Radio Frequency Ion Research Articles

Modelling the effect of deposited grid material on the power coupling of radio frequency ion thrusters

For radio-frequency(RF) ion thrusters, under nominal operating conditions, sputtering of the screen grid can lead to the formation of a conductive film of the grid material on the inner walls of the discharge chamber which leads to a decrease in RF coupling to the plasma. When the ion beam becomes unfocused, either due to off nominal operating conditions or as a result of lifetime degradation, this process can be accelerated. An RF ion thruster performance model is developed, which can quantitatively simulate the performance degradation caused by sputter deposition on the thruster. This model couples an RF power transmission model, a zero-dimensional thruster discharge chamber model, and a sputter deposition model. An experiment that intentionally enhances the erosion of the accelerator grid to accelerate the formation of the conductive film confirms the power transmission process described by the model. As a result, the deposition on the discharge chamber walls primarily originates from the sputtering of the accelerator grid by the ion beam. At a xenon flow rate of 0.63 sccm and RF power of 42 W, a 2.015 μm copper film deposited on the walls resulting in a decrease in thruster screen grid current. The simulated results indicate that the power absorbed by the plasma decreases after deposition, which is the primary cause of the screen grid current reduction. Using materials with low conductivity for the deposition layer in the construction of the accelerator grids can reduce the impact of the deposition layer on the thruster screen grid current.

Performance of radio frequency ion thruster with polytetrafluoroethylene propellant embedded in discharge chamber

Abstract Exploring solid propellants for electric thrusters can simplify the propellant storage and supply units in propulsion systems. In this study, polytetrafluoroethylene (PTFE), commonly used as a propellant in pulsed plasma thrusters, was embedded in the discharge chamber of a radio frequency ion thruster (RIT-4) to investigate the performance of an ablation-type RIT. Experimental results indicate that PTFE can decompose and ionize stably under plasma ablation within the discharge chamber, producing –C–F– and F– ion clusters that form a stable plasma. By adjusting the length of the PTFE propellant, it was observed that its decomposition rate influences the ion beam current of the thruster. Compared with xenon, PTFE generates an ion plume with a larger divergence angle, ranging from 16.05° to 22.74° at an ion beam current of 25 mA, with a floating potential distribution of 8 V to 56 V. Assuming that the proportion of neutral gas in the vacuum chamber matches the ion species ratio in the ion plume, thrust, specific impulse and efficiency parameters were calculated for the RIT-4 with embedded PTFE. Under 50 W RF power, the thrust was approximately 1.02 mN, the specific impulse was around 1236 s and the power-to-thrust ratio was approximately 93.14 W/mN. All results indicate that PTFE is a viable propellant for RIT, but the key is to control the rate of decomposition.

Characterization of a radiofrequency storage ion source using numerical simulations

Abstract A radiofrequency ion source routinely employed for laboratory astrophysics and astrochemistry experiments designated as the storage ion source was characterized using numerical simulations. The present work focuses on optimizing the storage and extraction of ions of astrophysical relevance having the $m/z$ range $3-330$, which covers most of the molecular ions detected in the interstellar medium and circumstellar envelopes. The crucial parameters for the storage of ions: radiofrequency signal frequency, $f_{RF}$ and amplitude, $V_{RF}$ were optimized, and the range of radiofrequency parameters that can be used to store ions inside the source is presented. The lifetimes of ions inside the source were estimated for various radiofrequency parameters. The difference in the lifetimes of ions of different $m/z$ was explained based on the ions' thermalization characteristics and the source's effective potential. The extraction of ions from the source was optimized, and a new design called the T-source was proposed to improve the extraction efficiency. We show that the T-source has better extraction efficiency than the original design, which is further enhanced by maintaining the source at a floating potential. Finally, we investigated the transmission characteristics of the extracted ions through a quadrupole ion guide, which may serve as an ion guide or a mass filter, leading to an ion storage device such as an ion trap or an ion storage ring.

Effect of Ion-Assisted Deposition Energy of RF Source on Optical Properties, Microstructure, and Residual Stress of HfO2 Thin Films

HfO2 thin films were prepared using radio frequency (RF) ion source-assisted deposition, and the effects of auxiliary ion energy on the microstructure, optical properties, and residual stress of the films were systematically studied. The experimental results showed that when the auxiliary ion energy increased, the extinction coefficient, compressive stress, and optical band gap were gradually increased. These changes were attributed to increased grain boundary defects, crystal structure disorder, and grain size decrease due to high-energy ion bombardment. The HfO2 films deposited at a lower ion energy (600 V) exhibited higher surface quality (RMS = 0.78 nm), better optical properties (k = 10⁻5), and lower residual stress (1.26 GPa).

Radio-frequency ion thruster with magnetic shielding of the discharge chamber walls

We presented the results of a computational study on optimizing the shape of the main elements of a radio-frequency ion thruster – the discharge chamber and the ion-extraction system grids. The possibility of improving the integral characteristics of thrusters and ion sources due to the use of an additional magnetostatic field in the RF discharge region was considered. The performed series of calculations made it possible to determine the optimal geometry of the discharge chamber and of the RIT ion-extraction system grids, as well as the configuration of the additional magnetic field, at which the best values of the integral characteristics were achieved.

Measurements of the Reaction Rate Coefficients of Atomic Hydrogen with Astrochemical Anions: CN− and C3N−

We present the temperature-dependent reaction rate coefficients of CN− and C3N− with atomic hydrogen in the temperature range from 7 to 290 K, measured in a 16-pole radio-frequency ion trap. The rate of C3N− with H steadily increases toward lower temperatures, while the rate coefficients for the CN− + H system show a sudden change around 160 K. Fits to the data were performed to determine temperature-dependent reaction rate coefficients. The fits reveal a rate coefficient of 4.1(3)×10−10(T/300)−0.31(6) cm3 s−1 for C3N− + H. For CN−, we determined a rate coefficient for the temperature regime below 160 K of 3.2(4)×10−10(T/300)−0.31(11) cm3 s−1. Given our present results, higher rate coefficients than previously reported must be assumed for the modeling of cold interstellar environments involving these H atom reactions.

Plasma discharge experiments of a Faraday shieldless driver for high-power and long-pulse radio frequency ion source for NBI application.

Due to the high stability and less maintenance, the radio frequency (RF) driven ion source is preferred for the neutral beam injection (NBI) system. In a popular design of the RF ion source for NBI application, a Faraday shield (FS) is installed inside the RF plasma driver to protect the discharge tube. However, the FS also brings some drawbacks, such as lowering the RF power transfer and increasing the processing difficulty. A prototype of the RF plasma driver without FS and with mature manufacturing technology has been developed by using a water-cooled discharge tube. After basic testing, this prototype was further tested under the RF plasma discharge experiments in views of high power, long pulse, and long term. The reliability and its plasma characteristics were the focus of these experiments, also for the hidden issues. The results show that the prototype could generate stable and high-density plasma without any damage or sputtering mark. An RF plasma discharge of 50 kW and 20s has been achieved. The expected frequency tuning was equally effective on the prototype. Moreover, compared to the RF plasma driver with FS, the prototype could produce higher electron density in the extraction region under the same RF power. Of course, some of the shortcomings of the prototype have also been exposed in the experiments and will be improved in subsequent experiments.

Investigation in improving the Cs-free negative hydrogen ion production with short-pulse low power in the afterglow of pulse-power-modulated plasma sources

Abstract Pulse plasma ion sources have been shown to be capable of achieving high negative hydrogen ion densities ( n H − ) or currents. The fast cooling of the electrons and reduction in the electron density (n e) provide favorable plasma conditions to improve the H− production, with a high density ratio of negative hydrogen ions to electrons during the pulse-off period. The purpose of this research is to further improve the performance of volume-produced H− ion sources based on the pulse power modulation. In this study, a time-modulated negative hydrogen plasma sustained by 10 kHz pulse power at the typical gas pressure of 0.3 Pa was numerically investigated using a global model. The model is compared with measurements obtained in a pulsed radio frequency ion source and shows a reasonable agreement. A steplike low-high power strategy in the active glow period and a short-pulse low power in part of the afterglow period are employed to mitigate overshoot of the electron temperature (T e) in the initial stage of the pulse period and to optimize H− production in the afterglow, respectively. The model predicts that a small-magnitude, short-duration low power operation in the afterglow increases n H − and decreases n e from the onset of the low power until the beginning of the next high power pulse, due to a modest temporary increase in the T e (less than 2 eV). It facilitates dissociative electron attachments and thus H− formation. The reduction in the n e indicates that positive ions lost to the walls cannot be compensated by weak ionization. H− production with a low number of co-extracted electrons can be optimized by adjusting the magnitude and duration of the low power in the afterglow.

Resolved-sideband cooling of a single Be+9 ion in a cryogenic multi-Penning-trap for discrete symmetry tests with (anti-)protons

Manipulating the motion of individual trapped ions at the single quantum level has become standard practice in radio-frequency ion traps, enabling sweeping advances in quantum information processing and precision metrology. The key step for motional-state engineering is ground-state cooling. Full motional control also bears great potential to explore another regime of sensitivities for fundamental physics tests in Penning traps. Here we demonstrate the key enabling step by implementing resolved-sideband cooling on the axial mode of a single Be+9 ion in a 5 Tesla cryogenic Penning trap. The system has been developed for the implementation of high-precision antimatter experiments to test the fundamental symmetries of the standard model with the highest accuracy in the baryonic sector. We measure an axial phonon number of n¯z=0.10(4) after cooling and demonstrate that the axial heating rate in our system is compatible with the implementation of quantum logic spectroscopy of (anti-)protons. Published by the American Physical Society 2024

Development and Evaluation of Ferrite Core Inductively Coupled Plasma Radio Frequency Ion Source for High-Current Ion Implanters in Semiconductor Applications.

This study presents the development of a ferrite core inductively coupled plasma (ICP) radio frequency (RF) ion source designed to improve the lifetime of ion sources in commercial ion implanters. Unlike existing DC methods, this novel approach aims to enhance the performance and lifetime of the ion source. We constructed a high-vacuum evaluation chamber to thoroughly examine RF ion source characteristics using a Langmuir probe. Comparative experiments assessed the extraction current of two upgraded ferrite core RF ion sources in a commercial ion implanter setting. Additionally, we tested the plasma lifetime of the ICP source and took temperature measurements of various components to verify the operational stability and efficiency of the innovative design. This study confirmed that the ICP RF ion source operated effectively under a high vacuum of 10-5 torr and in a high-voltage environment of 30 kV. We observed that the extraction current increased linearly with RF power. We also confirmed that BF3 gas, which presents challenging conditions, was stably ionized in the ICP RF ion sources.

Characteristics of inductively coupled plasma radio-frequency ion source of ion implanters for high number density dopant generation

In this study, we developed an inductively coupled plasma ion source that can be applied to implanters in semiconductor production. We employed an infrared camera and thermocouples to assess the temperature properties of the ion source operated at temperatures below 500 °C. This reduced temperature is expected to facilitate the adoption of various materials as the ion source. Ion densities of the direct current ion source measured using a double Langmuir probe were found to range from 1.66 × 1016 to 5.06 × 1016 m−3 within an input power range of 682–895 W. In contrast, the ion densities of a radio-frequency ion source ranged from 7.86 × 1016–9.58 × 1016 m−3 within an input power range of 700–900 W. This proposed ion source can serve as a next-generation solution because of its low operating temperature and high ion density.

Engineering design and manufacturing of a radio frequency plasma driver without Faraday shield for NBI application

A radio frequency (RF) driven ion source is favorable for high-power and long-pulse neutral beam injection (NBI) system. To reduce the damage caused by the isotropic heat and particle fluxes from the plasma, the traditional RF plasma driver of the NBI ion source introduces a Faraday shield (FS) for protection. However, the simulations and experiments show that the FS seriously affects the RF coupling and around 50 % of the input power deposits on the FS. The water-cooled discharge tubes with a double-layer ceramic structure have been developed to avoid using the FS structure. It's expected to improve the RF power transfer efficiency and to promote the development of high-power and long-pulse RF ion source. To verify the feasibility of the double-layer ceramic structure, the paper has carried out the fluid-thermal-structural coupling analysis and the fracture mechanical analysis on two proposed types: the alumina ceramic brazing structure and the silicon nitride ceramic bonding structure. The sample tests and the prototype manufacturing have been completed. Preliminary tests of the plasma discharge on the prototype of the alumina ceramic brazing structure have been launched. A plasma discharge of 30 kW and 20 s have been achieved.

Simple 3D PIC Analysis for Beam Phase Space Oscillation in RF Driven Negative Hydrogen Ion Source

Temporal oscillation of the negative hydrogen ion (H−) beam in the Radio Frequency (RF) ion source is investigated by a simple 3D3V Particle-In-Cell (PIC) model. The model solves electron, proton, and H− transport processes in the extraction region. The calculation domain is from the vicinity of the beam aperture to the ground electrode. To understand the relation between the plasma density oscillation and the extracted H− beam characteristics, the input electron and proton fluxes from the driver region are varied parametrically with the fundamental J-PARC RF frequency (2 MHz). The numerical results give an idea of the main physical processes between the oscillations of the plasma parameters and the extracted H− ion trajectories depending on the plasma meniscus shape in the different RF phases.

Development of a novel Internal Radio-frequency Ion Source for Cyclotrons (IRISC)

IRISC (Internal Radio-frequency Ion Source for Cyclotrons) is an innovative design of an internal ion source, primarily for producing H− ions, in which 2.45 GHz radio-frequency power is supplied to its electrodes for achieving electron emission. Theoretical work indicates that lower electrode sputtering and higher extraction efficiency of H− may be achieved as compared to its standard cold-cathode direct current (DC) Penning Ionization Gauge (PIG) counterparts. If achieved, IRISC would arise as a ground-breaking ion source with significant importance for compact cyclotrons. IRISC dimensions have been matched to CIEMAT’s AMIT cold-cathode DC PIG ion source so that, in the future, side-by-side testing can be carried out and, eventually, both types can be used in AMIT cyclotrons. This contribution presents IRISC key design aspects, outcome from simulations, its dedicated test bench and first low-power test results from a prototype.

Investigation of plasma chamber erosion in an RF ion source

Filament driven plasma sources are widely used to produce ion beams, but they require frequent maintenance due to the limited filament lifetime. External radio-frequency (RF) coupled ion source offers a filament-free plasma and hence better maintenance. However, one of the issues encountered during the development of a planar external RF-powered ion source at D-Pace was the erosion of its copper plasma chamber and subsequent formation of copper deposits on the Aluminum Nitride (AlN) RF window. The copper deposits on the RF window deteriorate the power coupling between the external antenna and the plasma. This paper investigates the erosion of the plasma chamber and describes some of the methods used to control the deposition of copper on the RF window.

Power transfer efficiency in an air-breathing radio frequency ion thruster

Abstract Due to a series of challenges such as low-orbit maintenance of satellites, the air-breathing electric propulsion has got widespread attention. Commonly, the radio frequency ion thruster is favored by low-orbit missions due to its high specific impulse and efficiency. In this paper, the power transfer efficiency of the radio frequency ion thruster with different gas composition is studied experimentally, which is obtained by measuring the radio frequency power and current of the antenna coil with and without discharge operation. The results show that increasing the turns of antenna coils can effectively improve the radio frequency power transfer efficiency, which is due to the improvement of Q factor. In pure N2 discharge, with the increase of radio frequency power, the radio frequency power transfer efficiency first rises rapidly and then exhibits a less steep increasing trend. The radio frequency power transfer efficiency increases with the increase of gas pressure at relatively high power, while declines rapidly at relatively low power. In N2/O2 discharge, increasing the N2 content at high power can improve the radio frequency power transfer efficiency, but the opposite was observed at low power. In order to give a better understanding of these trends, an analytic solution in limit cases is utilized, and a Langmuir probe was employed to measure the electron density. It is found that the evolution of radio frequency power transfer efficiency can be well explained by the variation of plasma resistance, which is related to the electron density and the effective electron collision frequency.

Particle-in-Cell simulation of radio-frequency ion thruster RIT-1.0

Ion propulsion systems with a small thrust can be used in space missions for highly accurate controllability while possessing low power and propellant consumption. At the University of Giessen, radio-frequency ion thrusters are miniaturized with thrusts in the order of micro-Newtons (μ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\mu$$\\end{document}N-RIT). As the size of the thruster becomes smaller the plasma properties can not be measured inside a closed plasma chamber. The simulations are needed to investigate plasma properties like temperature, density profile which would aid further opimization. In this work, we discuss kinetic simulations of plasma inside the RIT-1.0 thruster using in-house developed PlasmaPIC code that incorporates Monte-Carlo collisions (MCC) and Direct Simulation Monte Carlo (DSMC) for neutral gas distribution. We briefly present the features of PlasmaPIC and simulation of stable plasma generation. We also show the influence of neutral gas and extraction properties for the RIT-1.0 thruster under consideration.

Hydrogen Tag Shifts as Vibrational Reporters for Positional Isomers of Formylphenides: Surprising Mobility of the Carbanion Center upon Collisional Decarboxylation of the Parent Benzoates.

Infrared photodissociation of weakly bound "mass tags" is widely used to determine the structures of ions by analyzing their vibrational spectra. Molecular hydrogen is a common choice for tagging in cryogenic radio-frequency ion traps. Although the H2 molecules can introduce distortions in the target species, we demonstrate an advantage of H2 tagging in the analysis of positional isomers adopted by the molecular anions derived from decarboxylation of formylbenzoates. Attachment of H2 to the carbanion centers of three such isomers yields distinct shifts in the H2 stretch, which can be used to determine the distribution of isomers in an unknown sample. Electronic structure calculations indicate that the position-dependent shifts are due to different reactivities of the carbanion sites with respect to an intracluster proton-transfer reaction with the H2 molecule. We exploit this spectroscopic method to quantify the surprisingly facile migrations of the anionic center that have been previously reported for phenide rearrangements.

Experimental study of ion beam interaction with target surface aimed at developing a contactless method for space debris removal by an ion beam

Research and development in the field of space debris (SD) removal technologies is one of the most important and urgent tasks facing all spacefaring nations. By now, a large number of different concepts of removal have already been proposed. One of them is the SD removal by ion beam generated by an ion source installed on board a service spacecraft (SSC). A detailed understanding of the process of ion beam interaction with the SD surface is required to develop an optimal control algorithm for the virtual SSC-SD mated configuration in order to improve this method of SD removal. In addition, when designing the SSC, it is necessary to take into account back flows of the material sputtered from the surface of removed SD by the ion beam, which can contaminate the SSC operating surfaces during the removal maneuver. Within the framework of the presented work, experimental studies were performed to determine the coefficient of accommodation of the ion impulse during the ion beam interaction with the surface of the target simulating the external surface of the removed object. Besides, the flow density of the sputtered target material was experimentally evaluated during its exposure to the ion beam. To do this, we used the radio-frequency ion source (injector) with a beam diameter of 160 mm, which is supposed to be used as an actuating unit on board the SSC designed for transporting the SD objects to the disposal orbit or to the orbits with limited life. When measuring the ion beam accommodation coefficient, the presence of additional force arising on the target due to the flow of sputtered material leaving its surface, and the ion-electron emission process on the target, which could distort the experimental data, were taken into account. To estimate the magnitude of the flows of sputtered target material under the influence of the ion beam, a special experimental design was developed for simulating the presence of a point source of sputtered material. The results obtained in this work will be used for modeling the impact of the ion beam on the surface of real SD objects with complex geometry using the finite element method, for refining the control algorithm of the virtual SSC-SDO mated configuration and for developing proposals on the SSC layout, which should reduce or completely eliminate the negative impact associated with the material sputtering from the SDO surface onto the SSC elements. Successful implementation of the developed method of SDO removal will contribute to improving the safety of space activities for all countries and to the development of the rocket-and-space industry in the Russian Federation, in particular.

Kinetic simulations of low-pressure inductively coupled plasma: an implicit electromagnetic PIC/MCC model with the ADI-FDTD method

Low-pressure inductively coupled plasma (ICP) is promising for space electric propulsion. For the first time, an implicit electromagnetic particle-in-cell Monte Carlo collision model based on the alternating-direction-implicit finite-difference time-domain (ADI-FDTD) method is developed to investigate low-pressure xenon plasma characteristics of a miniature ICP source. The induced simulated electric field is well consistent with that calculated by the finite element method, indicating that this method can provide an accurate estimation of the electromagnetic field. The simulation time step used in the ADI-FDTD method is no longer restricted by the Courant–Friedrichs–Lewy constraints. Compared with the FDTD method, the ADI-FDTD method increases the size of the time step and significantly improves computational efficiency. The method is validated by comparing the simulated and measured electron density and plasma potential profile and reasonable agreement is reached. Therefore, the model is used to investigate the temporal and spatial distribution of plasma properties and the influence of the current amplitude of radio frequency (RF) coil, applied frequency of RF coil and neutral gas pressure on the plasma dynamics in the ionization chamber of a miniature gridded RF ion thruster. To explain the influence of the operating parameters, a concept called ‘the energy relaxation characteristics of electrons in response to the change of electric field’ is proposed and verified. The simulations also find that the oscillation frequency of plasma properties is twice the applied frequency of RF coil. The oscillation characteristics reveal the dynamic energy balance in the ICP. The experiment on the gridded RF ion thruster BHRIT-4 confirms the oscillation by measuring the plasma sheath potential.