The introduction of renewable energy generation sources onto the electrical grid is critically dependent on the development of reliable, inexpensive energy storage technology. Redox flow batteries (RFBs) may offer a solution, but many issues remain. For example, aqueous systems are only capable of relatively low cell voltages owing to the limited accessible potential window of water. While other electrochemically useful solvents could provide a larger window, their cost and durability have been problematic. Moreover, the need for an ion-exchange membrane to prevent crossover further increases cost and adds significant cell resistance, especially in nonaqueous systems.We have previously reported the use of linked electron donor/acceptor compounds D-L-A (where L represents a simple alkyl or aryl linker) to allow the replacement of the expensive ion-exchange membrane with a simple porous separator. Such systems have at least three accessible stable redox states: the “parent” D-L-A state, an oxidized form D+-L-A (catholyte), and a reduced form D-L-A- (anolyte).Numerous systems of this type have now been prepared and characterized, yielding nominal cell potentials over 2 V, with promising stability. Several of these systems have the capability of undergoing a net 2e- oxidation as well as a net 2e- reduction, thus providing increased energy density. One such compound is shown below.The electrochemical properties of several representative linked electron donor/acceptor materials will be described, including progress toward the development of a 4e- system having 9 (nine!) accessible stable redox states. Preliminary data from a prototype RFB device employing such compounds as active materials will also be presented. Figure 1
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