Salt Water Research Articles

Productivity, energy, and exergy analyses of a water desalination system-based vortex tubes with different configurations: An experimental implementation

The present implementation explores the use of vortex tubes (VTs) as an alternative thermal technology for water desalination systems (WDSs). VTs are utilized to provide hot air for evaporating salt water in the evaporator, while simultaneously supplying cold air to condense the water vapor in the condenser. The study investigates the influence of a number of operating parameters, including inlet water temperature (Ti,w), cold mass ratio (CR), and vacuum pressure (pvac) on the performance of WDS-based VTs through experimental analysis. Different configurations of VTs are tested for WDS applications, including WDS-based single vortex tube (VT), WDS-based two series vortex tubes (2SVTs), and WDS-based two parallel vortex tubes (2PVTs). Performance metrics such as the evaporation heat (QEvap), desalinated water production (DWP), gain output ratio (GOR), and exergy performance are evaluated for each configuration. Results show that the WDS-based 2SVTs exhibits the highest QEvap; while the WDS-based 2PVTs demonstrates the lowest value. Correlations are proposed to predict DWP for different configurations of WDS based on pvac, Ti,w, and CR with a maximum deviation of ±12.2 %. Furthermore, the WDS-based 2SVTs achieves the best GOR of 2.5 at an inlet water temperature of 80 °C, representing a significant improvement compared to the WDS-based VT and 2PVTs. The exergy efficiency (ηex) increases with higher CR, and the WDS-based 2SVTs ensures the best exergy performance, and its maximum overall ηex equals 78.2 %.

A hydrophobic phase-locking strategy enabling ultrarobust and water-stable self-healing elastomers for underwater ionotronics

Water-resistant conductive elastomers can endow soft electronic devices with reliable sensing performance for motion monitoring and real-time communication in aquatic environments. Nevertheless, traditional conductive elastomers typically suffer from notable shortcomings in terms of inferior mechanical robustness, weak stability, and self-healing capabilities in wet conditions and even underwater, significantly restricting their practical utility. Drawing inspiration from the optimization of multiphase structure, an ultrarobust underwater healable elastomer is constructed by incorporating biomass-derived long-chain segments with a large number of amide/benzene groups into a hierarchical H-bonding supramolecular network. The locking of multiple dynamic bonds by uniformly distributed hard-phase domains with dense hydrophobic barriers leads to the resultant elastomer gaining remarkably enhanced mechanical properties (stretchability, 2217.2 %; toughness, 272.97 MJ m−3) and outstanding capability to autonomously self-heal even underwater with a high ultimate strength over 10 MPa (aqueous healing for 24 h). Notably, it boasts exceptional healing stability to all types of harsh aqueous environments, such as strong acid/alkali, high temperature, and salty water. The application of the developed elastomer is also demonstrated by creating a multifunctional wearable sensor that can accurately detect and transmit information for a variety of human motions in both atmospheric and aquatic environments. The viable strategy reported herein for designing advanced multifunctional healable materials can be applicable for all-environment flexible iontronic devices.

Impacts of land use changes on the spatiotemporal evolution of groundwater quality in the Yinchuan area, China, based on long-term monitoring data

Agricultural activities and rapid urbanization have significantly impacted groundwater quality, especially in semi-arid and arid regions. This study comprehensively evaluated the quality of phreatic and confined groundwater in the Yinchuan area, China, using long-term monitoring data from 1991 to 2018. Geospatial analysis model was employed to explore the spatiotemporal evolution of groundwater hydrochemistry. The effects of land use changes on groundwater quality were assessed using correlation analysis and a multiple linear regression model (MLR). The findings indicate significant temporal variations in groundwater quality, with phreatic water consistently exhibiting high salinity and hardness. The groundwater quality indices for phreatic water were frequently more polluted than confined water. From 1991 to 2018, the hydrochemical composition of phreatic water evolved from HCO3-Mg and HCO3•SO4-Mg to more complex forms such as HCO3•SO4•Cl-Mg and HCO3•Cl-Mg. In contrast, confined water predominantly maintained its HCO3-Mg type and HCO3•Cl-Na (Na•Mg) type water. Urban land had rapidly expanded in the past three decades, increasing by 318.75% compared to 1991. The water body and urban area diminished the quality of phreatic water. High salt water in increase of TDS, Cl–, SO42–, Mn, TH, NO3–, F–, and Fe into phreatic water. NO3–, NH4+, and F− in phreatic water could be impacted by human and industrial activity in urban areas. This study provides valuable insights for local decision-makers to effectively manage groundwater resources and solve issues of groundwater scarcity and water quality problems in arid and semi-arid locations.

Preparation and characterization of MgO-based composites: Analysis of moisture, corrosion, and fungal resistance, and mechanical properties

Magnesium oxide (MgO) composite boards are valued in the construction industry because of their outstanding fire resistance, however, the long-term viability of MgO boards is affected by atmospheric humidity. This research work aims to investigate the environmental impacts and mechanical properties of four types of MgO boards from four different manufacturers under varying relative humidity (RH) levels. Three of them contained a high amount of chlorine known as magnesium oxychloride (MOC) boards, and one of them contained a high amount of sulfur known as magnesium oxysulfate (MOS) boards from their elemental composition observed by EDX. Microscopic images showed a rougher and porous surface for MOC boards, whereas smoother surface for MOS boards. MOS boards exhibited 37 % (average) lower moisture absorbency than MOC boards at 95 % RH and remained dry, while the MOC boards leaked salty water drops under the same condition. As a result, the MOS boards exhibited much better corrosion and fungal protection than the MOC boards. Mechanical properties, for example, tensile strength decreased by 45 % in MOC boards and 31 % in MOS boards at 95 % RH compared to 50 % RH. Therefore, the sourced MOS composite boards outperformed the contemporary MOC boards in all parameters.

Combining magnetized water with biodegradable film mulching reshapes soil water-salt distribution and affects processing tomatoes' yield in the arid drip-irrigated field of Northwest China

In arid areas, biodegradable film has recently had the potential to replace polyethylene (PE) film to address plastic pollution. However, the positive effect of biodegradable film on soil moisture and salt control is weaker than that of PE film. Magnetized irrigation water technology is expected to compensate for this limitation. This study comprised a field experiment in 20212023 to study how two types of biodegradable film (M1, black; M2, transparent) and six magnetization intensity on irrigation water (T0, 0 Gs; T1, 1000 Gs; T2, 2000 Gs; T3, 3000 Gs; T4, 4000 Gs; T5, 5000 Gs) affect the degradation rate of biodegradable film, soil watersalt distribution, growth, and quality of processing tomatoes. The traditional PE film mulching and non-magnetized irrigation were used as the control group (MPET0). The results demonstrated that magnetized water irrigation slowed down the degradation rate of biodegradable film. In addition, the magnetized irrigation water can redistributed the soil water-salt patterns under the biodegradable film, improving the soil water content and salt leaching efficiency, with better results in M1 than in M2. Moreover, magnetized water irrigation promoted the growth of tomato leaf area under the biodegradable film, enhancing photochemical efficiency and potential activity of PSII, thereby improving fruit yield, quality, and water use efficiency of tomato. Principal component analysis showed that the comprehensive score of M1T3 treatment was the highest throughout the three years. Furthermore, M1T3 treatment has the highest processing tomato economic benefits during 2021–2023 (24634986 CNY hm2 more than MPET0). Therefore, the use of 3000 Gs magnetized irrigation water combined with black biodegradable film is conducive to improving soil water and salt conditions, reducing residual film pollution, and improving the yield and quality of processing tomatoes, thus ensuring the sustainable development of oasis agriculture.

Produced Water from the Oil and Gas Industry as a Resource—South Kuwait as a Case Study

Produced Water (PW) represents the largest waste stream in the oil and gas industry. As a water resource and as a source of valuable minerals such as alkali salts, it is has been highly under-valued, especially in hyper-arid regions. The beneficial use of PW ranges from water reinjection to elevated oil recovery from reservoirs with almost instantaneous returns, to the extraction of minerals from PW, which involves a number of different processes and setups. The economic value of PW-derived end products offers alternative revenue sources, with market fluctuations and conditions different from those of the hydrocarbon market. The end products of water and industrial salt support local industries such as agriculture, reflecting positively on the gross domestic product (GDP). Furthermore, resource extraction from PW of the oil and gas industry helps countries augment their circular economy. In this regard, the economic feasibility of three scenarios—the use of PW for oil recovery, the use of PW as an alternate source of water and industrial salt, and a hybrid process of both—is explored. The results show that there is great potential for water reuse in Enhanced Oil Recovery operations, as well as in the reduction in freshwater consumption for oil- and gas-extraction operations in the state of Kuwait by up to 4.8 percent when PW generated by SK oilfields is considered, and by 42 percent if PW from all oilfields in Kuwait is reused in the same manner.

Field evaluation and characterization of a novel biostimulant for broccoli (Brassica oleracea var. italica) cultivation under drought and salt stress which increases antioxidant, glucosinolate and phytohormone content

Anthropogenic global warming is affecting crop yield and thus compromising food security. Drought and salinization of the irrigation water or soil are increasingly frequent in most arable land, specifically in arid and semiarid areas such as the Mediterranean basin. Many crops have been displaced or their yield has plummeted in recent years, causing food shortages and price increases. In a context of global population growth and reduction in the availability of natural resources used in agriculture, finding novel tools that help farmers to maintain yield in an increasingly arid and saline scenario is of pivotal importance. This is particularly important in organic agriculture, where the number of available tools is very limited. Biostimulants are substances or microorganisms of natural origin whose function is to stimulate plant processes related to nutrient absorption, nutrient use efficiency, tolerance to abiotic stress or the quality of the agricultural products obtained. In the present work, we have evaluated, in field, the agronomic effectiveness of a novel biostimulant formulation in a cruciferous crop of great interest in the Mediterranean basin (broccoli) under control conditions, water and salt stress. Our research has shown that our product had a positive effect on broccoli production and in delaying flowering time. We have also found that the application of our biostimulant increased enzymatic and non-enzymatic antioxidant defense under drought conditions. Similarly, when exposed to salinity, the biostimulant increased the concentration of different phytohormones and glucosinolates. Taken together, our biostimulant increases the tolerance of broccoli to salt stress and water limitation by increasing the antioxidant response, the level of glucosinolates and eliciting the hormonal response.

Experimental study on characterization of resilient modulus and prediction model of saline aeolian sand

The dynamic resilience characteristics of aeolian sand subgrade are influenced by salt content and water content, exhibiting significant stress dependence and anisotropy. The resilient modulus(MR) of aeolian sand represents the stress-strain nonlinearity under cyclic loading, serving as an important parameter for the design of aeolian sand subgrade in desert areas. In order to investigate the variation of MR of aeolian sand subgrade with salt content and water content under traffic loading, as well as the MR characteristics under these conditions, three types of aeolian sand samples with varying water content and four sulphate contents were prepared. The variation of MR of aeolian sand under different confining pressures and deviator stress levels, as well as the influences of water content and salt content, was studied through indoor dynamic triaxial testing. Based on the pattern of the fitting parameters of the benchmark model, a prediction model suitable for the MR of aeolian sand was constructed. The results indicate a rise in aeolian sand's MR with increasing deviator stress and confining pressure, with confining pressure having a more significant impact than deviator stress. With the increase in water content, the MR of aeolian sand decreases nonlinearly, and with the increase in salt content, it exhibits a wave-shaped trend of "increasing-decreasing-increasing," which is related to the dissolution state of sodium sulfate in the soil. Based on the experimental results, a prediction model of the MR of aeolian sand was established, derived from the benchmark model, which can reflect the influence of salt content and water content on the MR, introducing them as variables within the model.

COPPER AND MICROPLASTIC EXPOSURE AFFECTS THE GILL GENE EXPRESSION OF COMMON CARP DURING SALTWATER CHALLENGE

The aim of the present study was to assess if pre-exposure to water copper and/or polyvinyl chloride microparticles affects the transcriptional responses of common carp, Cyprinus carpio, to saltwater exposure. Fish were exposed to 0.25 mg/L copper alone (Cu) or in the presence of 0.5 mg/L polyvinyl chloride microparticles (Cu-MPVC) for 14 days, followed by 72 hours of salt water exposure (0 to 13 ppt NaCl). The copper content in the gills and the expression of heat shock protein (hsp70) and cytochrome P450 family 1 (cyp1a) transcripts were examined. The results showed that gill copper levels increased significantly (P = 0.008) in the Cu and Cu-MPVC treatments after 14 days of exposure, compared to the control fish; the Cu and Cu-MPVC treatments had similar gill copper levels. After 14 days of exposure, branchial expression of the hsp70 and cyp1a genes was significantly up-regulated in the Cu and Cu-MPVC treatments. Exposure to salt water led to a significant down-regulation of the gene transcripts in all treatments after 24 h of exposure. At this point, the Cu and Cu-MPVC treatments showed transcripts similar to those of the control fish prior to saltwater exposure. The fish treated with Cu-MPVC showed significantly higher hsp70 expression 72 h after saltwater exposure than the other treatments. At this time point, the control and Cu fish had significantly lower cyp1a expression than before saltwater exposure. In conclusion, the present data suggest that copper exposure induces stress in the fish gills, and the presence of MPCV in the water hampers normal transcriptomic responses of the fish gills to saltwater exposure.

Real-time integrated water availability – Salt intrusion modelling and management during droughts

Climate change and population increase are major challenges when guaranteeing a sustainable water supply in densely populated river basins worldwide, where different water users such as industry, drinking water production and agriculture typically come into conflict. During dry periods, real time monitoring and short term forecasting of the water availability are crucial to prepare and take appropriate action. Integrated water quantity and water quality models of complex surface water systems are indispensable to achieve this. However, existing model techniques often focus on a single aspect of the water system, are computationally too demanding and are hard to integrate with other sub models. This paper proposes a framework for developing efficient, integrated water quantity/quality models in support of real-time management and forecasting of complex surface water systems. Its three main components are: a low-flow prediction for the supplying river(s) during dry periods, a conceptual water quantity-quality model with semi-automated retrieval of necessary boundary conditions and input data, and classification models to predict the water quality state of the considered system during forecasts or scenario analyses. The novelty of the methodology lies in the use of parsimonious, computationally efficient sub-models that still allow to consider numerous operational rules, competing water users and water supply and quality constraints. The framework was tested in the context of water availability and salt intrusion management during droughts in the Campine Canals in the Scheldt-Meuse-Rhine delta, considering boundary conditions of shipping traffic, pumping at locks, hydropower stations, level regulation, and water abstractions for drinking water supply, industry, agriculture and nature reserves. Despite the complexity of the considered system, the model is able to describe the state of the water system in terms of water levels, discharges and salt intrusion impacts on water production with an acceptable accuracy. The research shows that the Campine Canal network is susceptible to water scarcity due to the increased risk of low flows in summer as a consequence of climate change. Local decision makers should adopt both effective adaptation strategies as well as real-time forecasts in acute drought situations to increase the region’s defence and resiliency against water shortages.

Molten salt synthesis of Ti-Si-C coating on SiC particles and hot pressing of the prepared powders

SiC particles coated with Ti-Si-C layer were prepared by the molten salt synthesis method using NaCl-KCl eutectic mixture as the reaction medium and Ti metal powder as the Ti source. The synthesis was conducted under static argon atmosphere at 900 °C for 1–3 h. The post-synthesis treatment included dissolution of salts in hot water, followed by ultrasonic dispersion and sedimentation procedures. The thickness of the Ti-Si-C layer varied from 0.1 to 0.9 μm as the ratio of Ti to SiC components in the starting mixture changed from 0.05 to 0.4. The layer contained mainly nanocrystalline Ti5Si3, minor phases were TiC and Ti3SiC2. The as-prepared powders were hot pressed under 30 MPa at 1700 °C. The densification behavior of the samples during hot pressing as well as changes both in phase composition and in microstructure were studied. The flexural strength of the hot-pressed samples increased with an increase in the Ti:SiC molar ratio, giving the value as high as 213 ± 20 MPa for the sample with Ti/SiC = 0.4.

Assessment of microplastics in highland rock salts of Northern Borneo

Mountain salts produced from the highland region in NE Sarawak have a market value and also provide basic income to the communities. During the salt-making process, microplastics (MPs) may enter into commercial table salts from various sources, which has not been explored yet. Hence, the current research investigates the presence of MPs in the rock salts produced from the highland saline water in two different locations (L1 and L2) in NE Sarawak. Among the brine water and rock salt samples analysed, the highest concentrations of MPs were detected from the salt samples. It has been revealed that both the water and salt samples have the highest concentration of MPs occurring within the size range of 1–1000 μm. Transparent MPs are the most common colour observed in both salt and water samples, followed by white, blue, red, and black. The most prevalent shapes of MPs are fibers, which account for almost 47% in water samples and 87% in salt samples. Based on the ATR-FTIR study, polyethylene (PE) is the most prevalent polymer observed in salt samples, followed by polypropylene (PP), polystyrene (PS), and polyethylene terephthalate (PET). In water samples, PP is the most dominating polymer, followed by PE and PS. Through SEM microphotographs, fiber-type MPs have smooth surfaces, fragment-type MPs have rough edges, and sheet-type MPs have layered surfaces. EDX analysis revealed that carbon (C) and oxygen (O) are the most abundant elements, followed by aluminium (Al) and sodium (Na) in MPs. Based on the results, it is inferred that the MPs in the rock salts are mainly sourced from the different stages of salt-making production. This preliminary study shed light on the presence and characteristics of MPs in rock salts in this region. The research outcomes could support sustainable management plans to improve the salt quality and enhance the market value.

Augmenting interfacial solar steam generation using 3D-printed hollow honeycomb structured pattern filled with rGO decorated natural fibres

In the present study, a hollow honeycomb structured (HHS) pattern is fabricated using fusion deposition modelling and filled with different natural fibres namely sugarcane (SC) and cotton sponge (CS). It is then called HHS-SC and HHS-CS interfacial solar evaporators. In addition, reduced graphene oxide (rGO) nanomaterial is coated on the top evaporative surface of the developed evaporators to investigate the performance of interfacial solar steam generation (ISSG). During experimentation, HHS-CS/rGO evaporator exhibits better performance than HHS-SC/rGO evaporator. At indoor conditions, mass loss of water (MW), evaporation flux (EF) and evaporation efficiency (EE) of the HHS-CS/rGO evaporator are 2.0 g, 3.493 kg/m2h and 84.04 % respectively. Consequently, the MW, EF and EE are 6.2 g, 1.35 kg/m2h and 61.29 % respectively at outdoor conditions. Results show that (i) the reduction in the size of porosity and improved capillary action of CS (ii) the super hydrophilicity nature of CS increases the water transportation (iii) the poor thermal conductivity of CS (iv) the higher thermal conductivity of rGO aids in trapping the sunlight. The stability and repeatability of the HHS-CS/rGO evaporator are investigated and found to be excellent for 8 repetitive cycles. Additionally, the prepared interfacial solar evaporator results better performance in dye molecule separation and salt water purification and hence, this can be recommended for commercial applications.

High-resolution UK’37 sea surface temperature reconstruction in the southwestern Atlantic Ocean during the Holocene

Modern sea surface temperatures (SST) were assessed using the alkenone calibration index (UK′37; SST-UK′37) values from twenty-one core-top sediment samples collected along the Southwestern Atlantic Ocean and validated by comparison with satellite-derived SSTs. The SST-UK′37 values revealed an annual signal between 28 and 30°S and a winter signal (83% of the region samples) between 30 and 34° S, with deviations falling within the UK′37 calibration error range. The paleotemperature (SST-UK′37) reconstruction through the Holocene was performed using two high-resolution marine sediment cores from 33 to 34°S latitude band. Millennial-scale variations dominate most of the SST-UK′37 results with changes up to ∼6 °C. Considering the modern ocean circulation dynamics, the SST-UK’37 in our records likely stems from the combined influence of the Subtropical Shelf Front (STSF) position and the interaction between the warm, salty, and nutrient-poor Subtropical Shelf Water (STSW) and the cold, fresh, and nutrient-rich Subantarctic Shelf Water (SASW). Our SST-UK’37 results also suggest that the northernmost position limit of the STSF reached around 33°S during the mid-to-late Holocene, while after ∼5500 cal yr BP the Plata Plume Water became the dominant influence on the regional SST-UK’37 signal. Spectral analyses revealed statistically significant oscillations of ∼8600 and ∼ 2250 years in record MDBT 557, and ∼ 5300 and ∼ 2600 years in record MDBT 561 which suggests the influence of Southern Westerly Winds (SWW) on the SST-UK’37, and therefore, on the STSF dynamic through the Holocene.

Effectiveness of different mixed physical barriers in controlling seawater intrusion in homogeneous and layered coastal aquifers

The intrusion of salt water into coastal regions threatens water resources, especially in arid and semi-arid regions. It damages large quantities of fresh water in these regions, and the productivity of the freshwater abstraction wells declines. Management of seawater intrusion (SWI) is therefore needed to improve fresh groundwater in these regions. This study investigated 12 different configurations of mixed physical subsurface barriers (MPBs) to control SWI in homogeneous and heterogeneous layered aquifers. The effectiveness of different MPB locations and configurations was tested, including (i) a barrier wall on the landward side and the subsurface dams on the seaward side, (ii) a barrier wall on the seaward side and a subsurface dam on the landward side, and (iii) the barrier wall was placed above the subsurface dam, both with different permeabilities. All simulations were based on the SEAWAT code. The numerical model was validated against experimental data. The results showed that a permeable cut-off wall above an impermeable subterranean dam (case MPB-3) with different permeabilities resulted in a reduction of the seawater wedge of 91% and 92% for homogeneous and heterogeneous layered aquifers, respectively. When the barrier wall was placed on the land side and the dam on the seaside (case MPB-1), the reduction of the seawater wedge reached 83% and 85% for homogeneous and heterogeneous layered aquifers, respectively. In contrast, when the dam was placed on the land side and the wall on the seaside (case MPB-2), the saltwater wedge was reduced by 73% for both homogeneous and heterogeneous layered aquifers. In addition, a case study was conducted on the Biscayne aquifer, southeast Florida, USA, with homogeneous conditions. Seawater intrusion was reduced by 36% and 44% in case MPB-1, 41% and 38% in case MPB-2, and 43% and 46% in case MPB-3. These seawater intrusion control methods offer numerous benefits, including improving freshwater storage, effectively controlling salinity during droughts, and potentially improving contaminant management.

New green hydrogen recipe: aluminum, caffeine, and salt water

New green hydrogen recipe: aluminum, caffeine, and salt water

Optimizing dual-layer composite membranes with functionalized CNT loadings using response surface methodology

ABSTRACT In this study, we optimized double-layer composite membranes comprising polyethersulfone (PES) and polyamide (PA) using response surface methodology (RSM). We assessed the impact of PES, piperazine (PIP), and trimesoyl chloride (TMC) concentrations, and interfacial polymerization (IP) reaction time on nanofiltration (NF) membrane performance, aiming to enhance pure water flux (PWF) and salt rejection. Optimal parameters for maximum PWF and salt rejection were determined: PES concentration at 14.0 wt%, PIP concentration at 1.5 w/v%, TMC concentration at 0.2 w/v%, and reaction time at 45 s. In addition, we improved membrane performance by incorporating functionalized multi-walled carbon nanotubes (f-MWCNTs) into the PES ultrafiltration substrate, enhancing hydrophilicity and porosity. The resulting PA NF membrane developed on a substrate containing 0.15 wt% f-MWCNT (TFNC) exhibited a PWF of 11.84 LMH/bar, surpassing the PWF of the same NF membrane on an unloaded substrate (TFC) by approximately 20%, while maintaining nearly identical salt rejection levels. Salt rejection followed the order: Na2SO4 > MgSO4 > NaCl, suggesting Donnan-exclusion mechanisms primarily governed the separation process due to repulsion forces between the negatively charged membrane surface and anions.

Self-Assembled Hydrazide-Based Nanochannels: Efficient Water Translocation and Salt Rejection.

Nature has ingeniously developed specialized water transporters that effectively reject ions, including protons, while transporting water across membranes. These natural water channels, known as aquaporins (AQPs), have inspired the creation of Artificial Water Channels (AWCs). However, replicating superfast water transport with synthetic molecular structures that exclude salts and protons is a challenging task. This endeavor demands the coexistence of a suitable water-binding site and a selective filter for precise water transportation. Here, we present small-molecule hydrazides 1b-1d that self-assemble into a rosette-type nanochannel assembly through intermolecular hydrogen bonding and π-π stacking interactions, and selectively transport water molecules across lipid bilayer membranes. The experimental analysis demonstrates notable permeability rates for the 1c derivative, enabling approximately 3.18 × 108 water molecules to traverse the channel per second. This permeability rate is about one order of magnitude lower than that of AQPs. Of particular significance, the 1c ensures exclusive passage of water molecules while effectively blocking salts and protons. MD simulation studies confirmed the stability and water transport properties of the water channel assembly inside the bilayer membranes at ambient conditions.

Irrigation and food security in the context of water shortage: legal issues and perspectives

The article examines the legal problems and prospects of ensuring the irrigation of agricultural land in conditions of a lack of traditional water resources. Modern hydromelioration reform in the form in which it is currently implemented is not a panacea. It mostly solves property and administrative-functional issues, but leaves a call for attention to environmental and natural resource problems. In view of the tendency to decrease the quantity and quality of water in the country, the question arises about the prospects of irrigation under such conditions. In recent decades, there has been a constant search for innovative solutions of not only technological, but also legal nature in the world for solving the complex problems of distributing limited resources and providing agriculture with vital moisture for maintaining food security. The objective problem of the lack of water suitable for irrigation against the background of the rapid growth of such needs is getting worse every year and in the long run can endanger the food security of the country. World experience demonstrates the approbation of various approaches to solving the problem of sufficient irrigation. According to the main way of achieving the goal, these approaches are presented by us in the form of three groups: 1) use of alternative sources of water resources (use of underground water, treated wastewater, desalinated salt water); 2) application of alternative irrigation technologies (modernization of irrigation systems; use of micro-irrigation); 3) use of alternative crops (voluntary and mandatory transition). Having analyzed the foreign and domestic experience of the legal regulation of selected methods of solving the problem of water shortage for irrigation, it is possible to trace some general trends: a) self-removal of the state from the implementation of large-scale irrigation projects, the need for which is generated by global environmental challenges; b) slow ecological transformation of legislation regulating agricultural irrigation; c) the predominance of separate legal norms and separate legal mechanisms aimed at regulating alternative irrigation, and the lack of comprehensive regulatory and legal support for the reconstruction of the irrigation system taking into account objective environmental problems.

Multifunctional Ti3C2Tx-based epoxy composite coating towards intelligent response and corrosion/wear resistance

Questions remain about the unreasonable collocation of Ti3C2Tx and nanocontainers resulting in the performance degradation of multi-function Ti3C2Tx-based epoxy composite coating. Here, mesoporous SiO2 nanocontainers (SNT) containing both potassium thiocyanate and hexadecyl trimethyl ammonium bromide (CTAB) were loaded on MXene-based platform (SNT-on-MP) to achieve a novel epoxy coating (SNT-on-MP@EP) with the integrated functions of self-warning, self-healing, anti-corrosion and anti-wear. In the damaged area, the thiocyanate groups combined with Fe3+ ions to form a blood-red color display, and the formed coordination compound and CTAB as corrosion inhibitors were deposited on the metal substrate, thus showing intelligent response function. Besides, because of passive and active synergistic protection functions, the lowest-frequency impedance value of SNT-on-MP@EP maintained 5.74 × 107 Ω·cm2 after 4 weeks of exposure in salt water environment, which was increased by two orders of magnitude compared with pure epoxy coating. Under the reciprocating sliding friction, the wear rate of SNT-on-MP@EP reached 5.32 × 10−5 mm3/N·m, and was reduced by 58.29 %, owing to the formation of lubricant film at the friction interface and the enhancement of the deformation resistance of the coating. The reasonable collocation of SNT and Ti3C2Tx-based platform eliminated the problem of weak interaction between traditional inorganic nanocontainer and water-based epoxy coating, thus giving full play to the advantages of both.