In this paper, the resistance to chloride ion permeability of multiple interfaces in alkali-activated slag/fly ash (GGBS/FA) based full recycled concrete was investigated using the immersion method. In order to objectively and accurately reflect the microhardness and width of the interface transition zone (ITZ), box plots were used to process the measured point data. The results indicated that the microhardness of the interface was significantly lower than that of the matrix. The microhardness of the old aggregate interface (ITZOA-OM), the new aggregate interface (ITZOA-NM) and the new mortar interface (ITZOM-NM) all decreased to varying degrees with the extension of the immersion ages, but remained higher than that of the uneroded specimens. Chloride ions penetrated into ITZOA-OM and reacted with a large amount of enriched Ca (OH)2 to form an expansive composite salt (CaCl2.Ca(OH)2.H2O), which improved the microstructure of the ITZ, increased the microhardness and decreased the width of the ITZ. The dense structure of ITZOA-NM and ITZOM-NM inhibited the migration of chloride ions to a certain extent. leading to minimal changes in the width and microhardness of the ITZ. The micro mechanisms of chloride ion penetration resistance at the interfaces of alkali-activated GGBS/FA-based recycled concrete were investigated using BSE and EDS. More reaction products were generated at the interfaces after chloride ion erosion, and the newly generated substances continuously filled the microcracks, resulting in a more uniform bond at the interfaces. This contributed to the improvement of the microstructure and the resistance to chloride ion penetration of alkali-activated GGBS/FA based recycled concrete.
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