The persistence of residual herbicides used in maize (Zea mays) silage crops was investigated in three field trials located in Waikato Taranaki and Canterbury Herbicides used included atrazine and acetochlor applied preemergence and mesotrione and nicosulfuron applied 612 weeks after planting Bioassay of soil samples collected about the time of silage harvest showed small but biologically toxic residues of only nicosulfuron and only at the Taranaki site A subsequent glasshouse study investigated whether the differences in persistence of nicosulfuron were due principally to soil characteristics (four soil types) or rainfall (amount and timing) Heavy rainfall (50 mm) in the first week or two after application or for several consecutive weeks was more effective in leaching the herbicide and reducing the residues than light (10 mm) or moderate (25 mm) rain applied at similar times Also residues of nicosulfuron disappeared faster in soils with low pH and high organic matter