Real-time acquisition of the dynamic information on the surface elemental composition of the first wall, especially in the divertor region, is of great significance for understanding the plasma-wall interaction (PWI) process and optimizing the experimental conditions of the tokamak. The effect of laser ablation angles (LAAs) needs to be further evaluated for the in-situ laser-induced breakdown spectroscopy (LIBS) system on the EAST upper divertor that is being upgraded. LIBS experiments with a coaxial collection configuration were carried out at 1 × 10−5 mbar in the laboratory and over a wide range of LAAs from 0° to 72°. Tungsten (W), molybdenum (Mo), and copper (Cu) which are important plasma-facing materials in EAST were ablated under variable LAAs. Their ablation depth and ablation mass were measured by confocal microscopy. The depth ablation rate show that the larger the LAAs, the higher the depth resolution of LIBS, which is helpful for the depth-profiling analysis of the wall surface. The number of photons at the characteristic spectral line radiated from the three elements at a certain solid angle were obtained by using the absolute calibration method. The variation trend of the photon numbers with the increase of LAAs is consistent with ablation mass but slower than the downward trend of laser power density. By analyzing the variation of the spot size, the spatial intensity distribution of the laser, and the ablation crater morphology caused by the LAAs, it is found that the lateral ablation of the laser is the possible reason for the difference. Moreover, the calibration coefficient of spectral intensity under variable LAAs is obtained, which provides a reference for in-situ LIBS measurement.
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