Electrical Distribution Systems (EDS) are extensively penetrated with Distributed Energy Resources (DERs) to cater the energy demands with the general perception that it enhances the system’s resilience. However, integration of DERs may adversely affect the grid operation and affect the system resilience due to various factors like their intermittent availability, dynamics of weather conditions, non-linearity, complexity, number of malicious threats, and improved reliability requirements of consumers. This paper proposes a methodology to evaluate the planning and operational resilience of power distribution systems under extreme events and determines the withstand capability of the electrical network. The proposed framework is developed by effectively employing the complex network theory. Correlated networks for undesirable configurations are developed from the time-series data of active power monitored at nodes of the electrical network. For these correlated networks, compute the network parameters such as clustering coefficient, assortative coefficient, average degree, and power law exponent for the anticipation; and percolation threshold for the determination of the network’s withstand capability under extreme conditions. The proposed methodology is also suitable for identifying the hosting capacity of solar panels in the system while maintaining resilience under different unfavorable conditions and identifying the most critical nodes of the system that could drive the system into non-resilience. This framework is demonstrated on IEEE 123 node test feeder by generating active power time-series data for a variety of electrical conditions using the simulation software, GridLAB-D. The percolation threshold resulted as an effective metric for the determination of the planning and operational resilience of the power distribution system.