This article presents a 13-b high-speed pipelined-successive-approximation-register (pipelined-SAR) analog-to-digital converter (ADC). By utilizing the comparator metastability, a tri-state SAR logic is introduced to achieve a fast approximation process. The tri-state SAR outputs three states by one comparator after each comparison cycle, and the effective-number-of-bits (ENOBs) can improve up to 1 b when the metastability boundary is set at ±1/4 LSB. In addition, an open-loop inverter-based residue amplifier (RA) is proposed with simple circuit implementation. The RA gain is well defined by <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$g_{m}$ </tex-math></inline-formula> ratio and is immune to process, voltage, and temperature (PVT) variations. Fabricated in 40-nm CMOS technology, the prototype ADC achieves a mean signal-to-noise plus distortion ratio (SNDR) of 59.8–62.8 dB, with 1- <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\sigma $ </tex-math></inline-formula> than 1.7 dB, at 600–625 MS/s over −40° to 125° temperature range and 1.1–1.2 V power supply range, a 67 dB dynamic range (DR), and a 62.4 dB SNDR for a Nyquist input while sampling at 625 MS/s. The overall power consumption is 7.05 mW.