This study aims to evaluate the durability of using coal gangue as a substitute for natural aggregates in shotcrete linings for coal mine roadways, addressing environmental concerns from resource consumption and coal gangue accumulation. The support structures of coal mine roadways endure dynamic loads and sulfate erosion during service, making it crucial to assess the long-term stability of these materials in such complex environments. Accordingly, coal gangue shotcrete (CGSC) specimens were immersed in Na2SO4 solution, and a Split Hopkinson Pressure Bar (SHPB) system was used to examine the impact of erosion on their dynamic mechanical properties. The results indicate that in the early stages of erosion (0–30 days), the dynamic compressive strength (DCS) of CGSC increased significantly. Under a condition of 0.06MPa, the DCS rose from 31.8MPa to 45.2MPa, representing a 42% increase. Similarly, under 0.10MPa, it increased from 93.9MPa to 99.0MPa, a 5.4% improvement. However, in the mid-to-late stages of erosion (30–120 days), the DCS gradually declined. Under 0.06MPa, it dropped to 28MPa (a decrease of 38%), and under 0.10MPa, it fell to 62.1MPa (a decrease of 37.3%). Microscopic structural characterizations conducted using NMR, XRD, and SEM revealed that the expansion and rupture of erosion products led to the propagation of microcracks, which contributed to the performance degradation. Additionally, the study analyzed the relationship between pore structure changes, fractal dimensions (D1 and D2), and the energy absorption coefficient (λ). A dynamic strength model was developed, quantitatively linking the duration of sulfate erosion to the energy dissipation rate. This research provides theoretical support for optimizing the sulfate erosion resistance of CGSC and enhancing the durability and safety of mining tunnel structures.
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