China’s building energy consumption is growing and the energy consumption of the whole process of buildings accounts for more than 46.5% of the country’s total energy consumption, of which the proportion of energy consumption used for heating, ventilation and air conditioning is as high as 50%. Solar energy has the greatest potential to achieve energy conservation in buildings. Buildings are the best carrier for solar energy utilization because of the advantages of local collection and local application. The combination of solar energy and buildings can meet a variety of energy and health needs in buildings, among which solar photovoltaic and CSP building integration technology is an important way to reduce building energy consumption and improve indoor air quality. This article presents a PV/T-based thermal storage wall system that efficiently utilizes solar energy. It outlines the PV/T technology’s fundamental principles and provides a detailed description of the system’s construction and operation, highlighting critical components like the solid thermal storage medium and heat transfer via a heat pump. The analysis indicates improved energy utilization and favorable economic feasibility. This technology offers a practical solution for the construction industry, promoting sustainable energy practices and environmental conservation.