As the proportion of recycled aluminum increased, the production of secondary aluminum dross (SAD) increased dramatically, putting enormous pressure on the enterprises and environment. The utilization rate of SAD was less than 30 % due to problems such as high discharge of acidic/alkaline wastewater or restrictions on the salt content of raw materials. In a previous study, authors achieved self-driven hydrolysis of SAD by water leaching. However, the removal of Na and K was incomplete, which was also found in alkaline leaching processes and was more serious. To further identify the causes, the transformation behaviors of Al, Si, N, F, Cl, Na, and K in SAD during the water leaching process were investigated in this study. In addition, the double-edged effects of aluminosilicates formation on denitrification and desalination during the leaching process of SAD were also revealed. The results showed that the generation of Al(OH)3 inclusions during the hydrolysis of AlN inhibited the deep denitrification, while NH3 provided an alkaline driving force for the dissolution of Al(OH)3 and Si/SiO2. Dissociated Al(OH)4- and H3SiO4- reacted with Na+/K+ to form aluminosilicates, which promoted denitrification but inhibited desalination. Eventually, after 480 min of water leaching (L/S = 1.5, T = 80 °C), the denitrification was 86.39 %, the removal rate of Cl was 99.61 %, and the contents of Na and K in leaching residues were 0.39 wt% and 0.24 wt%, respectively. The leaching residues with an Al content of 37.41 wt% showed no leaching toxicity, which reached Grade I bauxite grade.