The distortion of structure of a simple, inverse 12 soft-sphere fluid undergoing plane Couette flow is studied by nonequilibrium molecular dynamics (NEMD) and equilibrium molecular dynamics (EMD) with a high-shear-rate version of the nonequilibrium (NE) potential obtained recently from the NE distribution function theory of Gan and Eu [Phys. Rev. A 45, 3670; 46, 6344 (1992)]. The theory suggests a NE potential under which the equilibrium structure of the fluid is that of a NE fluid, and also suggests a corresponding Ornstein-Zernike equation with its closure relations. As in the low-shear-rate case [Yu. V. Kalyuzhnyi, S. T. Cui, P. T. Cummings, and H. D. Cochran, Phys. Rev. E 60, 1716 (1999)] the agreement between EMD and the modified hypernetted chain version of the theory is good. Although the high-shear-rate version of the NE potential improves the agreement between NEMD and EMD results (in comparison with the low-shear-rate version), its predictions are still unsatisfactory. With the high-shear-rate NE potential, EMD gives qualitatively correct predictions only for the shift of the position of the first maximum of the NE distribution function. The corresponding changes in the magnitude of the first maximum predicted by EMD have an opposite direction in comparison with those predicted by NEMD. It is concluded that the NE potential used is not very successful, and more accurate models for the potential are needed.