• Laser parameters optimized for laser beam pulse energy, and laser beam quality. • Lean-burn limits, flame kernel evolution, P-T Curve, and SoC determined for HCNG. • Flame kernel displacements were the maximum for λ = 1.1 for all HCNG mixtures. • Flame kernel displacements and combustible limits increased with H 2 enrichment. • Two-stage combustion increased with lowering λ and H 2 enrichment of CNG. • H 2 enrichment of CNG accelerated flame evolution from a 2D to a 3D phenomenon. Laser ignition of hydrogen-enriched compressed natural gas (HCNG) enables lean-burn combustion, a key technology for future emissions norms compliance for internal combustion (IC) engines. HCNG overcomes the limitations of low volumetric energy density and lowers the flame speed of CNG fueled spark ignition (SI) engine-powered vehicles. In this study, laser beam profile and beam quality (M 2 ) of a Q-switched Nd: YAG laser at fundamental wavelength of 1064 nm, having 6–9 ns pulse duration, were characterized. During the Constant volume combustion chamber (CVCC) experiments, relative air-fuel ratio (λ) of different HCNG blends were varied to identify the lean-burn limits, and observe flame kernel evolution, pressure–time history, and detect the start of combustion (SoC). At 10 bar initial chamber filling pressure, lean flammability limit increased due to hydrogen (H 2 ) enrichment of CNG. It was found to be λ = 1.6, 1.8, 1.9, 2.0, and 2.1 for CNG, 10HCNG (10% v/v hydrogen and balance CNG), 20HCNG, 30HCNG, and 40HCNG respectively. Flame kernel displacement (Early stages of flame initiation and its development in µs time-scale) was the highest for λ = 1.1 for all HCNG mixtures, irrespective of the test fuel composition. Knocking or two-stage combustion increased with lowering λ at 10 bar initial chamber filling pressure. SoC advanced and combustion duration (CD) decreased with increasing H 2 enrichment of CNG. Increased H 2 enrichment of CNG accelerated the flame kernel evolution and made it a predominantly a 3D combustion phenomenon (volumetric combustion). Lower λ and higher H 2 enriched CNG mixtures were effective in reducing the CD.
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