Rechargeable Research Articles

Electrochemical sodium storage properties in monolayer VOPO4: A density functional theory prediction

The unique structural properties of two-dimensional materials make them promising for energy storage applications. This work theoretically predicts for the first time that Monolayer VOPO4 (MNL VOPO4), exfoliated from the delithiated phase of tetragonal LiVOPO4, is stable at room temperature, exhibiting excellent thermodynamic and kinetic stability, thus making it a promising high-capacity anode material for sodium-ion batteries (SIBs). Compared to bulk VOPO4, the monolayer structure significantly reduces the sodium ion migration energy barrier from 1.006 to 0.0795 eV, thereby markedly enhancing sodium ion migration kinetics. MNL VOPO4 can adsorb up to 32 sodium ions, corresponding to a theoretical capacity of 634.88 mA h g−1 and an energy density of 895.18 Wh kg−1. Furthermore, the excellent structural stability of MNL VOPO4 favors its cycling performance during charge and discharge processes. This work provides theoretical insights for better utilizing and developing multi-atomic phosphate compounds as electrode materials for secondary batteries.

Defect-driven ion storage on hexagonal boron nitride for fire-safe and high-performance lithium-ion batteries

The mass market adoption of electric vehicles has increased the risk of safety concerns, such as overheating and flammability. Rational design of fire-safe and high-capacity anodes with thermal tolerance, capable of fast-charging and long cycle-life, is crucial for the development of next generation Li-ion batteries operating under extreme conditions. Here we report a defect engineered hexagonal boron nitride (hBN) anode to mediate the safety dilemma. We demonstrate that the defects generated via cryomilling catalyze the reversible LiF formation and enable the pseudocapacitive type Li-ion storage on hBN. The non-flammability and excellent thermal tolerance of hBN allows high specific capacity (880 mAh/g @ 25 mA/g), rate performance (480 mAh/g @ 5 A/g) and stable cycling (5000 cycles) at 60 °C. The Li-ion full-cell with the defective hBN anode and the conventional cathode (LiNiMnCoO2) delivers significantly higher energy (400 Wh kg−1) and power density (1 kW kg−1) when compared to graphite/LiNiMnCoO2 full-cells (121 Wh kg−1 and 250 W kg−1). First-principles calculations confirm that nitrogen antisite (NBVN) defects are responsible for the electrochemical activation of otherwise inactive hBN. The strategy of defect-induced electrochemical activation opens up new avenues in the design of high-performance electrode materials for numerous secondary batteries.

Adaptive-DMPC based energy management and pre-installation techno-economic analysis of a grid-tied cyber-physical community microgrid

The trends for creating smart cities is increasing as it gives assurance of high-quality living standards, however, converting an existing city into a smart one needs more time, investments and is highly tedious. Another concept of community based sustainable living that can be installed in and around outskirts of any city. All the features of smart cities can be brought in by most economical, sustainable, and environmental friendly way. A cyber-physical Community Microgrid (CMG) can have various loads such as heating, cooling, security and lighting purposes. The dependency on grid supply can be reduced by using renewable sources of electricity. Solar water heaters and biogas plant can take care of heating loads. Handling uncertainties in generation, time-varying load scenarios, and dynamics of supply grid are crucial for smooth operation of cyber-physical CMG. In this work, an Energy Management Strategy (EMS) for CMG is proposed using an adaptive Distributed Model Predictive Control (DMPC) that improves scalability with modular architecture, allow enhanced flexibility and adaptability, robustness and reliability, enhanced optimization and predictive capabilities. All possible intermittencies types due to renewables, time-variable demand profiles, smooth charging/discharging cycles and longevity of storage batteries, curtailing of noncritical loads, and dynamic price of grid consumption are applied. Further, use of EMS outcomes is done to develop pre-installation techno-economic analysis for establishing a CMG with optimal component sizing. The given DMPC scheme for CMG is verified by conducting comprehensive test case studies over 24 hrs interval on the Matlab/Simulink and hardware-in-loop testing.

Simultaneous measurement of temperature and pressure sensing technology based on double cavity matching in batteries

A compact sensor based on fiber Fabry-Pérot (FP) cavities dual-cavity matching technique cascaded with fiber Bragg grating (FBG) is proposed and demonstrated to measure pressure and temperature variations inside battery. The sensitivity amplification mechanism for two-parameter measurements is analyzed and a cased reference chamber scheme is designed. Low-cost, small-size, high-temperature and corrosion-resistant all-fiber-optic high sensitivity gas pressure sensors targeting the interior of energy storage batteries are fabricated and cascaded with FBGs to measure temperature parameters. The experimental results show that the sensor has a sensitivity of −26.8322 nm/MPa in a pressure range of 1.86 MPa, the gas pressure inside the battery and the temperature inside and outside the battery at different discharge rates of 1500mAH capacity monobloc batteries can be measured practically, directly and instantly. It has potential applications in detecting subtle pressure variations caused by gas precipitation inside the battery and in temperature measurement, and provides a new concept and a feasible technological path for the measurement of key parameters inside lithium-ion batteries.

NST3 induces ectopic transdifferentiation, forming secondary walls with diverse patterns and composition in Arabidopsis thaliana.

The master transcription factor NAC SECONDARY WALL THICKENING PROMOTING FACTOR3 (NST3), also known as SND1, plays a pivotal role in regulating secondary cell wall (SCW) development in interfascicular and xylary fibers in Arabidopsis thaliana. Despite progress in understanding SCW assembly in xylem vessel-like cells, the mechanisms behind its assembly across different cell types remain unclear. Overexpressing NST3 or its homolog NST1 leads to reduced fertility, posing challenges for studying their impact on secondary wall formation. This study aimed at developing a tightly regulated dexamethasone (DEX)-inducible expression system for NST3 and NST1 to elucidate the structure and assembly of diverse SCWs. Using the DEX-inducible system, we characterized ectopically formed SCWs for their diverse patterns, mesoscale organization, cellulose microfibril orientation, and molecular composition using spinning disk confocal microscopy, field emission scanning electron microscopy (FESEM), vibrational sum-frequency generation (SFG) spectroscopy and, histochemical staining and time-of-flight secondary ion mass spectrometry (ToF-SIMS), respectively. Upon DEX treatment, NST3 and NST1 transgenic hypocotyls underwent time-dependent transdifferentiation, progressing from protoxylem-like to metaxylem-like cells. NST3-induced plants exhibited normal growth but had rough secondary wall surfaces with delaminating S2 and S3 layers. Mesoscale examination of induced SCWs in epidermal cells revealed that macrofibril thickness and orientation were comparable to xylem vessels, while wall thickness resembled that of interfascicular fibers. Additionally, induced epidermal cells formed SCWs with altered cellulose and lignin contents. These findings suggest NST3 and/or NST1 induce SCWs with shared characteristics of both xylem and fiber-like cells forming loosely arranged cell wall layers and cellulose organized at multiple angles relative to the cell growth axis and with varied cellulose and lignin abundance. This inducible system opens avenues to explore ectopic SCWs for bioenergy and bioproducts, offering valuable insights into SCW patterning across diverse cell types and developmental stages.

Regulating structural units and morphology of SiOC anode for enhanced high-rate storage and long-life lithium ion batteries

The widespread use of silicon oxycarbide (SiOC) anodes in industry has been hampered by their limited reversible capacity, subpar rate performance, and complex manufacturing methods. In this research, a novel strategy is proposed to in situ construct SiOC with oxygen-rich structural units and flake morphology via one-pot synthesis, which integratively facilitates the reversible capacity and enhances the transport capability of Li+. Benefiting from these structural and compositional merits, the produced SiOC electrode showcases an impressive reversible capacity of 906 mAh g−1 at 0.1 A g−1, a remarkable rate capability of 591 mAh g−1 and cycling stability of 98 % capacity retention rate at 2.0 A g−1 after 1200 cycles. Characterization results prove that the SiOC with a higher content of oxygen-rich structural units and flakes is helpful in forming the stable solid-electrolyte interface film and buffering volume expansion. Furthermore, it is demonstrated that the SiOC anodes containing LixSiOy compounds reduce the irreversible use of Li-ions during the initial reaction. Our findings present an effective method to simultaneously manipulate the structural units and morphology of SiOC compounds, paving the way for superior electrochemical performance.

Adaptive optimal control strategy of fuel economy for fuel cell battery storage system using in HEV applications

Adaptive optimal control strategy of fuel economy for fuel cell battery storage system using in HEV applications

Designing sodium alloys for dendrite‐free sodium‐metal batteries

AbstractSodium metal, with a high theoretical specific capacity (∼1165 mA h g−1) and a low redox potential (−2.71 V vs. SHE) as well as low cost, becomes an attractive option for high‐energy‐density sodium secondary batteries. However, the practical application of sodium metal anodes is hindered by dendrite growth, which results in low energy efficiency, poor lifetime and serious safety issues. To address this challenge, researchers propose various strategies, including the formation of sodium alloys (Na‐M alloys, M = Sn, Sb, Bi, In, etc.) through alloying reaction. The alloying effect has a positive impact in terms of reducing the local current density, mitigating the volume expansion, and inhibiting the dendrite growth. It is thus an effective solution for constructing high‐performance sodium secondary batteries. This review systematically describes the mechanism of dendrite growth and the alloying process of Na‐M alloys, summarizes recent research progress and strategies for applying Na‐M alloys to create dendrite‐free sodium secondary batteries, as well as presents prospects for the development of Na‐M alloys and offers clear suggestions for future research. This review aims to inspire further efforts to build dendrite‐free, high‐performance sodium secondary batteries and broaden a new aspect for the next‐generation battery systems.

Genome-wide characterization and expression analysis of the CINNAMYL ALCOHOL DEHYDROGENASE gene family in Triticum aestivum.

CINNAMYL ALCOHOL DEHYDROGENASE (CAD) catalyzes the NADPH-dependent reduction of cinnamaldehydes into cinnamyl alcohols and is a key enzyme found at the final step of the monolignol pathway. Cinnamyl alcohols and their conjugates are subsequently polymerized in the secondary cell wall to form lignin. CAD genes are typically encoded by multi-gene families and thus traditionally organized into general classifications of functional relevance. In silico analysis of the hexaploid Triticum aestivum genome revealed 47 high confidence TaCAD copies, of which three were determined to be the most significant isoforms (class I) considered bone fide CADs. Class I CADs were expressed throughout development both in RNAseq data sets as well as via qRT-PCR analysis. Of the 37 class II TaCADs identified, two groups were observed to be significantly co-expressed with class I TaCADs in developing tissue and under chitin elicitation in RNAseq data sets. These co-expressed class II TaCADs were also found to be phylogenetically unrelated to a separate clade of class II TaCADs previously reported to be an influential resistance factor to pathogenic fungal infection. Lastly, two groups were phylogenetically identified as class III TaCADs, which possess distinct conserved gene structures. However, the lack of data supporting their catalytic activity for cinnamaldehydes and their bereft transcriptional presence in lignifying tissues challenges their designation and function as CADs. Taken together, our comprehensive transcriptomic analyses suggest that TaCAD genes contribute to overlapping but nonredundant functions during T. aestivum growth and development across a wide variety of agroecosystems and provide tolerance to various stressors.

Seed-Assisted Reversible Dissolution/Deposition of MnO2 for Long-Cyclic and Green Aqueous Zinc-Ion Batteries.

Manganese oxide (MnO2) based aqueous zinc-ion batteries (AZIBs) are considered to be a promising battery for grid-scale energy storage. However, they usually suffer from the great challenge of capacity attenuation due to Mn dissolution and irreversible structural transformation. Herein, full use of the shortcomings is made to design high-performance cathode-free AZIBs. Manganese-based Prussian blue analog (Mn-PBA) is selected as a seed layer to provide a stable MnO2 electrodeposition surface. Thanks to the large specific surface area and manganophilic nature of Mn-PBA, the deposition/dissolution kinetics between Mn2+ and MnO2 are significantly enhanced. Systematic studies revealed the mechanism of MnO2 deposition-dissolution related to the reversible transformation of manganese oxide hydroxide and zinc hydroxide sulfate hydrate. Based on this, the developed cathode-free AZIBs exhibit outstanding rate performance (with a specific capacity of 273.7 mAh g-1 at 1 A g-1) and extraordinary cycle stability (maintaining a specific capacity of 52.3 mAh g-1 after 50000 cycles at 20 A g-1). Furthermore, the AZIBs with non-toxic, biocompatible materials can be directly discarded after use, without causing pollution to the environment, which is expected to help achieve the sustainable development goals.

Impact of diverse material precursors on microstructure and ionic conductivity Li0.33La0.56TiO3 solid-state electrolyte properties

The development of rechargeable lithium-ion batteries (LIBs) with solid-state electrolyte (SSE) is gaining attention in recent years. Among various SSE materials, lithium lanthanum titanate (LLTO) has emerged as a promising candidate due to its high ionic conductivity and excellent chemical stability. This study aims to synthesis and investigate the potential of Indonesian locally source lanthanum oxide compared to commercial lanthanum oxide for use as an SSE material. LLTO powders were synthesized via the solid-state reaction method. The local LLTO pellet achieved an impressive relative density of 99 %, slightly higher than the commercial LLTO at 97 %. This high relative density enhances ionic conductivity. The local LLTO sample achieved the highest ionic conductivity of 2.68×10−5 S/cm at 100°C and 1.15×10−5 S/cm at room temperature, nearly double that of commercial LLTO measuring approximately 8.40×10−6 S/cm at 100°C and around 4.57×10−6 S/cm at room temperature. The research findings indicate that lanthanum oxalate sourced from waste generated during monazite sand mining operations in the Bangka Belitung region of Indonesia, exhibits potential as a material for lithium-ion-conducting electrolytes in all-solid-state batteries.

Layered Porous Ring-Like Carbon Network Protected FeNi Metal Atomic Pairs for Bifunctional Oxygen Electrocatalysis and Rechargeable Zn-Air Batteries.

Bimetallic atom catalysts exhibit ultra-high oxygen electrocatalytic activity by harnessing mutual promotion and synergistic effects between adjacent metal active centers, surpassing the performance of single metal atomic catalysts. Herein, FeNi atom pairs protected by hierarchical porous annular carbon grids (P-FeNi-NPC) are introduced using a mediator-assisted MOFs-derived strategy. The introduction of the multi-block copolymer P123 ensures the uniform confinement and dispersion of metal ions, followed by thermal decomposition to form a "planetary-ring-like" carbon framework that anchors the bimetallic atomic pairs in the active region. The homogeneous distribution of adjacent Fe-N4 and Ni-N4 active sites significantly enhances catalytic activity and stability. Leveraging unique electronic and geometric structures, the resulting P-FeNi-NPC catalyst demonstrates exceptional ORR and OER activities with an ΔE value of 0.705 (E1/2 = 0.845V, Ej = 10 = 1.55V). Theoretical calculations unveil that FeNi bimetallic sites loaded on nitrogen-doped carbon frameworks with specific curvature effectively modulate the energy of d-band centers, thus balancing the free energy of oxygen-containing intermediates. This study presents a novel and versatile approach for synthesizing advanced bifunctional catalysts, poised to drive the future development of Zn-air batteries.

Unlocking a Fast Track for Magnesium Migration in Cu1.8S1-xSex via Anion-Tuning Chemistry.

Rechargeable magnesium batteries (rMBs) are promising candidates for next-generation batteries in which sulfides are widely used as cathode materials. The slow kinetics, low redox reversibility, and poor magnesium storage stability induced by the large Coulombic resistance and ionic polarization of Mg2+ ions have obstructed the development of high-performance rMBs. Herein, a Cu1.8S1-xSex cathode material with a two-dimensional sheet structure has been prepared by an anion-tuning strategy, achieving improved magnesium storage capacity and cycling stability. Element-specific synchrotron radiation analysis is evidence that selenium incorporation has indeed changed the chemical state of Cu species. Density functional theory calculations combined with kinetics analysis reveal that the anionic substitution endows the Cu1.8S1-xSex electrode with favorable charge-transfer kinetics and low ion diffusion barrier. The principal magnesium storage mechanisms and structural evolution process have been revealed in details based on a series of ex situ investigations. Our findings provide an effective heteroatom-tuning tactic of optimizing electrode structure toward advanced energy storage devices.

Wormhole attack detection and mitigation model for Internet of Things and WSN using machine learning.

The Internet of Things (IoT) is revolutionizing diverse sectors like business, healthcare, and the military, but its widespread adoption has also led to significant security challenges. IoT networks, in particular, face increasing vulnerabilities due to the rapid proliferation of connected devices within smart infrastructures. Wireless sensor networks (WSNs) comprise software, gateways, and small sensors that wirelessly transmit and receive data. WSNs consist of two types of nodes: generic nodes with sensing capabilities and gateway nodes that manage data routing. These sensor nodes operate under constraints of limited battery power, storage capacity, and processing capabilities, exposing them to various threats, including wormhole attacks. This study focuses on detecting wormhole attacks by analyzing the connectivity details of network nodes. Machine learning (ML) techniques are proposed as effective solutions to address these modern challenges in wormhole attack detection within sensor networks. The base station employs two ML models, a support vector machine (SVM) and a deep neural network (DNN), to classify traffic data and identify malicious nodes in the network. The effectiveness of these algorithms is validated using traffic generated by the NS3.37 simulator and tested against real-world scenarios. Evaluation metrics such as average recall, false positive rates, latency, end-to-end delay, response time, throughput, energy consumption, and CPU utilization are used to assess the performance of the proposed models. Results indicate that the proposed model outperforms existing methods in terms of efficacy and efficiency.

A Comparative Evaluation of Community-Used District and Individual Battery Storage Systems for Photovoltaic Energy Systems

The significant expansion of renewable energies has led to an increased importance of storage systems. Decentralized storage solutions, including Home Battery Energy Storage Systems (HBESSs) and District Battery Energy Storage Systems (DBESSs), play a crucial role in this context. This study compares individual HBESSs with a community-used DBESS regarding the grade of autarky and self-consumption, specifically focusing on a planned residential area consisting of 36 single-family houses. A simulation tool was developed to conduct load flow simulations based on household electricity consumption, wallbox profiles for electric vehicle charging, and photovoltaic generation data across various battery capacities and system boundaries. The results demonstrate that the DBESS, compared to individual HBESSs with equivalent cumulative battery capacities, can achieve a maximum increase in the grade of autarky of up to 11.6%, alongside an 8.0% increase in the grade of self-consumption for the given use case. In terms of capacity, the DBESS allows for a saving of up to 68% compared to HBESS to achieve similar results for the studied neighborhood.

Transition towards net zero emissions: Integration of a PV/T system with a hydroelectric generator and the impact of demand-side management

With the aim of diversifying different energy sources and achieving net zero emissions, hybrid renewable energy sources (HRES) represent the future of the world. However, several HRES simulation software do not integrate the Photovoltaic/thermal (PV/T) system. This article designs an optimal design model for a tri-hybrid Photovoltaic/thermal/hydroelectric (PV/T/H) system for a rural locality in the North Cameroon region. The two Demand Side Management (DSM) strategies used reveal that the DSM strategy significantly reduced the energy cost by 59 % and the emission by CO2 22 % compared to the No-DSM mode. Although the use of battery storage (BSS) is used in both cases, the optimal solutions obtained thanks to the multi-objective optimization method implemented on Matlab led to 418 PV/T panels, 2 MH generators, 2 diesel generators (DG) and 217 PV/T panels and 1 DG for DSM and No-DSM mode respectively. This study is a demonstration of the effect of dynamic tariffs and active demand management technologies on PV/T/H modeling and optimization. It also reveals the need to hybridize PV/T with other energy systems to increase performance and achieve net zero emissions.

Performances of MnO2 and SnO2 Coated MnO2 as Cathode Materials for Aqueous Rechargeable Zinc-ion Batteries

In this study, the micro-emulsion method was used to create the manganese-based cathode materials MnO2 and MnO2@SnO2. For the use as cathode materials in rechargeable zinc-ion batteries, MnO2 and SnO2 coated MnO2@SnO2 were synthesized. FT-IR, Powder X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray Spectroscopy (EDS), and UV-visible Spectroscopy were used to characterize the as-prepared materials. Electrochemical impedance spectroscopy (EIS), battery charge-discharge (BCD), and cyclic voltammetry (CV) techniques were used to investigate the electrochemical properties of the prepared cathode materials for aqueous rechargeable zinc-ion batteries (ARZIBs). The CV profiles were measured in the potential range of 2.1-1.0 V at a scan rate of 20 mV/s. A pair of redox peaks can be seen in the cycle of CV curves. Charge/discharge cycles of SnO2 coated MnO2@SnO2 electrodes are higher than those of pristine MnO2. SnO2 coated MnO2@SnO2 electrodes have better initial charge/discharge capacities than pristine MnO2 electrodes, which is a factor to take into account. In the first cycle, SnO2 coated MnO2@SnO2 electrode has a 26% higher charge capacity than the bare MnO2 electrode. The SnO2 coating on MnO2 may be the cause of the enhanced charge and discharge capabilities of MnO2@SnO2. J. of Sci. and Tech. Res. 5(1): 83-92, 2023

Stable Zn metal anode enabled via ferroelectric nanotube arrays

Aqueous zinc-ion batteries are receiving increasing attention owing to their markedly high safety and low cost. However, the uncontrolled zinc dendrite growth and the side reactions at Zn-electrolyte interfaces hinder the practical application of aqueous rechargeable zinc-based batteries. Therefore, regulating the electrode/electrolyte interface to achieve dense zinc deposition is crucial for improving the electrochemical performance of zinc-ion batteries. Herein, ferroelectric composite nanotube arrays (BaTiO3 modified TiO2 nanotubes, TiO2@BaTiO3) are designed and fabricated as the three-dimensional current collector for Zn metal anode. Abundant zincophilic sites on the surface of BaTiO3 induce zinc nucleation, enabling a compact and horizontally-aligned Zn morphology. At external electric field, the depolarization field produced the ferroelectric BaTiO3 layer on the electrode surface can accelerate the dissociation of ZnSO4 and regulate the Zn-ion desolvation process at the interfaces, leading to dendrite-free Zn deposition and less byproducts. As a result, the TiO2@BaTiO3/Zn anode achieves reversible Zn plating/stripping with low overpotential for over 3000 h at 3 mA cm−2 in symmetric cells, and the assembled full battery exhibits a significantly enhanced cycling stability over 1800 cycles at 1 A g−1. Ferroelectric nanotube arrays brings new opportunities for next-generation aqueous zinc-ion batteries.

Crystalline Texture Reengineering of Zinc Powder-Based Fibrous Anode for Remarkable Mechano-Electrochemical Stability.

The challenge of inadequate mechano-electrochemical stability in rechargeable fibrous Zn-ion batteries (FZIBs) has emerged as a critical challenge for their broad applications. Traditional rigid Zn wires struggle to maintain a stable electrochemical interface when subjected to external mechanical stress. To address this issue, a wet-spinning technique has been developed to fabricate Zn powder based fibrous anode, while carbon nanotubes (CNTs) introduced to enhance the spinnability of Zn powder dispersion. The followed annealing treatment has been conducted to reengineer the Zn crystalline texture with CNTs assisted surface tension regulation to redirect (002) crystallographic textural formation. The thus-derived annealed Zn@CNTs fiber demonstrates great mechano-electrochemical stability after a long-term bending and electrochemical process. The fabricated FZIB demonstrates a remarkable durability, surpassing 800h at 1mAcm-2 and 1mAhcm-2, with a marginal voltage hysteresis increase of 21.7mV even after 100 twisting cycles under 180 degree twisting angle. The assembled FZIB full cell displays an 88.6% capacity retention even after a long cycle of a series of bending, knotting, and straightening deformation. It has been also woven into a 200cm2 size textile to demonstrate its capability to integrate into smart textiles.

Bifunctional self‐segregated electrolyte realizing high‐performance zinc‐iodine batteries

AbstractStatic rechargeable zinc‐iodine (Zn‐I2) batteries are superior in safety, cost‐effectiveness, and sustainability, giving them great potential for large‐scale energy storage applications. However, the shuttle effect of polyiodides on the cathode and the unstable anode/electrolyte interface hinder the development of Zn‐I2 batteries. Herein, a self‐segregated biphasic electrolyte (SSBE) was proposed to synergistically address those issues. The strong interaction between polyiodides and the organic phase was demonstrated to limit the shuttle effect of polyiodides. Meanwhile, the hybridization of polar organic solvent in the inorganic phase modulated the bonding structure, as well as the effective weakening of water activity, optimizing the interface during zinc electroplating. As a result, the Zn‐I2 coin cells performed a capacity retention of nearly 100% after 4000 cycles at 2 mA cm−2. And a discharge capacity of 0.6 Ah with no degradation after 180 cycles was achieved in the pouch cell. A photovoltaic energy storage battery was further achieved and displayed a cumulative capacity of 5.85 Ah. The successfully designed energy storage device exhibits the application potential of Zn‐I2 batteries for stationary energy storage.image