Rapid Evaporation Research Articles

Elastic, Janus 3D evaporator with arch-shaped design for low-footprint and high-performance solar-driven zero-liquid discharge

Solar-driven zero-liquid discharge (ZLD) is a promising wastewater management strategy for freshwater recovery and solid waste harvesting. However, practical application of the solar-driven ZLD is severely constrained due to its low evaporation efficiency, large footprint, and rapid salt accumulation. Here, we present a Janus arch-shaped solar-driven evaporator (▪) comprising a hydrophobic top photothermal layer for effective light absorption, solar-thermal conversion, and vapor evaporation, which exhibits an evaporation rate of 2.82 kg∙m−2∙h−1 in pure water. The design also includes shapable delignified longitudinal wood (D-L-wood) serving as the hydrophilic bottom water transport layer, which enables dual-directional saltwater transportation and salt crystallization. D-L-wood, with numerous aligned channels, exhibits a low thermal conductivity of 0.04 W·m−1·K−1 along perpendicular direction and can effectively localize heat on the photothermal layer of the evaporator. D-L-wood has excellent hydrophilicity, and the salty water can be transferred quickly along both ends of the wood, providing sufficient salty water for rapid evaporation. The anisotropy of the wood makes the heat transfer quickly along the channel, improving the thermal management ability of the evaporator. Moreover, during vapor evaporation on the hydrophilic-hydrophobic interface, salt is crystallized at the hydrophilic layer, resulting in an enhanced anti-salt performance, a 1.5 folds evaporation rate compared with non-Janus evaporator after 15 h test. Under the conditions of a salt concentration of 3.5 %, a high salt harvest performance of 62.4 g∙m−2∙h−1 can be obtained under AM 1.5 solar irradiation. The arch-shaped design fully utilizes the upper space and effectively reduces evaporator footprint, resulting in an evaporation area to footprint ratio of 1.57:1. The designed evaporator can also be utilized for ZLD treatment of other heavy metal polluted water including Cu2+, CrO42−, Co2+, and so on. Therefore, the Janus-arch-shaped, solar-driven evaporator enables a potentially low-footprint, low-cost, scalable, and practical ZLD strategy for sustainable wastewater treatment.

Silicon rib waveguide with palladium coated gold nanorods overlayer for hexane and N-methylaniline detection

The adsorption of hexane and N-methylaniline was investigated by on-chip vibrational spectroscopy. The interaction with the Pd surface significantly perturbs the vibrational modes of hexane. Near-infrared absorption spectroscopy on the waveguide detected a redshifted CH stretching vibration. We showed that while rapid evaporation of one component may occur, the modification facilitates the sensing for large molecules and mixtures of substances. Rib waveguides were modified with palladium to exhibit an enhanced electromagnetic field effect due to the electrostatic interaction of Pd and hydrogen, showing the drop in the amine overtone absorption of 7.6 dB and the overtone related to the bond of carbon to hydrogen of 6.8 dB. The absorption of hexane bonds in water is 5.5 dB. The obtained values are 100 times higher than those predicted by the electromagnetic simulator for pure rib waveguides. This may be explained by CH bonds in hexane that can be activated through a hydrogen bond-like interaction with metal substrates. This achievement holds promising potential for advancing hexane and N-Methylailine detection and analysis technologies, with implications for diverse applications in various industries, such as environmental monitoring, industrial processes, and safety measures.

Investigation on structure, evaporation, and desiccation cracking of soil with straw biochar

AbstractTo investigate the cracking behavior in the evaporation process of the soil surface with biochar as an additive, five experimental groups were established in the natural environment with 0, 12, 60, 120, and 170 g·kg−1 biochar. The results of an investigation on organic matter and aggregations indicate that a high content of biochar can significantly improve the content of organic matter and the amount of soil aggregates. After adding 60 and 170 g·kg−1 biochar, the content of organic matter increased by 19.47% and 84.12%, respectively, and the content of soil aggregates with an average diameter greater than 0.25 mm increased by 16.43% and 38.20%, respectively. The investigation also examines the evaporation and cracking characteristics of soils that contain biochar. The rate of evaporation is approximately a “step” type function with time. The rate of evaporation is observed in three stages: the rapid, decelerating, and final evaporation stages. In the rapid evaporation stage, the initial evaporation rate of the sample that contains biochar is increased on average by 46%. The fractal dimension and cracks rate are decreased by 22.95% and 20.99% with 120 g·kg−1 biochar addition. This means that the increase of soil organic matter after adding biochar plays a crucial role in the stability of aggregates. As a soil conditioner, biochar has the ability to enhance soil water retention capacity and is a sustainable strategy to improve soil properties.

Spray Coating of Wood with Nanoparticles from Lignin and Polylactic Glycolic Acid Loaded with Thyme Essential Oils.

Ensuring the longevity of wooden constructions depends heavily on the preservation process. However, several traditional preservation methods involving fossil-based compounds have become outdated because they pose a significant risk to the environment and to human health. Therefore, the use of bio-based and bioactive solutions, such as essential oils, has emerged as a more sustainable alternative in protecting wood from biotic attacks. The entrapment of essential oils in polymeric carrier matrices provides protection against oxidation and subsequent degradation or rapid evaporation, which implies the loss of their biocidal effect. In this work, lignin as well as PLGA nanoparticles containing the essential oils from two different thyme species (Thymus capitatus and T. vulgaris) were applied on beech wood samples using spray coating. The prepared coatings were investigated using FTIR imaging, SEM, as well as LSM analysis. Release experiments were conducted to investigate the release behavior of the essential oils from their respective lignin and PLGA carrier materials. The study found that lignin nanoparticles were more effective at trapping and retaining essential oils than PLGA nanoparticles, despite having larger average particle diameters and a more uneven particle size distribution. An analysis of the lignin coatings showed that they formed a uniform layer that covered most of the surface pores. PLGA nanoparticles formed a film-like layer on the cell walls, and after leaching, larger areas of native wood were evident on the wood samples treated with PLGA NPs compared to the ones coated with lignin NPs. The loading capacity and efficiency varied with the type of essential oil, while the release behaviors were similar between the two essential oil types applied in this study.

Water loss and shrinkage prediction in 3D printed concrete with varying w/c and specimen sizes

In 3D printed concrete (3DPC), the absence of formwork leads to increased shrinkage compared to traditional cast concrete which uses formwork. This increase in shrinkage is primarily due to the rapid evaporation of moisture during the early stages. Therefore, our research focused on how the initial water content and the exposed surface area affect the total shrinkage by varying water-to-cement ratio (w/c) and the surface-to-volume ratio (s/v). For 3DPC with high w/c, we used calcium formate (CaF) to improve its printability by increasing static yield stress. Dry environment makes the evaporation the predominant mode of water loss, significantly decelerating the hydration process in samples with fully exposed surfaces. At 28 d, the evaporated moisture in 3DPC is 2.8 times higher than the moisture consumed by hydration. A predictive model for the shrinkage properties of 3DPC has been developed by considering that 3DPC experiences both hydration and evaporation simultaneously from early stages on the basis of the water mass conservation principle. The predictions were found to align with actual shrinkage test results, as evidenced by quantitative analysis of parameters like internal RH, mass loss, degree of hydration, and porosity, thus validating the accuracy of the model.

Fabrication of Al@AIH@PVDF metastable composite film with enhanced laser ignition ability and combustion performance

Laser ignition technology has garnered significant attention for energetic materials in recent years, offering advantages over traditional electrical initiation methods, notably in mitigating issues related to stray currents and electromagnetic interference. Moreover, it can facilitate multi-point synchronous ignition. However, the persistent challenges of high ignition thresholds and delays in energetic materials necessitate effective resolutions. In this study, we address these challenges by converting the inert Al2O3 layer on the surface of aluminum powder into the active compound Aluminum Iodate Hexahydrate ([Al(H2O)6](IO3)3(HIO3)2, AIH) to prepare an Al@AIH@PVDF energetic composite film (ECF) with the aim of reducing the laser ignition threshold and delay of Al@PVDF ECF. The Al@AIH@PVDF ECF was synthesized through a simple wet chemistry method and a rapid evaporation process suing a simple, environmental-friendly, and cost-effective way. Differential scanning calorimetry-thermogravimetric analysis (DSC-TG) results demonstrate a lower exothermic reaction temperature (161 °C) and higher heat release (2900 J g−1) for Al@AIH@PVDF ECF. Laser ignition tests reveal a reduced laser ignition delay (11 ms) and threshold (1.59 J cm−2) for Al@AIH@PVDF ECF. Combustion experiments showcase elevated combustion flame temperature (3090 K), burning rate (4.11 cm s−1), and smaller condensed combustion products, while effectively igniting CL-20. Pressure tests indicate higher maximum combustion pressure (3.24 MPa) and pressure rise rate (4.05 GPa s−1) for Al@AIH@PVDF ECF. Finally, the reaction process and mechanism of Al@AIH@PVDF ECF was also investigated and proposed.

Precipitation and Soil Moisture Variation over the Tibetan Plateau to the Anomaly of Indian Summer Monsoon from 1979 to 2019

The Indian Summer Monsoon (ISM) can profoundly influence the summer precipitation patterns of the Tibetan Plateau (TP) and indirectly affect the TP’s soil humidity. This study investigates the responses of TP’s precipitation and soil moisture to the ISM in the monsoon season (June to September, JJAS) from 1979 to 2019. Precipitation in the TP and the ISM intensity generally exhibit a positive correlation in the west and a negative correlation in the east. The response of TP soil moisture to the ISM generally aligns with precipitation patterns, albeit with noted inconsistencies in certain TP regions. A region exhibiting these inconsistencies (30°–32°N, 80°–90°E) is selected as the study area, hereafter referred to as IRR. In periods of strong ISM, precipitation in IRR increases, yet soil moisture decreases. Conversely, in years with a weak ISM, the pattern is reversed. During strong ISM years, the rainfall increase in IRR is modest, and the soil remains drier compared to other TP regions. Under the combined effects of a marginal increase in precipitation and relatively rapid evaporation, soil moisture in the IRR decreased during years of strong ISM. During weak ISM years, the surface temperature in the IRR is higher compared to strong ISM years, potentially accelerating the melting of surface permafrost and snow in this region. Additionally, glacier meltwater, resulting from warmer temperatures in the northwest edge of the TP, may also result in the humidification of the soil in the IRR.

Fast-Growth Polymer: Fullerene Bulk-Heterojunction Thin Films for Efficient Organic Photovoltaics.

The bulk-heterojunction (BHJ) system that uses a π-conjugated polymer as an electron donor, and a fullerene derivative as an electron acceptor, is widely used in organic solar cells (OSCs) to facilitate efficient charge separation and extraction. However, the conventional BHJ system still suffers from unwanted phase segregation caused by the existence of significant differences in surface energy between the two BHJ components and the charge extraction layer during film formation. In the present work, we demonstrate a sophisticated control of fast film-growth kinetics that can be used to achieve a uniform distribution of donor and acceptor materials in the BHJ layer of OSCs without undesirable phase separation. Our approach involves depositing the BHJ solution onto a spinning substrate, thus inducing rapid evaporation of the solvent during BHJ film formation. The fast-growth process prevents the fullerene derivative from migrating toward the charge extraction layer, thereby enabling a homogeneous distribution of the fullerene derivative within the BHJ film. The OSCs based on the fast-growth BHJ thin film are found to exhibit substantial increases in JSC, fill factor, and a PCE up to 11.27 mA/cm2, 66%, and 4.68%, respectively; this last value represents a remarkable 17% increase in PCE compared to that of conventional OSCs.

Streamlining regular liquid chromatography with MALDI-TOF MS and NMR spectroscopy using automatic full-contact splitless spotting interface and flash-tap fractioning collection

BackgroundHigh-resolution matrix-assisted laser desorption/ionization-time of flight mass spectrometry (MALDI-TOF MS) and nuclear magnetic resonance (NMR) spectroscopy are powerful tools to identify unknown psychoactive substances. However, in complex matrices, trace levels of unknown substances usually require additional fractionation and concentration. Specialized liquid chromatography systems are necessary for both techniques. The small flow rate of nano LC, typically paired with MALDI-TOF MS, often results in prolonged fractionation times. Conversely, the larger flow rate of semi-preparative LC, used for NMR analysis, can be time-consuming and labor-intensive when concentrating samples. To address these issues, we developed an integrated automatic system that integrated to regular LC. ResultAutomatic spot collector (ASC) and automatic fraction collector (AFC) were present in this study. The ASC utilized in-line matrix mixing, full-contact spotting and real time heating (50 °C), achieving great capacity of 5 μL droplet on MALDI plate, high recovery (76–116%) and rapid evaporation in 2 min. The analytes were concentrated 4–8 times, forming even crystallization, reaching the detection limit at the concentration of 50 μg L−1 for 12 psychoactive substances in urine. The AFC utilizes flexible tubing which flash-tapped the microtube's upper rim (3 mm depth) instead of reaching the bottom. This method prevents sample loss and minimizes the robotic arm's movement, providing a high fractionating speed at 6 s 12 psychoactive compounds were fractionated in a single round analysis (recovery: 81%–114%). Methamphetamine and nitrazepam obtained from drug-laced coffee samples were successful analyzed with photodiode array (PDA) after one AFC round and NMR after five rounds. SignificanceThe ASC device employed real-time heating, in-line matrix mixing, and full-contact spotting to facilitate the samples spotting onto the MALDI target plate, thereby enhancing detection sensitivity in low-concentration and complex samples. The AFC device utilized the novel flash-tapping method to achieve rapid fractionation and high recovery rate. These devices were assembled using commercially available components, making them affordable (400 USD) for most laboratories while still meeting the required performance for advanced commercialized systems.

Scalable Fabric‐Based Solar Steam Generator

AbstractSolar steam generation has emerged as a promising approach to address water scarcity issues globally. However, a few challenges remain, including high cost, limited scalability, and salt accumulation, before this technique can be adopted by the general population. Here, an all‐in‐one photothermal fabric is reported such as a solar steam generator (SSG), consisting of commercial hydrophilic superfine denier polypropylene fiber and water‐repellent expandable polyethylene foam, manufactured via a conventional weaving machine. By tailoring the yarn twist and density, optimized micro‐macro hierarchical channels can be created in the SSG to provide sufficient water supplementation and continuous steam generation. Due to the Marangoni effect introduced by the temperature gradient along the yarns water with high salinity transports to the bulk water, realizing a salt‐rejecting property. As a result, the SSG demonstrates a rapid evaporation rate of 1.408 kg m−2 h−1 and energy efficiency of 92.43% under 1 sun, as well as outstanding stability for desalination of high salinity brine (10 wt% NaCl). Furthermore, this strategy provides a new solution to achieve excellent cost‐effectiveness in clean water production at ≈1700 g h−1 $−1. This work provides a sustainable fabric‐based SSG for practical large‐scale clean water production, and can potentially inspire other textiles‐based water treatment.

Deciphering the Kinetics of Spontaneous Generation of H2O2 in Individual Water Microdroplets.

Spontaneous generation of H2O2 in sub-10 μm-sized water microdroplets has received increasing interest since its first discovery in 2019. On the other hand, due to the short lifetime of these microdroplets (rapid evaporation) and lack of suitable tools to real-time monitor the generation of H2O2 in individual microdroplets, such a seemingly thermodynamically unfavorable process has also raised vigorous debates on the origin of H2O2 and the underlying mechanism. Herein, we prepared water microdroplets with a long lifetime (>1 h) by virtue of microwell confinement and dynamically monitored the spontaneous generation of H2O2 in individual microdroplets via time-lapsed fluorescence imaging. It was unveiled that H2O2 was continuously generated in the as-prepared water microdroplets and an apparent equilibrium concentration of ∼3 μM of H2O2 in the presence of a H2O2-consuming reaction can be obtained. Through engineering the geometry of these microdroplets, we further revealed that the generation rates of H2O2 in individual microdroplets were positively proportional to their surface-to-volume ratios. This also allowed us to extract a maximal H2O2 generation rate of 7.7 nmol m-2 min-1 in the presence of a H2O2-consuming reaction and derive the corresponding probability of spontaneous conversion of interfacial H2O into H2O2 for the first time, that is, ∼1 of 65,000 water molecules in 1 s. These findings delivered strong evidence that the spontaneous generation of H2O2 indeed occurs at the surface of microdroplets and provided us with an important starting point to further enhance the yield of H2O2 in water microdroplets for future applications.

Biphenyl-rGO composite room temperature gas sensor for enhanced amine sensing

Amines, which are classified as volatile organic compounds (VOCs), serve a variety of purposes in the fields of environmental monitoring, food safety, and healthcare diagnosis. The present technique for detecting amine levels involves sophisticated setups and bulky equipment. Here. In this study, a chemoresistive gas sensor is developed that is cost-effective and easy to operate at room temperature (RT). The sensor is designed specifically for the detection of Ammonia, dimethylamine (DMA), trimethylamine (TMA), and total volatile basic nitrogen (TVB-N). Using biphenyl-reduced graphene oxide (B-rGO) composite gas sensors effectively addresses the issues of low sensitivity-selectivity and long-term instability commonly observed in conventional amine sensors. B-rGO sensor produced sensitivity of ∼3500 and selectivity above 30 for TVB-N sensing. The sensor is stable for temperature fluctuations below 50 °C and shows stable sensing response for period of over 3 months. A Chemoresistive B-rGO sensor was developed using an ultrasonic spray deposition system with optimized flow rate of 50 mL/h. Rapid evaporation of solvent using hot plate has resulted in unique morphology for B-rGO film sensors. The highest sensitivity, ∼836, is obtained for 100 ppm of ammonia with ammonia > DMA > TMA as a sensitivity order. B-rGO showed almost seven times higher amine sensitivity than rGO which highlights the importance of biphenyl in the B-rGO composite. Sensor calibration curve has been presented in the study to understand change in the sensitivity of sensor with increasing analyte gas concentration. The calibration curve has an average R-squared value of 0.98.

The Yin and Yang of non-immune and immune responses in meibomian gland dysfunction

Meibomian gland dysfunction (MGD) is a leading cause of dry eye disease and one of the most common ophthalmic conditions encountered in eye clinics worldwide. These holocrine glands are situated in the eyelid, where they produce specialized lipids, or meibum, needed to lubricate the eye surface and slow tear film evaporation – functions which are critical to preserving high-resolution vision. MGD results in tear instability, rapid tear evaporation, changes in local microflora, and dry eye disease, amongst other pathological entities. While studies identifying the mechanisms of MGD have generally focused on gland obstruction, we now know that age is a major risk factor for MGD that is associated with abnormal cell differentiation and renewal. It is also now appreciated that immune-inflammatory disorders, such as certain autoimmune diseases and atopy, may trigger MGD, as demonstrated through a T cell-driven neutrophil response. Here, we independently discuss the underlying roles of gland and immune related factors in MGD, as well as the integration of these two distinct mechanisms into a unified perspective that may aid future studies. From this unique standpoint, we propose a revised model in which glandular dysfunction and immunopathogenic pathways are not primary versus secondary contributors in MGD, but are fluid, interactive, and dynamic, which we likened to the Yin and Yang of MGD.

Human robotic surgery with intraoperative tissue identification using rapid evaporation ionisation mass spectrometry

Instantaneous, continuous, and reliable information on the molecular biology of surgical target tissue could significantly contribute to the precision, safety, and speed of the intervention. In this work, we introduced a methodology for chemical tissue identification in robotic surgery using rapid evaporative ionisation mass spectrometry. We developed a surgical aerosol evacuation system that is compatible with a robotic platform enabling consistent intraoperative sample collection and assessed the feasibility of this platform during head and neck surgical cases, using two different surgical energy devices. Our data showed specific, characteristic lipid profiles associated with the tissue type including various ceramides, glycerophospholipids, and glycerolipids, as well as different ion formation mechanisms based on the energy device used. This platform allows continuous and accurate intraoperative mass spectrometry-based identification of ablated/resected tissue and in combination with robotic registration of images, time, and anatomical positions can improve the current robot-assisted surgical platforms and guide surgical strategy.

Evaluation of Lipid Oxidation Characteristics in Salmon after Simulation of Cold Chain Interruption Using Rapid Evaporation Ionization Mass Spectrometry.

Temperature fluctuations occurring during the cold chain logistics of salmon contribute to lipid oxidation. This study aimed to simulate cold chain interruption through freeze-thaw operations and evaluate the lipidomics data from salmon samples subjected to different numbers of freeze-thaw cycles by using rapid evaporative ionization mass spectrometry (REIMS) combined with an intelligent surgical knife (iKnife). The results indicated significant differences in the relative abundance of characteristic ions among the samples (p < 0.05). A total of 34 ions with variable importance for the projection values ≥1 were identified as potential biomarkers, including m/z 719.4233 ([PCC36:5-NH(CH3)3]-), m/z 337.3134 ([FAC22:1]-), m/z 720.4666 ([PEC35:6-H]-), m/z 309.2780 ([FAC20:1]-), m/z 777.4985 ([PCC40:4-NH(CH3)3]-), m/z 745.4421 ([PCC38:6-NH(CH3)3]-/[PEC38:6-NH3]-), m/z 747.4665 ([PCC38:5-NH(CH3)3]-/[PEC38:5-NH3]-), etc. The degree of lipid oxidation was found to be associated with the number of freeze-thaw cycles, exhibiting the most significant alterations in the relative abundance of lipid ions in the 8T samples. Additionally, sensory evaluation by the CIE-L*a*b* method and volatile analysis by headspace solid-phase microextraction gas chromatography-mass spectrometry demonstrated significant differences (p < 0.05) in color and odor among the salmon samples, with a correlation to the number of freeze-thaw cycles. The primary compounds responsible for alterations in salmon odor were aldehydes with lower odor thresholds. In summary, the iKnife-REIMS method accurately differentiated salmon muscle tissues based on varying levels of lipid oxidation, thus expanding the application of REIMS.

Photothermally driven decoupling of gas evolution at the solid-liquid interface for boosted photocatalytic hydrogen production.

The slow mass transfer, especially the gas evolution process at the solid-liquid interface in photocatalytic water splitting, restricts the overall efficiency of the hydrogen evolution reaction. Here, we report a novel gas-solid photocatalytic reaction system by decoupling hydrogen generation from a traditional solid-liquid interface. The success relies on annealing commercial melamine sponge (AMS) for effective photothermal conversion that leads to rapid water evaporation. The vapor flows towards the photocatalyst covering the surface of the AMS and is split by the catalyst therein. This liquid-gas/gas-solid coupling system avoids the formation of photocatalytic bubbles at the solid-liquid interface, leading to significantly improved mass transfer and conversion. Utilizing CdS nanorods anchored by highly dispersed nickel atoms/clusters as a model photocatalyst, the highest hydrogen evolution rate from water splitting reaches 686.39 μmol h-1, which is 5.31 times that of the traditional solid-liquid-gas triphase system. The solar-to-hydrogen (STH) efficiency can be up to 2.06%. This study provides a new idea for the design and construction of efficient practical photocatalytic systems.

Optical parameters extraction of zinc oxide thin films doped with manganese using an innovative technique based on the dragonfly algorithm and their correlation to the structural properties

Pure zinc oxide (ZnO) thin films, along with manganese (Mn) doped counterparts, were produced using rapid thermal evaporation technique on ordinary glass substrates. Postannealing treatments resulted in the formation of hexagonal wurtzite structures in the deposited layers. The Raman results unveiled the presence of A1(LO) and LVM vibration modes in each sample that were doped. Interestingly, the undoped sample lacked the LVM mode while showcasing the emergence of LA + TO combined phonons. Employing a novel approach reliant on the Dragonfly Algorithm, optical parameters were extracted, revealing a drop in the bandgap energy of the films from 3.95 eV to 3.79 eV.

Impact of spray interaction on ammonia/diesel dual-fuel combustion and emission under engine relevant conditions

This study investigates the combustion characteristics of ammonia and diesel sprays in a constant-volume vessel under conditions typical of internal combustion engines, focusing on the interplay between evaporation dynamics and flame interactions within the framework of the Direct Dual Fuel Stratification (DDFS) concept. Under non-evaporation conditions, ammonia and diesel sprays exhibit comparable evaporation profiles, but under evaporation scenarios, ammonia’s higher evaporation rate results in faster mixing with ambient gas than diesel despite the similar liquid penetration lengths of these two fuels. By utilizing meticulously designed arrangements of diesel and ammonia spray injectors, two distinct interaction scenarios between diesel spray and ammonia spray, early and late interaction, are explored. In the early interaction scenario, fuel-rich ammonia-air mixtures ignite directly by the diesel flame, achieving self-sustained propagation and significant heat release, thereby maintaining a high-temperature region for continuous combustion. Conversely, in late interaction scenarios, rapid ammonia evaporation leads to a fuel-lean ammonia/air mixture that cannot be ignited by the diesel flame, eventually leading to ammonia flame extinction. The study reveals that NOx and N2O emissions are sensitive to the diesel/ammonia flame interaction. N2O emissions, formed predominantly at the forefront of the quenching ammonia flame, pose a significant challenge due to the fast evaporation rate and slow oxidation rate in fuel-lean mixtures. These findings provide insights into the physics of ammonia–diesel combustion, highlighting the challenges and potential strategies for efficient and clean combustion in ammonia-fueled DDFS engines.

A cationic radical metal–organic framework enabling low water evaporation enthalpy and high photothermal conversion efficiency for solar-driven water purification

An innovative solar evaporator, combining Cu foam with a cationic radical MOF (PFC-771) as the photothermal absorber, demonstrates rapid and efficient solar energy-driven water evaporation.

Chemical Composition and Antimicrobial Activity of Essential Oils from Horse Chestnut Flowers

Essential oil of brown color was obtained by hydro-distillation from fresh flowers of horse chestnut. All major components of the corresponding oils were identified by gas chromatography-mass spectrometry. The microorganisms most sensitive to the studied essential oil of flowers were revealed: Staphylococcus aureus, Serratia marcescens, and Bacillus subtilis. Extensive documentation on the antimicrobial properties of essential oils and their constituents has been carried out by several workers. Although the mechanism of action of a few essential oil components has been elucidated in many pioneering works in the past, detailed knowledge of most of the compounds and their mechanism of action is still lacking. This knowledge is particularly important for the determination of the effect of essential oils on different microorganisms, how they work in combination with other antimicrobial compounds, and their interaction with food matrix components. Also, recent studies have demonstrated that nanoparticles (NPs) functionalized with essential oils have significant antimicrobial potential against multidrug-resistant pathogens due to an increase in chemical stability and solubility, decreased rapid evaporation and minimized degradation of active essential oil components.