We have designed a structure for a 2×2 silica-based optical waveguide switch that is based on a thermocapillarity effect. This switch can use the reflection walls on both sides of the slit, because the Goos–Hänchen shift effect was taken into account when the structure of the waveguides and the slit was designed. This switch can provide a cross/bar function through a single element, and the measured reflection losses in the reflection walls on both sides of the slit were consistent. The loss was comparable to the insertion loss of a Mach–Zender-interferometer-type thermo-optic switch.