Rapid Evaporation Research Articles

High Performance Solar-Driven Power-Water Cogeneration for Practical Application: From Micro/Nano Materials to Beyond.

Solar-driven water-electricity cogeneration is a promising strategy for tackling water scarcity and power shortages. However, comprehensive reviews on performance, scalability, commercialization, and power density are lacking. This Perspective presents an overview of recent developments and insights into the challenges and future outlooks for practical applications in this area. We summarize recent advances in high-efficiency water production, focusing on rapid evaporation and condensation. Then we categorize power-water cogeneration systems by power generation mechanisms like steam, evaporation, salinity gradient, photovoltaics, and temperature gradient, providing a comprehensive summary of the performance and applicability of these systems in different scenarios. Finally, we highlight challenges in current systems, considering nanoscale mechanisms and large-scale manufacturing, while also exploring potential trends for future practical applications.

Estimation of Friction for a Hydrodynamic Sliding Bearing for the Turbulent Regime From Single-Phase and Two-Phase Fluid Flow Behaviour

The hydrodynamic plain bearing relies on the generation of a lubricant film through the rotational movement of the journal. As the journal rotates, it creates a layer of lubricant between the bearing and journal surfaces. This lubricant film separates the two surfaces, preventing direct contact and minimizing friction and wear. The high speeds can lead to severe conditions such as cavitation due to rapid oil evaporation, which introduces a new phase into the flow. In this study, it is anticipated that a two-phase flow will occur through the shaft-bushing conjunction because of the rupture of the lubricating film near the contact outlet. Pressure disturbances above these rupture zones may induce vapor-cavity formation at a small scale. A numerical analysis was conducted by solving Navier–Stokes continuity equations and vapor-transport equations. The k-epsilon model was used to analyze friction at the fluid-bearing interface for the turbulent regime. The results indicate that higher flow velocity values and pressure were observed in the case of two-phase flow compared to one-phase flow.

Comparative performance investigation of conventional and modified stepped basin pyramid solar still with improved insulation: Experimental evaluation

This study focuses on modifying the insulation of a stepped basin pyramid solar still (SBPSS). The modified SBPSS with both side insulation and the conventional SBPSS with one side insulation of the base were compared in terms of basin and basin water temperature, freshwater output, energy and exergy efficiency, payback period, and production cost. The research was carried out on two identical SBPSSs, where 0.25 m2 was the evaporation area for each case. In modified SBPSS, the insulation on both sides of the base significantly reduced heat loss, which was justified by the higher basin and basin water temperatures than conventional SBPSS. The maximum basin temperatures for conventional and modified SBPSSs were 50.49 °C and 53.74 °C, respectively, with maximum basin water temperatures of 47.21 °C and 52.86 °C. The modified SBPSS provided more freshwater (1.24 L/m2) than conventional SBPSS (0.93 L/m2) as a result of the rapid evaporation rate caused by the higher basin water temperature. For conventional and modified SBPSSs, the average energy efficiency was 22.33 % and 27.51 %, respectively, and the average exergy efficiency was 4.71 % and 6.90 %, respectively. The modified SBPSS provided freshwater at a 24.27 % lower price than the conventional SBPSS.

Solar evaporation of liquid marbles with Fe3O4/CNT hybrid nanostructures

HypothesisThrough the rational design of nanomaterial composites, broadband light harvesting and good thermal insulation can be achieved simultaneously to improve the efficiency of water evaporation. ExperimentSolar evaporation experiments were carried out on liquid marbles (LMs) coated with Fe3O4 nanoparticles, carbon nanotubes (CNTs) and hybrid nanomaterials (Fe3O4/CNTs) with different mass ratios of 2:1, 1:1 and 1:2. FindingThe results showed that the mixture of Fe3O4/CNTs enhances the light harvesting ability and solar interfacial evaporation performance. Fe3O4/CNT-LM at the mass ratio of 2:1 case provides the highest evaporation rate of 11.03 μg/s, which is about 1.22 and 1.34 times higher than that of Fe3O4 and CNT, respectively. This high performance is mainly due to the synergistic effect between Fe3O4 nanoparticles and CNTs, as the hybrid nanostructure significantly improves the both photothermal conversion and heat localization capability. Numerical simulation further supports that the composite can concentrate the electromagnetic field and heat at the phase-change interface. This leads to a rapid evaporation of the boundary region. This study provides a novel approach to a three-dimensional interface by assembling nanomaterials on the drop surface to enhance evaporation, which may have far-reaching implications for seawater desalination.

Sweat Gland‐Like Fabric for Personal Thermal‐Wet Comfort Management

AbstractThe sweat evaporation strategy has shown great potential for passive cooling of the human body. However, the accumulation of sweat at the skin resulting from the hindrance by traditional fabrics increases the heat load and causes the clothing to stick to the skin. Sweat evaporation cooling textiles that perform the sweat‐wicking function of sweat glands are thus highly desirable. Here, a sweat gland‐like (Sg‐like) fabric is proposed for personal thermal‐wet comfort management. The Sg‐like channels formed in the fabric through spraying and ultrasonic welding processes can pull liquid water from the skin and spread it out over the outer layer of the fabric for rapid evaporation. The Sg‐like design principle is also well‐validated based on colored fabrics. In artificial sweating skin demonstrations, the temperature of skin covered with the Sg‐like fabric is comparable to that of bare skin and lower than that of skin covered with commercial textiles. In human body tests, a temperature reduction of ≈2 °C is observed in sweating for skin coated with the Sg‐like fabric compare with skin‐coated cotton. It is expected this work offers promising guidelines for developing a sweat‐evaporation cooling textile to meet the thermal‐wet comfort requirements of the human body.

Facile synthesis of carbon black and sodium alginate based particles system for efficient solar desalination of highly concentrated brine

Interfacial solar desalination of seawater/wastewater is one of the most promising strategies to mitigate the crisis of freshwater shortage. Tremendous progress on improving the evaporation rate has been achieved over the past ten years, however, with the rapid evaporation at the interfacial region of water and air, salt simultaneously aggregates on the solar absorbers, reducing the stability of the evaporative performance. It is essential to design salt-resistant solar evaporators, especially for dealing with highly concentrated brine, in which salt clogging is more likely to occur. Here, we demonstrate a facile and scalable synthesis of self-cleaning particles system by coating carbon black (CB) onto expanded polystyrene (EPS), which can generate freshwater from high salinity brine. With sodium alginate (SA) as a binder, the EPS core-CB shell particles are fabricated by a simple ‘rolling rice dumpling’ strategy. These particles spontaneously gather to a system in water attributing to the surface tension, which function coordinatively to realize the self-cleaning process through rotating ascribed to the unbalanced force after salt crystallization. Benefiting from the low cost of materials, facile synthesis procedure, and good performance in high salinity water, our EPS-CB particles system opens up an avenue for the practical applications of interfacial solar desalination.

Design of MOF-Based Solar Evaporators with Hierarchical Microporous/Nanobridged/Nanogranular Structures for Rapid Interfacial Solar Evaporation and Fresh Water Collection.

Interfacial solar evaporation (ISE) holds considerable promise to solve fresh water shortage, but it is challenging to achieve high evaporation rate (Reva) and fresh water yield in close system. Here, we report design and preparation of MOF-based solar evaporators with hierarchical microporous/nanobridged/nanogranular structures for rapid ISE and fresh water collection in close system. The evaporators are fabricated by growing silicone nanofilaments with variable length as nanobridges on a microporous silicone sponge followed by grafting with polydopamine nanoparticles and Cu-MOF nanocrystals. Integration of the unique structure and excellent photothermal composites endows the evaporators with high Reva of 3.5-20 wt% brines (3.60-2.90 kg m-2 h-1 in open system and 2.38-1.44 kg m-2 h-1 in close system) under simulated 1 sun, high Reva under natural sunlight, excellent salt resistance and high fresh water yield, which surpass most state-of-the-art evaporators. Moreover, when combined with a superhydrophilic cover, the evaporators show much higher average Reva of real seawater, remarkable fresh water yield and excellent long-term stability over one month continuous ISE under natural sunlight. The findings here will promote the development of advanced evaporators via microstructure engineering and their real-world ISE applications.

Effect of inlet diameter on the flow structure and performance for aluminum-based water-jet engine

Abstract In this study, the flow field and performance for the aluminum based water ramjet was analyzed through numerical simulation. The time decrease in evaporation heat absorption process expands the range of aluminum/water combustion and increase the specific impulse. If the diameter of atomized water droplets from the primary inlet is large, the evaporation efficiency will be further reduced, which is not conducive to the further propagation of the reaction. However, if the diameter is small, the flow field temperature will be rapidly dropped due to rapid evaporation, and a large range of low-temperature areas will appear in the reaction area of the combustor. The diameter reduction of atomized water droplets from the secondary water inlet is conducive to the diffusion of the reaction area downstream, further and makes the combustion range be expanded. This effect is benefit for increasing the specific impulse and can reduce the temperature near the wall.

Physics Of Two-Stage Evaporation Of Volatile Droplets Suspended In An Ultrasonic Levitator

The evaporation process of mono-component droplets in an ultrasonic levitator is experimentally monitored, focusing on three types of volatile liquids: methanol, ethanol, and 2-propanol. This investigation reveals a ‘two-stage’ evaporation process characterized by an initial rapid evaporation stage followed by a significantly slower evaporation stage; a pattern consistently observed across all three volatile liquids. However, for droplets of comparable size, methanol droplets evaporate faster in the rapid stage than ethanol and iso-propanol droplets and enter the slow evaporation stage earlier. On the other hand, during the slow evaporation stage, 2-propanol droplets exhibit the lowest evaporation rate compared to methanol and ethanol droplets. To explain the two-stage evaporation and the varying evaporation characteristics of mono-component droplets with different volatile components, the streaming patterns within the levitator, with and without a suspended droplet, are visualized and quantified using Particle Imaging Velocimetry (PIV). Two acoustic-induced jet flows, originating from the transducer and reflector of the levitator and considered as Eckart streaming, are observed within the empty levitator. These jet flows move toward the levitated droplet, influencing its evaporation process. Additionally, Stefan flow, carrying vapor away from the surface of the volatile droplet, is clearly observed due to rapid evaporation. The competition between Stefan flow and Eckart streaming ultimately determines the external streaming patterns around the investigated droplets. A theory combining the external streaming patterns and vapor enrichment is proposed to interpret the two-stage evaporation and the corresponding characteristics of the evaporating droplets suspended in the levitator. Furthermore, this study captures boundary-driven acoustic streaming near the droplet surface, known as Rayleigh–Schlichting streaming, whose dimensions and motion vary with the different liquid components and the properties of the corresponding vapor. In summary, the study highlights the presence of Eckart streaming in the ultrasonic levitator and Stefan flow outside an evaporating volatile droplet. Considering these flow patterns is essential for explaining the ‘two-stage’ evaporation and the relevant characteristics within the ultrasonic levitator.

TO HIGHLY PRODUCTIVE SYNTHESIS OF ALUMINUM NANOPARTICLES IN PLASMA FLOW AT ATMOSPHERIC PRESSURE

Purpose. To study the highly productive evaporation of aluminum micron powder in an atmospheric pressure plasma jet for the synthesis of nanoaluminum. Using special plasma technology, nanoparticles can be produced by rapid melting and evaporation of the initial micrometer particles and their subsequent re-nucleation. Research methods. Methods of mathematical and computer modeling of subsonic plasma turbulent jets at atmospheric pressure and experimental studies of two-phase processes during thermal plasma treatment using an arc plasma torch. Results. Based on computer modeling, a special reactor system was designed and developed, which includes a plasma-jet reactor with an electric arc plasma torch for the synthesis of aluminum nanoparticles. Numerical modeling makes it possible to determine the position of the melting point, evaporation and crushing of a molten particle, the evolution of the fractional composition of the dispersed phase, and find the speed and temperature of the particle in the area from its melting point to the crushing point. An experimental test of the operation of the reactor system was carried out using arc plasma torches with a power of 30 and 150 kW. It has been shown that intensifying the fragmentation of dispersed raw materials in a plasma jet can be useful in technologies for producing nanomaterials. The consequence of the fragmentation process is the redistribution of the fractional composition of the powder along the plasma jet and the accompanying changes in the dynamics of movement, heating and evaporation of particles. It has been determined that when the temperature of the largest aluminum particles reaches 2500 C, the total amount of evaporated mass is theoretically equal to 100%. The main parameters influencing the behavior of particles in a plasma jet are particle diameter, powder injection rate, flow rate, temperature and composition of the plasma gas. Taking these parameters into account will allow the process to operate at increased productivity. Scientific novelty. A mathematical description of the process of fragmentation a polydisperse powder, based on a continuum approach, has been obtained, which makes it possible to determine the position of the crushing point of a molten particle, the fractional composition of the dispersed phase, and find the speed and temperature of the particle in the area from its melting point to the point of crushing and evaporation. It was shown for the first time that it is possible to carry out a process in which complete evaporation of a molten drop is achieved due to the high enthalpy of the plasma before the end of mixing with steam. Practical value. A special reactor system has been designed and developed, which includes a plasma-jet reactor with an electric arc plasmatron for the synthesis of aluminum nanoparticles. The operating parameters of the reactor system have been determined, which will allow the synthesis of aluminum nanoparticles to be carried out with high productivity.

Polymer crystallization and optical birefringence modulated by solvent evaporation in sessile droplets

Solvent evaporation is a dynamic process associated with mass transfer, heat exchange and complex internal flow. Their complicated effects on crystallization remain unclear in evaporating sessile droplets. Here, we study crystallization in evaporating poly(ethylene oxide) (PEO) sessile droplets and obtain three kinds of spherulites with monochromatic, anisotropic or negative birefringence. Monochromatic spherulites are generated at very slow solvent evaporation and low molecular weight, while high anisotropic spherulites are created under flow field at rapid solvent evaporation and large molecular weight. Ordinary negative spherulites appear at intermediate conditions. The temperature variation is verified during solvent evaporation, but plays an insignificant thermodynamic effect on crystallization. The experimental findings are further validated in different solvents and polymer systems. This work establishes the relationship between solvent evaporation and polymer crystallization in sessile droplets and also provides a guideline for modulating optical properties of deposited films using droplet processing techniques.

Nanocluster-agminated amorphous cobalt nanofilms for highly selective electroreduction of nitrate to ammonia

Developing highly-efficient electrocatalysts for the nitrate reduction reaction (NITRR) is a persistent challenge. Here, we present the successful synthesis of 14 amorphous/low crystallinity metal nanofilms on three-dimensional carbon fibers (M-NFs/CP), including Al, Ti, Mn, Fe, Co, Ni, Cu, Zn, Ag, In, Sn, Pb, Au, or Bi, using rapid thermal evaporation. Among these samples, our study identifies the amorphous Co nanofilm with fine agglomerated Co clusters as the optimal electrocatalyst for NITRR in a neutral medium. The resulting Co-NFs/CP exhibits a remarkable Faradaic efficiency (FENH3) of 91.15 % at − 0.9 V vs RHE, surpassing commercial Co foil (39 %) and Co powder (20 %), despite sharing the same metal composition. Furthermore, during the electrochemical NITRR, the key intermediates on the surface of the Co-NFs/CP catalyst were detected by in situ Fourier-transform infrared (FTIR) spectroscopy, and the possible reaction ways were probed by Density functional theory (DFT) calculations. Theoretical calculations illustrate that the abundant low-coordinate Co atoms of Co-NFs/CP could enhances the adsorption of *NO3 intermediates compared to crystalline Co. Additionally, the amorphous Co structure lowers the energy barrier for the rate-determining step (*NH2→*NH3). This work opens a new avenue for the controllable synthesis of amorphous/low crystallinity metal nano-catalysts for various electrocatalysis reaction applications.

Tree-inspired coir fiber-based array evaporator with rapid water transportation and effective solar water evaporation

Coconut husk as a raw material for the production of solar water evaporators has received considerable attention due to its abundance and availability. However, common treatment methods such as carbonization applied to capacitate the coconut husks for photothermal conversion were not favor for realizing rapid evaporation, as they failed to exploit the original structure of coconut husks. Herein, coir fibers extracted from the coconut husks were directly supplied to the production of functionalized evaporators with carbon nanoparticle coating, which preserved the pristine structure of coir fibers and allowed them to rapidly transport water in multiple directions like trees. These fibers were further assembled into array evaporators to maximize their exposed surface area for efficient evaporation. As a result, the carbon-coated coir fiber array evaporator prepared in the present work showed the highest evaporation rate of 4.19 kg m-2h−1 during solar water evaporation experiments under 1.0 sun illumination. Our work presents an approach for achieving effective solar water evaporation based on carbon-coated coir fiber array evaporator with large exposed surface area and tree-inspired multidirectional fast water transportation.

In-flight iron ore reduction and nanoparticle formation in an atmospheric pressure hydrogen microwave plasma

The in-flight reduction of iron ore particles using an atmospheric pressure hydrogen plasma is investigated. Iron ore particles with a size less than 75 µm are aerosolized and carried with an argon-hydrogen (90%–10%) gas mixture through an atmospheric pressure microwave plasma. After the treatment, the collected particles are observed to follow three distinct populations: (i) fully reduced nanoparticles, (ii) partially reduced spheres, larger than the feedstock, and (iii) partially melted, partly reduced agglomerates. A model is developed to explain the possible mechanism for the origin of the three populations. The nanoparticles (i) are found to be likely formed from the previously evaporated material whereas the particles (ii) and (iii) result from the partial/complete melting of the particles and agglomerates flowing through the reactor. The gas temperature is estimated to be more than 2000 K, which enables the rapid melting, evaporation, and reduction of these particles within residence times of only a few 10 ms.

Highly Stable Heating Fibers of Ti3C2Tx MXene and Polyacrylonitrile via Synergistic Thermal Annealing.

Nanohybrid assemblies provide an effective platform for integrating the intrinsic properties of individual components into microscale fibers. In this study, a novel approach for creating mechanically and environmentally stable MXene fibers through the synergistic assembly of MXene and polyacrylonitrile (PAN), is introduced. Unlike fibers generated via a conventional stabilization process, which relies on air-based stabilization to transform the PAN molecules into ring structures fundamental to carbon fibers, the hybrid fibers are annealed in an Ar atmosphere. This unique approach suggests MXene can serve as an oxygen provider that is essential for stabilizing PAN. As a result, significantly improved interfiber compactness is achieved and the oxidation stability of MXene is enhanced under atmospheric conditions. The resulting fibers exhibit exceptional stability, even after extended exposure to high humidity and elevated temperatures. This highlights the suitability of the thermally annealed MXene-PAN (T-MX-PAN) fibers as robust electric heating elements. Notably, these fibers consistently generate heat over 1800 bending cycles. When integrated into fabrics, they demonstrate the capability to generate sufficient heat for melting ice and rapid evaporation. This study highlights the potential of T-MX-PAN fibers as next-generation wearable heaters and offers valuable insights into advancing wearable technology in demanding environments.

Contributions of microlayer to flow boiling heat transfer in the mini-channel

Flow boiling stands out as an efficient mode of heat transfer with significant potential for reducing carbon footprint. Based on a coupled Volume-of-Fluid and Level Set (VOSET) method, this numerical study reveals the microlayer and its evaporative heat flux distributions, as well as the effects of microlayer evaporation and depletion on bubble dynamic behavior, flow pattern, wall superheat distribution, and boiling crisis for the flow boiling in a mini-channel. These aspects are firstly comprehensively reported by the numerical method. Results indicate that the rapid evaporation of a thin microlayer positioned beneath elongated bubbles significantly contributes to heat dissipation during flow boiling in a mini-channel. The heat flux through the microlayer surpasses 300 kW/m2, accounting for approximately 42% of heat dissipation at 200 kW/m2. Furthermore, this contribution increases to over 70% as the heat flux exceeds 500 kW/m2. As a result, in comparison to scenarios without microlayers, the presence of microlayers results in an average heat transfer coefficient (HTC) that is 3.97 times larger within the range of 200–500 kW/m2. Additionally, microlayer evaporation delays the happening of flow boiling crisis. Without microlayers, the wall superheat exceeds 180 K at 500 kW/m2, whereas under microlayer influence, the maximum local wall superheat is only 37.09 K at 1000 kW/m2. With further increases in heat flux, the emergence of large dry patches resulting from microlayer depletion induces the beginning of heat transfer deterioration. Finally, the ongoing coalescence of elongated bubbles necessitates a prolonged period for rewetting dry patches at the exit of the mini-channel, triggering the flow boiling crisis at 1300 kW/m2. The study results provide crucial guidance for the development and application of the flow boiling heat transfer technology for the thermal management of data centers.

The Preparation of Crumpled Graphene Oxide Balls and Research in Tribological Properties.

In this study, crumpled graphene oxide balls (CGBs) were prepared via capillary compression using a rapidly evaporating aerosol droplet method. The CGBs were observed using scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and Raman spectroscopy. The size distributions of crumpled particles were obtained using a laser nanometer particle size analyzer (DLS). The dispersibility of the water and the ionic liquid (IL) was tested by ultrasonic dispersion. The tribological properties of water or ionic liquids containing crumpled graphene oxide ball additives (W/IL-CGB) were tested by a reciprocating friction tester and compared with water/ionic liquids with graphene oxide. The morphology of the wear scar was observed by a three-dimensional optical microscope and its lubrication mechanism was analyzed. The results show that the CGBs were successfully prepared by rapid evaporation of aerosol droplets, and the obtained CGBs were crumpled paper spheres. The CGBs had good water dispersion and ionic liquid dispersion, and IL-CGB has excellent anti-friction and anti-wear effects on steel-steel friction pairs. During the friction process, the CGB was adsorbed at the interface of the steel-steel friction pair to form a protective layer, which avoids the direct contact of the friction pair, thereby reducing friction and wear.

Non-destructive strategy to extract sustainable helix and high-strength Musa core fibers for rapid water conduction and evaporation

The reuse and development of natural waste resources is a hotspots and challenges in the research of new fiber materials and the resolution of environmental concern globally. Herein, this study aimed to develop a simple and direct manual extraction process to extract Musa core fibers (MCFs) for rapid water conduction and evaporation. Through simple processes such as ring cutting and stretching, this green and non-destructive inside-out extraction strategy enabled Musa fibers to be naturally and harmlessly degummed from natural Musa stems, with good maintenance of the fiber structure and highly helical morphology. The extracted fibers are composed of regularly and closely arranged cellulose nanofibrils in the shape of ribbon spirally arranged multi-filaments, and the single filament is about 2.65 μm. The high-purity fibers exhibit ultra-high tensile strength under a non-destructive extraction process, and the ultimate tensile strength in dry state is as high as 742.95 MPa. The tensile strength is affected by the number of fiber bundles, which shows that tensile strength and tensile modulus is higher than those of vascular bundle fibers in dry or wet condition. In addition, the MCFs membrane indicates good water conductivity, with a water absorption height of 50 mm for the sample in only 60 s. Moreover, the water evaporation rate of MCFs reaches 1.37 kg m−2 h−1 in 30 min, which shows that MCFs have excellent water conductivity and evaporation rate compared with ordinary cotton fibers. These results indicate that MCFs have great potential in replacing the use of chemical methods to extract fibers from vascular bundles, providing an effective way to achieve sustainability in quick-drying applications, as well as in the sustainable development of natural waste resources.

Recent Advances in High-Rate Solar-Driven Interfacial Evaporation.

Recent advances in solar-driven interfacial evaporation (SDIE) have led to high evaporation rates that open promising avenues for practical utilization in freshwater production and industrial application for pollutant and nutrient concentration, and resource recovery. Breakthroughs in overcoming the theoretical limitation of 2D interfacial evaporation have allowed for developing systems with high evaporation rates. This study presents a comprehensive review of various evaporator designs that have achieved pure evaporation rates beyond 4kgm-2h-1, including structural and material designs allowing for rapid evaporation, passive 3D designs, and systems coupled with alternative energy sources of wind and joule heating. The operational mechanisms for each design are outlined together with discussion on the current benefits and areas for improvement. The overarching challenges encountered by SDIE concerning the feasibility of direct integration into contemporary practical settings are assessed, and issues relating to sustaining elevated evaporation rates under diverse environmental conditions are addressed.

Ultra-long room temperature phosphorescence, intrinsic mechanisms and application based on host-guest doping systems

To construct efficient room-temperature phosphorescence (RTP) doping systems by simple doping methods, isomers 2-(2-(9H-carbazol-9-yl)benzyl)malononitrile (o-CzCN), 2-(3-(9H-carbazol-9-yl)benzyl)malononitrile (m-CzCN) and 2-(4-(9H-carbazol-9-yl)benzyl)malononitrile (p-CzCN) were designed and synthesized by choosing commercial carbazole. Based on the structure-function relationships of three isomers and excellent compatibility between carbazole and benzocarbazole, 2-(3-(9H-carbazol-9-yl)benzyl)malononitrile (Lm-CzCN) and 2-(3-(5H-benzo[b]carbazol-5-yl)benzyl)malononitrile (m-BCzCN) were prepared by self-made carbazole and 2-naphthylamine. Then, Lm-CzCN/m-BCzCN was constructed and optimized by dissolution and rapid evaporation, as well as tuning the mass ratios between Lm-CzCN and m-BCzCN. Lm-CzCN shows excitation dependent RTP and afterglow lifetimes, as well as concentration dependent RTP emission in poly(vinyl alcohol) (PVA) films, while 1% m-BCzCN@PVA film emits bright green afterglow, with RTP and afterglow lifetimes of 2.303 and 17 s in turn, as well as RTP quantum yield of 0.22. More importantly, Lm-CzCN/m-BCzCN presents ultra-long room temperature phosphorescence, with RTP and afterglow lifetimes of 597.58 ms and 8 s, respectively. Moreover, crystals m-CzCN and p-CzCN, as well as Lm-CzCN/m-BCzCN can be excited by visible light of 440 nm, showing yellow afterglow of 1–4 s. Noteworthy, polymorphism o-CzCNY and o-CzCNB were found, whose different emission was investigated by molecular conformation, intermolecular arrangement and stacking patterns. Finally, multiple encryptions were successfully constructed based on the different luminescent properties.