Due to limited on-chip caching, data-driven applications with large memory footprint encounter frequent cache misses. Such applications suffer from recurring miss penalty when they re-reference recently evicted cache blocks. To meet the worst-case performance requirements, Network-on-Chip (NoC) routers are provisioned with input port buffers. However, recent studies reveal that these buffers remain underutilised except during network congestion. Trace buffers are Design-for-Debug (DfD) hardware employed in NoC routers for post-silicon debug and validation. Nevertheless, they become non-functional once a design goes into production and remain in the routers left unused. In this article, we exploit the underutilised NoC router buffers and the unused trace buffers to store recently evicted cache blocks. While these blocks are stored in the buffers, future re-reference to these blocks can be replied from the NoC router. Such an opportunistic caching of evicted blocks in NoC routers significantly reduce the miss penalty. Experimental analysis shows that the proposed architectures can achieve up to 21 percent (16 percent on average) reduction in miss penalty and 19 percent (14 percent on average) improvement in overall system performance. While we have a negligible area and leakage power overhead of 2.58 and 3.94 percent, respectively, dynamic power reduces by 6.12 percent due to the improvement in performance.