methods during thermal spraying

Plasma spraying-physical vapor deposition (PS-PVD) and atmospheric plasma spraying (APS), as new thermal spraying process, could prepare advanced thermal barrier coatings by successive scanning deposition layer by layer. To investigate the layer structure of the coating, the transient in-situ deposit surface temperature was investigated by varying the scanning methods. Results show that, compared to unidirectional scanning method, alternating scanning method results in doubling heating duration, higher in-situ deposit temperature rising and thereby thicker well-bonded layer structure during each spray cycle for the coating deposited at the edge position of the scanning path. The erosion resistance of the coatings deposited by unidirectional scanning method is independent on deposition positions including edge position and center position. However, the erosion resistance of the coatings deposited at edge position by alternating scanning method is one time higher than those deposited by unidirectional scanning method. Finally, the erosion mechanism of layer spallation is revealed to explain the difference between different scanning methods.

High-temperature corrosion behavior of bare and NiCr-coated AISI 422 steel by varying the coating thickness in the Na2SO4 + 60%V2O5 environment

It is difficult to assess fatalities due to high temperature corrosion, such as plant closure time, production loss, decrease in productivity, contamination, etc. In this context, the AISI 422 martensitic steel is a popular choice for high temperature applications due to its unique properties. The durability of this material can be increased by coating technology. The Ni-20Cr composite powder is a highly recommended choice for high-temperature applications. In this research, Ni-20Cr coating was sprayed on AISI 422 steel, using a flame spray process with two different thicknesses of 250–350 µm and 350–450 µm. Corrosion studies have been carried out at temperatures of 600 °C and 900 °C for Na2SO4 + 60%V2O5 salt solution environment. The corrosion kinetics were studied with the help of the Wagner equation. Micrographics analysis has been performed by Scanning electron microscopy (SEM) coupled with energy-dispersive spectroscopy (EDS), and X-ray diffraction (XRD) technique. Coated material has been shown better corrosion resistance compared to bare. The low-thickness coating has better corrosion resistance corresponding to both bare and high-thickness.

Assessment of human safety risks from the use of plant protection products

Agriculture is a very serious sector in the life of mankind, with a history that goes back thousands of years, and we know from history that many wars have been fought to gain land in order to obtain better farmland. To meet the needs of growing societies and the increasing pressures that came with it, various technologies were adopted to increase both the quality and quantity of crops. Increasing attention has been paid to the control of crop pests, leading to the emergence of plant protection, which aims not only to kill crop pests but also to produce healthier products for human consumption and to prevent the spread of weeds and their destruction. In the course of our work, we have grouped pesticides by active substance. Knowledge of these groups is essential to assess the risks associated with each of these products and, after a detailed risk assessment of the spraying process, to make recommendations for risk reduction to address high unacceptable risks in order to make agricultural work safer for the use of pesticides.

Heterogeneous microstructural evolution during hydrodynamic penetration of a high-velocity copper microparticle impacting copper

Microparticle hydrodynamic penetration (HDP) may be associated with the erosion regime in cold spray processing and other high-velocity impact events. Here, in an experimental approach where we can individually launch particles and study the impact sites, we explore copper microparticles impacted on copper substrates at velocities above 900 m/s where HDP begins. We lift cross-sectional lamellae from the impact sites with a focused-ion beam for further microstructural characterization using electron backscatter diffraction and scanning transmission electron microscopy. Due to the gradients of strain, strain rate, and temperature associated with HDP, heterogeneous microstructures result. The structural evolution processes observed include deformation twinning and multiple dislocation-mediated grain recrystallization mechanisms—geometric dynamic recrystallization (gDRX), discontinuous DRX (dDRX), and meta DRX (mDRX). The higher strains at the interface lead to the most significant structural changes and complex mechanisms. In contrast, there is a gradient to more conventional dislocation plasticity away from the interface (on either the particle or substrate side). These microstructural observations are consistent with the deformation map for copper and extend the observations of impact-induced recrystallization across new regimes of behavior.

Cavitation resistance of FeMnCrSi coatings processed by different thermal spray processes

Cavitation-resistant FeMnCrSi coatings were developed in the past years as a cost-effective alternative to Co-containing alloys to increase the lifespan of hydraulic machinery. The effect of different chemical compositions, surface finishing, and post-processing treatments was investigated for various processing techniques, namely: Arc Spraying Process (ASP), High-Velocity Oxy-Fuel (HVOF), High-Velocity Air-Fuel (HVAF), Plasma Transferred Arc (PTA), and Cold Gas Spray (CGS). This works consists of a compilation and review of original and literature results, and discusses the microstructure changes imparted by each type of processing and their impact on the coating properties and cavitation resistance. Low heat input high-velocity processes (HVOF, HVAF, CGS) developed a reduced degree of oxidation and porosity, accounting for a cavitation resistance higher than that of the coatings that ASP processed. In addition, ASP coatings showed reduced cohesive strength, with the oxidized inter-splat interface being a preferential site for crack propagation.

Novel Effective Photocatalytic Self-Cleaning Coatings: TiO2-Polyfluoroalkoxy Coatings Prepared by Suspension Plasma Spraying.

Photocatalytic coatings can degrade volatile organic compounds into non-toxic products, which has drawn the attention of scholars around the world. However, the pollution of dust on the coating adversely affects the photocatalytic efficiency and service life of the coating. Here, a series of TiO2-polyfluoroalkoxy (PFA) coatings with different contents of PFA were fabricated by suspension plasma spraying technology. The results demonstrate that the hybrid coatings contain a large number of circular and ellipsoidal nanoparticles and a porous micron-nano structure due to the inclusion of PFA. According to the optimized thermal spraying process parameters, TiO2 nanoparticles were partially melted to retain most of the anatase phases, whereas PFA did not undergo significant carbonization. As compared to the TiO2 coating, the static contact angle of the composite coating doped with 25 wt.% PFA increased from 28.2° to 134.1°. In addition, PFA strongly adsorbs methylene blue, resulting in a greater involvement of methylene blue molecules in the catalyst, where the catalytic rate of hybrid coatings is up to 95%. The presented nanocomposite coatings possess excellent photocatalytic and self-cleaning properties and are expected to find wider practical applications in the field of photocatalysis.